CN106857592A - A kind of compound pesticide composition containing polyoxin and quinolinone - Google Patents
A kind of compound pesticide composition containing polyoxin and quinolinone Download PDFInfo
- Publication number
- CN106857592A CN106857592A CN201710195642.5A CN201710195642A CN106857592A CN 106857592 A CN106857592 A CN 106857592A CN 201710195642 A CN201710195642 A CN 201710195642A CN 106857592 A CN106857592 A CN 106857592A
- Authority
- CN
- China
- Prior art keywords
- polyoxin
- quinolinone
- composition containing
- compound pesticide
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of compound pesticide composition containing polyoxin and quinolinone, belong to a kind of free of contamination safe bactericide of high-efficiency broad spectrum low toxicity and low residue of technical field of pesticide, a kind of active ingredient of compound pesticide composition containing polyoxin and copper 8-hydroxyquinolinate of the invention is polyoxin and copper 8-hydroxyquinolinate, and the percentage that polyoxin and copper 8-hydroxyquinolinate account for the compound pesticide composition gross mass is：Polyoxin 1~30%, Bravo 1~60%, remaining is usual auxiliaries and filler.Pesticidal preparations and fruits and vegetables toner field are the composite can be widely applied to, without antagonism, dosage is reduced, agricultural cost is saved.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to a kind of Recompounded pesticide combination containing polyoxin and quinolinone
Thing.
Background technology
The occupation mode of traditional agricultural chemicals, mainly missible oil and pulvis.In the case where past productivity level is not very high,
In order to prevent pest and disease damage, capture agricultural foison, this occupation mode ensures that people's lives serve irreplaceable effect.So
And, with the raising of living standards of the people and scientific and technological level, the quality requirements to agricultural product are also accordingly improved, and international community
Ecological environmental protection and the cry requirement for carrying out sustainable development are also accordingly improved, by contrast, the application of missible oil and pulvis
Drawback is also evident from, and slowly changes to green pesticide form
The invention of agricultural chemicals and use, while bringing tremendous economic interests to the mankind, due to pesticide species and consumption not
Disconnected to increase, residue problem of the agricultural chemicals in food and environment also increasingly causes concern, our searching more low toxicity and low residues
Compound pesticide composition.
Polyoxin, chemical name：Peptide pyrimidine nucleotide antibiotics, be a kind of wide spectrum low toxicity it is efficient, using micro- life
Thing interference cell chitin biosynthesis, the polyoxin complex bactericide with preferable Uptake and translocation effect.
Quinolinone, clamp together the organic copper fungicide of state you, the features such as with efficient, wide spectrum, low toxicity and low-residual, for cause of disease
Inside bacterium, suppress the activity and conduction of the main conduction thing of pathogen, the diaphragm of densification is formed in crop surface, kill in film
Pathogen, for fungi and bacterial disease.
The content of the invention
Goal of the invention：The purpose of the present invention is intended to improve the accuracy of existing compound pesticide composition proportioning, improves
Drug effect, reduces loss and wastes, there is provided a kind of compound pesticide composition containing polyoxin and quinolinone.
Technical scheme：In order to realize foregoing invention purpose, the technical solution adopted in the present invention is：
A kind of compound pesticide composition containing polyoxin and quinolinone, with quinolinone and polyoxin as active ingredient,
The percentage that the polyoxin and quinolinone account for composition gross mass is：
Quinolinone 1~60%；
Polyoxin 1~30%；
Remaining is usual auxiliaries and filler.
The percentage that preferred polyoxin and quinolinone account for composition gross mass is：
Quinolinone 1~50%；
Polyoxin 1~20%；
Remaining is usual auxiliaries and filler.
The percentage that most preferred polyoxin and quinolinone account for composition gross mass is：
Quinolinone 1~50%；
Polyoxin 1~10%；
Remaining is usual auxiliaries and filler.
Usual auxiliaries include disintegrant, binding agent, dispersant, wetting agent, defoamer, antifreezing agent, stabilizer, emulsifying agent and
Deionized water.
Filler includes diatomite, kaolin, ammonium sulfate, soluble starch, sepiolite, white carbon, talcum powder, montmorillonite
Deng.
Wetting agent has anionic and nonionic surface active agent.Anionic surfactant includes alkylsurfuric acid
Salt, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic acid soaps, phosphate etc..Nonionic surface active agent includes polyoxy
Vinyl alkyl phenolic ether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer etc..
Dispersant is that anion or non-ionic surface are lived including naphthalene sulfonate, polycarboxylate, lignin, aliphatic alcohol polyether etc.
Property agent.
The composition pesticide that the present invention is provided is adapted to be processed into any formulation for agriculturally allowing to use, and it is more preferably
Formulation has wettable powder, water dispersible granules, suspending agent, suspension emulsion and aqueous emulsion.
In preparation active ingredient polyoxin and quinolinone quality sum account for the gross mass of composition pesticide 5%~
80%.
When composition pesticide of the present invention is water dispersible granules, copper 8-hydroxyquinolinate 10%~60%, polyoxin 5~30%, wetting
Agent 1~5%, dispersant 1~15%, filler is that soluble starch or ammonium sulfate or kaolin or diatomite complement to 100%.Will
Dry pulverization process, granulation, drying, screening preparation system obtain final product copper 8-hydroxyquinolinate polyoxin water dispersible granules to above-mentioned formula in proportion.
When composition pesticide of the present invention is suspending agent, copper 8-hydroxyquinolinate 20~50%, polyoxin 5~20%, wetting dispersing agent 2
~5%, wetting agent 1~6%, propane diols 4~8%, xanthans 0.05~0.4%, mould inhibitor 0.1~0.5%, defoamer 0.1
~0.5%, water complements to 100%.
Above-mentioned formula material is disperseed in advance in proportion, then is imported grinding in sand mill, be eventually adding xanthans, passed through
Allocated after high shear mixing and copper 8-hydroxyquinolinate polyoxin suspending agent is obtained.
When composition pesticide of the present invention is wettable powder, copper 8-hydroxyquinolinate 20~50%, polyoxin 2~10%, wetting agent 1
~3%, dispersant 1~5%, white carbon 3~8%, the filler such as kaolin or precipitated calcium carbonate complements to 100%.Match somebody with somebody above-mentioned
Enter in blender after square coarse crushing in proportion and be well mixed, then i.e. prepared copper 8-hydroxyquinolinate polyoxin is wettable after air-flow crushing
Property pulvis.
The auxiliary agent used in composition pesticide of the present invention includes solvent, dispersant, stabilizer, emulsifying agent, antifreezing agent, thickening
Agent etc. and other be beneficial to the known substance that drug effect is stablized and played to active ingredient in the formulation, be all commonly use in pesticidal preparations or
The various composition for using is allowed, is not particularly limited, specific composition and consumption are determined according to recipe requirements by simple experiment.
Beneficial effect：Compared with prior art, its advantage is the present invention：
1st, more a kind of compound pesticide composition containing polyoxin and quinolinone belongs to the broad spectrum type bactericide of low toxicity, is efficient
The safety-type agricultural chemicals of low toxicity non-environmental-pollution.
2nd, a kind of compound pesticide composition containing polyoxin and quinolinone, R50Between 0.5~1.5, show as substantially
Addition, without antagonism, reduce dosage, save agricultural cost.
3rd, a kind of compound pesticide composition containing polyoxin and quinolinone has excellent adherence, strengthens composition pesticide
It is ageing, reduce the waste caused by the factor of rain drop erosion and wind.
4th, a kind of compound pesticide composition containing polyoxin and quinolinone have significantly delay resistance to the action of a drug feature.
5th, a kind of compound pesticide composition containing polyoxin and quinolinone has more extensive prevention and treatment range and and fits
Use scope.
6th, a kind of compound pesticide composition containing polyoxin and quinolinone has broader preparation type selection model
Enclose.
7th, a kind of compound pesticide composition proportioning containing polyoxin and quinolinone more precisely, is reduced because of error in dipping
Medicine waste, environmental pollution and the crops residue problem for causing.
8th, a kind of compound pesticide composition containing polyoxin and quinolinone more suits the big life of agricultural modernization industrialization
The reality of product.
9th, a kind of compound pesticide composition containing polyoxin and quinolinone can effectively delay the resistance to the action of a drug of bacterial fungus.
10th, a kind of compound pesticide composition metabolic rate containing polyoxin and quinolinone is faster.
11st, a kind of compound pesticide composition containing polyoxin and quinolinone also is used as being that industrial fungicide and fruits and vegetables are protected
Fresh dose.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1
The polyoxin water dispersible granules of 50% copper 8-hydroxyquinolinate+10%.
Copper 8-hydroxyquinolinate 50%, polyoxin 10%, wetting agent lauryl sodium sulfate 1~5%, dispersant polycarboxylate 1~
10%, soluble starch 10~20%, kaolin or diatomite complement to 100%.By above-mentioned formula in proportion dry pulverization process, make
Grain, dry, screening preparation system obtain final product 60% copper 8-hydroxyquinolinate polyoxin water dispersible granules.
Embodiment 2
The polyoxin suspending agent of 30% copper 8-hydroxyquinolinate+10%.
Copper 8-hydroxyquinolinate 30%, polyoxin 10%, anion and non-ionic complex TERSPERSE 4,894 2~5%, naphthalene
Sulfonate and formaldehyde condensation product 1~6%, propane diols 4~8%, xanthans 0.05~0.4%, mould inhibitor 0.1~0.5%, defoamer
0.1~0.5%, water complements to 100%.
Above-mentioned formula material is disperseed in advance in proportion, then is imported grinding in sand mill, be eventually adding xanthans, passed through
Allocated after high shear mixing and 40% copper 8-hydroxyquinolinate polyoxin suspending agent is obtained.
Embodiment 3
The Wettable polyoxin powder of 45% copper 8-hydroxyquinolinate+5%.
Copper 8-hydroxyquinolinate 45%, polyoxin 5%, lauryl sodium sulfate 1~3%, naphthalenesulfonate formaldehyde condensation compound 1~5%,
White carbon 3~8%, kaolin complements to 100%.
It is well mixed entering in blender after above-mentioned formula in proportion coarse crushing, then 50% is obtained after air-flow crushing
Copper 8-hydroxyquinolinate Wettable polyoxin powder.
Embodiment 4
50% polyoxin quinolinone wettable powder prevents and treats pear tree black spot field control effectiveness test
Test objective
By field test, preventing and treating of the clear and definite 50% polyoxin quinolinone wettable powder to pear tree black spot is imitated
Really, effective concentration, suitably use technology and security, for product registration foundation is provided.
Experimental condition
The selection of 2.1 subjects, works and kind
Subjects：Black spot, Alternaria alternate (Fr.) Keissler.
Trial crops and kind：Pear tree, golden pear.
2.2 arable farmings and environmental condition
Experiment garden 2.5 × 3m2 of seeding row spacing, age of tree life in 12 years, fruit bagging, black spot over the years occurs serious and uniform.Examination
Pear tree breeding time is the young sprout pumping phase during testing.The cultivation condition (soil types, fertility, farming etc.) one of all experimental plots
Cause, meet the agricultural practice of local science.
3 experimental designs and arrangement
3.1 medicaments
3.1.1 test medicine
50% polyoxin quinolinone wettable powder, Sinon Chemical (China) Co., Ltd. provides.
3.1.2 comparison medicament
10% Wettable polyoxin powder (Pola peace), Japanese Kaken Pharmaceufical Co., Ltd.'s product.
33.5% quinolinone suspending agent (must be green), the positive chemical industry share-holding system Co., Ltd product in Zhejiang sea.
3.1.3 dosing is numbered with treatment
It is as shown in table 1 for the design of medicine reagent test
The reagent agent experimental design of table 1
Table 1 is for the design of medicine reagent test
3.2 cell arrangements
The distribution of cell random alignment is as shown in table 2
Cell random alignment distribution map (north ← ↑ east)
The cell random alignment distribution table of table 2
3.2.2 plot area and repetition
Plot area：4 plants of every cell is into age fruit tree, if protecting row.
Number of repetition：4 repetitions.
3.3 application methods
3.3.1 application method
Spraying is watered, being filled up again after first being dissolved with a small amount of water needs water；Pears positive and negative must be made equal during spraying
Even medicine, untill dripping.
3.2.2 Agent spraying machine
Spraying equipment uses Su Nong 3WH-36 type high pressure power driven sprayers；Injection diameter 1.0mm, the bar of operating pressure 3.0,
Single hole flow 2.5L/min.
3.3.3 spraying time and number of times
Spring tip premorbid (May 30) day dispenser first, is spaced and once, altogether sprays within 10 days or so 7 times later.Specific dispenser day
Phase is on May 30th, 2011, June 11, June 24, July 6, July 21, August 2 days, August 11 days.
3.3.4 capacity is used
Every mu of reality uses amount of liquid medicine 300Kg.
3.3.5 the medicament data of other pest and disease damages is prevented and treated
During experiment, each cell applies 10% imidacloprid wettable powder 2000 times of preventing and treating Schizaphis piricolas, 2% in May 30
3000 times of preventing and treating pear suckers of abamectin emulsifiable concentrate, June 24, July 20 mix 2% abamectin emulsifiable concentrate, 3000 times of preventing and treating pear woods
Lice, June 24, July 20 mix 2% abamectin emulsifiable concentrate, 3000 times of preventing and treating pear suckers.
4 investigation, record and measuring method
4.1 meteorological and soil informations
4.1.1 meteorological data
The same day of dispenser first is fine, gentle breeze, 23.3 DEG C of temperature on average；(30 days~August of May 30 days) co-falling rain 31 during experiment
Secondary, gross precipitation is 426.4mm；Daily mean temperature, the highest temperature, lowest temperature excursion are successively 16.6 DEG C~28.2
DEG C, between 20 DEG C~34.2 DEG C, 12.5 DEG C~24.3 DEG C (refer to meteorological data table).
4.1.2 soil information
Experiment garden be level land, soil, the content of organic matter 1% or so, there are a small amount of weeds on ground.
4.2 investigation methods, time and number of times
4.2.1 control time and number of times
Morbidity radix (field has no symptom) is investigated before medicine, because 50% polyoxin quinolinone wettable powder dispenser
When field medication repeatedly, the investigation of tip phase in spring can not reflect its drug effect, therefore can only (the August 30 days) investigation 16 days after dispenser terminates
Drug effect.
4.2.2 investigation method
Investigate 2 plants per cell, every plant by East, West, South, North, in 5 directions fix 5 branches, the hair of the whole blades of investigation
State of an illness condition, records the sick numbers of blade at different levels.
Attached blade grade scale：
0 grade：Without pinta；
1 grade：Pinta area accounts for less than the 10% of whole leaf area；
3 grades：Pinta area accounts for the 11~25% of whole leaf area；
5 grades：Pinta area accounts for the 26~40% of whole leaf area；
7 grades：Pinta area accounts for the 41~65% of whole leaf area；
9 grades：Pinta area accounts for more than the 66% of whole leaf area；
4.2.3 drug effect computational methods
A, disease refer to=Σ { [the sick numbers of sheets at different levels × relative value of series]/investigation total number of sheets × 9 } × 100%
B, prevention effect (%)=[control disease refers to-process that disease refers to]/control disease refer to × 100%
4.3 directly affect to plant
On for trying Pear Trees with Various Cultivars without influence.
The yield and quality of 4.4 products
No requirement (NR).
4.5 influence on other biological
4.5.1 to the influence of other pest and disease damages
The non-targeted biology that experiment garden occurs is Chrysopa, and 50% polyoxin quinolinone wettable powder grows hair to it
Educate without influence.
5 results and analysis
As shown in table 2, it is that 50% polyoxin copper 8-hydroxyquinolinate suspending agent preventing and treating pear tree black spot result of the test collects.
The polyoxin copper 8-hydroxyquinolinate suspending agent of table 2 50% prevents and treats pear tree black spot result of the test
Note：Data are and pat mean everywhere in table
Significance test uses " DMRT " method.
Evaluating drug：The autumn growth phase is investigated, 50% 1200 times, 1000 times, 800 times of polyoxin quinolinone wettable powder
Treatment preventive effect is respectively 72.77%, 77.07%, 85.68%, and 1000 times and 1200 are significantly better than in 800 times of levels of preventive effect 1%
Two treatment again, preventive effect is without significant difference between 1000 times, 1200 times of two treatment；The Wettable polyoxin powder of comparison medicament 10%
1200 times of preventive effects are 76.53%, and 800 times of test medicine is substantially less than in 1% level, and remaining is processed without significance difference with test medicine
It is different；33.5% 1000 times of quinolinone suspending agent preventive effect 70.51%, is substantially less than 800 times of reagent, in 5% level in 1% level
Substantially less than 1000 times of test medicine, with 1200 times of no significant differences of test medicine.Above-mentioned result of the test shows, anti-mildew more than 50%
Prevention effect and 10% Wettable polyoxin powder (Pola peace) phase of the plain quinolinone wettable powder to pear tree very pinta
When better than the 33.5% quinolinone suspending agent (must be green) that existing market is sold.During experiment, test medicine and comparison medicament are to pears
Tree young sprout safety, without key, because of fruit bagging, fails security of the observation to young fruit.
As shown in table 3, it is 50% polyoxin quinolinone wettable powder preventing and treating pear tree black spot experiment initial data
Statistical form.
The polyoxin copper 8-hydroxyquinolinate wettable powder of table 3 50% preventing and treating pear tree black spot experiment initial data statistical form
The above is only the preferred embodiment of the present invention, it should be pointed out that：For the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of compound pesticide composition containing polyoxin and quinolinone, it is characterised in that：The composition pesticide effectively into
It is divided into polyoxin and quinolinone, the percentage that the polyoxin and quinolinone account for composition gross mass is：
Polyoxin 1~30%；
Quinolinone 1~60%；
Remaining is usual auxiliaries and filler.
2. a kind of Recompounded pesticide combination containing polyoxin and quinolinone according to claim 1, it is characterised in that：It is many
The percentage that the quality sum of antimycin and quinolinone accounts for composition pesticide gross mass is 5%~80%.
3. a kind of compound pesticide composition containing polyoxin and quinolinone according to claim 1, it is characterised in that：
Usual auxiliaries are disintegrant, binding agent, dispersant, wetting agent, defoamer, antifreezing agent, stabilizer, emulsifying agent and deionized water.
4. a kind of compound pesticide composition containing polyoxin and quinolinone according to claim 1, it is characterised in that：
The composition pesticide can be processed into any formulation for agriculturally allowing to use, and more preferably formulation has wettable powder, moisture
Shot agent, suspending agent, suspension emulsion and aqueous emulsion.
5. a kind of compound pesticide composition containing polyoxin and quinolinone according to claim 1, it is characterised in that：
Described filler is any filler for agriculturally allowing to use, and more preferably filler has diatomite, kaolin, ammonium sulfate, solubility
Starch, sepiolite, white carbon, talcum powder, montmorillonite.
6. a kind of compound pesticide composition containing polyoxin and quinolinone according to claim 1, it is characterised in that：
The percentage that the polyoxin and quinolinone account for composition gross mass is：
Polyoxin 1~20%；
Quinolinone 1~50%；
Remaining is usual auxiliaries and filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710195642.5A CN106857592A (en) | 2017-03-29 | 2017-03-29 | A kind of compound pesticide composition containing polyoxin and quinolinone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710195642.5A CN106857592A (en) | 2017-03-29 | 2017-03-29 | A kind of compound pesticide composition containing polyoxin and quinolinone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106857592A true CN106857592A (en) | 2017-06-20 |
Family
ID=59159505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710195642.5A Pending CN106857592A (en) | 2017-03-29 | 2017-03-29 | A kind of compound pesticide composition containing polyoxin and quinolinone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106857592A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104542653A (en) * | 2014-12-29 | 2015-04-29 | 海利尔药业集团股份有限公司 | Antibacterial composition containing polyoxin and oxine-copper |
-
2017
- 2017-03-29 CN CN201710195642.5A patent/CN106857592A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104542653A (en) * | 2014-12-29 | 2015-04-29 | 海利尔药业集团股份有限公司 | Antibacterial composition containing polyoxin and oxine-copper |
Non-Patent Citations (1)
| Title |
|---|
| 马安民等主编: "《园林植物杀菌剂应用技术》", 31 October 2016, 河南科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103053610A (en) | Glufosinate-aryloxyphenoxypropionic acid herbicide weeding composition | |
| CN101642117A (en) | Pesticidal composition with synergistic effect | |
| CN104488949A (en) | Dinotefuran-containing insecticidal combination | |
| CN103271073A (en) | Insecticidal composition containing epoxy worm moiety and buprofezin | |
| CN100393212C (en) | Sterilizing and insecticidal composition | |
| CN102696601A (en) | Insecticidal composition containing flubendiamide | |
| CN102919251A (en) | Bactericidal composition containing benthiavalicarb isopropyl and captan | |
| CN104982451A (en) | Bactericidal composition containing pyribencarb | |
| CN103190420B (en) | Propiconazole-containing bactericidal composition | |
| CN102228056A (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN104996450A (en) | Sterilization composite contained with pyribencarb | |
| CN104521980A (en) | Pymetrozine-containing insecticidal composition | |
| CN101473828B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN104770374B (en) | A kind of bactericidal composition | |
| CN114617127A (en) | Pesticide sterilization composition and application thereof | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN106857592A (en) | A kind of compound pesticide composition containing polyoxin and quinolinone | |
| CN102239875A (en) | Insecticidal composition containing 1-(3-fluoro-4-chlorphenyl)-2-methylthioethanone-O-(2-hydroxymethyl-3-methyl)aether and partial nicotine compounds | |
| CN102771488B (en) | Bactericidal composition containing isothiazolone | |
| CN101697722A (en) | Famoxadone-containing bactericidal composition | |
| CN102293215B (en) | Bactericidal composition containing coumoxystrobin and prochloraz | |
| CN101496518A (en) | Eugenol and myclobutanil compositional bactericidal agent for preventing and treating anthracnose of crop | |
| CN105052997A (en) | Pesticide composition containing Dufulin and antibiotic bactericide, and bactericide thereof | |
| CN106172453B (en) | A kind of bactericidal composition and its application | |
| CN115281199B (en) | Insecticidal composition for preventing and controlling spinach plutella xylostella |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |