CN106833113A - Ink suitable for glass bending shaping and the application mobile phone - Google Patents
Ink suitable for glass bending shaping and the application mobile phone Download PDFInfo
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- CN106833113A CN106833113A CN201710043952.5A CN201710043952A CN106833113A CN 106833113 A CN106833113 A CN 106833113A CN 201710043952 A CN201710043952 A CN 201710043952A CN 106833113 A CN106833113 A CN 106833113A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention discloses a kind of ink suitable for glass bending shaping, in parts by weight, the ink includes polyvinyl alcohol, the polyvinyl butyral resin of 3~10 parts of molecular weight 30000~45000,8~17 parts of waterborne organic silicon resin, 10~25 parts of water, 10~25 parts of silica, 15~30 parts of zirconium oxide, 1~4.5 part of cosolvent and 0.01~0.5 part of the auxiliary agent that 3~10 parts of molecular weight is 25000~250000.Many high polymers relatively low using molecular weight in above-mentioned ink, therefore ink printability is good, good water solubility.Silica, zirconium oxide and waterborne organic silicon resin form the material for being similar to ceramics so that ink can high temperature resistant as film forming matter.Therefore above-mentioned ink can be pre-printed on glass, in glass press bending process together with glass sinter molding, so as to reduce the complexity of decorative ink process, and reduce the energy consumption of whole process.
Description
Technical field
The present invention relates to ink area, especially, it is related to a kind of ink suitable for glass bending shaping.Additionally, this hair
It is bright to further relate to a kind of application including the ink that is molded suitable for glass bending mobile phone.
Background technology
With the development of smart mobile phone and closing on for 5G epoch, the front and rear covers of mobile phone are applicable 3D glass can increasingly turn into industry
Main flow.In order to solve the problems, such as the coating of 3D glass frame decorative inks, two kinds of applicable at present techniques of producer are：1. passing through will be general
Logical PET ink is printed on the softer PET materials for carrying UV glue, after solidification, PET is transferred into 3D by special instrument
On glass, then UV solidifications.2., by the full leaf fat ink of spraying, the pattern of needs is carved out using the technique of laser carving then.
It is recessed that technique 1 can only do two parallel edges, it is impossible to meets the recessed glass in needs four sides, and PET film can only be with once, and high cost is imitated
Rate is low, wastes than more serious.Technique 2 is low for large area efficiency, high to equipment requirement, and laser carving produces many toxic gases, shadow
Sound employee is healthy, and laser carving easily damages glass, causes to scrap.
The content of the invention
The invention provides a kind of application suitable for the ink of glass bending shaping mobile phone, to solve existing 3D glass
The technical problem of glass frame device complex process.
The technical solution adopted by the present invention is as follows：
One aspect of the present invention disclose it is a kind of suitable for glass bending shaping ink, in parts by weight, ink include 3~
10 parts of molecular weight is the polyvinyl alcohol contracting of 25000~250000 polyvinyl alcohol, 3~10 parts of molecular weight 30000~45000
Butyraldehyde, 8~17 parts of waterborne organic silicon resin, 10~25 parts of water, 10~25 parts of silica, 15~30 parts of oxidation
Zirconium, 1~4.5 part of cosolvent and 0.01~0.5 part of auxiliary agent.
Further, ink includes dividing for the polyvinyl alcohol, 5~10 parts that 5~10 parts of molecular weight is 30000~150000
Polyvinyl butyral resin, 10~17 parts of waterborne organic silicon resin, 15~25 parts of water, 19~25 of son amount 30000~40000
Part silica, 20~30 parts of zirconium oxide, 2.5~4.5 parts of cosolvent and 0.2~0.5 part of auxiliary agent.
Further, ink includes polyvinyl alcohol, 5~10 parts of the molecule that 10 parts of molecular weight is 30000~150000
Amount 30000~40000 polyvinyl butyral resin, 10~17 parts of waterborne organic silicon resin, 15~18 parts of water, 19~22 parts
Silica, 24~28 parts of zirconium oxide, 4~4.5 parts of cosolvent and 0.4~0.5 part of auxiliary agent.
Further, silica is nano silicon, and zirconium oxide is nano zircite.
Further, waterborne organic silicon resin includes waterborne organic silicon epoxy resin, waterborne organic silicon polyester resin, aqueous
Silicone alkyd or waterborne organic silicon acrylic resin.
Further, cosolvent is methyl alcohol, ethanol, propyl alcohol, ethylene glycol, glycerine or DAA, it is preferable that cosolvent
It is ethanol, glycerine or DAA.
Further, auxiliary agent includes levelling agent and defoamer.
Further, inorganic pigment is also included in ink, inorganic pigment includes that iron oxide red, iron oxide black, titanium dioxide, cobalt blue and vanadium are yellow
In one or more.
Another aspect of the present invention discloses the above-mentioned application suitable for the ink of glass bending shaping mobile phone.
The invention has the advantages that：The above-mentioned ink suitable for glass bending shaping in ink to use molecule more
The relatively low high polymer of amount, therefore ink printability is good, good water solubility, obtains suitable printing effect.And waterborne organic silicon
Resin can also provide suitable medium for silica and zirconium oxide, silica and zirconium oxide is sintered in glass well
On.Silica, zirconium oxide and waterborne organic silicon resin are used as final film forming matter so that ink can high temperature resistant.Therefore it is above-mentioned
Ink can be pre-printed on flat glass, and the heat energy in being bent using glass in glass press bending process is sintered together with glass
Shaping.Ink adhesive force on glass is 5B, and hardness is suitable with glass, therefore need not subsequently republish ink solidification shaping.Profit
Adoring 3D glass frame with above-mentioned ink filling can reduce the complexity of decorative ink process, and reduce the energy of whole process
Consumption.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages.
The present invention is further detailed explanation below.
Specific embodiment
It is described in detail below in conjunction with to embodiments of the invention, but the present invention can be defined by the claims and cover
The multitude of different ways of lid is implemented.
The preferred embodiments of the present invention provide a kind of ink suitable for glass bending shaping, in parts by weight, ink
Including polyvinyl alcohol that 3~10 parts of molecular weight are 25000~250000,3~10 parts of molecular weight 30000~45000 it is poly-
Vinyl butyral, 8~17 parts of waterborne organic silicon resin, 10~25 parts of water, 10~25 parts of silica, 15~30 parts
Zirconium oxide, 1~4.5 part of cosolvent and 0.01~0.5 part of auxiliary agent.
Polyvinyl alcohol is PVA resins, and polyvinyl butyral resin is PVB resin.During high-temperature molding, polyvinyl alcohol
Decomposed with polyvinyl butyral resin and volatilized.When polyvinyl alcohol and excessive polyvinyl butyral resin molecular weight, during high-temperature molding, gather
Vinyl alcohol and polyvinyl butyral resin decomposition temperature can be higher, cause volatilization incomplete, in partly remaining in ink so that oil
Occur abnormal color spot, the outward appearance after influence ink shaping on ink.And work as polyvinyl alcohol and polyvinyl butyral resin molecular weight mistake
Hour, bad to the powder body material parcel in ink, obtained ink oiliness is poor, and mobility is bad, and printability is poor, printing
Difficult levelling, is also easy to produce the surface defects such as pin hole, orange peel afterwards, diaphanous spot easily occurs by high temperature sintering, influences the OD values of ink,
Even scrap.Therefore, it is 25000~250000 polyvinyl alcohol and molecular weight 30000~45000 molecular weight to be selected in ink
Polyvinyl butyral resin.
The main resin of ink is then waterborne organic silicon resin, not only provides suitable printability, and in glass high temperature
Suitable medium can also be provided for nano silicon and nano zircite in press bending process, make silica and zirconium oxide very
Good is sintered on glass.During waterborne organic silicon resin high-temperature molding, film can be formed, be similar to ceramic structure.Silica and oxygen
Change zirconium and suitable colourity and glazing effect are provided in sintering process.Nano silicon, nano zircite and waterborne organic silicon
Resin is used as film forming matter so that ink can more than 1000 DEG C of high temperature resistant high temperature.
Comprising the polyethylene that the molecular weight that parts by weight are 3~10 parts is 25000-250000 in the ink that the present invention is provided
Alcohol, the polyvinyl butyral resin of 3~8 parts of molecular weight 30000-45000,8~15 parts of waterborne organic silicon resin, using its as
Film forming matter during surface drying, there is provided good printability.This proportioning is it can be found that in ink of the invention use molecular weight more
Relatively low high polymer, the common feature of this kind of material is that printability is good, and good water solubility, high temperature easily decomposes volatilization, is closed
Suitable printing effect.As pectin/polyvinyl alcohol, polyvinyl butyral resin, the content of waterborne organic silicon resin are too high, bent in glass
In the time of shaping, have little time to be completely decomposed of volatile, will remain in the ink of final molding, abnormal color spot occur.Such as
Fruit vinyl alcohol, polyvinyl butyral resin, the content of waterborne organic silicon resin are too low, during Printing ink producing, to the bag of powder
Wrap up in not enough, obtained ink oiliness is poor, and mobility is bad, and printability is poor, difficult levelling, is also easy to produce pin hole, orange peel after printing
Etc. surface defect, easily occur diaphanous spot by high temperature sintering, influence the OD values of ink, or even scrap.Silica and oxidation
Very little, not enough, easy printing opacity, OD values are inadequate for the richness of ink after sinter molding for zirconium content.Silica and zirconia content are too
Height, obtained ink oiliness is poor, and mobility is bad, and printability is poor, and difficult levelling, is also easy to produce the tables such as pin hole, orange peel after printing
, easily there is diaphanous spot by high temperature sintering in planar defect, influences the OD values of ink, or even scraps.The temperature of glass bending shaping
Up to 700~900 DEG C, general ink can not be printed on glass due to non-refractory, be sintered into glass
Type.Ink of the present invention has resistant to elevated temperatures property and ink adhesive force on glass is 5B, and hardness is suitable with glass, thus
Can be pre-printed on flat glass, heat energy and glass one in being bent using glass during glass bends into 3D shapes
Play sinter molding.
The invention has the advantages that：The above-mentioned ink suitable for glass bending shaping in ink to use molecule more
The relatively low high polymer of amount, therefore ink printability is good, good water solubility, obtains suitable printing effect.And waterborne organic silicon
Resin can also provide suitable medium for silica and zirconium oxide, silica and zirconium oxide is sintered in glass well
On.Silica, zirconium oxide and waterborne organic silicon resin are used as final film forming matter so that ink can high temperature resistant.Therefore it is above-mentioned
Ink can be pre-printed on flat glass, and the heat energy in being bent using glass in glass press bending process is sintered together with glass
Shaping.Ink adhesive force on glass is 5B, and hardness is suitable with glass, therefore need not subsequently republish ink solidification shaping.Profit
Adoring 3D glass frame with above-mentioned ink filling can reduce the complexity of decorative ink process, and reduce the energy of whole process
Consumption.
Alternatively, ink includes polyvinyl alcohol, 5~10 parts of the molecule that 5~10 parts of molecular weight is 30000~150000
Amount 30000~40000 polyvinyl butyral resin, 10~17 parts of waterborne organic silicon resin, 15~25 parts of water, 19~25 parts
Silica, 20~30 parts of zirconium oxide, 2.5~4.5 parts of cosolvent and 0.2~0.5 part of auxiliary agent.
Alternatively, ink includes polyvinyl alcohol, 5~10 parts of the molecular weight that 10 parts of molecular weight is 30000~150000
30000~40000 polyvinyl butyral resin, 10~17 parts of waterborne organic silicon resin, 15~15.6 parts of water, 19~22 parts
Silica, 24~28 parts of zirconium oxide, 4~4.5 parts of cosolvent and 0.4~0.5 part of auxiliary agent.
Alternatively, silica is nano silicon, and zirconium oxide is nano zircite.From nano silicon and receiving
Rice zirconium oxide causes that ink is more fine and smooth, and form and aspect are more preferable.
Alternatively, waterborne organic silicon resin includes waterborne organic silicon epoxy resin, waterborne organic silicon polyester resin, aqueous has
Machine silanol acid resin or waterborne organic silicon acrylic resin.
Alternatively, cosolvent is methyl alcohol, ethanol, propyl alcohol, ethylene glycol, glycerine or DAA, it is preferable that cosolvent is
Ethanol, glycerine or DAA.
Alternatively, auxiliary agent includes levelling agent and defoamer.The ratio of levelling agent and defoamer can be according to general 1:1~2
Ratio is added.
Alternatively, inorganic pigment is also included in ink, inorganic pigment is included in iron oxide red, iron oxide black, titanium dioxide, cobalt blue and vanadium Huang
One or more.Addition pigment can make ink that different colors are presented.The addition of pigment can be drunk according to required shade
Feelings are added.
Another aspect of the present invention discloses the above-mentioned application suitable for the ink of glass bending shaping mobile phone.
Embodiment 1
Each Composition Weight Parts of ink are listed in Table 1 below in embodiment 1.
Table 1
| Ink | Parts by weight |
| Pure water | 25 |
| Ethanol | 2.7 |
| PVA resins | 10 |
| PVB resin | 5 |
| Waterborne organic silicon alkyd resin | 14 |
| Aqueous levelling agent | 0.2 |
| Aqueous defoamer | 0.1 |
| Nano silicon | 13 |
| Nano zircite | 30 |
Rotating speed is 500~1000 revs/min, and the material in table 1 is sequentially added while stirring, after being well mixed, then is used
2000~3000 revs/min of rotating speed disperses 15~30 minutes.
With 200~400 mesh nets, equably be printed on the plate glass handled well ink by 65~80 ° of frictioning,
80 DEG C are toasted 10~15 minutes, then calcine shaping with glass in 700~900 DEG C of glass bending furnace.
Embodiment 2
Each Composition Weight Parts of ink are listed in Table 2 below in embodiment 2.
Table 2
Rotating speed is 500~1000 revs/min, and the material in table 2 is sequentially added while stirring, after being well mixed, then is used
2000~3000 revs/min of rotating speed disperses 15~30 minutes.
With 200~400 mesh nets, equably be printed on the plate glass handled well ink by 65~80 ° of frictioning,
80 DEG C are toasted 10~15 minutes, then calcine shaping with glass in 700~900 DEG C of glass bending furnace.
Embodiment 3
Each Composition Weight Parts of ink are listed in Table 3 below in embodiment 3.
Table 3
| Ink | Parts by weight |
| Pure water | 20.6 |
| Ethanol | 4 |
| PVA resins | 10 |
| PVB resin | 5 |
| Waterborne organic silicon acrylic resin | 17 |
| Aqueous levelling agent | 0.2 |
| Aqueous defoamer | 0.2 |
| Nano silicon | 15 |
| Nano zircite | 28 |
Rotating speed is 500~1000 revs/min, and the material in table 3 is sequentially added while stirring, after being well mixed, then is used
2000~3000 revs/min of rotating speed disperses 15~30 minutes.
With 200~400 mesh nets, equably be printed on the plate glass handled well ink by 65~80 ° of frictioning,
80 DEG C are toasted 10~15 minutes, then calcine shaping with glass in 700~900 DEG C of glass bending furnace.
Embodiment 4
Each Composition Weight Parts of ink are listed in Table 4 below in embodiment 4.
Table 4
Rotating speed is 500~1000 revs/min, and the material in table 4 is sequentially added while stirring, after being well mixed, then is used
2000~3000 revs/min of rotating speed disperses 15~30 minutes.
With 200~400 mesh nets, equably be printed on the plate glass handled well ink by 65~80 ° of frictioning,
80 DEG C are toasted 10~15 minutes, then calcine shaping with glass in 700~900 DEG C of glass bending furnace.
Comparative example 1
Each Composition Weight Parts of ink are listed in table 5 and table 6 in comparative example.
Table 5
| Ink host component | Parts by weight |
| Bisphenol A epoxide resin | 20 |
| Novolac epoxy resin | 15 |
| Isophorone | 15 |
| Dispersant | 1.5 |
| Levelling agent | 0.3 |
| Defoamer | 0.2 |
| Aerosil | 3 |
| Titanium dioxide | 35 |
Rotating speed is 800~1500 revs/min, and the material in table 5 is sequentially added while stirring, after being well mixed, then is used
2500~3500 revs/min of rotating speed disperses 25~35 minutes.Fineness is ground on three-roller again for less than 5 microns.
Table 6
| Curing agent | Parts by weight |
| 2-methylimidazole | 8 |
| Isophorone | 2 |
Dispersing and dissolving is complete.
Host and curing agent are well mixed according to 9/1 ratio, 3% isophorone adjustment viscosity is added.Pass through
Cross the 3D glass pre-treatments of hot bending：Spraying ink, 180 DEG C solidify 30~40 minutes, after cooling, repeat ink of spray, Gu
Change, after cooling, laser carving.
Comparative example 2
Each Composition Weight Parts of ink are listed in table 7 and table 8 in comparative example.
Table 7
| Ink host component | Parts by weight |
| Hydroxylated acrylic resin | 30 |
| Polyester resin | 25 |
| Isophorone | 17 |
| Dispersant | 1.5 |
| Levelling agent | 0.3 |
| Defoamer | 0.2 |
| Aerosil | 1 |
| Carbon black | 15 |
Rotating speed is 800~1500 revs/min, and the material in table 5 is sequentially added while stirring, after being well mixed, then is used
2500~3500 revs/min of rotating speed disperses 25~35 minutes.Fineness is ground on three-roller again for less than 5 microns.
Table 8
| Curing agent | Parts by weight |
| Toluene di-isocyanate(TDI) | 10 |
Host and curing agent are well mixed according to 9/1 ratio, 3% isophorone adjustment viscosity is added.Pass through
Cross the recessed 3D glass pre-treatments in curved both sides：Ink is printed on special PET film, 120 DEG C solidify 30~40 minutes, cooling
Afterwards, PET film hot pressing is solidified on glass by special roller.
Embodiment 1~4 and comparative example 1~2 prepare ink performance test result and are listed in Table 9 below.
Comparative example is the basic with when ink application method of the conventional 3D glass inks of in the market, and according to national standard
Test and obtain that the results are shown in Table 9.
The embodiment 1~4 of table 9 and comparative example 1~2 prepare ink performance test result
From table 9, the ink combination property prepared in embodiment 3 and 4 is optimal, with acquired results phase in comparative example
Than the ink properties that the present invention is prepared are more excellent.
Pencil hardness test standard is with reference to GB/T6739-2006
Adhesive force testing standard is with reference to GB/T6739-2006
Water boils testing standard with reference to GB/T1733 (second method)
QUV testing standards are with reference to GB/T23987-2009
Resistance to cosmetics testing standard is with reference to GB/T1766
Hot and humid testing standard is with reference to GB/1740
Acid proof test standard is with reference to GB1785-79
Solvent resistance test standard is with reference to GB/T1733 (first method)
Alkaline-resisting testing standard is with reference to GB1763-79
Salt spray resistance testing standard is with reference to GB1771-79
The preferred embodiments of the present invention are the foregoing is only, is not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.It is all within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (9)
1. it is a kind of suitable for glass bending shaping ink, it is characterised in that in parts by weight, the ink include 3~10 parts
Molecular weight be 25000~250000 polyvinyl alcohol, the polyvinyl alcohol contracting fourth of 3~10 parts of molecular weight 30000~45000
Aldehyde, 8~17 parts of waterborne organic silicon resin, 10~25 parts of water, 10~25 parts of silica, 15~30 parts of zirconium oxide, 1
~4.5 parts of cosolvent and 0.01~0.5 part of auxiliary agent.
2. it is according to claim 1 suitable for glass bending shaping ink, it is characterised in that the ink include 5~
10 parts of molecular weight is the polyvinyl alcohol contracting of 30000~150000 polyvinyl alcohol, 5~10 parts of molecular weight 30000~40000
Butyraldehyde, 10~17 parts of waterborne organic silicon resin, 15~25 parts of water, 19~25 parts of silica, 20~30 parts of oxidation
Zirconium, 2.5~4.5 parts of cosolvent and 0.2~0.5 part of auxiliary agent.
3. it is according to claim 2 suitable for glass bending shaping ink, it is characterised in that the ink include 10 parts
Molecular weight be 30000~150000 polyvinyl alcohol, the polyvinyl alcohol contracting fourth of 5~10 parts of molecular weight 30000~40000
Aldehyde, 10~17 parts of waterborne organic silicon resin, 15~18 parts of water, 19~22 parts of silica, 24~28 parts of zirconium oxide,
4~4.5 parts of cosolvent and 0.4~0.5 part of auxiliary agent.
4. the ink suitable for glass bending shaping according to claim 1, it is characterised in that the silica is to receive
Rice silica, the zirconium oxide is nano zircite.
5. according to any one of claims 1 to 3 suitable for glass bending shaping ink, it is characterised in that it is described
Waterborne organic silicon resin include waterborne organic silicon epoxy resin, waterborne organic silicon polyester resin, waterborne organic silicon alkyd resin or
Waterborne organic silicon acrylic resin.
6. according to any one of claims 1 to 3 suitable for glass bending shaping ink, it is characterised in that it is described
Cosolvent is methyl alcohol, ethanol, propyl alcohol, ethylene glycol, glycerine or DAA, it is preferable that the cosolvent is ethanol, glycerine
Or DAA.
7. according to any one of claims 1 to 3 suitable for glass bending shaping ink, it is characterised in that it is described
Auxiliary agent includes levelling agent and defoamer.
8. according to any one of claims 1 to 3 suitable for glass bending shaping ink, it is characterised in that it is described
Also include inorganic pigment in ink, the inorganic pigment includes the one kind or several in iron oxide red, iron oxide black, titanium dioxide, cobalt blue and vanadium Huang
Kind.
9. the application suitable for the ink of glass bending shaping mobile phone any one of a kind of claim 1~8.
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| CN201710043952.5A CN106833113B (en) | 2017-01-19 | 2017-01-19 | Ink suitable for glass hot bending forming and application of ink in mobile phone |
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| CN201710043952.5A CN106833113B (en) | 2017-01-19 | 2017-01-19 | Ink suitable for glass hot bending forming and application of ink in mobile phone |
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| CN106833113B CN106833113B (en) | 2020-03-13 |
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| CN109181415A (en) * | 2018-07-20 | 2019-01-11 | 中材江西电瓷电气有限公司 | A kind of porcelain insulator high temperature resistant two dimensional code material and its preparation method and application |
| CN110157236A (en) * | 2019-05-20 | 2019-08-23 | 深圳市博耀新材料有限公司 | A kind of tasteless environmentally friendly glass ink and preparation method thereof applied to 3D, 4D heat-bending glass |
| CN110218483A (en) * | 2019-07-03 | 2019-09-10 | 东莞市格孚节能科技有限公司 | A kind of aqueous, environmental protective insulation deep draw ink and preparation method thereof |
| CN110305529A (en) * | 2019-07-29 | 2019-10-08 | 佛山市高明绿色德化工有限公司 | A kind of high temperature resistant ink for devitrified glass and preparation method thereof, application method |
| CN112409844A (en) * | 2020-07-14 | 2021-02-26 | 湖南松井新材料股份有限公司 | Water-based ink for realizing 3D glass matte effect and preparation method and application thereof |
| CN112479599A (en) * | 2020-12-22 | 2021-03-12 | 湖州安盛医疗器械有限公司 | Preparation method of frosted glass without fluorine |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109181415A (en) * | 2018-07-20 | 2019-01-11 | 中材江西电瓷电气有限公司 | A kind of porcelain insulator high temperature resistant two dimensional code material and its preparation method and application |
| CN110157236A (en) * | 2019-05-20 | 2019-08-23 | 深圳市博耀新材料有限公司 | A kind of tasteless environmentally friendly glass ink and preparation method thereof applied to 3D, 4D heat-bending glass |
| CN110218483A (en) * | 2019-07-03 | 2019-09-10 | 东莞市格孚节能科技有限公司 | A kind of aqueous, environmental protective insulation deep draw ink and preparation method thereof |
| CN110305529A (en) * | 2019-07-29 | 2019-10-08 | 佛山市高明绿色德化工有限公司 | A kind of high temperature resistant ink for devitrified glass and preparation method thereof, application method |
| CN112409844A (en) * | 2020-07-14 | 2021-02-26 | 湖南松井新材料股份有限公司 | Water-based ink for realizing 3D glass matte effect and preparation method and application thereof |
| CN112479599A (en) * | 2020-12-22 | 2021-03-12 | 湖州安盛医疗器械有限公司 | Preparation method of frosted glass without fluorine |
| CN113637402A (en) * | 2021-09-17 | 2021-11-12 | 深圳市金达盛化工有限公司 | Preparation method of protective coating in glass hot bending process |
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Address after: 410600 No. 777 North Third Ring Road, Ningxiang Economic and Technological Development Zone, Changsha City, Hunan Province Applicant after: Hunan Matsui new materials Limited by Share Ltd Address before: 410600 No. 777 North Third Ring Road, Ningxiang Economic and Technological Development Zone, Changsha City, Hunan Province Applicant before: Hu'nan Sokan New Material Co., Ltd. |
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