CN106832488A - A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof - Google Patents

A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof Download PDF

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Publication number
CN106832488A
CN106832488A CN201611264661.0A CN201611264661A CN106832488A CN 106832488 A CN106832488 A CN 106832488A CN 201611264661 A CN201611264661 A CN 201611264661A CN 106832488 A CN106832488 A CN 106832488A
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China
Prior art keywords
parts
stearic acid
stretch
low temperature
temperature resistant
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Withdrawn
Application number
CN201611264661.0A
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Chinese (zh)
Inventor
何俊文
何帮定
何国
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SINYU CABLE GROUP Co Ltd
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SINYU CABLE GROUP Co Ltd
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Priority to CN201611264661.0A priority Critical patent/CN106832488A/en
Publication of CN106832488A publication Critical patent/CN106832488A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/02Rubber derivatives containing halogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of stretch-proof low temperature resistant cable jacket formula, it is made up of the following raw material according to parts by weight:10 ~ 50 parts of nitrile chloride rubber, 5 ~ 25 parts of Stearic Acid, 6 ~ 18 parts of plant ash, 4 ~ 16 parts of di-t-butyl, 3 ~ 13 parts of methylphenol, 6 ~ 24 parts of silicone masterbatch, 6 ~ 18 parts of vinyltrimethoxy silane, 7 ~ 21 parts of hydration zinc borate, 4 ~ 12 parts of pitch, 4 ~ 16 parts of stearic acid, 5 ~ 15 parts of modified Nano powder, 3 ~ 13 parts of SA dibutyl ester, 1 ~ 11 part of antiager, 4 ~ 16 parts of copper deactivator, 3 ~ 13 parts of adhesive, 1 ~ 7 part of antismoke agent, 1 ~ 9 part of colouring agent.The present invention has the advantages that low temperature resistant, stretch-proof effect is good and long service life.

Description

A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof
Technical field
The present invention relates to field of cables, more particularly to a kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof.
Background technology
At present, used as a kind of common data signal transmission equipment, it has steady signal transmission and the traffic to cable Widely used by people the advantages of big, therefore people are also also improving constantly in the requirement to cable, can adapt to more Complicated working environment, existing cable cover(ing) only with some common materials, these materials can not make cable compared with Normal work at low temperature, and the situation for surface abrasion occur is easy to during long-term dragging, it is unfavorable for people's Long-term use.
The content of the invention
In order to overcome the defect of above-mentioned prior art, it is an object of the invention to provide a kind of stretch-proof low temperature resistant cable sheath Formula and preparation method thereof.
The present invention takes following technical scheme to realize:A kind of stretch-proof low temperature resistant cable jacket formula, by following Raw material according to parts by weight is constituted:10 ~ 50 parts of nitrile chloride rubber, 5 ~ 25 parts of Stearic Acid, 6 ~ 18 parts of plant ash, di-t-butyl 4 ~ 16 parts, 3 ~ 13 parts of methylphenol, 6 ~ 24 parts of silicone masterbatch, 6 ~ 18 parts of vinyltrimethoxy silane, hydration zinc borate 7 ~ 21 Part, 4 ~ 12 parts of pitch, 4 ~ 16 parts of stearic acid, 5 ~ 15 parts of modified Nano powder, 3 ~ 13 parts of SA dibutyl ester, 1 ~ 11 part of antiager, 4 ~ 16 parts of copper deactivator, 3 ~ 13 parts of adhesive, 1 ~ 7 part of antismoke agent, 1 ~ 9 part of colouring agent.
A kind of above-mentioned stretch-proof low temperature resistant cable jacket formula, is made up of the following raw material according to parts by weight:Chlorination 10 ~ 45 parts of nitrile rubber, 5 ~ 20 parts of Stearic Acid, 6 ~ 16 parts of plant ash, 4 ~ 14 parts of di-t-butyl, 3 ~ 11 parts of methylphenol, silicone 6 ~ 22 parts of masterbatch, 6 ~ 16 parts of vinyltrimethoxy silane, 7 ~ 18 parts of hydration zinc borate, 4 ~ 10 parts of pitch, 4 ~ 14 parts of stearic acid, 5 ~ 13 parts of modified Nano powder, 3 ~ 11 parts of SA dibutyl ester, 1 ~ 10 part of antiager, 4 ~ 14 parts of copper deactivator, 3 ~ 11 parts of adhesive, 1 ~ 5 part of antismoke agent, 1 ~ 7 part of colouring agent.
A kind of above-mentioned stretch-proof low temperature resistant cable jacket formula, is made up of the following raw material according to parts by weight:Chlorination 30 parts of nitrile rubber, 15 parts of Stearic Acid, 12 parts of plant ash, 10 parts of di-t-butyl, 8 parts of methylphenol, 15 parts of silicone masterbatch, ethene 12 parts of base trimethoxy silane, 14 parts of hydration zinc borate, 8 parts of pitch, 10 parts of stearic acid, 10 parts of modified Nano powder, SA two 8 parts of pungent fat, 6 parts of antiager, 10 parts of copper deactivator, 8 parts of adhesive, 4 parts of antismoke agent, 5 parts of colouring agent.
A kind of preparation method of above-mentioned stretch-proof low temperature resistant cable jacket formula, comprises the steps of:
(1)The material composition number in claim 3 is chosen, by nitrile chloride rubber, Stearic Acid, plant ash, di-t-butyl, first Base phenol, silicone masterbatch, vinyltrimethoxy silane, hydration zinc borate, pitch, stearic acid, modified Nano powder and SA Dibutyl ester is put into the stirring of agitating device inside, and mixing time is 50min, and addition treatment is carried out to it while stirring, plus Hot temperature is 100 ~ 120 DEG C, and the heat time is 25min, obtains batch mixing A;
(2)Antiager, copper deactivator, adhesive, antismoke agent and colouring agent will be added in batch mixing A, be stirred place to it again Reason, mixing time is 80min, and being put into batch mixing after the completion of stirring carries out pulverization process inside reducing mechanism, grinding time is 50min, obtains finished product.
In sum the invention has the advantages that:The present invention has low temperature resistant, stretch-proof effect good and uses the longevity The advantages of ordering long, can make cable long-term use under the relatively low environment of temperature, be not in the situation of distorted signals, make people Use more facilitate.
Specific embodiment
A kind of stretch-proof low temperature resistant cable jacket formula, is made up of the following raw material according to parts by weight:Nitrile chloride rubber 10 ~ 50 parts of glue, 5 ~ 25 parts of Stearic Acid, 6 ~ 18 parts of plant ash, 4 ~ 16 parts of di-t-butyl, 3 ~ 13 parts of methylphenol, silicone masterbatch 6 ~ 24 parts, 6 ~ 18 parts of vinyltrimethoxy silane, 7 ~ 21 parts of hydration zinc borate, 4 ~ 12 parts of pitch, 4 ~ 16 parts of stearic acid is modified to receive 5 ~ 15 parts of ground rice, 3 ~ 13 parts of SA dibutyl ester, 1 ~ 11 part of antiager, 4 ~ 16 parts of copper deactivator, 3 ~ 13 parts of adhesive, antismoke agent 1 ~ 7 part, 1 ~ 9 part of colouring agent.
A kind of above-mentioned stretch-proof low temperature resistant cable jacket formula, is made up of the following raw material according to parts by weight:Chlorination 10 ~ 45 parts of nitrile rubber, 5 ~ 20 parts of Stearic Acid, 6 ~ 16 parts of plant ash, 4 ~ 14 parts of di-t-butyl, 3 ~ 11 parts of methylphenol, silicone 6 ~ 22 parts of masterbatch, 6 ~ 16 parts of vinyltrimethoxy silane, 7 ~ 18 parts of hydration zinc borate, 4 ~ 10 parts of pitch, 4 ~ 14 parts of stearic acid, 5 ~ 13 parts of modified Nano powder, 3 ~ 11 parts of SA dibutyl ester, 1 ~ 10 part of antiager, 4 ~ 14 parts of copper deactivator, 3 ~ 11 parts of adhesive, 1 ~ 5 part of antismoke agent, 1 ~ 7 part of colouring agent.
A kind of above-mentioned stretch-proof low temperature resistant cable jacket formula, is made up of the following raw material according to parts by weight:Chlorination 30 parts of nitrile rubber, 15 parts of Stearic Acid, 12 parts of plant ash, 10 parts of di-t-butyl, 8 parts of methylphenol, 15 parts of silicone masterbatch, ethene 12 parts of base trimethoxy silane, 14 parts of hydration zinc borate, 8 parts of pitch, 10 parts of stearic acid, 10 parts of modified Nano powder, SA two 8 parts of pungent fat, 6 parts of antiager, 10 parts of copper deactivator, 8 parts of adhesive, 4 parts of antismoke agent, 5 parts of colouring agent.
A kind of preparation method of above-mentioned stretch-proof low temperature resistant cable jacket formula, comprises the steps of:
(1)The material composition number in claim 3 is chosen, by nitrile chloride rubber, Stearic Acid, plant ash, di-t-butyl, first Base phenol, silicone masterbatch, vinyltrimethoxy silane, hydration zinc borate, pitch, stearic acid, modified Nano powder and SA Dibutyl ester is put into the stirring of agitating device inside, and mixing time is 50min, and addition treatment is carried out to it while stirring, plus Hot temperature is 100 ~ 120 DEG C, and the heat time is 25min, obtains batch mixing A;
(2)Antiager, copper deactivator, adhesive, antismoke agent and colouring agent will be added in batch mixing A, be stirred place to it again Reason, mixing time is 80min, and being put into batch mixing after the completion of stirring carries out pulverization process inside reducing mechanism, grinding time is 50min, obtains finished product.
The present invention has the advantages that low temperature resistant, stretch-proof effect is good and long service life, and cable can be made relatively low in temperature In the environment of long-term use, be not in the situation of distorted signals, the use of people is more facilitated.
The above is embodiments of the invention, therefore all constructions according to described in the present patent application scope, feature and principle institute The equivalent change or modification done, is included in the range of present patent application.

Claims (4)

1. a kind of stretch-proof low temperature resistant cable jacket formula, it is characterised in that be made up of the following raw material according to parts by weight:Chlorine Change 10 ~ 50 parts of nitrile rubber, 5 ~ 25 parts of Stearic Acid, 6 ~ 18 parts of plant ash, 4 ~ 16 parts of di-t-butyl, 3 ~ 13 parts of methylphenol, silicon 6 ~ 24 parts of ketone masterbatch, 6 ~ 18 parts of vinyltrimethoxy silane, 7 ~ 21 parts of hydration zinc borate, 4 ~ 12 parts of pitch, stearic acid 4 ~ 16 Part, 5 ~ 15 parts of modified Nano powder, 3 ~ 13 parts of SA dibutyl ester, 1 ~ 11 part of antiager, 4 ~ 16 parts of copper deactivator, adhesive 3 ~ 13 Part, 1 ~ 7 part of antismoke agent, 1 ~ 9 part of colouring agent.
2. a kind of stretch-proof low temperature resistant cable jacket formula according to claim 1, it is characterised in that by following according to weight Measure the raw material composition of number:10 ~ 45 parts of nitrile chloride rubber, 5 ~ 20 parts of Stearic Acid, 6 ~ 16 parts of plant ash, di-t-butyl 4 ~ 14 Part, 3 ~ 11 parts of methylphenol, 6 ~ 22 parts of silicone masterbatch, 6 ~ 16 parts of vinyltrimethoxy silane, 7 ~ 18 parts of hydration zinc borate, drip Blue or green 4 ~ 10 parts, 4 ~ 14 parts of stearic acid, 5 ~ 13 parts of modified Nano powder, 3 ~ 11 parts of SA dibutyl ester, 1 ~ 10 part of antiager, copper suppresses 4 ~ 14 parts of agent, 3 ~ 11 parts of adhesive, 1 ~ 5 part of antismoke agent, 1 ~ 7 part of colouring agent.
3. a kind of stretch-proof low temperature resistant cable jacket formula according to claim 1, it is characterised in that by following according to weight Measure the raw material composition of number:30 parts of nitrile chloride rubber, 15 parts of Stearic Acid, 12 parts of plant ash, 10 parts of di-t-butyl, methylphenol 8 parts, 15 parts of silicone masterbatch, 12 parts of vinyltrimethoxy silane, 14 parts of hydration zinc borate, 8 parts of pitch, 10 parts of stearic acid changes Property 10 parts of nano powder, 8 parts of SA dibutyl ester, 6 parts of antiager, 10 parts of copper deactivator, 8 parts of adhesive, 4 parts of antismoke agent, coloring 5 parts of agent.
4. the preparation method of a kind of stretch-proof low temperature resistant cable jacket formula according to claim 1-3, it is characterised in that Comprise the steps of:
(1)The material composition number in claim 3 is chosen, by nitrile chloride rubber, Stearic Acid, plant ash, di-t-butyl, first Base phenol, silicone masterbatch, vinyltrimethoxy silane, hydration zinc borate, pitch, stearic acid, modified Nano powder and SA Dibutyl ester is put into the stirring of agitating device inside, and mixing time is 50min, and addition treatment is carried out to it while stirring, plus Hot temperature is 100 ~ 120 DEG C, and the heat time is 25min, obtains batch mixing A;
(2)Antiager, copper deactivator, adhesive, antismoke agent and colouring agent will be added in batch mixing A, be stirred place to it again Reason, mixing time is 80min, and being put into batch mixing after the completion of stirring carries out pulverization process inside reducing mechanism, grinding time is 50min, obtains finished product.
CN201611264661.0A 2016-12-30 2016-12-30 A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof Withdrawn CN106832488A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286396A (en) * 2017-06-30 2017-10-24 上海蓝昊电气江苏有限公司 A kind of super low-temperature resistant oil resistant flame retardant jacket materials and its preparation technology
CN107286406A (en) * 2017-06-30 2017-10-24 上海蓝昊电气有限公司 A kind of super low-temperature resistant cable semiconductive material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778192A (en) * 2016-04-05 2016-07-20 江苏亨通高压电缆有限公司 Deep-sea cable water-blocking enhanced buffer strip and preparation method thereof
CN105860177A (en) * 2016-05-18 2016-08-17 安徽华星电缆集团有限公司 Formula and preparation method of anti-corrosion insulating cable sheath

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778192A (en) * 2016-04-05 2016-07-20 江苏亨通高压电缆有限公司 Deep-sea cable water-blocking enhanced buffer strip and preparation method thereof
CN105860177A (en) * 2016-05-18 2016-08-17 安徽华星电缆集团有限公司 Formula and preparation method of anti-corrosion insulating cable sheath

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286396A (en) * 2017-06-30 2017-10-24 上海蓝昊电气江苏有限公司 A kind of super low-temperature resistant oil resistant flame retardant jacket materials and its preparation technology
CN107286406A (en) * 2017-06-30 2017-10-24 上海蓝昊电气有限公司 A kind of super low-temperature resistant cable semiconductive material

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Application publication date: 20170613