CN105860177A - Formula and preparation method of anti-corrosion insulating cable sheath - Google Patents

Formula and preparation method of anti-corrosion insulating cable sheath Download PDF

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Publication number
CN105860177A
CN105860177A CN201610327737.3A CN201610327737A CN105860177A CN 105860177 A CN105860177 A CN 105860177A CN 201610327737 A CN201610327737 A CN 201610327737A CN 105860177 A CN105860177 A CN 105860177A
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CN
China
Prior art keywords
parts
rubber
raw material
mixture
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610327737.3A
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Chinese (zh)
Inventor
陈永军
曹中年
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Huaxing Cable Group Co Ltd
Original Assignee
Anhui Huaxing Cable Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Anhui Huaxing Cable Group Co Ltd filed Critical Anhui Huaxing Cable Group Co Ltd
Priority to CN201610327737.3A priority Critical patent/CN105860177A/en
Publication of CN105860177A publication Critical patent/CN105860177A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/005Hydrogenated nitrile rubber
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a formula of an anti-corrosion insulating cable sheath which is prepared from raw materials in parts by weight as follows: 4-16 parts of silicone rubber, 5-25 parts of nitrile rubber, 4-20 parts of EPDM (ethylene propylene diene monomer) rubber,4-10 parts of nano-clay, 2-8 parts of a silane coupling agent,4-10 parts of a vulcanizing agent,5-15 parts of dioctyl sebacate, 2-10 parts of modified polypropylene, and 4-16 parts of triphenyl phosphate. The anti-corrosion insulating cable sheath has the advantages of good anti-corrosion effect, long service life and the like.

Description

A kind of anticorrosive insulation cable cover(ing) formula and preparation method thereof
Technical field
The present invention relates to field of cables, particularly relate to a kind of anticorrosive insulation cable cover(ing) formula and preparation method thereof.
Background technology
At present, along with the development of science and technology, either industry or the daily life of the mankind, all towards electrified side To development, cable is then in industry and power domain, and its status is also gradually rising, and the existing construction of cable includes that many are led Body, it is coated on several parts such as the insulating barrier outside each conductor, braid and sheath, but the cable of this structure is anti- External disturbance performance and envelope eapsulotomy are poor, are easily caused distorted signals, and therefore signal transmission is the most unstable, the image of transmission The most unintelligible, and existing cable humidity resistance is not fine, it is easy to oxidized and general in the environment of some strong acid and strong bases Logical cable can not be effectively competent at, and brings a biggest difficult problem to enterprise.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, it is an object of the invention to provide a kind of anticorrosive insulation cable cover(ing) and join Side and preparation method thereof.
The present invention takes techniques below scheme to realize: a kind of anticorrosive insulation cable cover(ing) formula, by following heavy The raw material composition of amount number: silicone rubber 4-16 part, nitrile chloride rubber 5-25 part, ethylene propylene diene rubber 4-20 part, nanoclay 4-10 part, silane coupler 2-8 part, vulcanizing agent 4-10 part, SA dioctyl ester 5-15 part, modified polypropene 2-10 part, phosphoric acid Triphenylmethyl methacrylate 4-16 part.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula, is made up of according to the raw material of weight portion following: silicone rubber 4- 14 parts, nitrile chloride rubber 5-22 part, ethylene propylene diene rubber 4-18 part, nanoclay 4-9 part, silane coupler 2-6 part, sulfuration Agent 4-8 part, SA dioctyl ester 5-12 part, modified polypropene 2-8 part, triphenyl phosphate 4-14 part.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula, is made up of according to the raw material of weight portion following: silicone rubber 10 Part, nitrile chloride rubber 15 parts, ethylene propylene diene rubber 12 parts, nanoclay 7 parts, silane coupler 5 parts, vulcanizing agent 7 parts, certain herbaceous plants with big flowers two Dioctyl phthalate 10 parts, modified polypropene 6 parts, triphenyl phosphate 10 parts.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula and preparation method thereof, comprises the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by silicone rubber, nitrile chloride rubber, ethylene propylene diene rubber with receive Rice clay is put into and is carried out sufficient stir process in batch mixer, makes material mix homogeneously, obtains mixture A;
(2) by silane coupler, vulcanizing agent, SA dioctyl ester, modified polypropene and triphenyl phosphate at a temperature of 80 DEG C It is dried stir process, removes the moisture contained in raw material, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
The method have the advantages that the present invention has that anticorrosion ability is good and length in service life etc. is excellent in sum Point, even if cable also is able to normally work in the environment of strong acid and strong base, does not haves situation about being corroded, extends cable Service life.
Detailed description of the invention
A kind of anticorrosive insulation cable cover(ing) formula, is made up of the raw material of following parts by weight: silicone rubber 4-16 part, chlorination Nitrile rubber 5-25 part, ethylene propylene diene rubber 4-20 part, nanoclay 4-10 part, silane coupler 2-8 part, vulcanizing agent 4-10 Part, SA dioctyl ester 5-15 part, modified polypropene 2-10 part, triphenyl phosphate 4-16 part.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula, is made up of according to the raw material of weight portion following: silicone rubber 4- 14 parts, nitrile chloride rubber 5-22 part, ethylene propylene diene rubber 4-18 part, nanoclay 4-9 part, silane coupler 2-6 part, sulfuration Agent 4-8 part, SA dioctyl ester 5-12 part, modified polypropene 2-8 part, triphenyl phosphate 4-14 part.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula, is made up of according to the raw material of weight portion following: silicone rubber 10 Part, nitrile chloride rubber 15 parts, ethylene propylene diene rubber 12 parts, nanoclay 7 parts, silane coupler 5 parts, vulcanizing agent 7 parts, certain herbaceous plants with big flowers two Dioctyl phthalate 10 parts, modified polypropene 6 parts, triphenyl phosphate 10 parts.
Above-mentioned a kind of anticorrosive insulation cable cover(ing) formula and preparation method thereof, comprises the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by silicone rubber, nitrile chloride rubber, ethylene propylene diene rubber with receive Rice clay is put into and is carried out sufficient stir process in batch mixer, makes material mix homogeneously, obtains mixture A;
(2) by silane coupler, vulcanizing agent, SA dioctyl ester, modified polypropene and triphenyl phosphate at a temperature of 80 DEG C It is dried stir process, removes the moisture contained in raw material, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
The present invention has that anticorrosion ability is good and the advantage such as length in service life, even if cable is also in the environment of strong acid and strong base Can normally work, not have situation about being corroded, extend the service life of cable.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute The equivalence change done or modification, in the range of being all included in present patent application.

Claims (4)

1. an anticorrosive insulation cable cover(ing) formula, it is characterised in that be made up of the raw material of following parts by weight: silicone rubber 4- 16 parts, nitrile chloride rubber 5-25 part, ethylene propylene diene rubber 4-20 part, nanoclay 4-10 part, silane coupler 2-8 part, sulfur Agent 4-10 part, SA dioctyl ester 5-15 part, modified polypropene 2-10 part, triphenyl phosphate 4-16 part.
A kind of anticorrosive insulation cable cover(ing) formula the most according to claim 1, it is characterised in that by following according to weight The raw material composition of part: silicone rubber 4-14 part, nitrile chloride rubber 5-22 part, ethylene propylene diene rubber 4-18 part, nanoclay 4-9 Part, silane coupler 2-6 part, vulcanizing agent 4-8 part, SA dioctyl ester 5-12 part, modified polypropene 2-8 part, triphenyl phosphate 4-14 part.
A kind of anticorrosive insulation cable cover(ing) formula the most according to claim 1, it is characterised in that by following according to weight The raw material composition of part: 10 parts of silicone rubber, nitrile chloride rubber 15 parts, ethylene propylene diene rubber 12 parts, nanoclay 7 parts, silane is even Connection agent 5 parts, vulcanizing agent 7 parts, SA dioctyl ester 10 parts, modified polypropene 6 parts, triphenyl phosphate 10 parts.
4. according to a kind of anticorrosive insulation cable cover(ing) formula described in claim 1-3 and preparation method thereof, it is characterised in that Comprise the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by silicone rubber, nitrile chloride rubber, ethylene propylene diene rubber with receive Rice clay is put into and is carried out sufficient stir process in batch mixer, makes material mix homogeneously, obtains mixture A;
(2) by silane coupler, vulcanizing agent, SA dioctyl ester, modified polypropene and triphenyl phosphate at a temperature of 80 DEG C It is dried stir process, removes the moisture contained in raw material, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
CN201610327737.3A 2016-05-18 2016-05-18 Formula and preparation method of anti-corrosion insulating cable sheath Pending CN105860177A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610327737.3A CN105860177A (en) 2016-05-18 2016-05-18 Formula and preparation method of anti-corrosion insulating cable sheath

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610327737.3A CN105860177A (en) 2016-05-18 2016-05-18 Formula and preparation method of anti-corrosion insulating cable sheath

Publications (1)

Publication Number Publication Date
CN105860177A true CN105860177A (en) 2016-08-17

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CN201610327737.3A Pending CN105860177A (en) 2016-05-18 2016-05-18 Formula and preparation method of anti-corrosion insulating cable sheath

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832488A (en) * 2016-12-30 2017-06-13 新宇电缆集团股份有限公司 A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103739925A (en) * 2013-12-24 2014-04-23 上海至正道化高分子材料有限公司 Environment-friendly low-temperature anti-twisting and low-smoke halogen-free flame retardant cable material and preparation method thereof
CN103881166A (en) * 2014-03-26 2014-06-25 苏州红麒麟塑胶有限公司 Low smoke halogen-free flame retardant material applicable to photovoltaic cable and manufacturing method thereof
CN104629369A (en) * 2015-01-26 2015-05-20 安徽国华电缆集团有限公司 Environment-friendly composite cable jacket material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103739925A (en) * 2013-12-24 2014-04-23 上海至正道化高分子材料有限公司 Environment-friendly low-temperature anti-twisting and low-smoke halogen-free flame retardant cable material and preparation method thereof
CN103881166A (en) * 2014-03-26 2014-06-25 苏州红麒麟塑胶有限公司 Low smoke halogen-free flame retardant material applicable to photovoltaic cable and manufacturing method thereof
CN104629369A (en) * 2015-01-26 2015-05-20 安徽国华电缆集团有限公司 Environment-friendly composite cable jacket material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832488A (en) * 2016-12-30 2017-06-13 新宇电缆集团股份有限公司 A kind of stretch-proof low temperature resistant cable jacket formula and preparation method thereof

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Application publication date: 20160817

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