CN105860541A - Antioxidative cable insulation sheath formula and preparation method thereof - Google Patents

Antioxidative cable insulation sheath formula and preparation method thereof Download PDF

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Publication number
CN105860541A
CN105860541A CN201610328418.4A CN201610328418A CN105860541A CN 105860541 A CN105860541 A CN 105860541A CN 201610328418 A CN201610328418 A CN 201610328418A CN 105860541 A CN105860541 A CN 105860541A
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CN
China
Prior art keywords
parts
cable insulation
raw material
mixture
antioxidant
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Pending
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CN201610328418.4A
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Chinese (zh)
Inventor
盛业华
王洁然
丁建新
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Anhui Huaneng Cable Group Co Ltd
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Anhui Huaneng Cable Group Co Ltd
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Priority to CN201610328418.4A priority Critical patent/CN105860541A/en
Publication of CN105860541A publication Critical patent/CN105860541A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antioxidative cable insulation sheath formula. The antioxidative cable insulation sheath formula comprises the following raw materials in parts by weight: 6-20 parts of methyl vinyl silicone rubber, 6-20 parts of modified epoxide resin, 1-7 parts of lubricating agent, 4-12 parts of antioxidant, 6-20 parts of ethylene propylene terpolymer, 4-10 parts of inorganic flame retardant, 5-15 parts of copper chloride and 1-9 parts of curing agent. The antioxidative cable insulation sheath formula has the advantages of good antioxidant effect, long service life and the like.

Description

A kind of antioxidation cable insulation jacket formula and preparation method thereof
Technical field
The present invention relates to field of cables, particularly relate to a kind of antioxidation cable insulation jacket formula and preparation method thereof.
Background technology
At present, along with science and technology development, industry etc. field also at rapid advances, bring therewith is cable consumption Increasing, cable is typically several or the cable of at least two stranded similar ropes often organized by several groups of wires, often organizes wire Between mutually insulated, and be often twisted into around a center, whole outside is surrounded by the cover layer of high-insulation, and the kind of cable has very Many, it is different for can applying the use environment in fields different in a lot of fields, therefore also has cable not Same requirement, if existing cable works for a long time under some more rugged environment, it is easy to occur that epidermis is rotten The situation of erosion, causes cable shorter for service life, increases entreprise cost.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, it is an object of the invention to provide a kind of antioxidation cable insulation jacket and join Side and preparation method thereof.
The present invention takes techniques below scheme to realize: a kind of antioxidation cable insulation jacket formula, following press Raw material according to weight portion forms: methyl vinyl silicone rubber 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxygen Agent 4-12 part, ethylene propylene diene rubber 6-20 part, inorganic combustion inhibitor 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
Above-mentioned a kind of antioxidation cable insulation jacket formula, is made up of according to the raw material of weight portion following: ethylene methacrylic Base silicone rubber 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxidant 4-12 part, ethylene propylene diene rubber 6-20 Part, inorganic combustion inhibitor 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
Above-mentioned a kind of antioxidation cable insulation jacket formula, is made up of according to the raw material of weight portion following: ethylene methacrylic 13 parts of base silicone rubber, modified epoxy 13 parts, lubricant 4 parts, antioxidant 8 parts, ethylene propylene diene rubber 13 parts, inorganic fire-retarded Agent 7 parts, copper chloride 10 parts, 5 parts of firming agent.
Above-mentioned a kind of antioxidation cable insulation jacket formula and preparation method thereof, comprises the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by methyl vinyl silicone rubber, modified epoxy, ternary second Third rubber and copper chloride are put into and are carried out sufficient stir process in batch mixer, make material mix homogeneously, obtain mixture A;
(2) lubricant, antioxidant, inorganic combustion inhibitor and firming agent are dried stir process, removal raw material contains Moisture, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
The method have the advantages that the present invention has that antioxidant effect is good and length in service life etc. is excellent in sum Point, and cable life-time service can be made, do not have oxidized situation, extend the service life of cable.
Detailed description of the invention
A kind of antioxidation cable insulation jacket formula, is made up of according to the raw material of weight portion following: methyl ethylene silicon rubber Glue 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxidant 4-12 part, ethylene propylene diene rubber 6-20 part, nothing Machine fire retardant 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
Above-mentioned a kind of antioxidation cable insulation jacket formula, is made up of according to the raw material of weight portion following: ethylene methacrylic Base silicone rubber 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxidant 4-12 part, ethylene propylene diene rubber 6-20 Part, inorganic combustion inhibitor 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
Above-mentioned a kind of antioxidation cable insulation jacket formula, is made up of according to the raw material of weight portion following: ethylene methacrylic 13 parts of base silicone rubber, modified epoxy 13 parts, lubricant 4 parts, antioxidant 8 parts, ethylene propylene diene rubber 13 parts, inorganic fire-retarded Agent 7 parts, copper chloride 10 parts, 5 parts of firming agent.
Above-mentioned a kind of antioxidation cable insulation jacket formula and preparation method thereof, comprises the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by methyl vinyl silicone rubber, modified epoxy, ternary second Third rubber and copper chloride are put into and are carried out sufficient stir process in batch mixer, make material mix homogeneously, obtain mixture A;
(2) lubricant, antioxidant, inorganic combustion inhibitor and firming agent are dried stir process, removal raw material contains Moisture, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
The present invention has that antioxidant effect is good and the advantage such as length in service life, and can make cable life-time service, will not go out Existing oxidized situation, extends the service life of cable.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute The equivalence change done or modification, in the range of being all included in present patent application.

Claims (4)

1. an antioxidation cable insulation jacket formula, it is characterised in that be made up of according to the raw material of weight portion following: methyl second Thiazolinyl silicone rubber 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxidant 4-12 part, ethylene propylene diene rubber 6- 20 parts, inorganic combustion inhibitor 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
A kind of antioxidation cable insulation jacket formula the most according to claim 1, it is characterised in that by following according to weight The raw material composition of part: methyl vinyl silicone rubber 6-20 part, modified epoxy 6-20 part, lubricant 1-7 part, antioxidant 4- 12 parts, ethylene propylene diene rubber 6-20 part, inorganic combustion inhibitor 4-10 part, copper chloride 5-15 part, firming agent 1-9 part.
A kind of antioxidation cable insulation jacket formula the most according to claim 1, it is characterised in that by following according to weight The raw material composition of part: methyl vinyl silicone rubber 13 parts, modified epoxy 13 parts, lubricant 4 parts, antioxidant 8 parts, ternary 13 parts of EP rubbers, inorganic combustion inhibitor 7 parts, copper chloride 10 parts, 5 parts of firming agent.
4. according to a kind of antioxidation cable insulation jacket formula described in claim 1-3 and preparation method thereof, it is characterised in that Comprise the following steps:
(1) raw material is weighed according to the weight portion in claim 3, by methyl vinyl silicone rubber, modified epoxy, ternary second Third rubber and copper chloride are put into and are carried out sufficient stir process in batch mixer, make material mix homogeneously, obtain mixture A;
(2) lubricant, antioxidant, inorganic combustion inhibitor and firming agent are dried stir process, removal raw material contains Moisture, and make raw material be sufficiently mixed, obtain mixture B;
(3) mixture A and mixture B is placed in drying device again it is dried process, stirred by agitating device Mix process, make mixture A and mixture B carry out mixing and pelletize process by screw extruder, obtain finished product C.
CN201610328418.4A 2016-05-18 2016-05-18 Antioxidative cable insulation sheath formula and preparation method thereof Pending CN105860541A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610328418.4A CN105860541A (en) 2016-05-18 2016-05-18 Antioxidative cable insulation sheath formula and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610328418.4A CN105860541A (en) 2016-05-18 2016-05-18 Antioxidative cable insulation sheath formula and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105860541A true CN105860541A (en) 2016-08-17

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336587A (en) * 2016-08-31 2017-01-18 阮丽丽 Nano-modified ageing resistant composite material and preparation method thereof
CN106349708A (en) * 2016-08-23 2017-01-25 陈建琴 Intensive ultraviolet resistant silicone rubber material for cable
CN106832945A (en) * 2016-12-30 2017-06-13 新宇电缆集团股份有限公司 A kind of anti-aging cable cover(ing) formula of high temperature resistant
CN111138862A (en) * 2019-12-31 2020-05-12 江苏江扬电缆有限公司 Silicone rubber belt and underwater cable comprising same
CN112599292A (en) * 2020-12-15 2021-04-02 陈小栓 Composite cable and preparation process thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349708A (en) * 2016-08-23 2017-01-25 陈建琴 Intensive ultraviolet resistant silicone rubber material for cable
CN106336587A (en) * 2016-08-31 2017-01-18 阮丽丽 Nano-modified ageing resistant composite material and preparation method thereof
CN106832945A (en) * 2016-12-30 2017-06-13 新宇电缆集团股份有限公司 A kind of anti-aging cable cover(ing) formula of high temperature resistant
CN111138862A (en) * 2019-12-31 2020-05-12 江苏江扬电缆有限公司 Silicone rubber belt and underwater cable comprising same
CN111138862B (en) * 2019-12-31 2022-04-19 江苏江扬电缆有限公司 Silicone rubber belt and underwater cable comprising same
CN112599292A (en) * 2020-12-15 2021-04-02 陈小栓 Composite cable and preparation process thereof

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Application publication date: 20160817

RJ01 Rejection of invention patent application after publication