CN105295487B - A kind of conch meal wall covering and its production and use - Google Patents
A kind of conch meal wall covering and its production and use Download PDFInfo
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- CN105295487B CN105295487B CN201510762012.2A CN201510762012A CN105295487B CN 105295487 B CN105295487 B CN 105295487B CN 201510762012 A CN201510762012 A CN 201510762012A CN 105295487 B CN105295487 B CN 105295487B
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- 235000012054 meals Nutrition 0.000 title claims abstract description 56
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 239000002086 nanomaterial Substances 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 238000001354 calcination Methods 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 150000004703 alkoxides Chemical class 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 238000010791 quenching Methods 0.000 claims description 6
- 230000000171 quenching effect Effects 0.000 claims description 6
- COPQLVQNMDXRMW-UHFFFAOYSA-N diethoxy-(1-fluoroethoxy)-octylsilane Chemical class CCCCCCCC[Si](OCC)(OCC)OC(C)F COPQLVQNMDXRMW-UHFFFAOYSA-N 0.000 claims description 5
- 239000005543 nano-size silicon particle Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- -1 silester Chemical compound 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910052755 nonmetal Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 4
- 238000009776 industrial production Methods 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 6
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- UVSMIEOWIMUEOU-UHFFFAOYSA-N triethoxy(8-fluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCCCF UVSMIEOWIMUEOU-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of conch meal wall covering and its production and use, described conch meal wall covering contains the nano-material modified conch meal of 50-60% percentage by weight.Modified by various ingredients and material of coating of the present invention, and specific components selection collocation and specific preparation method, so that played synergistic function between each component, and then make that obtained coating has good not viscous persistency, hardness is high, anti-wear performance is good, there is good application potential and industrial production value widely.
Description
Technical field
The present invention relates to a kind of coating and its production and use, relate more specifically to a kind of conch meal wall covering and its production and use, belong to technical field of coatings.
Background technology
Coating, be a kind of body surface that can be coated in order to protect or the functional chemical industry preparation of decorating objects, it usually forms the thin film of secure adhesion with coated article, and shows diversified defencive function.
Wall covering is known by paint field, existing wall covering function singleness, is particularly easily subject to oil pollution.Existing wall covering, the coating owing to being formed does not have enough mechanical strengths and wearability, after being subject to long-time impact and mechanism, can quickly wear and tear, or even peel off and lose the protective effect to base material.Along with the prolongation of the time of use, the loss of organic silicone oil, viscosity will not be gradually lowered, and therefore cannot there is not viscously the problem that persistency is not enough.Therefore, it remains desirable to metope can improve further in application and performance, especially in thin film-forming method, film-forming temperature, hardness, wearability, not viscous persistency.
Conch meal is that it can be applicable in various chemical products such as coating, has certain absorption and sterilizing function by the shell of various shells passes through the powder processed.Therefore, for the comprehensive utilization of conch meal, not only can consuming substantial amounts of shell on the one hand, thus protecting environment, can turn waste into wealth on the other hand, it is achieved its deep processing and utilization.Therefore, for using the research of the various chemical productss of conch meal, become the focus and emphasis problem of a research at present, and achieve many achievements.Such as, up to the present, it have been reported that several functions coating especially comprises the coating of conch meal in prior art.But, the conch meal of nano modification is used for not gluing wall covering but without open report by prior art.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, in order to prepare conch meal wall covering, this is conducted in-depth research by the present inventor, having paid substantial amounts of creative work and after further investigation is explored, thus completing the present invention.In order to realize the purpose of the present invention, intend adopting the following technical scheme that
One aspect of the present invention relates to a kind of conch meal wall covering, it is characterised in that described conch meal wall covering contains the nano-material modified conch meal of 50-60% percentage by weight.
In a preferred embodiment of the present invention, described nano-material modified conch meal is made up of the nano aluminium oxide of 5-10% percentage by weight, the nano silicon of 5-10% and the conch meal of surplus.
In another preferred embodiment of the present invention, described nano-material modified conch meal is prepared by method and prepares:
(1) being calcined 60-80 minute at 750-850 DEG C by clean oyster shell, be then naturally cooling to room temperature, after calcining, shell is pulverized, is ground, and crosses 200-300 mesh sieve, obtains conch meal, be separately added into nano aluminium oxide and nano silicon oxide, mix homogeneously；
(2) gradient calcining and quenching it are sequentially carried out, concrete operations are: carry out calcining 10-15 minute at 380-420 DEG C, then it is warmed up to 480-520 DEG C with the heating rate of 8-12 DEG C/min, and insulation is calcined 20-25 minute at such a temperature, it is placed in the ethanol water of 15-25% volumetric concentration while hot and lowers the temperature quenches；Filtering after quenching, filtering residue is warmed up to 680-720 DEG C with the heating rate of 3-7 DEG C/min, and insulation is calcined 30-40 minute at such a temperature；Calcining naturally cools to room temperature after terminating, and is again pulverized by conch meal, grinds, crosses 200-300 mesh sieve, obtain nano-material modified conch meal.
In a preferred embodiment of the present invention, described conch meal wall covering is possibly together with the fluoric silane of the alkoxide of 8-12% percentage by weight, the pigment of 5-10% percentage by weight, the water of 20-30% percentage by weight and 3-5% percentage by weight；Preferably, described conch meal wall covering does not contain other component.
In a preferred embodiment of the present invention, described alkoxide is selected from metal alkoxide or nonmetal alkoxide；As preferably, described alkoxide is selected from one or more in tetrabutyl titanate, silester, aluminum isopropylate..
In a preferred embodiment of the present invention, described pigment is black selected from titanium dioxide, carbon black, graphite, high titanium ash, titanium yellow, cobalt titanate green, ferrimanganic, in cobalt blue, copper-chrome black one or several:
In a preferred embodiment of the present invention, described fluoric silane is selected from one or both in ten difluoro heptyl propyl trimethoxy silicanes, 13 fluoro octyl triethoxysilanes.
In a preferred embodiment of the present invention, the hardness of described conch meal wall covering is more than or equal to 9H.
In a preferred embodiment of the present invention, the wearability number of times of described conch meal wall covering is more than 8600 times.
The preparation method that another aspect of the present invention further relates to above-mentioned conch meal wall covering, it is characterised in that comprise the steps: that titanium dioxide and all nano-material modified conch meal and 13 fluoro octyl triethoxysilanes by 50% disperse dispersion 1 in dispersion machine；It is heated to 35-45 DEG C in the titanium dioxide of other 50%, whole tetrabutyl titanate and deionized water and stirring situation, Heat preservation 10-20 minute, resulting dispersion 2, dispersion 1 and 2 is mixed, stirring, 400 orders obtain wall covering after filtering.
The invention still further relates to the using method of above-mentioned coating, by wall covering spraying on the metope adopting putty to process, toast under infrared lamp.
Modified by various ingredients and material of coating of the present invention, and specific components selection collocation and specific preparation method, formula is simple, synergistic function is played between each component, and then make that obtained coating has good not viscous persistency, hardness is high, anti-wear performance is good, there is good application potential and industrial production value widely.
Detailed description of the invention
If not specified, that technological means used in embodiment is well known to those skilled in the art conventional means.
Embodiment 1:
Method of testing in detection method:
1* (heat resistance): cated film will be sprayed after 180 DEG C of baking 2h, put in the Ovenized electric furnace of potential difference meter verification, temperature is raised by 5 DEG C/min, starting timing with furnace temperature to requirement of experiment temperature, sample, after continuous high temperature, takes out, it is cooled to room temperature (25 DEG C), coating surface situation is observed, as without be full of cracks, obscission, namely illustrated that coating heat resistance can be good with magnifier.
2* (not viscosity test): spraying cated film, heating, to 90 DEG C, directly places a raw egg peeled off on its surface；Being always maintained at heating, until the complete fry cooked of egg, promote egg gently with wooden scoop, as egg peels off naturally, non-sticky property is excellent；Slightly adhering to (adhered area is less than 30%), non-sticky property is general；Adhering to serious (adhered area is more than 60%), even can not peel off, non-sticky property is for poor.
3* (resistance to high wet performance): just spray cated film after 180 DEG C of baking 2h, be cooled to room temperature, then test piece be positioned in the distilled water of 100 DEG C, heat and destroy to paint film, occur such as phenomenons such as foaming, loss of gloss, variable color, be full of cracks.
Synthesis example 1: the preparation method of nano-material modified conch meal
(1) being calcined 60-80 minute at 800 DEG C by clean oyster shell, be then naturally cooling to room temperature, after calcining, shell is pulverized, is ground, cross 200-300 mesh sieve, obtain conch meal, be separately added into the nano aluminium oxide and nano silicon oxide that account for conch meal weight 10%, mix homogeneously.
(2) gradient calcining and quenching it are sequentially carried out, concrete operations are: carry out calcining 10-15 minute at 400 DEG C, then it is warmed up to 500 DEG C with the heating rate of 8-12 DEG C/min, and insulation is calcined 20-25 minute at such a temperature, it is placed in the ethanol water of 20% volumetric concentration while hot and lowers the temperature quenches；Filtering after quenching, filtering residue is warmed up to 700 DEG C with the heating rate of 3-7 DEG C/min, and insulation is calcined 30-40 minute at such a temperature；Calcining naturally cools to room temperature after terminating, and is again pulverized by conch meal, grinds, crosses 200-300 mesh sieve, obtain nano-material modified conch meal.
Embodiment 1
(1) raw material is weighed: the tetrabutyl titanate of 10% weight；The titanium dioxide of 7% weight；The deionized water of 24% weight；4% 13 fluoro octyl triethoxysilane；55% nano-material modified conch meal.
(2) titanium dioxide of 50% and all nano-material modified conch meal and 13 fluoro octyl triethoxysilanes are disperseed 2 hours resulting dispersion 1 in dispersion machine high speed；40 DEG C it are heated in the titanium dioxide of other 50%, whole tetrabutyl titanate and deionized water and stirring situation, Heat preservation 15 minutes, resulting dispersion 2, dispersion 1 and 2 is mixed, then high-speed stirred 2 hours, 400 orders obtain wall covering 1 after filtering.
With the spraying on the metope adopting putty to process of the above-mentioned wall covering 1 prepared, toast 120 minutes under infrared lamp, obtain the film that thickness is 35 μm.Detect the performance of film is as shown in table 1.
Table 1:
Can be seen that from testing result above, modified by various ingredients and material of coating of the present invention, and specific components selection collocation and specific preparation method, so that played synergistic function between each component, and then make that obtained coating has good not viscous persistency, hardness is high, anti-wear performance is good, there is good application potential and industrial production value widely.
The above is the preferred embodiments of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from principle of the present invention; can also making some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (10)
1. a conch meal wall covering, it is characterised in that described conch meal wall covering contains the nano-material modified conch meal of 50-60% percentage by weight；Described nano-material modified conch meal is made up of the nano aluminium oxide of 5-10% percentage by weight, the nano silicon of 5-10% and the conch meal of surplus；Described nano-material modified conch meal is prepared by method and prepares:
(1) being calcined 60-80 minute at 750-850 DEG C by clean oyster shell, be then naturally cooling to room temperature, after calcining, shell is pulverized, is ground, and crosses 200-300 mesh sieve, obtains conch meal, be separately added into nano aluminium oxide and nano silicon oxide, mix homogeneously；
(2) gradient calcining and quenching it are sequentially carried out, concrete operations are: carry out calcining 10-15 minute at 380-420 DEG C, then it is warmed up to 480-520 DEG C with the heating rate of 8-12 DEG C/min, and insulation is calcined 20-25 minute at such a temperature, it is placed in the ethanol water of 15-25% volumetric concentration while hot and lowers the temperature quenches；Filtering after quenching, filtering residue is warmed up to 680-720 DEG C with the heating rate of 3-7 DEG C/min, and insulation is calcined 30-40 minute at such a temperature；Calcining naturally cools to room temperature after terminating, and is again pulverized by conch meal, grinds, crosses 200-300 mesh sieve, obtain nano-material modified conch meal.
2. conch meal wall covering according to claim 1, described conch meal wall covering is possibly together with the fluoric silane of the alkoxide of 8-12% percentage by weight, the pigment of 5-10% percentage by weight, the water of 20-30% percentage by weight and 3-5% percentage by weight.
3. conch meal wall covering according to claim 2, described conch meal wall covering does not contain other component.
4. the conch meal wall covering according to Claims 2 or 3, described alkoxide is selected from metal alkoxide or nonmetal alkoxide.
5. conch meal wall covering according to claim 4, one or more in tetrabutyl titanate, silester, aluminum isopropylate. of described alkoxide.
6. the conch meal wall covering according to claim 4 or 5, described pigment is black selected from titanium dioxide, carbon black, graphite, high titanium ash, titanium yellow, cobalt titanate green, ferrimanganic, in cobalt blue, copper-chrome black one or several.
7. the conch meal wall covering according to claim 4 or 5, described fluoric silane is selected from one or both in ten difluoro heptyl propyl trimethoxy silicanes, 13 fluoro octyl triethoxysilanes.
8. the conch meal wall covering according to claim 4 or 5, the hardness of described conch meal wall covering is more than or equal to 9H；The wearability number of times of described conch meal wall covering is more than 8600 times.
9. the preparation method of the conch meal wall covering according to claim 4 or 5, it is characterised in that comprise the steps: that titanium dioxide and all nano-material modified conch meal and 13 fluoro octyl triethoxysilanes by 50% disperse resulting dispersion 1 in dispersion machine；It is heated to 35-45 DEG C in the titanium dioxide of other 50%, whole tetrabutyl titanate and deionized water and stirring situation, Heat preservation 10-20 minute, resulting dispersion 2, dispersion 1 and 2 is mixed, stirring, 400 orders obtain wall covering after filtering.
10. the using method of coating described in claim 1-9 any one, by wall covering spraying on the metope adopting putty to process, toasts under infrared lamp.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510762012.2A CN105295487B (en) | 2015-11-11 | 2015-11-11 | A kind of conch meal wall covering and its production and use |
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| CN201510762012.2A CN105295487B (en) | 2015-11-11 | 2015-11-11 | A kind of conch meal wall covering and its production and use |
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| CN105295487A CN105295487A (en) | 2016-02-03 |
| CN105295487B true CN105295487B (en) | 2016-06-29 |
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| CN106497185A (en) * | 2016-11-22 | 2017-03-15 | 广州最氧环保科技有限公司 | A kind of mould proof metope dry powder paint of conch meal |
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| CN103980744A (en) * | 2014-03-28 | 2014-08-13 | 广西万家康科技股份有限公司 | Special dry powder type ecologic shell powder interior wall coating for children's rooms |
| CN104087035A (en) * | 2014-07-21 | 2014-10-08 | 关锦池 | Water-based paint containing cooked shell powder and ash calcium powder |
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| KR100968108B1 (en) * | 2009-11-30 | 2010-07-07 | 재단법인 한국계면공학연구소 | The manufacturing method and composite of coating agent using oyster shells |
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