CN106824121A - A kind of preparation method of ceramic-metal compound air purification material - Google Patents
A kind of preparation method of ceramic-metal compound air purification material Download PDFInfo
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- CN106824121A CN106824121A CN201510906384.8A CN201510906384A CN106824121A CN 106824121 A CN106824121 A CN 106824121A CN 201510906384 A CN201510906384 A CN 201510906384A CN 106824121 A CN106824121 A CN 106824121A
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- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
Abstract
The invention discloses a kind of preparation method of ceramic-metal compound air purification material, by the drying of wood sawdust；Activated carbon, ceramic, zinc powder, titanium dioxide, nano zircite, rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water are added, is stirred at room temperature, stood；Removal supernatant, drying, then solid matter heated under vacuum is activated；After S5, activation, it is cooled to room temperature and pulverizes, sieve, then add epoxy resin, sodium dichloro cyanurate and silane coupler, carry out heat temperature raising, the process of intensification is not stopped stirring, by comminutor, is made particulate ceramic-metal composite air scavenging material.Preparation method of the present invention is simple to operation, and the cost of material is low for the compound air purification for obtaining, good purification.
Description
Technical field
The present invention relates to technical field of air purification, more particularly to a kind of ceramic metal composite air scavenging material
Preparation method.
Background technology
With socio-economic development and the raising of living standards of the people, modern is for signifying quality of life
Living environment pay attention to day by day, however various new decorative material for building especially chemical composite materials are carried greatly
The toxic gases such as formaldehyde, benzene homologues, the ammonia of amount, cause serious pollution to room air, eyes dry,
The malaise symptoms such as skin is itched, has a headache, failure of memory frequently occur.The research of material for air purification is
The focus of attention as scientist.
Absorption method is because its method is simple and the pollution-free absorption for being widely used in pernicious gas.But majority absorption
Agent has that adsorption efficiency is low, saturated velocity fast, or relatively costly, or even some can bring secondary pollution etc.
Shortcoming, therefore the research and development of cost effective scavenging material easy to use are very urgent.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that a kind of ceramic-metal composite air is net
Change the preparation method of material, preparation method is simple to operation, and the cost of material is low for the compound air purification for obtaining,
Good purification.
A kind of preparation method of ceramic-metal compound air purification material proposed by the present invention, it is characterised in that
Comprise the following steps：
S1,80-140 parts of wood sawdust, activated carbon 50-120 parts, ceramic 20-80 are weighed by weight
Part, zinc powder 30-60 parts, nano zircite 20-50 parts, titanium dioxide 30-50 parts, epoxy resin 10-15
Part, high rare earth 20-50 parts, vitamin C 0.5-1 parts, sodium dichloro cyanurate 12-18 parts, bentonite
2-8 parts, diatomite 5-15 parts, sepiolite 2-8 parts, tourmaline 1-5 parts, silane coupler 1-5 parts；
S2, by wood sawdust 50-70 DEG C dry 8-12h；
S3, add activated carbon, ceramic, zinc powder, titanium dioxide, nano zircite, rare earth high, swollen
Profit soil, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature 1-3h, stand 5-10h；
S4, removal supernatant, 50-70 DEG C of drying, then by solid matter heated under vacuum to 200-500 DEG C
Activated；
S5, activation 1-3h after, be cooled to room temperature and pulverize, cross 80-120 mesh sieves, then add epoxy resin,
Sodium dichloro cyanurate and silane coupler, are warming up to 150-180 DEG C, and the process of intensification does not stop stirring, leads to
Comminutor is crossed, the metal composite air scavenging material of particulate ceramic one is made.
Preferably, in S1,85-135 parts of wood sawdust, activated carbon 55-115 parts, pottery are weighed by weight
25-75 parts of porcelain micro mist, zinc powder 35-55 parts, nano zircite 25-45 parts, titanium dioxide 35-45 parts,
Epoxy resin 11-14 parts, high rare earth 25-45 parts, vitamin C 0.6-0.9 parts, sodium dichloro cyanurate
13-17 parts, bentonite 3-7 parts, diatomite 8-12 parts, sepiolite 3-7 parts, tourmaline 2-4 parts, silicon
2-4 parts of alkane coupling agent.
Preferably, in S1,110 parts of wood sawdust, 85 parts of activated carbon, ceramic are weighed by weight
50 parts, it is 45 parts of zinc powder, 35 parts of nano zircite, 40 parts of titanium dioxide, 12.5 parts of epoxy resin, high
35 parts of rare earth, 0.75 part of vitamin C, 15 parts of sodium dichloro cyanurate, 5 parts of bentonite, diatomite
10 parts, 5 parts of sepiolite, 3 parts of tourmaline, 3 parts of silane coupler.
Preferably, the particle diameter of nano zircite is 20-50 nanometers.
Preferably, silane coupler is Silane coupling agent KH550, silane coupler KH551, silane coupler
One or more mixtures in KH580 and silane coupler KH792.
Preferably, in S2, wood sawdust is dried into 9-11h at 55-65 DEG C.
Preferably, in S3, add activated carbon, ceramic, zinc powder, titanium dioxide, nano zircite,
Rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature 1.5-2.5h,
Stand 6-9h.
Preferably, in S4, supernatant, 55-65 DEG C of drying are removed, then will add under solid matter vacuum condition
Heat is activated to 250-450 DEG C.
Preferably, in S5, after activation 1.5-2.5h, it is cooled to room temperature and pulverizes, crosses 85-115 mesh sieves, so
Addition epoxy resin, sodium dichloro cyanurate and silane coupler, are warming up to 155-175 DEG C afterwards, intensification
Process does not stop stirring, by comminutor, is made particulate ceramic-metal composite air scavenging material.
Preferably, in S5, after activation 2h, it is cooled to room temperature and pulverizes, cross 100 mesh sieves, then adds ring
Oxygen tree fat, sodium dichloro cyanurate and silane coupler, are warming up to 165 DEG C, and the process of intensification does not stop stirring,
By comminutor, particulate ceramic-metal composite air scavenging material is made.
The preparation method of a kind of ceramic-metal compound air purification material of the invention, with wood sawdust, activity
Charcoal, ceramic, zinc powder, nano zircite, titanium dioxide, epoxy resin, rare earth high, vitamin C,
Sodium dichloro cyanurate, bentonite, diatomite, sepiolite, tourmaline and silane coupler are used as the present invention
Raw material, using wood sawdust, activated carbon, bentonite, diatomite, sepiolite and tourmaline etc. as porous
Material, by adding, zinc powder, nano zircite and titanium dioxide are used as metal or metal oxide is urged as light
Agent act on, effectively increase the efficiency and quality of purification of air, by add epoxy resin, vitamin C,
Sodium dichloro cyanurate and silane coupler so that structure of the invention is more compact and stable, effectively carries
The high quality and the quality of purification of air of product；
The present invention has following distinguishing feature：
(1) material for air purification is invented, raw material sources are extensively, cheap；
(2) the material for air purification preparation method is invented simply, adsorption rate is high；
(3) the material for air purification stable performance is invented, long lifespan can for a long time be preserved and used.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for
The bright present invention, rather than for limiting the invention, any modification made on the basis of the present invention,
Equivalent etc. is within the scope of the present invention.
In specific embodiment, the weight portion of wood sawdust can for 80 parts, 85 parts, 90 parts, 95 parts,
100 parts, 105 parts, 110 parts, 115 parts, 120 parts, 125 parts, 130 parts, 135 parts, 140 parts；
The weight portion of activated carbon can for 50 parts, 55 parts, 60 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85
Part, 90 parts, 95 parts, 100 parts, 105 parts, 110 parts, 115 parts, 120 parts；The weight of ceramic
Part can for 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts, 65
Part, 70 parts, 75 parts, 80 parts；The weight portion of zinc powder can for 30 parts, 35 parts, 40 parts, 45 parts,
50 parts, 55 parts, 60 parts；The weight portion of nano zircite can for 20 parts, 25 parts, 30 parts, 35 parts,
40 parts, 45 parts, 50 parts；The weight portion of titanium dioxide can for 30 parts, 35 parts, 40 parts, 45 parts,
50 parts；The weight portion of epoxy resin can for 10 parts, 10.5 parts, 11 parts, 11.5 parts, 12 parts, 12.5
Part, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts；The weight portion of rare earth high can for 20 parts,
25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts；Ascorbic weight portion can for 0.5 part,
0.6 part, 0.7 part, 0.8 part, 0.9 part, 1 part；The weight portion of sodium dichloro cyanurate can for 12 parts,
13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts；Bentonitic weight portion can for 2 parts, 3 parts,
4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Diatomaceous weight portion can for 5 parts, 6 parts, 7 parts, 8 parts,
9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight portion of sepiolite can for 2 parts,
3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of tourmaline can for 1 part, 2 parts, 3 parts,
4 parts, 5 parts；The weight portion of silane coupler can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
Embodiment 1
A kind of preparation method of ceramic-metal compound air purification material proposed by the present invention, including following step
Suddenly：
S1,110 parts of wood sawdust, 85 parts of activated carbon, 50 parts of ceramic, zinc powder are weighed by weight
45 parts, 35 parts of the nano zircite that particle diameter is 35 nanometers, 40 parts of titanium dioxide, 12.5 parts of epoxy resin,
35 parts of rare earth high, 0.75 part of vitamin C, 15 parts of sodium dichloro cyanurate, 5 parts of bentonite, diatomite
10 parts, 5 parts of sepiolite, 3 parts of tourmaline, 3 parts of Silane coupling agent KH550；
S2, by wood sawdust 60 DEG C dry 10h；
S3, add activated carbon, ceramic, zinc powder, titanium dioxide, particle diameter to be 35 nanometers it is nano oxidized
Zirconium, rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature
2h, stands 7.5h；
S4, removal supernatant, 60 DEG C of drying, then solid matter heated under vacuum is carried out to 350 DEG C
Activation；
After S5, activation 2h, it is cooled to room temperature and pulverizes, cross 100 mesh sieves, then adds epoxy resin, dichloro
Sodium isocyanurate and Silane coupling agent KH550, are warming up to 165 DEG C, and the process of intensification does not stop stirring, by making
Grain machine, is made particulate ceramic-metal composite air scavenging material.
Silane coupler is, silane coupler KH551, silane coupler KH580 and silane coupler KH792
In one or more mixtures.
Embodiment 2
A kind of preparation method of ceramic-metal compound air purification material proposed by the present invention, including following step
Suddenly：
S1,80 parts of wood sawdust, 120 parts of activated carbon, 20 parts of ceramic, zinc powder are weighed by weight
60 parts, 50 parts of the nano zircite that particle diameter is 20 nanometers, 30 parts of titanium dioxide, 15 parts of epoxy resin,
20 parts of rare earth high, 1 part of vitamin C, 12 parts of sodium dichloro cyanurate, 8 parts of bentonite, diatomite 5
Part, 8 parts of sepiolite, 1 part of tourmaline, 1 part of silane coupler KH580；
S2, by wood sawdust 70 DEG C dry 8h；
S3, add activated carbon, ceramic, zinc powder, titanium dioxide, particle diameter to be 20 nanometers it is nano oxidized
Zirconium, rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature
3h, stands 5h；
S4, removal supernatant, 70 DEG C of drying, then solid matter heated under vacuum is carried out to 200 DEG C
Activation；
After S5, activation 3h, it is cooled to room temperature and pulverizes, cross 80 mesh sieves, then adds epoxy resin, dichloro
Sodium isocyanurate and silane coupler KH551, are warming up to 180 DEG C, and the process of intensification does not stop stirring, by making
Grain machine, is made particulate ceramic-metal composite air scavenging material.
Embodiment 3
A kind of preparation method of ceramic-metal compound air purification material proposed by the present invention, including following step
Suddenly：
S1,140 parts of wood sawdust, 50 parts of activated carbon, 80 parts of ceramic, zinc powder are weighed by weight
30 parts, 20 parts of the nano zircite that particle diameter is 50 nanometers, 50 parts of titanium dioxide, 10 parts of epoxy resin,
50 parts of rare earth high, 0.5 part of vitamin C, 18 parts of sodium dichloro cyanurate, 2 parts of bentonite, diatomite
15 parts, 2 parts of sepiolite, 5 parts of tourmaline, 5 parts of silane coupler KH580；
S2, by wood sawdust 50 DEG C dry 12h；
S3, add activated carbon, ceramic, zinc powder, titanium dioxide, particle diameter to be 20 nanometers it is nano oxidized
Zirconium, rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature
3h, stands 5h；
S4, removal supernatant, 70 DEG C of drying, then solid matter heated under vacuum is carried out to 200 DEG C
Activation；
After S5, activation 3h, it is cooled to room temperature and pulverizes, cross 80 mesh sieves, then adds epoxy resin, dichloro
Sodium isocyanurate and silane coupler KH580, are warming up to 180 DEG C, and the process of intensification does not stop stirring, by making
Grain machine, is made particulate ceramic-metal composite air scavenging material.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention not office
Be limited to this, any one skilled in the art the invention discloses technical scope in, according to this
The technical scheme of invention and its inventive concept are subject to equivalent or change, should all cover in protection of the invention
Within the scope of.
Claims (10)
1. a kind of preparation method of ceramic-metal compound air purification material, it is characterised in that including as follows
Step：
S1,80-140 parts of wood sawdust, activated carbon 50-120 parts, ceramic 20-80 are weighed by weight
Part, zinc powder 30-60 parts, nano zircite 20-50 parts, titanium dioxide 30-50 parts, epoxy resin 10-15
Part, high rare earth 20-50 parts, vitamin C 0.5-1 parts, sodium dichloro cyanurate 12-18 parts, bentonite
2-8 parts, diatomite 5-15 parts, sepiolite 2-8 parts, tourmaline 1-5 parts, silane coupler 1-5 parts；
S2, by wood sawdust 50-70 DEG C dry 8-12h；
S3, add activated carbon, ceramic, zinc powder, titanium dioxide, nano zircite, rare earth high, swollen
Profit soil, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature 1-3h, stand 5-10h；
S4, removal supernatant, 50-70 DEG C of drying, then by solid matter heated under vacuum to 200-500 DEG C
Activated；
S5, activation 1-3h after, be cooled to room temperature and pulverize, cross 80-120 mesh sieves, then add epoxy resin,
Sodium dichloro cyanurate and silane coupler, are warming up to 150-180 DEG C, and the process of intensification does not stop stirring, leads to
Comminutor is crossed, particulate ceramic-metal composite air scavenging material is made.
2. the preparation method of ceramic-metal compound air purification material according to claim 1, it is special
Levy and be, in S1, weigh by weight 85-135 parts of wood sawdust, activated carbon 55-115 parts, ceramics it is micro-
Powder 25-75 parts, zinc powder 35-55 parts, nano zircite 25-45 parts, titanium dioxide 35-45 parts, epoxy
Resin 11-14 parts, high rare earth 25-45 parts, vitamin C 0.6-0.9 parts, sodium dichloro cyanurate 13-17
Part, bentonite 3-7 parts, diatomite 8-12 parts, sepiolite 3-7 parts, tourmaline 2-4 parts, it is silane coupled
Agent 2-4 parts.
3. the preparation method of ceramic-metal compound air purification material according to claim 1 and 2,
Characterized in that, in S1,110 parts of wood sawdust, 85 parts of activated carbon, ceramic are weighed by weight
50 parts, it is 45 parts of zinc powder, 35 parts of nano zircite, 40 parts of titanium dioxide, 12.5 parts of epoxy resin, high
35 parts of rare earth, 0.75 part of vitamin C, 15 parts of sodium dichloro cyanurate, 5 parts of bentonite, diatomite
10 parts, 5 parts of sepiolite, 3 parts of tourmaline, 3 parts of silane coupler.
4. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-3
Method, it is characterised in that the particle diameter of nano zircite is 20-50 nanometers.
5. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-4
Method, it is characterised in that silane coupler is Silane coupling agent KH550, silane coupler KH551, silane idol
One or more mixtures in connection agent KH580 and silane coupler KH792.
6. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-5
Method, it is characterised in that in S2,9-11h is dried by wood sawdust at 55-65 DEG C.
7. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-6
Method, it is characterised in that in S3, adds activated carbon, ceramic, zinc powder, titanium dioxide, nano oxidized
Zirconium, rare earth high, bentonite, vitamin C, diatomite, sepiolite, tourmaline powder and water, are stirred at room temperature
1.5-2.5h, stands 6-9h.
8. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-7
Method, it is characterised in that in S4, removes supernatant, 55-65 DEG C of drying, then by solid matter vacuum condition
Under be heated to 250-450 DEG C and activated.
9. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-8
Method, it is characterised in that in S5, after activation 1.5-2.5h, is cooled to room temperature and pulverizes, and crosses 85-115 mesh sieves,
Then addition epoxy resin, sodium dichloro cyanurate and silane coupler, are warming up to 155-175 DEG C, heat up
Process do not stop stirring, by comminutor, be made particulate ceramic-metal composite air scavenging material.
10. the preparation side of the ceramic-metal compound air purification material according to claim any one of 1-9
Method, it is characterised in that in S5, after activation 2h, is cooled to room temperature and pulverizes, and crosses 100 mesh sieves, Ran Houtian
Plus epoxy resin, sodium dichloro cyanurate and silane coupler, 165 DEG C are warming up to, the process of intensification is not stopped
Stirring, by comminutor, is made particulate ceramic-metal composite air scavenging material.
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Cited By (1)
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| CN107352886A (en) * | 2017-08-18 | 2017-11-17 | 苏州格瑞格登新材料科技有限公司 | A kind of heat insulating energy saving material and preparation method thereof |
Citations (7)
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