CN106811329A - 一种抗菌防螨的洗衣片及其制备方法 - Google Patents
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Abstract
本发明提供了一种抗菌防螨的洗衣片及其制备方法，该洗衣片包括以下原料：非离子表面活性剂、阴离子表面活性剂、去离子水、无水乙醇、崩解剂、糯米浆、抗菌防螨微胶囊、交联剂、蛋白质酶、酸剂、香精、着色剂和防腐剂。其制备方法是先将交联剂、着色剂、酸剂、香精、防腐剂加入去离子水中，再加入非离子表面活性剂、阴离子表面活性剂，蛋白质酶的混合物，乳化后加入糯米浆和崩解剂，然后加入抗菌防螨微胶囊分散液，所得混合料经烘干、成形，得到洗衣片。本发明通过在产品中添加具有抗菌防螨效果的纯天然精油微胶囊，达到洗涤后吸附在衣物上、在使用过程中缓慢释放出抗菌防螨效果。
Description
技术领域
本发明属于洗涤剂制品技术领域，具体涉及一种抗菌防螨的洗衣片及其制备方法。
背景技术
洗衣片作为一种新的洗涤剂形态，在近几年发展比较迅速，其所具备的优势很明显，主要是以下几点：一、改变了洗衣粉、洗衣液需要计量使用的繁琐；二、与传统的洗衣粉、洗涤剂相比，洗衣片含有更多的有效成分，极大减少了填充料、辅材、水等的使用，配方实现节约资源的效果；三、洗衣片以其体积小，重量轻、包装耗材小、储存方便、不易变质等优点，相对对传统洗衣液复杂的罐装流程，洗衣片在降本方面更具优势，在绿色、环保方面也有突出的贡献。
目前功能型洗衣片存在以下几个问题：一、洗衣片溶解性相对洗衣液而言差，机洗效果难达到洗衣液水平；二、目前现有的发明专利中，洗衣片所采用的成膜剂均为化学成分物质，对环境、消费者均存在不良影响；三、目前抗菌防螨洗衣片所添加的物质为人工合成抗菌防螨剂，无法满足消费者绿色健康的消费理念。
发明内容
解决的技术问题：本发明的目的是提供一种抗菌防螨的洗衣片及其制备方法，通过在产品中添加具有抗菌防螨效果的纯天然精油微胶囊，达到洗涤后吸附在衣物上、在使用过程中缓慢释放出抗菌防螨效果。
技术方案：一种抗菌防螨的洗衣片，以重量份计包括以下原料：非离子表面活性剂20-30份，阴离子表面活性剂20-50份，去离子水30.0-60.0份，无水乙醇2.0-6.0份，崩解剂6.0-12.0份，糯米浆1.0-3.0份，抗菌防螨微胶囊1.0-3.0份，交联剂0.5-1.0份，蛋白质酶0.1-1.0份，酸剂0.05-1.0份，香精0.01-0.1份，着色剂0.01-0.04份，防腐剂0.01-0.03份。
进一步地，所述交联剂为水性聚氨酯型交联剂。
进一步地，所述非离子表面活性剂为醇醚糖苷，所述阴离子表面活性剂选自脂肪酸甲酯磺酸钠、α-烯基磺酸钠或脂肪醇醚硫酸钠中的一种或几种。
进一步地，所述崩解剂为羧甲基淀粉钠。
进一步地，所述抗菌防螨微胶囊为艾草油微胶囊、桉叶油微胶囊或肉桂油微胶囊中的一种或几种的混合物。
上述抗菌防螨的洗衣片的制备方法，包括以下步骤：
步骤1，将交联剂、着色剂、酸剂、香精、防腐剂加入去离子水中，搅拌，得到溶液；
步骤2，将非离子表面活性剂、阴离子表面活性剂，蛋白质酶粉碎，混合，得到混合物；
步骤3，将步骤2所得的混合物加至步骤1所得溶液中，乳化，得到混合料一；
步骤4，将抗菌防螨微胶囊分散在无水乙醇中，搅拌、分散，得到抗菌防螨微胶囊分散液；
步骤5，将糯米浆、崩解剂添加到步骤3所得混合料一中，搅拌，得到混合料二；
步骤6，将步骤4所得抗菌防螨微胶囊分散液加至步骤5所得混合料二中，搅拌，得到混合料三；
步骤7，将步骤6所得混合料三加入到滚筒烘干设备上烘干、成形；
步骤8，将成形后的洗衣片放入机器中切成所需规格尺寸、包装。
有益效果：
(1)使用的表面活性剂体系不含APEO，保证了使用后排污无毒、生物降解性好。
(2)醇醚糖苷属于新型绿色表面活性剂，无毒、无刺激，易于生物降解对人体和环境更安全。醇醚糖苷低温水溶性好、耐硬水性能好，醇醚糖苷通过氢键与H2O及H3O+结合，从而使醇醚糖苷分子带有一定的正电性。此时溶液中的阴离子表面活性剂，产生类似于异电性表面活性剂之间的电性作用。其在配方中的主要作用是能加速表面活性剂各组分的扩散溶解，提高洗涤去污效果。
(3)将崩解剂均匀混合在配方中，能起到遇水迅速分解洗衣片的作用，加速表面活性剂溶解速度。
(4)使用糯米浆替代其他发明中的聚乙烯醇等化学成膜剂，不仅使耐潮性明显提升，糯米浆中支链淀粉高达80％左右，又可称胶淀粉，分子相对较大，一般由几千个葡萄糖残基组成，支链淀粉难溶于水，只有外围的支链能被水解。所以糯米淀粉浆烘干成型后，具有阻止水解的作用，起到防潮效果，支链淀粉的分子量远大于表面活性剂分子，在洗涤过程中对于污垢具有较好的吸附、抗沉积效果，使洗下的污垢随洗涤液排出，起到助洗的作用，且原料工艺绿色环保，使消费者使用、储存携带都得到安全、方便，洗涤后产生的生活污水，也比化学成膜剂易于降解。
(5)抗菌防螨微胶囊选用纯天然物质作为抗菌防螨剂，在杀灭细菌，趋避螨虫方面有较好效果，但是微胶囊长期与水接触，会造成囊壁因溶胀破裂使产品失效的风险。本发明选用无水乙醇作为分散液，既保证分散效果好，不会造成囊壁破裂，又能保证在后期加工过程中无水乙醇在烘干过程中被迅速蒸发，不残留，可用于洗衣片中。
具体实施方式
下面通过具体实施方式对发明作进一步详细说明。但本领域技术人员将会理解下列实施例仅用于说明本发明，而不应视为限定本发明的范围。
实施例1
(一)抗菌防螨洗衣片原料组分
醇醚糖苷20份，脂肪酸甲酯磺酸钠10份，α-烯基磺酸钠5份，脂肪醇醚硫酸钠10份，去离子水30.0份，交联剂0.5份，艾草精油微胶囊1.0份，无水乙醇2.0份，糯米浆1.0份，羧甲基淀粉钠6.0份，蛋白质酶0.2份，柠檬酸0.1份，香精0.01份、着色剂0.02份、防腐剂0.01份。
(二)制备步骤
步骤1：将去离子水加入到乳化机中，打开搅拌装置。依次加入称量好的交联剂、着色剂、柠檬酸、香精、防腐剂，搅拌10min。
步骤2：将称量好的醇醚糖苷，脂肪酸甲酯磺酸钠，α-烯基磺酸钠，脂肪醇醚硫酸钠，蛋白质酶加入到粉碎机中充分粉碎混合。
步骤3：将步骤2所得的混合物缓慢添加到步骤1溶液中，调节乳化机加热温度为50-60℃，搅拌2小时。
步骤4：将艾草精油微胶囊分散在无水乙醇中，搅拌30min，备用。
步骤5：将糯米浆、羧甲基淀粉钠加入到步骤3的混合料中，搅拌30min。
步骤6：将步骤4制备的艾草精油微胶囊分散液添加到步骤5混合料中，继续搅拌混合30min。
步骤7：将步骤6获得的混合料加入到滚筒烘干设备上烘干，烘干温度100℃，成形。
步骤8：将成形后的洗衣片放入机器中切成所需规格尺寸、包装。
实施例2
(一)抗菌防螨洗衣片原料组分
醇醚糖苷25份，脂肪酸甲酯磺酸钠15份，α-烯基磺酸钠5份，脂肪醇醚硫酸钠10份，去离子水50.0份，交联剂1.0份，肉桂精油微胶囊2.0份，无水乙醇4.0份，糯米浆2.0份、羧甲基淀粉钠8.0份，蛋白质酶0.4份，柠檬酸0.5份，香精0.5份、着色剂0.03份、防腐剂0.02份。
(二)制备步骤
步骤1：将去离子水加入到乳化机中，打开搅拌装置。依次加入称量好的交联剂、着色剂、柠檬酸、香精、防腐剂，搅拌10min。
步骤2：将称量好的醇醚糖苷，脂肪酸甲酯磺酸钠，α-烯基磺酸钠，脂肪醇醚硫酸钠，蛋白质酶加入到粉碎机中充分粉碎混合。
步骤3：将步骤2所得的混合物，缓慢添加到步骤1溶液中，调节乳化机加热温度为50-60℃，搅拌2小时。
步骤4：将肉桂精油微胶囊分散在无水乙醇中，搅拌30min，备用。
步骤5：将糯米浆、羧甲基淀粉钠加入到步骤3的混合料中，搅拌30min。
步骤6：将步骤4制备的肉桂精油微胶囊分散液添加到步骤5混合料中，继续搅拌混合30min。
步骤7：将步骤6获得的混合料加入到滚筒烘干设备上烘干，烘干温度100℃，成形。
步骤8：将成形后的洗衣片放入机器中切成所需规格尺寸、包装。
实施例3
(一)抗菌防螨洗衣片原料组分
醇醚糖苷30份，脂肪酸甲酯磺酸钠12份，α-烯基磺酸钠3份，脂肪醇醚硫酸钠15份，去离子水60.0份，交联剂1.0份，桉叶精油微胶囊2.0份，肉桂精油微胶囊1.0份，无水乙醇6.0份，糯米浆3.0份，羧甲基淀粉钠12.0份，蛋白质酶0.8份，柠檬酸1.0份，香精0.8份、着色剂0.04份、防腐剂0.03份。
(二)制备步骤
步骤1：将去离子水加入到乳化机中，打开搅拌装置。依次加入称量好的着色剂、柠檬酸、香精、防腐剂，搅拌10min。
步骤2：将称量好的醇醚糖苷，脂肪酸甲酯磺酸钠，α-烯基磺酸钠，脂肪醇醚硫酸钠，蛋白质酶加入到粉碎机中充分粉碎混合。
步骤3：将步骤2所得的混合物，缓慢添加到步骤1溶液中，调节乳化机加热温度为50-60℃，搅拌2小时。
步骤4：将桉叶、肉桂精油微胶囊分散在无水乙醇中，搅拌30min，备用。
步骤5：将糯米浆、羧甲基淀粉钠加入到步骤3的混合料中，搅拌30min。
步骤6：将步骤4制备的桉叶、肉桂精油微胶囊分散液添加到步骤5混合料中，继续搅拌混合30min。
步骤7：将步骤6获得的混合料加入到滚筒烘干设备上烘干，烘干温度100℃，成形。
步骤8：将成形后的洗衣片放入机器中切成所需规格尺寸、包装。
对照例1
对照例1与实施例2的区别在于，不添加抗菌防螨微胶囊、交联剂、无水乙醇。
对照例2
对照例2与实施例2的区别在于，抗菌防螨微胶囊添加量为0.2份，其他均不变。
对照例3
对照例3与实施例2的区别在于，抗菌防螨微胶囊添加量为4.0份，其他均不变。
对照例4
对照例4与实施例2的区别在于，步骤4使用水作为分散剂，不使用无水乙醇作为分散剂.
对照例5
对照例5与实施例2的区别在于，不加入糯米浆。
检测：以市售泉立方纳米超浓缩洗衣片作为对照，将实施例和对照例进以下项目测定：
由实施例2，对照例1可知，添加抗菌防螨微胶囊的洗衣片，其具备抗菌防螨性能；
由实施例2，对照例2可知，抗菌防螨微胶囊添加量过少，无法起到抗菌防螨效果；
由实施例2与对照例3可知，抗菌防螨微胶囊添加量过多，会引起产品稳定性出现问题，更加容易沉淀；
由实施例2与对照例4可知，使用水作为抗菌防螨微胶囊分散剂，会引起微胶囊抗菌防螨功能失效，并且对产品稳定性也不利；
由实施例2与对照例5可知，不添加淀粉浆作为成膜剂、粘合剂，其制成的洗衣片防潮性能较差，无法达到长期储存的效果。
Claims (6)
1.一种抗菌防螨的洗衣片，其特征在于：以重量份计包括以下原料：非离子表面活性剂20.0-30.0份，阴离子表面活性剂20.0-50.0份，去离子水30.0-60.0份，无水乙醇2.0-6.0份，崩解剂6.0-12.0份，糯米浆1.0-3.0份，抗菌防螨微胶囊1.0-3.0份，交联剂0.5-1.0份，蛋白质酶0.1-1.0份，酸剂0.05-1.0份，香精0.01-0.1份，着色剂0.01-0.04份，防腐剂0.01-0.03份。
2.根据权利要求1所述的抗菌防螨的洗衣片，其特征在于：所述交联剂为水性聚氨酯型交联剂。
3.根据权利要求1所述的抗菌防螨的洗衣片，其特征在于：所述非离子表面活性剂为醇醚糖苷，所述阴离子表面活性剂选自脂肪酸甲酯磺酸钠、α-烯基磺酸钠或脂肪醇醚硫酸钠中的一种或几种。
4.根据权利要求1所述的抗菌防螨的洗衣片，其特征在于：所述崩解剂为羧甲基淀粉钠。
5.根据权利要求1所述的抗菌防螨的洗衣片，其特征在于：所述抗菌防螨微胶囊为艾草油微胶囊、桉叶油微胶囊或肉桂油微胶囊中的一种或几种的混合物。
6.权利要求1所述的抗菌防螨的洗衣片的制备方法，其特征在于：包括以下步骤：
步骤1，将交联剂、着色剂、酸剂、香精、防腐剂加入去离子水中，搅拌，得到溶液；
步骤2，将非离子表面活性剂、阴离子表面活性剂，蛋白质酶粉碎，混合，得到混合物；
步骤3，将步骤2所得的混合物加至步骤1所得溶液中，乳化，得到混合料一；
步骤4，将抗菌防螨微胶囊分散在无水乙醇中，搅拌、分散，得到抗菌防螨微胶囊分散液；
步骤5，将糯米浆、崩解剂添加到步骤3所得混合料一中，搅拌，得到混合料二；
步骤6，将步骤4所得抗菌防螨微胶囊分散液加至步骤5所得混合料二中，搅拌，得到混合料三；
步骤7，将步骤6所得混合料三加入到滚筒烘干设备上烘干、成形；
步骤8，将成形后的洗衣片放入机器中切成所需规格尺寸、包装。
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