CN106810074A - A kind of metal-lustrous glaze and preparation method thereof - Google Patents
A kind of metal-lustrous glaze and preparation method thereof Download PDFInfo
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- CN106810074A CN106810074A CN201611061674.8A CN201611061674A CN106810074A CN 106810074 A CN106810074 A CN 106810074A CN 201611061674 A CN201611061674 A CN 201611061674A CN 106810074 A CN106810074 A CN 106810074A
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- China
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- metal
- glaze
- lustrous
- lustrous glaze
- dolomite
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to metal-lustrous glaze technical field, more particularly to a kind of metal-lustrous glaze.Its material composition for including following mass percent：Aluminum oxide 8 12%；Calcite 5 10%；Lime stone 10 20%；Dolomite 5 10%；Aluminum phosphate 8 12%；Iron oxide 1 5%；Crisp ball element 15 25%；Balance of quartz.Beneficial effects of the present invention are：Metal-lustrous glaze is prepared with the conventional ceramic such as aluminum oxide, lime stone, dolomite raw material and iron oxide etc., the preferable metal-lustrous glaze of effect is obtained, metallic luster becomes strong, and colour generation is good, and glaze paint is smooth, and glazing effect is good.
Description
Technical field
The present invention relates to metal-lustrous glaze technical field, more particularly to a kind of metal-lustrous glaze.
Background technology
Metal glaze refers to that the one kind of transition metal oxide or many such as Ti, Co, Cr, Mn, Fe, Ni, Zn, Cu are added in parent glaze
Kind, saturation is reached at high temperature, crystal is separated out, glaze paint is produced the artistic effect of metallic luster.Glaze paint with metallic luster
The favor of ceramic industry and consumer is enjoyed because of its graceful, thick and heavy makings, in the market metal-lustrous glaze mainly have yellow,
The kinds such as silver color, black, copper red, brown.In order to obtain the preferable glazing effect of gloss, it is necessary to use leaded or boron frit
Glaze, with the raising of environmental protection consciousness, this product has been prohibited.
The content of the invention
It is an object of the invention to be directed to the existing state of the art, there is provided a kind of metal-lustrous glaze.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that：
A kind of metal-lustrous glaze, including following mass percent material composition：
Aluminum oxide 8-12%；
Calcite 5-10%；
Lime stone 10-20%；
Dolomite 5-10%；
Aluminum phosphate 8-12%；
Iron oxide 1-5%；
Crisp ball element 15-25%；
Balance of quartz.
Further, described a kind of metal-lustrous glaze：
Aluminum oxide 10%；
Calcite 7%；
Lime stone 18%；
Dolomite 8%；
Aluminum phosphate 10%；
Iron oxide 2.3%；
Crisp ball element 22%；
Balance of quartz.
Each raw material is weighed by proportion speed, using ball mill ball milling, 1320 DEG C of maximum temperature is raised to, after held for some time
Natural cooling.
Further, Ball-milling Time is 30min.
Further, using glaze method glazing, glazed thickness is about 1.0mm.
Beneficial effects of the present invention are：Prepared with the conventional ceramic such as aluminum oxide, lime stone, dolomite raw material and iron oxide etc.
Metal-lustrous glaze, obtains the preferable metal-lustrous glaze of effect, and metallic luster becomes strong, and colour generation is good, and glaze paint is smooth, and glazing effect is good
It is good.
Specific embodiment
In order that juror can be further understood that to the purpose of the present invention, feature and function, preferred embodiment is hereby lifted detailed
Carefully it is described as follows：
Each raw material is weighed by proportion speed, ball grinder is added, using ball mill ball milling, Ball-milling Time is 30min, ball-milling technology ginseng
Number：Material：Ball：Water=l：2：0.8.Additional 0.2% CMC improves flowing and the stability of slurry, using glaze method glazing, glaze layer
Thickness is about 1.0mm, is burnt till using laboratory chamber type electric resistance furnace, is raised to 1320 DEG C of maximum temperature, natural after held for some time
Cooling.
Embodiment 1：
Aluminum oxide 11%；
Calcite 8%；
Lime stone 18%；
Dolomite 8%；
Aluminum phosphate 11%；
Iron oxide 4%；
Crisp ball element 22%；
Balance of quartz.
Embodiment 2：
Aluminum oxide 8-12%；
Calcite 5%；
Lime stone 17%；
Dolomite 7%；
Aluminum phosphate 10%；
Iron oxide 2%；
Crisp ball element 17%；
Balance of quartz.
Embodiment 3：
Aluminum oxide 12%；
Calcite 9%；
Lime stone 20%；
Dolomite 10%；
Aluminum phosphate 11%；
Iron oxide 4%；
Crisp ball element 23%；
Balance of quartz.
Embodiment 4：
Aluminum oxide 9%；
Calcite 6%；
Lime stone 15%；
Dolomite 7%；
Aluminum phosphate 11%；
Iron oxide 3%；
Crisp ball element 23%；
Balance of quartz.
Embodiment 5：
Aluminum oxide 10%；
Calcite 7%；
Lime stone 18%；
Dolomite 8%；
Aluminum phosphate 10%；
Iron oxide 2.3%；
Crisp ball element 22%；
Balance of quartz.
When phosphoric acid aluminium content is 7% in formula, gained sample glaze paint is coarse, does not have metallic luster, and color is partially black, presents
Obvious raw burn；When its content increases to 8-12%, glaze paint becomes smooth, and metallic luster becomes strong, and colour generation is good, illustrates in the burning
Glaze can be melted completely at a temperature of, and preferable glazing effect is presented after cooling；But when its content increases to 13%, glaze paint goes out
Existing pin hole, coarse, glossiness declines, the obvious burning of its texture.
When iron oxide content is 0.8%, glazed metal gloss is slightly weak, dim in colour cast；When the content of iron oxide increases
During to 1%, gained glaze paint is smooth, and metallic luster is strong, and colour generation is good；When iron oxide content increases to 5%, the metallic luster of glaze paint
Do not changed significantly with texture, but when its content reaches 6%, glazed metal gloss weakens, and colour generation is slightly biased red.Work as oxidation
Iron content can obtain the preferable metal-lustrous glaze of glazing effect between 1-5%.
When crisp ball cellulose content is 14% in glaze, glaze paint glossiness is 66；When its content increases to 15%, glaze paint light
Damp degree linearly increases to 81；Then it is further continued for increasing the content of crisp ball element in glaze, glaze paint glossiness increase tends to-individual phase
To stationary value, therefore, the addition of crisp ball element is 15-25% in glaze.
General principle of the invention and principal character and advantages of the present invention, the technology of the industry has been shown and described above
Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention, the claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (5)
1. a kind of metal-lustrous glaze, it is characterised in that the material composition including following mass percent：
Aluminum oxide 8-12%；
Calcite 5-10%；
Lime stone 10-20%；
Dolomite 5-10%；
Aluminum phosphate 8-12%；
Iron oxide 1-5%；
Crisp ball element 15-25%；
Balance of quartz.
2. a kind of metal-lustrous glaze according to claim 1, it is characterised in that：
Aluminum oxide 10%；
Calcite 7%；
Lime stone 18%；
Dolomite 8%；
Aluminum phosphate 10%；
Iron oxide 2.3%；
Crisp ball element 22%；
Balance of quartz.
3. the preparation method of a kind of metal-lustrous glaze according to claim 1, it is characterised in that：Weighed respectively by proportion speed
Raw material, using ball mill ball milling, is raised to 1320 DEG C of maximum temperature, natural cooling after held for some time.
4. the preparation method of a kind of metal-lustrous glaze according to claim 3, it is characterised in that：Ball-milling Time is 30min.
5. the preparation method of a kind of metal-lustrous glaze according to claim 3, it is characterised in that：Using glaze method glazing,
Glazed thickness is about 1.0mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611061674.8A CN106810074A (en) | 2016-11-28 | 2016-11-28 | A kind of metal-lustrous glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611061674.8A CN106810074A (en) | 2016-11-28 | 2016-11-28 | A kind of metal-lustrous glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106810074A true CN106810074A (en) | 2017-06-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611061674.8A Pending CN106810074A (en) | 2016-11-28 | 2016-11-28 | A kind of metal-lustrous glaze and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111517825A (en) * | 2020-04-27 | 2020-08-11 | 佛山科学技术学院 | Ceramic glaze with metal texture and preparation method and application thereof |
| CN111792844A (en) * | 2020-08-11 | 2020-10-20 | 鲁山花瓷股份有限公司 | Gold glaze material and glazing method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935234A (en) * | 2010-09-28 | 2011-01-05 | 广东道氏标准制釉股份有限公司 | Low-temperature golden yellow metallic luster glaze and manufacturing method thereof |
| CN103833419A (en) * | 2014-01-02 | 2014-06-04 | 惠达卫浴股份有限公司 | Purple bronze glaze with metallic luster and preparation method thereof |
-
2016
- 2016-11-28 CN CN201611061674.8A patent/CN106810074A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935234A (en) * | 2010-09-28 | 2011-01-05 | 广东道氏标准制釉股份有限公司 | Low-temperature golden yellow metallic luster glaze and manufacturing method thereof |
| CN103833419A (en) * | 2014-01-02 | 2014-06-04 | 惠达卫浴股份有限公司 | Purple bronze glaze with metallic luster and preparation method thereof |
Non-Patent Citations (2)
| Title |
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| 刘欣等: "银灰色无铅金属光泽釉的研制", 《陶瓷学报》 * |
| 西北轻工业学院等编: "《陶瓷工艺学》", 30 April 1993 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111517825A (en) * | 2020-04-27 | 2020-08-11 | 佛山科学技术学院 | Ceramic glaze with metal texture and preparation method and application thereof |
| CN111792844A (en) * | 2020-08-11 | 2020-10-20 | 鲁山花瓷股份有限公司 | Gold glaze material and glazing method thereof |
| CN111792844B (en) * | 2020-08-11 | 2022-05-27 | 鲁山花瓷股份有限公司 | Gold glaze material and glazing method thereof |
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Application publication date: 20170609 |