CN106804555A - Application and its method of modifying of the metal ion-modified zeolite molecular sieve in mosquito is caught - Google Patents
Application and its method of modifying of the metal ion-modified zeolite molecular sieve in mosquito is caught Download PDFInfo
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- CN106804555A CN106804555A CN201710045702.5A CN201710045702A CN106804555A CN 106804555 A CN106804555 A CN 106804555A CN 201710045702 A CN201710045702 A CN 201710045702A CN 106804555 A CN106804555 A CN 106804555A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
- A01M1/023—Attracting insects by the simulation of a living being, i.e. emission of carbon dioxide, heat, sound waves or vibrations
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
- A01M1/04—Attracting insects by using illumination or colours
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Engineering & Computer Science (AREA)
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- General Life Sciences & Earth Sciences (AREA)
- Insects & Arthropods (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention discloses application of the metal ion-modified zeolite molecular sieve in mosquito is caught, metal ion-modified zeolite molecular sieve is placed in mosquito booby trap and is aided in or is predominantly lured mosquito.Method of modifying is comprised the following steps：Zeolite molecular sieve is packed into ion exchange column, to being passed through helium in ion exchange column；Dissolving metal salts are obtained into metal salt solution in deionized water, is reacted during metal salt solution is added into ion exchange column；Stop adding metal salt solution and using deionized water rinsing zeolite molecular sieve after reaction, then take out drying；To helium is passed through in dried zeolite molecular sieve, metal ion-modified zeolite molecular sieve is obtained.It is of the present invention to carry out luring mosquito using adsorb and desorb the metal ion-modified zeolite molecular sieve of carbon dioxide, fully the respective efficiency of carbon dioxide and air-flow is combined further with the air-flow of catching mosquito simultaneously, the sucking action for luring light source can also be utilized to realize the purpose of efficient mosquito killing.
Description
Technical field
The present invention relates to the technical field of killing mosquito, more particularly, it is related to a kind of metal ion-modified zeolite molecules
Sieve the application in mosquito is caught and method of modifying.
Background technology
Mosquito is the carrier of various cause of diseases, is propagated including the various diseases including malaria, dengue fever etc., the serious harm mankind
Health.Chemical synthesis medicament mosquito eradication is widely used at present, though the method has certain effect, chemical synthesis medicament exists potential
Pollution, influence of the excessive close contact to health for a long time can not be ignored.
Research shows：When target is found, what is relied primarily on is carbon dioxide, heat and some volatileization to mosquito
Material is learned, and the carbon dioxide receptor of mosquito can allow them that immediate reaction, only two are made to minimal amount of carbon dioxide
Carbonoxide can just attract mosquito, without the auxiliary of other smells.
As people are to the pursuit of high-quality healthy living and the raising of environmental consciousness, using the titanium dioxide in air
Carbon, carries out luring the method for mosquito-killing gradually to be paid attention to using harmless bionical mode.
The content of the invention
In order to solve the problems of the prior art, mosquito is being caught the invention provides a kind of metal ion-modified zeolite molecular sieve
In application and its method of modifying, so as to carry out luring mosquito-killing using harmless bionical mode.
One aspect of the present invention provides application of the metal ion-modified zeolite molecular sieve in mosquito is caught.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, by metal ion
Modified zeolite molecular sieve is placed in mosquito booby trap and aids in or predominantly lure mosquito.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the metal from
Sub- modified zeolite molecular sieve is obtained at least one zeolite molecular sieve in X-type, Y types, A types, β types, ZSM types is modified.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the metal from
Sub- modified zeolite molecular sieve is to react the zeolite molecular sieve by Metal Ions Modification to be formed using slaine and zeolite molecular sieve.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the metal from
Son is the one kind in calcium ion, potassium ion, lithium ion, magnesium ion and cesium ion, and the slaine is calcium, potassium, lithium, magnesium or caesium
One kind in chloride, sulfate, nitrate, carbonate, phosphate, chlorate and hydroxide.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the mosquito lures
Killing device includes：
Shell body；
Inner barrel, is arranged in the shell body, including top air inlet；
First wind-force unit, is arranged in the shell body and is located at the lower section of the inner barrel, and for described interior
The air inlet of cylinder produces the air-flow for entering the inner barrel；
Mosquito collector unit, is arranged on the shell body lower section and is located at the lower section of the first wind-force unit, with inner cylinder
The mosquito that body is connected and the air inlet for collecting from inner barrel enters；
Carbon dioxide enriched unit, is arranged in the shell body and is disposed adjacently with the inner barrel, and inside is set
There is heating unit, by positioned at the carbon dioxide enriched unit lower section and being arranged on the passage on shell body and connecting with air
Logical, top is carbon dioxide escape orifice, wherein, it is mounted with zeolite molecular sieve or modified zeolite in the carbon dioxide enriched unit
Molecular sieve；
Second wind-force unit, is arranged on the bottom of the carbon dioxide enriched unit and for the ventilation in the shell body
Hole produces the air-flow for entering the carbon dioxide enriched unit.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, described device is also
Light source is lured including mosquito, the mosquito lures light source to be arranged on the air inlet of the inner barrel.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the mosquito is drawn
It is CDC lamps, black light lamp, CCFL lamps or uviol lamp to lure light source.
According to one embodiment of application of the metal ion-modified zeolite molecular sieve of the invention in mosquito is caught, the mosquito is received
Collection unit is removably inserted into the lower section of the shell body and including the first collector and the second collector, and described first receives
Storage is the inverted round stage structure that entrance is big and outlet is small, and second collector is cuboid or cube structure, described first
Collector is sleeved in second collector, wherein, first collector also includes the filter screen around inverted round stage structure, institute
Stating the second collector also includes being located at the exhaust vent of outside portion.
Another aspect provides the method for modifying of above-mentioned metal ion-modified zeolite molecular sieve, its feature exists
In the method for modifying is comprised the following steps：
A, zeolite molecular sieve is packed into ion exchange column, to being passed through helium in ion exchange column；
B, dissolving metal salts are obtained into metal salt solution in deionized water, the metal salt solution is added into ion exchange
Reacted in post, wherein, the concentration of the metal salt solution is 0.1~0.8M；
Stop adding metal salt solution and using deionized water rinsing zeolite molecular sieve after C, reaction, then take out drying；
D, to helium is passed through in dried zeolite molecular sieve, obtain metal ion-modified zeolite molecular sieve.
One embodiment of method of modifying according to metal ion-modified zeolite molecular sieve of the invention, in step, helium
Be passed through speed for 50~500mL/min and be passed through the time for 0.5~2h；In stepb, control the reaction time for 60~
120min, controls the metal salt solution to be flowed out with the speed of 1~5mL/s；In step C, drying condition is to be risen in 1~2h
Temperature is to 250~500 DEG C of 24~36h of vacuum drying treatment；In step D, the speed that is passed through of helium is 50~500mL/min and leads to
The angle of incidence is 0.5~2h.
It is of the present invention to carry out luring mosquito to catch mosquito using adsorb and desorb the metal ion-modified zeolite molecular sieve of carbon dioxide,
On the one hand mosquito is lured using the characteristic of its carbon dioxide-enriched, while further with the air-flow of catching mosquito fully by two
The respective efficiency of carbonoxide and air-flow is combined, and can also utilize the sucking action for luring light source, and then realization efficiently catches and kills mosquito
The purpose of worm.Also, the ability of the zeolite molecular sieve absorbing carbon dioxide from air after method modified by this invention is modified
Have a distinct increment, and by after long-term adsorption-desorption cycle use, still keeping the absorption to carbon dioxide relatively stablized to conciliate
Energy-absorbing power.Carbon dioxide used in the present invention is existing material in air, does not result in carbon dioxide and produces and greenhouse effect
Should, while it is also harmless using bionical mode, have a good application prospect.
Brief description of the drawings
Fig. 1 shows the decomposition texture schematic diagram of mosquito booby trap according to an embodiment of the invention.
Fig. 2 shows the side structure schematic view of mosquito booby trap in Fig. 1.
Fig. 3 shows the overlooking the structure diagram of mosquito booby trap in Fig. 1.
Fig. 4 shows the decomposition texture schematic diagram of mosquito booby trap in accordance with another embodiment of the present invention.
Fig. 5 shows the side structure schematic view of mosquito booby trap in Fig. 4.
Fig. 6 shows the overlooking the structure diagram of mosquito booby trap in Fig. 4.
Description of reference numerals：
1- shell bodies, 2- inner barrels, the carbon dioxide enriched units of 3-, the second wind-force of 4- unit, the collectors of 5- first, 6-
Two collectors, 7- heating units, 8- passages, 9- power switches, the first wind-force of 10- unit, 11- lamp sockets, 12- bulbs, 13- lamps
Covered on cover, 14- exhaust vents, 15- photodiodes, 16- power interfaces, 17- filter screens, 18-.
Specific embodiment
All features disclosed in this specification, or disclosed all methods or during the step of, except mutually exclusive
Feature and/or step beyond, can combine by any way.
Any feature disclosed in this specification (including any accessory claim, summary and accompanying drawing), except non-specifically is chatted
State, can alternative features equivalent by other or with similar purpose replaced.I.e., unless specifically stated otherwise, each feature
It is an example in a series of equivalent or similar characteristics.
Existing utilization carbon dioxide catches mosquito product, it is common to use dioxide bottle, and not only source of the gas is difficult to obtain, and
There is potential safety hazard, can only use out of doors.
Zeolite molecular sieve (Zeolite) be it is a kind of be widely used in gas isolate and purify, ion exchange, the nothing of catalytic reaction
Machine crystalline material.There are some researches show, zeolite molecular sieve can be adsorbed and desorb carbon dioxide, and present invention discover that using metal from
The modified zeolite molecular sieve of son then has stronger carbon dioxide adsorption ability and makes by long-term adsorption-desorption cycle
The carbon dioxide adsorption and desorption ability relatively stablized are maintained to after.Therefore, it is of the invention by metal ion-modified zeolite
Molecular sieve is applied to catch mosquito.
Specifically, metal ion-modified zeolite molecular sieve is placed in mosquito booby trap and aids in or predominantly lure mosquito
Worm, then kills mosquito using mosquito booby trap.
The metal ion-modified zeolite molecular sieve used in the present invention reacts preferably with slaine and zeolite molecular sieve
The zeolite molecular sieve by Metal Ions Modification for being formed, is specifically as follows at least one in X-type, Y types, A types, β types, ZSM types
Zeolite molecular sieve is modified to be obtained, but the invention is not restricted to this.Wherein, above-mentioned metal ion can for calcium ion, potassium ion, lithium from
One kind in son, magnesium ion and cesium ion, above-mentioned slaine can be chloride, sulfate, the nitric acid of calcium, potassium, lithium, magnesium or caesium
One kind in salt, carbonate, phosphate, chlorate and hydroxide.
Invention also provides the method for modifying of above-mentioned metal ion-modified zeolite molecular sieve, example of the invention
Property embodiment, above-mentioned method of modifying is comprised the following steps：
Step A：
Zeolite molecular sieve is packed into ion exchange column, to being passed through helium in ion exchange column.Preferably, helium is logical
Enter speed for 50~500mL/min and be passed through the time for 0.5~2h.
The purpose of this step is to be excluded the air in ion exchange column, reducing its influence to subsequent reactions.
Step B：
Dissolving metal salts are obtained into metal salt solution in deionized water, is entered during metal salt solution is added into ion exchange column
Row reaction, wherein, the concentration of metal salt solution is 0.1~0.8M.
Above-mentioned slaine can be chloride, sulfate, nitrate, carbonate, the phosphoric acid for calcium, potassium, lithium, magnesium or caesium
One kind in salt, chlorate and hydroxide.
Metal ion in metal salt solution reacts to be formed by the zeolite molecular sieve of Metal Ions Modification with zeolite molecular sieve.
In this step, control the reaction time for 60~120min, control metal salt solution is flowed out with the speed of 1~5mL/s, to ensure
Fully reaction.
Step C：
Stop adding metal salt solution and using deionized water rinsing zeolite molecular sieve after reaction, then take out drying.Rinse
Zeolite molecular sieve is to remove unreacted metal salt solution, it is to avoid the harmful effect to zeolite molecular sieve.
Wherein, drying condition is preferably and 250~500 DEG C of 24~36h of vacuum drying treatment is warming up in 1~2h.
Step D：
To helium is passed through in dried zeolite molecular sieve, metal ion-modified zeolite molecular sieve is obtained.The mesh of this step
, contact of the air with modified zeolite molecular sieve is reduced before the drying.
Preferably, being passed through speed for 50~500mL/min and being passed through the time for 0.5~2h for helium is controlled.This gas velocity
Spending and be passed through the time can fully ensure that air has less contact with modified zeolite molecular sieve.
The present invention has been carried out under normal temperature and pressure to air respectively to zeolite molecular sieve and metal ion-modified zeolite molecular sieve
The absorption-desorption test of middle carbon dioxide and stability test.
Under the room temperature condition of relative humidity 70%, distinguish in zeolite molecular sieve and metal ion-modified zeolite molecular sieve
200 DEG C of desorption 1h are heated to after blowing air absorption 30min, the absorption-desorption amount of carbon dioxide is recorded, this absorption-desorption is repeated
Circulate operation, while the parallel performance change situation for carrying out testing and recording zeolite molecular sieve for 3 times.Wherein, it is metal ion-modified
Zeolite molecular sieve includes that metal calcium ion modification zeolite molecular sieve, metallic potassium ion modification zeolite molecular sieve, metal-lithium ion change
Property zeolite molecular sieve, magnesium metal ion modification zeolite molecular sieve and metal cesium ion modified zeolite molecular sieve.
Result is as shown in table 1, it is seen that zeolite molecular sieve has certain absorption-desorption ability to Carbon Dioxide in Air；
And metal ion-modified zeolite molecular sieve is compared with unmodified zeolite molecular sieve, its absorption-solution to Carbon Dioxide in Air
Energy-absorbing power maintains a long-term stability, and absorption-desorption amount, apparently higher than unmodified zeolite molecular sieve, rear data are with system before modified
Meter learns meaning.
The test result of table 1
Remarks：* p ＜ 0.05；* p ＜ 0.01, compared with zeolite molecular sieve before modified.
The metal ion-modified zeolite molecular sieve that the present invention is preferably possible to adsorb and desorb carbon dioxide is loaded in mosquito
In worm killing trapping device, the characteristics of sucking blood source can be found by carbon dioxide according to mosquito, will be carbon dioxide enriched in air
And discharge, the high local concentrations carbon dioxide of the air inlet of mosquito booby trap is caused, attract mosquito to be close to and draw mosquito
Lure to the axial direction of air inlet, quickly be sucked into mosquito booby trap mosquito by the air-flow for recycling axial direction to produce
Air-dry till death, complete the work that mosquito is killed in trapping.The carbon dioxide that the present invention is used derives from air, takes conveniently, does not increase
Plus the carbon dioxide in air, do not cause greenhouse effects.The mosquito booby trap that uses of the present invention can be in the prior art
Some devices, the mosquito booby trap of preferably following structures.
The structure and principle of the mosquito booby trap used to the present invention are described in detail below.
Fig. 1 shows the decomposition texture schematic diagram of mosquito booby trap according to an embodiment of the invention, and Fig. 2 shows
The side structure schematic view of mosquito booby trap in Fig. 1, Fig. 3 shows the overlooking the structure diagram of mosquito booby trap in Fig. 1.
As shown in Figure 1 to Figure 3, exemplary embodiment of the invention, the mosquito booby trap include shell body 1,
Inner barrel 2, the first wind-force unit 10, mosquito collector unit, the wind-force unit 4 of carbon dioxide enriched unit 3 and second.
Specifically, inner barrel 2 is arranged in shell body 1, and inner barrel 2 includes the air inlet on top, air-flow and mosquito
Enter in inner barrel 2 with by the air inlet.
First wind-force unit 10 is arranged in shell body 1 and is located at the lower section of inner barrel 2, and for the air intake in inner barrel 2
Mouth produces the air-flow for entering inner barrel 2.Wherein, the first wind-force unit 10 can make air enter inner cylinder heavily through air inlet
In body 2, then produce to the air-flow inside inner barrel 2.First wind-force unit 10 can be the components such as fan or air exhauster.
Mosquito collector unit is arranged on the lower section of shell body 1 and is located at the lower section of the first wind-force unit 10, and the mosquito is collected single
The mosquito that unit connects with inner barrel 2 and the air inlet for collecting from inner barrel 2 enters.According to one embodiment of present invention,
The mosquito collector unit includes the first collector 5 and the second collector 6, and the first collector 5 is the rounding that entrance is big and outlet is small
Platform structure, the second collector 6 is cuboid or cube structure, and the first collector 5 is sleeved in the second collector 6, wherein, the
One collector 5 also includes the filter screen 17 around inverted round stage structure, and the second collector 6 also includes the exhaust vent 14 positioned at outside portion.
But the invention is not restricted to the mosquito collector unit of said structure, as long as the collection to entering the mosquito in inner barrel 2 can be realized
Effect.Wherein, mosquito is inhaled into mosquito collector unit with the air-flow that the first wind-force unit 10 is produced, i.e., by first
Collector 5 simultaneously enters in the second collector 6, and mosquito air-dries till death in being left on the second collector 6, and air is then from the row of exhaust vent 14
Go out.As illustrated in fig. 1, it is preferred that mosquito collector unit is removably inserted into the lower section of shell body 1, it is possible thereby to easy cleaning
With safeguard mosquito collector unit.
Carbon dioxide enriched unit 3 is arranged in shell body 1 and is disposed adjacently with inner barrel 2, carbon dioxide enriched list
Unit 3 includes inner chamber body and being internally provided with heating unit 7, and it is by positioned at the lower section of carbon dioxide enriched unit 3 and setting outside
Passage 8 and atmosphere on housing 1, its top include upper lid 18, for carbon dioxide effusion.Wherein, it is carbon dioxide enriched
Above-mentioned zeolite molecular sieve or modified zeolite molecular sieve are mounted with unit 3.
That is, carbon dioxide enriched unit 3 is by being loaded in zeolite molecular sieve therein or modified zeolite molecular sieve come rich
Collection carbon dioxide simultaneously discharges carbon dioxide using the heating zeolite molecular sieve of heating unit 7 or modified zeolite molecular sieve, thus, it is possible to
It is enough to form the high local concentrations carbon dioxide of air inlet in apparatus of the present invention, thus attract mosquito near and by mosquito lure to
On the axial direction of air inlet, trapping is then sucked and realized by air-flow.Preferably, heating unit 7 is heating plate, resistance wire
Deng heating component.
Second wind-force unit 4 is arranged on the bottom of carbon dioxide enriched unit 3 and is produced for the passage 8 in shell body 1
The raw air-flow for entering carbon dioxide enriched unit 3.Second wind-force unit 4 can be the components such as fan or air exhauster.
After the second wind-force unit 4 is opened, air passage 8 from below enters in carbon dioxide enriched unit 3, loads
Zeolite molecular sieve or modified zeolite molecular sieve in carbon dioxide enriched unit 3 then adsorb the titanium dioxide in the air for passing through
Carbon, after a certain amount of carbon dioxide to be adsorbed, can close the second wind-force unit 4 and open heating unit 7, inhaled
The desorption of Annex II carbonoxide, carbon dioxide is then released into the air inlet of device especially inner barrel 2, is then enriched with and draws
Lure mosquito.
Fig. 4 shows the decomposition texture schematic diagram of mosquito booby trap in accordance with another embodiment of the present invention, and Fig. 5 shows
The side structure schematic view of mosquito booby trap in Fig. 4, Fig. 6 shows that the plan structure of mosquito booby trap in Fig. 4 is illustrated
Figure.As shown in Figures 4 to 6, another thinking of the invention, device of the invention can also lure light source including mosquito,
Mosquito lures light source to be arranged on the air inlet of inner barrel 2, and mosquito is lured by the way that carbon dioxide is combined with light source, can further carry
Height catches mosquito efficiency.Preferably, the airflow direction and mosquito that the first wind-force unit 10 is produced lure the light direction that light source sends out
Concentrate on the axial direction of inner barrel 2.On the one hand the carbon dioxide of enrichment and mosquito lure light source to lure to interior mosquito
On the axial direction of the air inlet of cylinder, on the other hand the first wind-force unit 10 will be lured to entering in the air-flow that axial direction is produced
Mosquito on the axial direction of air port is quickly sucked into mosquito collector unit and air-dries till death, largely improves trapping mosquito
Effect and realize the purpose of efficient mosquito killing.
Wherein, mosquito lure light source include lamp socket 11, bulb 12 and lampshade 13, bulb can be CDC lamps, black light lamp, purple
Outer lamp or CCFL lamps etc..
Device of the invention also includes power control unit, the first wind-force unit 10, the second wind-force unit 4, heating unit 7
Lure unit to be electrically connected with power control unit respectively to realize the effective control to device with mosquito.Wherein, power supply list
Unit at least includes photodiode 15, power interface 16 and power switch 9.
Due to zeolite molecular sieve absorbing carbon dioxide from air ability not as metal ion-modified zeolite molecular sieve from
The ability of absorbing carbon dioxide in air, so if what is loaded in mosquito booby trap of the invention is zeolite molecular sieve,
Then preferably while setting mosquito in a device lures light source, to improve attractant effect；If in mosquito booby trap of the invention
Middle loading is metal ion-modified zeolite molecular sieve, then can set mosquito and lure light source, it is also possible to be not provided with mosquito and lure
Light source.
With reference to specific embodiment, the invention will be further described.
Embodiment 1：The modified 10X type zeolite molecular sieves of calcium nitrate
(1) 700g 10X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 200mL/min
1h；
(2) by calcium nitrate deionized water dissolving, the calcium nitrate solution that concentration is 1.5M is obtained；
(3) calcium nitrate solution is added in ion exchange column, control valve makes calcium nitrate solution with the speed stream of 1mL/s
Go out；
(4) stop adding calcium nitrate solution after 70min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 300 DEG C are warming up in 1h and 24h is dried under vacuum；
(6) helium 1h is passed through with the speed of 300mL/min to dried zeolite molecular sieve, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 2：The modified 13X type zeolite molecular sieves of calcium chloride
(1) 700g 13X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 250mL/min
1.5h；
(2) by calcium chloride deionized water dissolving, the calcium chloride solution that concentration is 3.5M is obtained；
(3) calcium chloride solution is added in ion exchange column, control valve makes calcium chloride solution with the speed of 1.8mL/s
Outflow；
(4) stop adding calcium chloride solution after 85min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 350 DEG C are warming up in 1.5h and are dried under vacuum
24h；
(6) helium 1h is passed through with the speed of 200mL/min to dried zeolite molecular sieve, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 3：Calcium chlorate modified zeolite of Y-type molecular sieve
(1) 700g Y-type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 500mL/min
1.5h；
(2) by calcium chlorate deionized water dissolving, the chloric acid calcium solution that concentration is 1M is obtained；
(3) chloric acid calcium solution is added in ion exchange column, control valve makes chloric acid calcium solution with the speed stream of 5mL/s
Go out；
(4) stop adding chloric acid calcium solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 500 DEG C are warming up in 1.5h and 35h is vacuum dried；
(6) helium 1h is passed through with the speed of 200mL/min to dried zeolite molecular sieve, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 4：The modified 4A type zeolite molecular sieves of calcium chloride
(1) 300g 4A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 430mL/min
1.5h；
(2) by calcium chloride deionized water dissolving, the calcium chloride solution that concentration is 0.8M is obtained；
(3) calcium chloride solution is added in ion exchange column, control valve makes calcium chloride solution with the speed stream of 3mL/s
Go out；
(4) stop adding calcium chloride solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 450 DEG C are warming up in 1h and 36h is dried under vacuum；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 100mL/min, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 5：The modified 5A type zeolite molecular sieves of calcium nitrate
(1) 800g 5A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 450mL/min
1.5h；
(2) by calcium nitrate deionized water dissolving, the calcium nitrate solution that concentration is 0.5M is obtained；
(3) calcium nitrate solution is added in ion exchange column, control valve makes calcium nitrate solution with the speed stream of 4mL/s
Go out；
(4) stop adding calcium nitrate solution after 80min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 250 DEG C are warming up in 1.5h and 28h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 200mL/min, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 6：Calcium chlorate modified ZSM-5 type zeolite molecular sieve
(1) 700g ZSM-5 type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 350mL/min
1h；
(2) by calcium chlorate deionized water dissolving, the chloric acid calcium solution that concentration is 0.5M is obtained；
(3) chloric acid calcium solution is added in ion exchange column, control valve simultaneously makes chloric acid calcium solution with the speed of 3mL/s
Outflow；
(4) stop adding chloric acid calcium solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 400 DEG C are warming up in 1h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 400mL/min, modified completion obtains calcium metal
Ion modification zeolite molecular sieve.
Embodiment 7：The modified 10X type zeolite molecular sieves of potassium sulfate
(1) 200g 10X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 200mL/min
1h；
(2) by potassium sulfate deionized water dissolving, the potassium sulfate solution that concentration is 0.5M is obtained；
(3) potassium sulfate solution is added in ion exchange column, control valve simultaneously makes potassium sulfate solution with the speed of 1mL/s
Outflow；
(4) stop adding potassium sulfate solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 260 DEG C are warming up in 1h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 200mL/min, modified completion obtains metallic potassium
Ion modification zeolite molecular sieve.
Embodiment 8：The modified 13X type zeolite molecular sieves of potassium chloride
(1) 1000g 13X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 450mL/min
1.5h；
(2) by potassium chloride deionized water dissolving, the Klorvess Liquid that concentration is 2.5M is obtained；
(3) Klorvess Liquid is added in ion exchange column, control valve simultaneously makes Klorvess Liquid with the speed of 3.5mL/s
Degree outflow；
(4) stop adding Klorvess Liquid after 85min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 300 DEG C are warming up in 1.5h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 300mL/min, modified completion obtains metal
Potassium ion modified zeolite molecular sieve.
Embodiment 9：Potassium nitrate modified zeolite of Y-type molecular sieve
(1) 500g Y-type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 280mL/min
0.5h；
(2) by potassium nitrate deionized water dissolving, the potassium nitrate solution that concentration is 3.5M is obtained；
(3) potassium nitrate solution is added in ion exchange column, control valve simultaneously makes potassium nitrate solution with the speed of 3.3mL/s
Degree outflow；
(4) stop adding potassium nitrate solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 450 DEG C are warming up in 1h and 30h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 100mL/min, modified completion obtains metallic potassium
Ion modification zeolite molecular sieve.
Embodiment 10：Potassium carbonate modified 4A types zeolite molecular sieve
(1) 200g 4A type zeolite molecular sieves are fitted into ion exchange column, helium 2h is passed through with the speed of 350mL/min；
(2) by potassium carbonate deionized water dissolving, the solution of potassium carbonate that concentration is 7M is obtained；
(3) solution of potassium carbonate is added in ion exchange column, control valve simultaneously makes solution of potassium carbonate with the speed of 4.2mL/s
Degree outflow；
(4) stop adding solution of potassium carbonate after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 350 DEG C are warming up in 1.5h and 30h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 0.5h with the speed of 250mL/min, modified completion obtains metal
Potassium ion modified zeolite molecular sieve.
Embodiment 11：The modified 5A type zeolite molecular sieves of potassium phosphate
(1) 800g 5A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 400mL/min
0.5h；
(2) by potassium phosphate deionized water dissolving, the potassium phosphate solution that concentration is 1M is obtained；
(3) potassium phosphate solution is added in ion exchange column, control valve simultaneously makes potassium phosphate solution with the speed of 5mL/s
Outflow；
(4) stop adding potassium phosphate solution after 80min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 500 DEG C are warming up in 1h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 230mL/min, modified completion obtains metal
Potassium ion modified zeolite molecular sieve.
Embodiment 12：Potassium hydroxide modified ZSM-5 type zeolite molecular sieve
(1) 200g ZSM-5 type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 350mL/min
2h；
(2) by potassium hydroxide deionized water dissolving, the potassium hydroxide solution that concentration is 4M is obtained；
(3) potassium hydroxide solution is added in ion exchange column, control valve simultaneously makes potassium hydroxide solution with 1.7mL/s
Speed outflow；
(4) stop adding potassium hydroxide solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 400 DEG C are warming up in 1.5h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 100mL/min, modified completion obtains metallic potassium
Ion modification zeolite molecular sieve.
Embodiment 13：The modified 10X type zeolite molecular sieves of lithium sulfate
(1) 800g 10X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 270mL/min
1.5h；
(2) by lithium sulfate deionized water dissolving, the lithium sulfate solution that concentration is 2M is obtained；
(3) lithium sulfate solution is added in ion exchange column, control valve simultaneously makes lithium sulfate solution with the speed of 3mL/s
Outflow；
(4) stop adding lithium sulfate solution after 65min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 450 DEG C are warming up in 1h and 30h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 0.5h with the speed of 200mL/min, modified completion obtains metal
Lithium ion modified zeolite molecular sieve.
Embodiment 14：The modified 13X type zeolite molecular sieves of lithium chloride
(1) 500g 13X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 450mL/min
0.5h；
(2) by lithium chloride deionized water dissolving, the lithium chloride solution that concentration is 0.5M is obtained；
(3) lithium chloride solution is added in ion exchange column, control valve simultaneously makes lithium chloride solution with the speed of 4mL/s
Outflow；
(4) stop adding lithium chloride solution after 90min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 250 DEG C are warming up in 1.5h and 32h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 250mL/min, modified completion obtains lithium metal
Ion modification zeolite molecular sieve.
Embodiment 15：Lithium nitrate modified zeolite of Y-type molecular sieve
(1) 200g Y-type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 500mL/min
1.5h；
(2) by lithium nitrate deionized water dissolving, the lithium nitrate solution that concentration is 2M is obtained；
(3) lithium nitrate solution is added in ion exchange column, control valve simultaneously makes lithium sulfate solution with the speed of 2mL/s
Outflow；
(4) stop adding lithium nitrate solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 500 DEG C are warming up in 1.5h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 400mL/min, modified completion obtains lithium metal
Ion modification zeolite molecular sieve.
Embodiment 16：The modified 4A type zeolite molecular sieves of lithium sulfate
(1) 300g 4A type zeolite molecular sieves are fitted into ion exchange column, helium 2h is passed through with the speed of 300mL/min；
(2) by lithium sulfate deionized water dissolving, the lithium sulfate solution that concentration is 2.1M is obtained；
(3) lithium sulfate solution is added in ion exchange column, control valve simultaneously makes lithium sulfate solution with the speed of 3.5mL/s
Degree outflow；
(4) stop adding lithium sulfate solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 350 DEG C are warming up in 1h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 70mL/min, modified completion obtains metal
Lithium ion modified zeolite molecular sieve.
Embodiment 17：Lithium hydroxide modified 5A types zeolite molecular sieve
(1) 700g 5A type zeolite molecular sieves are fitted into ion exchange column, helium 1h is passed through with the speed of 270mL/min；
(2) by lithium hydroxide deionized water dissolving, the lithium hydroxide solution that concentration is 0.1M is obtained；
(3) lithium hydroxide solution is added in ion exchange column, control valve simultaneously makes lithium hydroxide solution with 1.7mL/s
Speed outflow；
(4) stop adding lithium hydroxide solution after 100min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 280 DEG C are warming up in 2h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 450mL/min, modified completion obtains lithium metal
Ion modification zeolite molecular sieve.
Embodiment 18：Lithium chloride modified ZSM-5 type zeolite molecular sieve
(1) 100g ZSM-5 type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 200mL/min
2h；
(2) by lithium chloride deionized water dissolving, the lithium chloride solution that concentration is 1.5M is obtained；
(3) lithium chloride solution is added in ion exchange column, control valve simultaneously makes lithium chloride solution with the speed of 3.3mL/s
Degree outflow；
(4) stop adding lithium chloride solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 320 DEG C are warming up in 1h and 30h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 400mL/min, modified completion obtains metal
Lithium ion modified zeolite molecular sieve.
Embodiment 19：The magnesium-modified 10X types zeolite molecular sieve of chlorination
(1) 800g 10X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 300mL/min
1h；
(2) by magnesium chloride deionized water dissolving, the magnesium chloride solution that concentration is 3M is obtained；
(3) magnesium chloride solution is added in ion exchange column, control valve simultaneously makes magnesium chloride solution with the speed of 1.5mL/s
Degree outflow；
(4) stop adding magnesium chloride solution after 100min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 310 DEG C are warming up in 1h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 200mL/min, modified completion obtains magnesium metal
Ion modification zeolite molecular sieve.
Embodiment 20：The magnesium-modified 13X types zeolite molecular sieve of sulfuric acid
(1) 500g 13X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 300mL/min
1h；
(2) by magnesium sulfate deionized water dissolving, the Adlerika that concentration is 2.6M is obtained；
(3) Adlerika is added in ion exchange column, control valve simultaneously makes Adlerika with the speed of 3.5mL/s
Degree outflow；
(4) stop adding Adlerika after 65min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 450 DEG C are warming up in 1h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 350mL/min, modified completion obtains magnesium metal
Ion modification zeolite molecular sieve.
Embodiment 21：Magnesium nitrate modified zeolite of Y-type molecular sieve
(1) 500g Y-type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 350mL/min
0.5h；
(2) by magnesium nitrate deionized water dissolving, the magnesium nitrate solution that concentration is 2.5M is obtained；
(3) magnesium nitrate solution is added in ion exchange column, control valve simultaneously makes magnesium nitrate solution with the speed of 1mL/s
Outflow；
(4) stop adding magnesium nitrate solution after 90min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 260 DEG C are warming up in 2h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 0.5h with the speed of 330mL/min, modified completion obtains metal
Magnesium ion modified zeolite molecular sieve.
Embodiment 22：The magnesium-modified 4A types zeolite molecular sieve of nitric acid
(1) 1000g 4A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 300mL/min
1h；
(2) by magnesium nitrate deionized water dissolving, the magnesium nitrate solution that concentration is 1.8M is obtained；
(3) magnesium nitrate solution is added in ion exchange column, control valve simultaneously makes magnesium nitrate solution with the speed of 3mL/s
Outflow；
(4) stop adding magnesium nitrate solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 300 DEG C are warming up in 1.5h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 300mL/min, modified completion obtains magnesium metal
Ion modification zeolite molecular sieve.
Embodiment 23：The magnesium-modified 5A types zeolite molecular sieve of chlorination
(1) 200g 5A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 270mL/min
1.5h；
(2) by magnesium chloride deionized water dissolving, the magnesium chloride solution that concentration is 0.5M is obtained；
(3) magnesium chloride solution is added in ion exchange column, control valve simultaneously makes magnesium chloride solution with the speed of 1.5mL/s
Degree outflow；
(4) stop adding magnesium chloride solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 450 DEG C are warming up in 2h and 30h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 300mL/min, modified completion obtains metal
Magnesium ion modified zeolite molecular sieve.
Embodiment 24：Magnesium sulfate modified ZSM-5 type zeolite molecular sieve
(1) 100g ZSM-5 type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 500mL/min
0.5h；
(2) by magnesium sulfate deionized water dissolving, the Adlerika that concentration is 1.3M is obtained；
(3) Adlerika is added in ion exchange column, control valve simultaneously makes Adlerika with the speed of 1mL/s
Outflow；
(4) stop adding Adlerika after 90min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 500 DEG C are warming up in 1.5h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 200mL/min, modified completion obtains magnesium metal
Ion modification zeolite molecular sieve.
Embodiment 25：The modified 10X type zeolite molecular sieves of cesium sulfate
(1) 200g 10X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 400mL/min
1h；
(2) by cesium sulfate deionized water dissolving, the cesium sulfate solution that concentration is 1M is obtained；
(3) cesium sulfate solution is added in ion exchange column, control valve simultaneously makes cesium sulfate solution with the speed of 1.5mL/s
Degree outflow；
(4) stop adding cesium sulfate solution after 90min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 400 DEG C are warming up in 1.5h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1.5h with the speed of 200mL/min, modified completion obtains metal
Cesium ion modified zeolite molecular sieve.
Embodiment 26：The modified 13X type zeolite molecular sieves of cesium chloride
(1) 500g 13X type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 200mL/min
0.5h；
(2) by cesium chloride deionized water dissolving, the cesium chloride solution that concentration is 0.2M is obtained；
(3) cesium chloride solution is added in ion exchange column, control valve simultaneously makes cesium chloride solution with the speed of 1mL/s
Outflow；
(4) stop adding cesium chloride solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 300 DEG C are warming up in 2h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 0.5h with the speed of 200mL/min, modified completion obtains metal
Cesium ion modified zeolite molecular sieve.
Embodiment 27：Cesium nitrate modified zeolite of Y-type molecular sieve
(1) 550g Y-type zeolite molecular sieves are fitted into ion exchange column, helium 1h is passed through with the speed of 450mL/min；
(2) by cesium nitrate deionized water dissolving, the cesium nitrate solution that concentration is 0.8M is obtained；
(3) cesium nitrate solution is added in ion exchange column, control valve simultaneously makes cesium nitrate solution with the speed of 4.5mL/s
Degree outflow；
(4) stop adding cesium nitrate solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 300 DEG C are warming up in 1.5h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 2h with the speed of 300mL/min, modified completion obtains metal caesium
Ion modification zeolite molecular sieve.
Embodiment 28：The modified 4A type zeolite molecular sieves of cesium carbonate
(1) 900g 4A type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 200mL/min
1.5h；
(2) by cesium carbonate deionized water dissolving, the cesium carbonate solution that concentration is 0.6M is obtained；
(3) cesium carbonate solution is added in ion exchange column, control valve simultaneously makes cesium carbonate solution with the speed of 4mL/s
Outflow；
(4) stop adding cesium carbonate solution after 100min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 250 DEG C are warming up in 1h and 28h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 0.5h with the speed of 400mL/min, modified completion obtains metal
Cesium ion modified zeolite molecular sieve.
Embodiment 29：The modified 5A type zeolite molecular sieves of cesium sulfate
(1) 300g 5A type zeolite molecular sieves are fitted into ion exchange column, helium 1h is passed through with the speed of 300mL/min；
(2) by cesium sulfate deionized water dissolving, the cesium sulfate solution that concentration is 1.5M is obtained；
(3) cesium sulfate solution is added in ion exchange column, control valve simultaneously makes cesium sulfate solution with the speed of 5mL/s
Outflow；
(4) stop adding cesium sulfate solution after 60min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 380 DEG C are warming up in 1h and 36h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 50mL/min, modified completion obtains metal caesium
Ion modification zeolite molecular sieve.
Embodiment 30：Cesium chloride modified ZSM-5 type zeolite molecular sieve
(1) 200g ZSM-5 type zeolite molecular sieves are fitted into ion exchange column, helium is passed through with the speed of 500mL/min
0.5h；
(2) by cesium chloride deionized water dissolving, the cesium chloride solution that concentration is 0.5M is obtained；
(3) cesium chloride solution is added in ion exchange column, control valve simultaneously makes cesium chloride solution with the speed of 4mL/s
Outflow；
(4) stop adding cesium chloride solution after 120min, use deionized water rinsing zeolite molecular sieve；
(5) will be taken out with the zeolite molecular sieve of deionized water rinsing, 280 DEG C are warming up in 1h and 24h is vacuum dried；
(6) dried zeolite molecular sieve is passed through helium 1h with the speed of 100mL/min, modified completion obtains metal caesium
Ion modification zeolite molecular sieve.
Experimental example 1：Zeolite molecular sieve is tested with the application effect of metal ion-modified zeolite molecular sieve
The mosquito booby trap that the present embodiment is used is the structure shown in Fig. 4 to Fig. 6, and light source is lured which provided mosquito
And bulb is CDC lamps.
Inventor is according to GB《GB/T 27785-2011 hygienic biocide apparatuses efficacy in laboratory determines and evaluates electronics and goes out
Mosquitos and flies device》It is tested, 150g is unmodified not to load zeolite molecular sieve, loading in the mosquito booby trap of the present embodiment
Zeolite molecular sieve, loading each metal ion-modified zeolite molecular sieves of 150g (are respectively adopted calcium nitrate, potassium chloride, lithium sulfate, chlorination
Magnesium, cesium sulfate are modified) catch mosquito contrast and experiment as shown in table 2 and table 3, it is seen that metal ion-modified zeolite molecular sieve
Setting substantially increase mosquito booby trap lure mosquito effect, and metal ion-modified zeolite molecular sieve in the present embodiment mosquito
The mosquito effect that lures in worm killing trapping device lures mosquito effect better than unmodified zeolite molecular sieve, uses data before and after zeolite molecular sieve
With statistical significance.
The partial results for luring mosquito measure of merit of mosquito booby trap in the experimental example 1 of table 2
The partial results for luring mosquito measure of merit of mosquito booby trap in the experimental example 1 of table 3
Remarks：* p ＜ 0.01；Compared with not loading zeolite molecular sieve and only using photo-induction.
##p ＜ 0.01；Compared with " photo-induction+unmodified zeolite molecular sieve ".
Experimental example 2：Zeolite molecular sieve is tested with the application effect of metal ion-modified zeolite molecular sieve
The mosquito booby trap for using is the structure shown in Fig. 1 to Fig. 3, wherein being not provided with mosquito lures light source.
Inventor is according to GB《GB/T 27785-2011 hygienic biocide apparatuses efficacy in laboratory determines and evaluates electronics and goes out
Mosquitos and flies device》Be tested, loaded respectively in the mosquito booby trap of the present embodiment the unmodified zeolite molecular sieves of 150g and
Each metal ion-modified zeolite molecular sieves of 150g (are respectively adopted calcium nitrate, potassium chloride, lithium sulfate, magnesium chloride, cesium sulfate to be changed
Property) to catch mosquito contrast and experiment as shown in table 3, it is seen that the mosquito that lures that the setting of zeolite molecular sieve improves mosquito booby trap is imitated
Really, and metal ion-modified zeolite molecular sieve in the present embodiment mosquito booby trap lure mosquito effect be better than unmodified boiling
Stone molecular sieve lures mosquito effect, before modified after data there is statistical significance.
Mosquito booby trap lures mosquito measure of merit result in the experimental example 2 of table 3
Remarks：* p ＜ 0.01, compared with unmodified zeolite molecular sieve.
In sum, it is of the present invention to be carried out using adsorb and desorb the metal ion-modified zeolite molecular sieve of carbon dioxide
Lure mosquito to catch mosquito, on the one hand lure mosquito using the characteristic of its carbon dioxide-enriched, while further with the air-flow of catching mosquito
Fully the respective efficiency of carbon dioxide and air-flow is combined, the sucking action for luring light source can also be utilized, and then realize
The purpose of efficient mosquito killing.Also, the zeolite molecular sieve after method modified by this invention is modified adsorbs dioxy from air
The ability for changing carbon has a distinct increment, and by after long-term adsorption-desorption cycle use, still keeping relatively stablizing to carbon dioxide
Absorption and desorption ability.Carbon dioxide used in the present invention is existing material in air, does not result in carbon dioxide product
Raw and greenhouse effects, at the same it is also harmless using bionical mode, have a good application prospect.
The invention is not limited in foregoing specific embodiment.The present invention is expanded to and any in this manual disclosed
New feature or any new combination, and disclose any new method or process the step of or any new combination.
Claims (11)
1. application of the metal ion-modified zeolite molecular sieve in mosquito is caught.
2. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 1, it is characterised in that by metal
Ion modification zeolite molecular sieve is placed in mosquito booby trap and aids in or predominantly lure mosquito.
3. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 1, it is characterised in that the gold
Category ion modification zeolite molecular sieve is obtained at least one zeolite molecular sieve in X-type, Y types, A types, β types, ZSM types is modified.
4. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 3, it is characterised in that the gold
Category ion modification zeolite molecular sieve is to react the zeolite by Metal Ions Modification to be formed point using slaine and zeolite molecular sieve
Son sieve.
5. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 4, it is characterised in that the gold
Category ion be calcium ion, potassium ion, lithium ion, magnesium ion and cesium ion in one kind, the slaine be calcium, potassium, lithium, magnesium or
One kind in the chloride of caesium, sulfate, nitrate, carbonate, phosphate, chlorate and hydroxide.
6. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 2, it is characterised in that the mosquito
Worm killing trapping device includes：
Shell body；
Inner barrel, is arranged in the shell body, including top air inlet；
First wind-force unit, is arranged in the shell body and is located at the lower section of the inner barrel, and in the inner barrel
Air inlet produce enter the inner barrel air-flow；
Mosquito collector unit, is arranged on the shell body lower section and is located at the lower section of the first wind-force unit, connects with inner barrel
The mosquito that logical and for collecting from inner barrel air inlet enters；
Carbon dioxide enriched unit, is arranged in the shell body and is disposed adjacently with the inner barrel, is internally provided with and adds
Hot cell, by positioned at the carbon dioxide enriched unit lower section and being arranged on the passage on shell body and atmosphere, pushes up
Portion is carbon dioxide escape orifice, wherein, zeolite molecular sieve or modified zeolite molecule are mounted with the carbon dioxide enriched unit
Sieve；
Second wind-force unit, is arranged on the bottom of the carbon dioxide enriched unit and is produced for the passage in the shell body
The raw air-flow for entering the carbon dioxide enriched unit.
7. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 6, it is characterised in that the dress
Put and also lure light source including mosquito, the mosquito lures light source to be arranged on the air inlet of the inner barrel.
8. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 7, it is characterised in that the mosquito
It is CDC lamps, black light lamp, CCFL lamps or uviol lamp that worm lures light source.
9. application of the metal ion-modified zeolite molecular sieve in mosquito is caught according to claim 6, it is characterised in that the mosquito
Worm collector unit is removably inserted into the lower section of the shell body and including the first collector and the second collector, described
One collector is entrance big and export small inverted round stage structure, and second collector is cuboid or cube structure, described
First collector is sleeved in second collector, wherein, first collector also includes the filter around inverted round stage structure
Net, second collector also includes the exhaust vent positioned at outside portion.
10. the method for modifying of the metal ion-modified zeolite molecular sieve as described in any one of claim 1 to 9, its feature exists
In the method for modifying is comprised the following steps：
A, zeolite molecular sieve is packed into ion exchange column, to being passed through helium in ion exchange column；
B, dissolving metal salts are obtained into metal salt solution in deionized water, during the metal salt solution added into ion exchange column
Reacted, wherein, the concentration of the metal salt solution is 0.1~0.8M；
Stop adding metal salt solution and using deionized water rinsing zeolite molecular sieve after C, reaction, then take out drying；
D, to helium is passed through in dried zeolite molecular sieve, obtain metal ion-modified zeolite molecular sieve.
The method of modifying of 11. metal ion-modified zeolite molecular sieves according to claim 10, it is characterised in that in step A
In, the speed that is passed through of helium is 50~500mL/min and is passed through the time for 0.5~2h；In stepb, the reaction time is controlled to be
60~120min, controls the metal salt solution to be flowed out with the speed of 1~5mL/s；In step C, drying condition is in 1~2h
Inside it is warming up to 250~500 DEG C of 24~36h of vacuum drying treatment；In step D, the speed that is passed through of helium is 50~500mL/min
And the time is passed through for 0.5~2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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