CN106818675A - The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught - Google Patents
The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught Download PDFInfo
- Publication number
- CN106818675A CN106818675A CN201710045776.9A CN201710045776A CN106818675A CN 106818675 A CN106818675 A CN 106818675A CN 201710045776 A CN201710045776 A CN 201710045776A CN 106818675 A CN106818675 A CN 106818675A
- Authority
- CN
- China
- Prior art keywords
- molecular sieve
- zeolite molecular
- mosquito
- modified
- helium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
- A01M1/04—Attracting insects by using illumination or colours
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Insects & Arthropods (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught, zeolite molecular sieve or modified zeolite molecular sieve are placed in mosquito booby trap and are aided in or is predominantly lured mosquito.The method of modifying of modified zeolite molecular sieve is comprised the following steps：Zeolite molecular sieve is packed into reactor, to being passed through helium in reactor；Make helium by the bubbler containing amines, then the helium containing saturation amines steam is passed through in reactor；Again to helium is passed through in reactor to remove the amines with zeolite molecular sieve weak binding, modified zeolite molecular sieve is obtained.It is of the present invention to carry out luring mosquito to catch mosquito using adsorb and desorb the zeolite molecular sieve or modified zeolite molecular sieve of carbon dioxide, mosquito is lured using the characteristic of its carbon dioxide-enriched, fully the respective efficiency of carbon dioxide and air-flow is combined further with the air-flow of catching mosquito simultaneously, the sucking action for luring light source can also be utilized, and then realizes the purpose of efficient mosquito killing.
Description
Technical field
The present invention relates to the technical field of killing mosquito, more particularly, it is related to a kind of zeolite molecular sieve or modified zeolite
Application and method of modifying of the molecular sieve in mosquito is caught.
Background technology
Mosquito is the carrier of various cause of diseases, is propagated including the various diseases including malaria, dengue fever etc., the serious harm mankind
Health.Chemical synthesis medicament mosquito eradication is widely used at present, though the method has certain effect, chemical synthesis medicament exists potential
Pollution, influence of the excessive close contact to health for a long time can not be ignored.
Research shows：When target is found, what is relied primarily on is carbon dioxide, heat and some volatileization to mosquito
Material is learned, and the carbon dioxide receptor of mosquito can allow them that immediate reaction, only two are made to minimal amount of carbon dioxide
Carbonoxide can just attract mosquito, without the auxiliary of other smells.
As people are to the pursuit of high-quality healthy living and the raising of environmental consciousness, using the titanium dioxide in air
Carbon, carries out luring the method for mosquito-killing gradually to be paid attention to using harmless bionical mode.
The content of the invention
In order to solve the problems of the prior art, exist the invention provides a kind of zeolite molecular sieve or modified zeolite molecular sieve
The application in mosquito and its method of modifying are caught, so as to carry out luring mosquito-killing using harmless bionical mode.
One aspect of the present invention provides the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, by zeolite
Molecular sieve or modified zeolite molecular sieve are placed in mosquito booby trap and aid in or predominantly lure mosquito.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the boiling
Stone molecular sieve is at least one in X-type, Y types, A types, β types, ZSM types, and the modified zeolite molecular sieve is X-type, Y types, A types, β
At least one in type, ZSM types is modified and obtains.
It is described to change according to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught
Property zeolite molecular sieve is the zeolite molecules for including primary amine and/or secondary amine formed using amines modification of zeolite molecular sieve
Sieve.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the amine
Compound is ethylenediamine, MEA, TEPA, trien, three (2- aminoethyls) amine and diethylenetriamines
In one kind.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the mosquito
Worm killing trapping device includes：
Shell body；
Inner barrel, is arranged in the shell body, including top air inlet；
First wind-force unit, is arranged in the shell body and is located at the lower section of the inner barrel, and for described interior
The air inlet of cylinder produces the air-flow for entering the inner barrel；
Mosquito collector unit, is arranged on the shell body lower section and is located at the lower section of the first wind-force unit, with inner cylinder
The mosquito that body is connected and the air inlet for collecting from inner barrel enters；
Carbon dioxide enriched unit, is arranged in the shell body and is disposed adjacently with the inner barrel, and inside is set
There is heating unit, by positioned at the carbon dioxide enriched unit lower section and being arranged on the passage on shell body and connecting with air
Logical, top is carbon dioxide escape orifice, wherein, it is mounted with zeolite molecular sieve or modified zeolite in the carbon dioxide enriched unit
Molecular sieve；
Second wind-force unit, is arranged on the bottom of the carbon dioxide enriched unit and for the ventilation in the shell body
Hole produces the air-flow for entering the carbon dioxide enriched unit.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the dress
Put and also lure light source including mosquito, the mosquito lures light source to be arranged on the air inlet of the inner barrel.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the mosquito
It is CDC lamps, black light lamp, CCFL lamps or uviol lamp that worm lures light source.
According to one embodiment of the application of zeolite molecular sieve of the present invention or modified zeolite molecular sieve in mosquito is caught, the mosquito
Worm collector unit is removably inserted into the lower section of the shell body and including the first collector and the second collector, described
One collector is entrance big and export small inverted round stage structure, and second collector is cuboid or cube structure, described
First collector is sleeved in second collector, wherein, first collector also includes the filter around inverted round stage structure
Net, second collector also includes the exhaust vent positioned at outside portion.
Another aspect provides the method for modifying of above-mentioned modified zeolite molecular sieve, it is characterised in that described to change
Property method is comprised the following steps：
A, zeolite molecular sieve is packed into reactor, to being passed through helium in reactor；
B, make helium by the bubbler containing amines, be then passed through the helium containing saturation amines steam
In reactor, the time is passed through for 30~60min；
C, again to helium is passed through in reactor to remove the amines with zeolite molecular sieve weak binding, obtain modified zeolite
Molecular sieve.
One embodiment of method of modifying according to modified zeolite molecular sieve of the present invention, in step A and step B, helium
The speed that is passed through with the helium containing saturation amines steam is 50~500mL/min；In step C, when being passed through of helium
Between be 12~24h.
It is of the present invention to carry out luring mosquito using adsorb and desorb the zeolite molecular sieve or modified zeolite molecular sieve of carbon dioxide
Mosquito is caught, on the one hand mosquito is lured using the characteristic of its carbon dioxide-enriched, while abundant further with the air-flow of catching mosquito
Be combined for the respective efficiency of carbon dioxide and air-flow by ground, can also utilize the sucking action for luring light source, and then realize efficient
The purpose of mosquito killing.Also, the absorbing carbon dioxide from air of the zeolite molecular sieve after method modified by this invention is modified
Ability have a distinct increment, and by after long-term adsorption-desorption cycle use, still keeping the suction to carbon dioxide relatively stablized
Echo desorption ability.Carbon dioxide used in the present invention be air in existing material, do not result in carbon dioxide produce and
Greenhouse effects, at the same it is also harmless using bionical mode, have a good application prospect.
Brief description of the drawings
Fig. 1 shows the decomposition texture schematic diagram of mosquito booby trap according to an embodiment of the invention.
Fig. 2 shows the side structure schematic view of mosquito booby trap in Fig. 1.
Fig. 3 shows the overlooking the structure diagram of mosquito booby trap in Fig. 1.
Fig. 4 shows the decomposition texture schematic diagram of mosquito booby trap in accordance with another embodiment of the present invention.
Fig. 5 shows the side structure schematic view of mosquito booby trap in Fig. 4.
Fig. 6 shows the overlooking the structure diagram of mosquito booby trap in Fig. 4.
Description of reference numerals：
1- shell bodies, 2- inner barrels, the carbon dioxide enriched units of 3-, the second wind-force of 4- unit, the collectors of 5- first, 6-
Two collectors, 7- heating units, 8- passages, 9- power switches, the first wind-force of 10- unit, 11- lamp sockets, 12- bulbs, 13- lamps
Covered on cover, 14- exhaust vents, 15- photodiodes, 16- power interfaces, 17- filter screens, 18-.
Specific embodiment
All features disclosed in this specification, or disclosed all methods or during the step of, except mutually exclusive
Feature and/or step beyond, can combine by any way.
Any feature disclosed in this specification (including any accessory claim, summary and accompanying drawing), except non-specifically is chatted
State, can alternative features equivalent by other or with similar purpose replaced.I.e., unless specifically stated otherwise, each feature
It is an example in a series of equivalent or similar characteristics.
Existing utilization carbon dioxide catches mosquito product, it is common to use dioxide bottle, and not only source of the gas is difficult to obtain, and
There is potential safety hazard, can only use out of doors.
Zeolite molecular sieve (Zeolite) be it is a kind of be widely used in gas isolate and purify, ion exchange, the nothing of catalytic reaction
Machine crystalline material.There are some researches show zeolite molecular sieve can be adsorbed and desorb carbon dioxide, and present invention discover that modified boiling
Stone molecular sieve then has stronger carbon dioxide adsorption ability and is remained able to after by long-term adsorption-desorption cycle
Keep relatively stable carbon dioxide adsorption and desorption ability.Therefore, the present invention should by zeolite molecular sieve or modified zeolite molecular sieve
For catching mosquito.
Specifically, zeolite molecular sieve or modified zeolite molecular sieve are placed in mosquito booby trap and aid in or predominantly lure
Mosquito, then kills mosquito using mosquito booby trap.
The zeolite molecular sieve used in the present invention is at least one in X-type, Y types, A types, β types, ZSM types.
The bag that the modified zeolite molecular sieve used in the present invention is formed preferably with amines modification of zeolite molecular sieve
The zeolite molecular sieve of primary amine and/or secondary amine is included, at least one being specifically as follows in X-type, Y types, A types, β types, ZSM types is modified
Obtain, but the invention is not restricted to this, it would however also be possible to employ the modified zeolite molecular sieve of other methods.Wherein, the amines is
One kind in ethylenediamine, MEA, TEPA, trien, three (2- aminoethyls) amine and diethylenetriamines.
Invention also provides the method for modifying of above-mentioned modified zeolite molecular sieve, exemplary implementation of the invention
Example, above-mentioned method of modifying is comprised the following steps：
Step A：
Zeolite molecular sieve is packed into reactor, to being passed through helium in reactor.
The purpose of this step is to by the air discharge in reactor, make subsequent reactions be carried out under helium environment.
Step B：
Make helium by the bubbler containing amines, be then passed through anti-the helium containing saturation amines steam
Answer in device, be passed through the time for 30~60min.
In this step, zeolite molecular sieve reacts to form primary amine and/or secondary amine with the amines entrained by helium,
And then form the zeolite molecular sieve for including primary amine and/or secondary amine.Wherein it is preferred to carry out this using ethylenediamine or MEA
That invents is modified.
Step C：
Again to being passed through helium in reactor to remove the amines with zeolite molecular sieve weak binding, modified zeolite point is obtained
Son sieve.
Preferably, in step A and step B, control helium and helium containing saturation amines steam are passed through speed
It is 50~500mL/min to spend, and to ensure that the air in reactor is fully discharged, and amines steam fills with zeolite molecular sieve
Divide reaction；In step C, control helium is passed through the time for 12~24h, to ensure the amination with zeolite molecular sieve weak binding
Compound is removed completely.
The present invention has been carried out under normal temperature and pressure to titanium dioxide in air respectively to zeolite molecular sieve and modified zeolite molecular sieve
The absorption-desorption test of carbon and stability test.
Under the room temperature condition of relative humidity 70%, adsorbed to blowing air in zeolite molecular sieve or modified zeolite molecular sieve
200 DEG C of desorption 1h are heated to after 30min, the absorption-desorption amount of carbon dioxide is recorded, the operation of this adsorption-desorption cycle is repeated, together
Shi Pinghang carries out 3 times and tests and record zeolite molecular sieve performance change situation.Wherein, modified zeolite molecular sieve is zeolite molecular sieve
Obtained with ethylenediamine and MEA reaction respectively.
Result is as shown in table 1, it is seen that zeolite molecular sieve has certain absorption-desorption ability to Carbon Dioxide in Air；
And modified zeolite molecular sieve, compared with unmodified zeolite molecular sieve, its absorption-desorption to Carbon Dioxide in Air can try hard to keep
Hold steady in a long-term, and absorption-desorption amount, apparently higher than unmodified zeolite molecular sieve, there is data statistics to anticipate afterwards before modified
Justice.
The test result of table 1
Remarks：* p ＜ 0.05；* p ＜ 0.01, compared with zeolite molecular sieve before modified.
The zeolite molecular sieve or modified zeolite molecular sieve that the present invention is preferably possible to adsorb and desorb carbon dioxide are loaded
In mosquito booby trap, the characteristics of sucking blood source can be found by carbon dioxide according to mosquito, by the carbon dioxide in air
It is enriched with and discharges, cause the high local concentrations carbon dioxide of the air inlet of mosquito booby trap, attracts mosquito near and by mosquito
Worm is lured to the axial direction of air inlet, and mosquito is quickly sucked into the air-flow for recycling axial direction to produce mosquito traping and killing dress
Put the interior work for air-drying till death, completing trapping killing mosquito.The carbon dioxide that the present invention is used derives from air, takes conveniently,
Do not increase the carbon dioxide in air, do not cause greenhouse effects.The mosquito booby trap that the present invention is used can be prior art
In existing device, the mosquito booby trap of preferably following structures.
The structure and principle of the mosquito booby trap used to the present invention are described in detail below.
Fig. 1 shows the decomposition texture schematic diagram of mosquito booby trap according to an embodiment of the invention, and Fig. 2 shows
The side structure schematic view of mosquito booby trap in Fig. 1, Fig. 3 shows the overlooking the structure diagram of mosquito booby trap in Fig. 1.
As shown in Figure 1 to Figure 3, exemplary embodiment of the invention, the mosquito booby trap include shell body 1,
Inner barrel 2, the first wind-force unit 10, mosquito collector unit, the wind-force unit 4 of carbon dioxide enriched unit 3 and second.
Specifically, inner barrel 2 is arranged in shell body 1, and inner barrel 2 includes the air inlet on top, air-flow and mosquito
Enter in inner barrel 2 with by the air inlet.
First wind-force unit 10 is arranged in shell body 1 and positioned at the lower section of inner barrel 2, and for the air intake in inner barrel 2
Mouth produces the air-flow for entering inner barrel 2.Wherein, the first wind-force unit 10 can make air enter inner cylinder heavily through air inlet
In body 2, then produce to the air-flow inside inner barrel 2.First wind-force unit 10 can be the components such as fan or air exhauster.
Mosquito collector unit is arranged on the lower section of shell body 1 and is located at the lower section of the first wind-force unit 10, and the mosquito is collected single
The mosquito that unit connects with inner barrel 2 and the air inlet for collecting from inner barrel 2 enters.According to one embodiment of present invention,
The mosquito collector unit includes the first collector 5 and the second collector 6, and the first collector 5 is the rounding that entrance is big and outlet is small
Platform structure, the second collector 6 is cuboid or cube structure, and the first collector 5 is sleeved in the second collector 6, wherein, the
One collector 5 also includes the filter screen 17 around inverted round stage structure, and the second collector 6 also includes the exhaust vent 14 positioned at outside portion.
But the invention is not restricted to the mosquito collector unit of said structure, as long as the collection to entering the mosquito in inner barrel 2 can be realized
Effect.Wherein, mosquito is inhaled into mosquito collector unit with the air-flow that the first wind-force unit 10 is produced, i.e., by first
Collector 5 simultaneously enters in the second collector 6, and mosquito air-dries till death in being left on the second collector 6, and air is then from the row of exhaust vent 14
Go out.As illustrated in fig. 1, it is preferred that mosquito collector unit is removably inserted into the lower section of shell body 1, it is possible thereby to easy cleaning
With safeguard mosquito collector unit.
Carbon dioxide enriched unit 3 is arranged in shell body 1 and is disposed adjacently with inner barrel 2, carbon dioxide enriched list
Unit 3 includes inner chamber body and being internally provided with heating unit 7, and it is by positioned at the lower section of carbon dioxide enriched unit 3 and setting outside
Passage 8 and atmosphere on housing 1, its top include upper lid 18, for carbon dioxide effusion.Wherein, it is carbon dioxide enriched
Above-mentioned zeolite molecular sieve or modified zeolite molecular sieve are mounted with unit 3.
That is, carbon dioxide enriched unit 3 is by being loaded in zeolite molecular sieve therein or modified zeolite molecular sieve come rich
Collection carbon dioxide simultaneously discharges carbon dioxide using the heating zeolite molecular sieve of heating unit 7 or modified zeolite molecular sieve, thus, it is possible to
It is enough to form the high local concentrations carbon dioxide of air inlet in apparatus of the present invention, thus attract mosquito near and by mosquito lure to
On the axial direction of air inlet, trapping is then sucked and realized by air-flow.Preferably, heating unit 7 is heating plate, resistance wire
Deng heating component.
Second wind-force unit 4 is arranged on the bottom of carbon dioxide enriched unit 3 and is produced for the passage 8 in shell body 1
The raw air-flow for entering carbon dioxide enriched unit 3.Second wind-force unit 4 can be the components such as fan or air exhauster.
After the second wind-force unit 4 is opened, air passage 8 from below enters in carbon dioxide enriched unit 3, loads
Zeolite molecular sieve or modified zeolite molecular sieve in carbon dioxide enriched unit 3 then adsorb the titanium dioxide in the air for passing through
Carbon, after a certain amount of carbon dioxide to be adsorbed, can close the second wind-force unit 4 and open heating unit 7, inhaled
The desorption of Annex II carbonoxide, carbon dioxide is then released into the air inlet of device especially inner barrel 2, is then enriched with and draws
Lure mosquito.
Fig. 4 shows the decomposition texture schematic diagram of mosquito booby trap in accordance with another embodiment of the present invention, and Fig. 5 shows
The side structure schematic view of mosquito booby trap in Fig. 4, Fig. 6 shows that the plan structure of mosquito booby trap in Fig. 4 is illustrated
Figure.As shown in Figures 4 to 6, another thinking of the invention, device of the invention can also lure light source including mosquito,
Mosquito lures light source to be arranged on the air inlet of inner barrel 2, and mosquito is lured by the way that carbon dioxide is combined with light source, can further carry
Height catches mosquito efficiency.Preferably, the airflow direction and mosquito that the first wind-force unit 10 is produced lure the light direction that light source sends out
Concentrate on the axial direction of inner barrel 2.On the one hand the carbon dioxide of enrichment and mosquito lure light source to lure to interior mosquito
On the axial direction of the air inlet of cylinder, on the other hand the first wind-force unit 10 will be lured to entering in the air-flow that axial direction is produced
Mosquito on the axial direction of air port is quickly sucked into mosquito collector unit and air-dries till death, largely improves trapping mosquito
Effect and realize the purpose of efficient mosquito killing.
Wherein, mosquito lure light source include lamp socket 11, bulb 12 and lampshade 13, bulb can for CDC lamps, black light lamp,
CCFL lamps or uviol lamp etc..
Device of the invention also includes power control unit, the first wind-force unit 10, the second wind-force unit 4, heating unit 7
Lure unit to be electrically connected with power control unit respectively to realize the effective control to device with mosquito.Wherein, power supply list
Unit at least includes photodiode 15, power interface 16 and power switch 9.
Because the ability of zeolite molecular sieve absorbing carbon dioxide from air is inhaled not as modified zeolite molecular sieve from air
The ability of Annex II carbonoxide, so if what is loaded in mosquito booby trap of the invention is zeolite molecular sieve, then it is preferably same
When mosquito be set in a device lure light source, to improve attractant effect；If loaded in mosquito booby trap of the invention
It is modified zeolite molecular sieve, then mosquito can be set and lures light source, it is also possible to be not provided with mosquito and lure light source.
With reference to specific embodiment, the invention will be further described.
Embodiment 1：The modified 10X type zeolite molecular sieves of ethylenediamine
(1) 600g 10X type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 200mL/min
Gas；
(2) make helium with the speed of 200mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 30min；
(3) helium 12h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 200mL/min, are obtained
Modified zeolite molecular sieve.
Embodiment 2：The modified 13X type zeolite molecular sieves of ethylenediamine
(1) 350g 13X type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 300mL/min
Gas；
(2) make helium with the speed of 500mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 50min；
(3) helium 24h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 300mL/min, are obtained
Modified zeolite molecular sieve.
Embodiment 3：Ethylenediamine modified zeolite of Y-type molecular sieve
(1) 200g Y-type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 150mL/min；
(2) make helium with the speed of 350mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 45min；
(3) helium 12h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 150mL/min, are obtained
Modified zeolite molecular sieve.
Embodiment 4：The modified 4A type zeolite molecular sieves of ethylenediamine
(1) 100g 4A type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 80mL/min；
(2) make helium with the speed of 80mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 35min；
(3) helium 24h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 80mL/min, are changed
Property zeolite molecular sieve.
Embodiment 5：The modified 5A type zeolite molecular sieves of ethylenediamine
(1) 250g 5A type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 500mL/min；
(2) make helium with the speed of 400mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 60min；
(3) helium 16h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 500mL/min, are obtained
Modified zeolite molecular sieve.
Embodiment 6：Ethylenediamine modified ZSM-5 type zeolite molecular sieve
(1) 550g ZSM-5 type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 150mL/min
Gas；
(2) make helium with the speed of 50mL/min by the bubbler containing ethylenediamine at room temperature, make ethylenediamine steam
The helium of saturation is passed through reactor 35min；
(3) helium 20h removals and the ethylenediamine of zeolite molecular sieve weak binding are passed through using the speed of 150mL/min, are obtained
Modified zeolite molecular sieve.
Embodiment 7：The modified 10X type zeolite molecular sieves of MEA
(1) 300g 10X type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 100mL/min
Gas；
(2) make helium with the speed of 80mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 55min；
(3) MEA of helium 20h removals and zeolite molecular sieve weak binding is passed through using the speed of 100mL/min.Institute
State the modified completion of zeolite molecular sieve.
Embodiment 8：The modified 13X type zeolite molecular sieves of MEA
(1) 100g 13X type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 80mL/min；
(2) make helium with the speed of 100mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 30min；
(3) MEA of helium 24h removals and zeolite molecular sieve weak binding is passed through using the speed of 80mL/min.It is described
Zeolite molecular sieve is modified to be completed.
Embodiment 9：MEA modified zeolite of Y-type molecular sieve
(1) 200g Y-type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 500mL/min；
(2) make helium with the speed of 250mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 40min；
(3) MEA of helium 16h removals and zeolite molecular sieve weak binding is passed through using the speed of 200mL/min.Institute
State the modified completion of zeolite molecular sieve.
Embodiment 10：The modified 4A type zeolite molecular sieves of MEA
(1) 100g 4A type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 150mL/min；
(2) make helium with the speed of 180mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 40min；
(3) MEA of helium 18h removals and zeolite molecular sieve weak binding is passed through using the speed of 150mL/min.Institute
State the modified completion of zeolite molecular sieve.
Embodiment 11：The modified 5A type zeolite molecular sieves of MEA
(1) 250g 5A type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 350mL/min；
(2) make helium with the speed of 120mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 35min；
(3) MEA of helium 24h removals and zeolite molecular sieve weak binding is passed through using the speed of 350mL/min.Institute
State the modified completion of zeolite molecular sieve.
Embodiment 12：MEA modified ZSM-5 type zeolite molecular sieve
(1) 250g ZSM-5 type zeolite molecular sieves are packed into reactor, helium is then passed through with the speed of 150mL/min
Gas；
(2) make helium with the speed of 450mL/min by the bubbler containing MEA at room temperature, make MEA
Vapour-saturated helium is passed through reactor 50min；
(3) MEA of helium 12h removals and zeolite molecular sieve weak binding is passed through using the speed of 150mL/min.Institute
State the modified completion of zeolite molecular sieve.
Embodiment 13：Zeolite molecular sieve is tested with the application effect of modified zeolite molecular sieve
The mosquito booby trap that the present embodiment is used is the structure shown in Fig. 4 to Fig. 6, and light source is lured which provided mosquito
And bulb is CDC lamps.
Inventor is according to GB《GB/T 27785-2011 hygienic biocide apparatuses efficacy in laboratory determines and evaluates electronics and goes out
Mosquitos and flies device》It is tested, 150g is unmodified not to load zeolite molecular sieve, loading in the mosquito booby trap of the present embodiment
Zeolite molecular sieve, load 150g modified zeolite molecular sieves (ethylenediamine is modified) to catch mosquito contrast and experiment as shown in table 2, it is seen that
What the setting of modified zeolite molecular sieve substantially increased mosquito booby trap lures mosquito effect, and modified zeolite molecular sieve in this reality
The mosquito effect that lures applied in a mosquito booby trap lures mosquito effect better than unmodified zeolite molecular sieve, uses modified zeolite molecule
Data have statistical significance before and after sieve.
Mosquito booby trap lures mosquito measure of merit result in the embodiment 13 of table 2
Remarks：* p ＜ 0.01；Compared with not loading zeolite molecular sieve and only using photo-induction.
##p ＜ 0.01；Compared with " photo-induction+unmodified zeolite molecular sieve ".
Embodiment 14：Zeolite molecular sieve is tested with the application effect of modified zeolite molecular sieve
The mosquito booby trap for using is the structure shown in Fig. 1 to Fig. 3, wherein being not provided with mosquito lures light source.
Inventor is according to GB《GB/T 27785-2011 hygienic biocide apparatuses efficacy in laboratory determines and evaluates electronics and goes out
Mosquitos and flies device》Be tested, loaded respectively in the mosquito booby trap of the present embodiment the unmodified zeolite molecular sieves of 150g and
150g modified zeolite molecular sieves (MEA be modified) to catch mosquito contrast and experiment as shown in table 3, it is seen that zeolite molecular sieve
What setting improve mosquito booby trap lures mosquito effect, and modified zeolite molecular sieve is in the present embodiment mosquito booby trap
Mosquito effect is lured to lure mosquito effect better than unmodified zeolite molecular sieve, rear data have statistical significance before modified.
Mosquito booby trap lures mosquito measure of merit result in the embodiment 14 of table 3
Remarks：* p ＜ 0.01, compared with unmodified zeolite molecular sieve.
In sum, utilization of the present invention can be adsorbed and desorb the zeolite molecular sieve or modified zeolite molecular sieve of carbon dioxide
Carry out luring mosquito to catch mosquito, on the one hand mosquito is lured using the characteristic of its carbon dioxide-enriched, while further with catching mosquito
Fully be combined for the respective efficiency of carbon dioxide and air-flow by air-flow, can also utilize the sucking action for luring light source, and then
Realize the purpose of efficient mosquito killing.Also, the zeolite molecular sieve after method modified by this invention is modified is adsorbed from air
The ability of carbon dioxide has a distinct increment, and by after long-term adsorption-desorption cycle use, still keeping relatively stablizing to dioxy
Change absorption and the desorption ability of carbon.Carbon dioxide used in the present invention is existing material in air, does not result in titanium dioxide
Carbon is produced and greenhouse effects, at the same it is also harmless using bionical mode, have a good application prospect.
The invention is not limited in foregoing specific embodiment.The present invention is expanded to and any in this manual disclosed
New feature or any new combination, and disclose any new method or process the step of or any new combination.
Claims (11)
1. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught.
2. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 1, it is characterised in that will
Zeolite molecular sieve or modified zeolite molecular sieve are placed in mosquito booby trap and aid in or predominantly lure mosquito.
3. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 1, it is characterised in that institute
It is at least one in X-type, Y types, A types, β types, ZSM types to state zeolite molecular sieve, and the modified zeolite molecular sieve is X-type, Y types, A
At least one in type, β types, ZSM types is modified and obtains.
4. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 3, it is characterised in that institute
It is the zeolite point for including primary amine and/or secondary amine formed using amines modification of zeolite molecular sieve to state modified zeolite molecular sieve
Son sieve.
5. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 4, it is characterised in that institute
Amines is stated for ethylenediamine, MEA, TEPA, trien, three (2- aminoethyls) amine and diethylidene
One kind in triamine.
6. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 2, it is characterised in that institute
Stating mosquito booby trap includes：
Shell body；
Inner barrel, is arranged in the shell body, including top air inlet；
First wind-force unit, is arranged in the shell body and is located at the lower section of the inner barrel, and in the inner barrel
Air inlet produce enter the inner barrel air-flow；
Mosquito collector unit, is arranged on the shell body lower section and is located at the lower section of the first wind-force unit, connects with inner barrel
The mosquito that logical and for collecting from inner barrel air inlet enters；
Carbon dioxide enriched unit, is arranged in the shell body and is disposed adjacently with the inner barrel, is internally provided with and adds
Hot cell, by positioned at the carbon dioxide enriched unit lower section and being arranged on the passage on shell body and atmosphere, pushes up
Portion is carbon dioxide escape orifice, wherein, zeolite molecular sieve or modified zeolite molecule are mounted with the carbon dioxide enriched unit
Sieve；
Second wind-force unit, is arranged on the bottom of the carbon dioxide enriched unit and is produced for the passage in the shell body
The raw air-flow for entering the carbon dioxide enriched unit.
7. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 6, it is characterised in that institute
State device and also lure light source including mosquito, the mosquito lures light source to be arranged on the air inlet of the inner barrel.
8. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 7, it is characterised in that institute
It is CDC lamps, black light lamp, CCFL lamps or uviol lamp to state mosquito and lure light source.
9. the application of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught according to claim 6, it is characterised in that institute
State mosquito collector unit and be removably inserted into the lower section of the shell body and including the first collector and the second collector, institute
The first collector is stated for entrance is big and exports small inverted round stage structure, second collector is cuboid or cube structure,
First collector is sleeved in second collector, wherein, first collector is also included around inverted round stage structure
Filter screen, second collector also include positioned at outside portion exhaust vent.
10. the method for modifying of the modified zeolite molecular sieve as described in any one of claim 1 to 9, it is characterised in that described to change
Property method is comprised the following steps：
A, zeolite molecular sieve is packed into reactor, to being passed through helium in reactor；
B, make helium by the bubbler containing amines, the helium containing saturation amines steam is then passed through reaction
In device, the time is passed through for 30~60min；
C, again to being passed through helium in reactor to remove the amines with zeolite molecular sieve weak binding, obtain modified zeolite molecule
Sieve.
The method of modifying of 11. modified zeolite molecular sieves according to claim 10, it is characterised in that in step A and step B
In, the speed that is passed through of helium and the helium containing saturation amines steam is 50~500mL/min；In step C, helium
The time is passed through for 12~24h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710045776.9A CN106818675A (en) | 2017-01-20 | 2017-01-20 | The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710045776.9A CN106818675A (en) | 2017-01-20 | 2017-01-20 | The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106818675A true CN106818675A (en) | 2017-06-13 |
Family
ID=59119780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710045776.9A Pending CN106818675A (en) | 2017-01-20 | 2017-01-20 | The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106818675A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970327A (en) * | 2018-05-21 | 2018-12-11 | 成都威能士医疗科技有限公司 | Method using carbon dioxide in active material or modified active material capture and enriched air and the application in catching insects |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182005A (en) * | 2007-11-09 | 2008-05-21 | 浙江大学 | Method for preparing titanium-containing zeolite molecular sieve by natural zeolite modification |
| CN102350303A (en) * | 2011-07-18 | 2012-02-15 | 中国科学院宁波材料技术与工程研究所 | Zeolite molecular sieve material which has high-efficiency CO2 capturing function and preparation method thereof |
| CN103203159A (en) * | 2013-04-08 | 2013-07-17 | 浙江师范大学 | Method for separating nitrous oxide and carbon dioxide by using zeolite-like molecular sieve skeleton material |
| GB2503948A (en) * | 2012-07-14 | 2014-01-15 | Paul Keith Guerrier | Insect trap |
| WO2016075205A1 (en) * | 2014-11-11 | 2016-05-19 | Lithos Industrial Minerals Gmbh | Particles for releasing ingredients |
| CN205357869U (en) * | 2015-01-26 | 2016-07-06 | 优得科技有限公司 | Electronic mosquito trapping lamp |
| CN105941369A (en) * | 2016-05-26 | 2016-09-21 | 成都威能士医疗科技有限公司 | A bottom-to-top type mosquito trapping device |
| CN205624039U (en) * | 2016-04-29 | 2016-10-12 | 成都威能士医疗科技有限公司 | Novel cellular type electron is trapped and killed by mosquito device |
| WO2016187274A1 (en) * | 2015-05-18 | 2016-11-24 | Ppg Industries Ohio, Inc. | Device for evaporative delivery of volatile substance |
| CN205756697U (en) * | 2016-05-18 | 2016-12-07 | 东富电器股份有限公司 | The Mosquito catching device of improvement |
-
2017
- 2017-01-20 CN CN201710045776.9A patent/CN106818675A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182005A (en) * | 2007-11-09 | 2008-05-21 | 浙江大学 | Method for preparing titanium-containing zeolite molecular sieve by natural zeolite modification |
| CN102350303A (en) * | 2011-07-18 | 2012-02-15 | 中国科学院宁波材料技术与工程研究所 | Zeolite molecular sieve material which has high-efficiency CO2 capturing function and preparation method thereof |
| GB2503948A (en) * | 2012-07-14 | 2014-01-15 | Paul Keith Guerrier | Insect trap |
| CN103203159A (en) * | 2013-04-08 | 2013-07-17 | 浙江师范大学 | Method for separating nitrous oxide and carbon dioxide by using zeolite-like molecular sieve skeleton material |
| WO2016075205A1 (en) * | 2014-11-11 | 2016-05-19 | Lithos Industrial Minerals Gmbh | Particles for releasing ingredients |
| CN205357869U (en) * | 2015-01-26 | 2016-07-06 | 优得科技有限公司 | Electronic mosquito trapping lamp |
| WO2016187274A1 (en) * | 2015-05-18 | 2016-11-24 | Ppg Industries Ohio, Inc. | Device for evaporative delivery of volatile substance |
| CN205624039U (en) * | 2016-04-29 | 2016-10-12 | 成都威能士医疗科技有限公司 | Novel cellular type electron is trapped and killed by mosquito device |
| CN205756697U (en) * | 2016-05-18 | 2016-12-07 | 东富电器股份有限公司 | The Mosquito catching device of improvement |
| CN105941369A (en) * | 2016-05-26 | 2016-09-21 | 成都威能士医疗科技有限公司 | A bottom-to-top type mosquito trapping device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970327A (en) * | 2018-05-21 | 2018-12-11 | 成都威能士医疗科技有限公司 | Method using carbon dioxide in active material or modified active material capture and enriched air and the application in catching insects |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN205495283U (en) | Cellular active carbon adsorption device | |
| CN104089337B (en) | Indoor air purifier | |
| CN203040489U (en) | Mosquito-killing lamp | |
| CN106818675A (en) | The application and method of modifying of zeolite molecular sieve or modified zeolite molecular sieve in mosquito is caught | |
| CN206866441U (en) | Mosquito catching device | |
| CN105994215A (en) | Efficient wind-suction mosquito killer | |
| CN106804555A (en) | Application and its method of modifying of the metal ion-modified zeolite molecular sieve in mosquito is caught | |
| CN206674859U (en) | A kind of bionic mosquito booby trap | |
| CN103975912B (en) | There are storage mosquito and the household electrical appliances of mosquito killing function | |
| CN207855933U (en) | The smokeless purification moxibustion device of cycle in a kind of | |
| CN108207924A (en) | A kind of intelligence, which is driven, catches mosquito method | |
| CN208912098U (en) | A kind of air purifying type reagent cabinet | |
| CN203913090U (en) | A kind of electric bug catcher | |
| CN111316963B (en) | CO regeneration based on wet method2Mosquito trap of trapping material and mosquito trapping method | |
| CN201270731Y (en) | Photocatalysis mosquito and fly eradicating equipment | |
| CN106332795A (en) | Pet breeding cage capable of purifying air | |
| CN207221561U (en) | A kind of air cleaning unit in agricultural greenhouse | |
| CN108212115A (en) | A kind of method for preparing PM2.5 adsorbents using discarded maize straw | |
| WO2019223111A1 (en) | Method of capturing and enriching carbon dioxide from air by using active material or modified active material and application thereof in catching insect | |
| CN206165563U (en) | High efficiency mosquito killer that induced drafts | |
| CN208794134U (en) | It is a kind of for purifying the ornament lamp of humidifying air | |
| CN207269688U (en) | A kind of Mosquito killer lamp with purification function | |
| CN212591061U (en) | Medicine storage device | |
| CN211354458U (en) | High school's teaching management is with dampproofing archives frame | |
| CN209701250U (en) | A kind of storage device of solid organic fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170613 |
|
| RJ01 | Rejection of invention patent application after publication |