CN1067669C - Method for processing golden stone by using natural granite - Google Patents

Method for processing golden stone by using natural granite Download PDF

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Publication number
CN1067669C
CN1067669C CN98113380A CN98113380A CN1067669C CN 1067669 C CN1067669 C CN 1067669C CN 98113380 A CN98113380 A CN 98113380A CN 98113380 A CN98113380 A CN 98113380A CN 1067669 C CN1067669 C CN 1067669C
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stone material
liquid
baking
look
degreening
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CN98113380A
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CN1210781A (en
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詹月星
王竻
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HUAYI (GROUP) STONE PRODUCTS CO Ltd GUANGDONG PROV
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HUAYI (GROUP) STONE PRODUCTS CO Ltd GUANGDONG PROV
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Abstract

The present invention relates to a method for producing a golden stone by processing natural granite. The present invention comprises two process steps which are selecting and preparing the coloring liquid and the color catalyzing liquid and processing the golden stone, wherein the color catalyzing liquid can be transformer oil, or automobile automatically-gearing oil (namely lubricating oil) or a mixture of the transformer oil and the automobile lubricating oil, and the coloring liquid is formed from ferric nitrate, a penetrating agent and water being uniformly mixed by a definite weight percentage. The processing technology mainly comprises the following steps: baking the natural granite, soaking the natural granite in the color catalyzing liquid, baking the natural granite at constant high temperature, soaking the natural granite in the coloring liquid, baking the natural granite at constant high temperature, soaking the natural granite in the coloring liquid again, baking the natural granite at constant high temperature again, grinding and polishing the natural granite and waxing and cutting the natural granite. The present invention can process white granite into a yellow stone that is the same in the interior as at the surface, is golden, is good in color keeping and fixing effect, and is acid-proof, alkali-proof, corrosion-proof and high-temperature resistant; the present invention is simple in process, easy in operation and low in cost.

Description

A kind of method with natural granite processing of stone gold colored stone material
The present invention is with the method for natural granite processing of stone gold colored stone material, belongs to building material technology, particularly with lithotome tinction production technology.
Along with improving constantly of people's economy, the level of cultural life, also more and more higher to the requirement of household, Working environment, therefore, the construction and decoration industry is also more and more higher to the requirement of building materials.For example wish to have very much the stone material of various different colours.Yet the color of general natural granite stone material all is white or lead, and for satisfying people's needs, so the stone material coloration and dyeing arises at the historic moment in market economic development.At present, the big or small producer of domestic coloration and dyeing stone material has developed into nearly various schools of thinkers, but in existing technology with the lithotome coloration and dyeing, adopt the high pressure vacuum high temperature dyeing no matter be, still adopt normal temperature and pressure coloration and dyeing stone material, can only produce pale red, bright red, scarlet or light yellow, yellow, green stone material.Prior art production is light red, bright red, the scarlet stone material is to produce the red stone material of fixed by physical chemistry, and faint yellow, yellow, the green stone material of prior art coloration and dyeing production at present, be to adopt inorganic color material directly to infiltrate in the stone material painted all, the stone material that the direct tinction of the various pigment of this usefulness comes out, not only color is not bright-coloured, non-refractory, acid and alkali-resistance not, and protect the look colour fixation and be on duty mutually, not only dye stone material color limited to, and make and on purposes, also be subjected to certain restriction.Though in the prior art formula, the method baking of adopting physical chemistry to combine is yellow for the first time, baking has become light red for the second time, baking has become redness for the third time, but in fact baking once is the xanchromatic stone material, and its technical quality is unreliable, and color is not saturating deeply, fail to act and think in the same way, the user uses just faded less than 3 months.And baking is often, complex process, and cost is just high.At present, still can't adopt physico-chemical process in the prior art, really produce reliable in quality, protect the good yellow and green stone material (except the redness) of look fixation, wish to produce this technical barrier of gold colored stone material for a long time and more can't solve people.
Purpose of the present invention is exactly can not produce gold colored stone material in order to overcome and to solve existing coloration and dyeing production color stone material technology existence, and the color stone material of producing is not saturating deeply, color is not bright-coloured, fail to act and think in the same way, it is poor to protect the look fixation, easily fade, non-refractory, acid and alkali-resistance not, and complex manufacturing, shortcoming that cost is more high and problem, research and design is a kind of to solve the technical barrier that people wish to produce gold colored stone material for a long time, and the gold colored stone material color of producing is golden yellow deep and thorough, the same outside and inside, it is good, high temperature resistant to protect the look fixation, acid and alkali-resistance, and production technique is simple, the method that cost is low with natural granite processing of stone gold colored stone material.
The present invention realizes by following method scheme: the principle of the inventive method is: at first the natural granite building material of spending in vain is dried processing, putting into degreening liquid after the cooling at normal temperatures soaks, make the degreening liquid rapid osmotic in the crystalline structure of stone material, take out then and put into the baker heated baking, be put into again in the look liquid after the cooling and soak, put into the baker heated baking after the taking-up again, making degreening liquid and look liquid produce physical-chemical reaction in stone material in baking heat-processed makes its variable color, makes stone surface and stone material inside produce new fixed gold look equably.The inventive method comprises the selection preparation of degreening liquid and look liquid and the processing step of processing gold colored stone material: the selection of (1) degreening liquid preparation: selecting transformer oil or automobile is that the automobile of 80%~90% transformer oil and 10%~20% stirs with lubricating oil and mixes degreening liquid with lubricating oil or with weight percent, and be contained in container or the degreening liquid pond standby: the preparation of (2) look liquid: its formulation weight per-cent is:
Iron nitrate: 30~50%
Methyl alcohol or ethanol: 3~5%
Water: 45~67% its blending process are: normal temperature adds the water of above-mentioned formulation weight per-cent in the corrosion-resistant container earlier down, again the iron nitrate of above-mentioned weight percent is added mix in the entry stir molten, adding the methyl alcohol of above-mentioned weight percent or ethanol at last mixes to stir evenly and is prepared from look liquid, it is standby in corrosion-resistant container or the look liquid pool to pack at last, its preparation technology's schema is as shown in Figure 1: (3) are with the production craft step of natural granite processing of stone gold colored stone material: 1. the natural granite stone material is placed in the roaster and toasts, oven dry is handled, storing temperature is 160~220 ℃, storing time is constant temperature insulation 1~2 hour, flame-out stop baking after, naturally cool to 30~40 ℃ (summer is for being cooled to normal temperature): 2. will dry cooled stone material and put into the degreening liquid pond, again degreening liquid is poured into and carried out the stone material immersion in the degreening liquid pond, soaking depth can be flooded stone material with degreening liquid and is advisable, soak time is 4~8 hours, takes out the nature airing about 1 hour; The stone material that 3. will soak degreening liquid and natural airing is put in the roaster and is toasted, and storing temperature is 160~220 ℃, and storing time is constant temperature afterheat baking 2~3 hours, flame-out stop baking after, naturally cool to normal temperature and take out; 4. the above-mentioned stone material that soaked degreening liquid and drying is put in the look liquid pool at normal temperatures for the first time and soaked, soak time is 4~8 hours, extracts look liquid then from the look liquid pool out, and stone material stays that natural airing takes out after about 1 hour in the look liquid pool; The stone material that 5. will soak look liquid and natural airing is put into roaster again and is toasted, the heated baking temperature is 160~220 ℃, constant temperature afterheat baking 2~3 hours, flame-out stop baking after, naturally cooling to normal temperature takes out, degreening liquid and look liquid in the stone material carries out the chemical reaction first time in stone material at this moment, just becomes golden yellow; 6. will produce flavous stone material and put into the look liquid pool for the second time and soaked 4~8 hours again, and then the look liquid in the look liquid pool is extracted out, stone material stays that natural airing took out after 1 hour in the look liquid pool; 7. will soak the stone material of look liquid for the second time, putting into roaster again carries out heated baking, and storing temperature is 160~220 ℃, constant temperature afterheat baking 2~3 hours, flame-out stop baking after, naturally cool to normal temperature and take out, just can make and protect the good gold colored stone material of look fixation; 8. to carrying out sanding and polishing, waxing cutting after the finished product gold colored stone material surface cleaning, just finished the technology of producing gold colored stone material.Its producing process programflow chart as shown in Figure 2.
The present invention compared with prior art has following advantage and beneficial effect: 1 pair of all natural big Meadowfoam Seed Oil hilllock all available the inventive method processing of rock material becomes the color patterned stone material of various gold.All adularescent flower point granite building materials all become gold colored stone material through present technique; 2. the gold colored stone material that produces with the inventive method is bright-colored, golden light is magnificent, golden yellow kind is varied, colourful; 3. use the gold colored stone material of the inventive method processing, not only can keep former stone material crystalline structure, but also can increase stone material intensity, hardness and glossiness, glossiness can reach more than 82 gloss unit, and performance quality is better than former lithotome; 4. the gold colored stone material with the inventive method processing can guarantee that gold look color penetration is even, thinks and acts in one and the same way, and color is true to nature, the stone surface color can compare favourably with gold; 5. with the stone material product acid and alkali-resistance of the inventive method processing, corrosion-resistant, high temperature resistant and freezing, do not fade; 6. technology of the present invention is simple, technology is reliable, simple to operate, less investment, cost is low, efficient is high; 7. use the end-use of the inventive method processing wide, class is high, can be applicable to multiple building decoration, especially to various irregular stones, as cylinder stone material, Artistic stone material etc., after the inventive method processing special practical value and ornamental value arranged.
Below Figure of description is further specified as follows: Fig. 1 is degreening liquid of the present invention and look liquid preparing process programflow chart, and Fig. 2 is for producing the processing sequence schema of gold colored stone material with the natural granite processing of stone.
Embodiments of the present invention be we can say fairly simple, as long as operate by the preparation prescription of described degreening liquid of top specification sheets and look liquid and technology and with the processing step of natural granite processing of stone production gold colored stone material, just can finish enforcement of the present invention.The contriver is through prolonged and repeated test, and research creates the inventive method.Various times successful implementation was once arranged, obtained the gold colored stone section product high-quality, bright-colored, that golden light is magnificent like a bomb.Below only for several embodiment shown in following table table 1:
Implementing has with the major equipment of natural granite stone processing gold colored stone material: 1. roaster can be bought the large-scale roaster (of commodity You Ming oven) maybe can to make roaster by oneself (be that all stone product factory can both homemade prior art, also can order or please it design with baker manufacturer, make), for example self-control comprises the diesel combustion machine, the power supply temperature-controlled cabinet, heat exchanger, blower fan, the burning diesel oil formula baker of baker thorax, the dimensions of baker burner hearth can be according to the length of the largest stones specification of processing, width, quantity what and decide, for example the baker size of burner hearth can be: length * wide * height=3.5m * 2.7m * 2.9m; 2. urge the look pond: available steel plate or stainless steel plate welding processing form, and its dimensions can be according to length, the width of the largest stones specification of required processing, quantity what and decide; 3. look liquid pool: available stainless steel plate and the welding of corrosion resistant glass reinforced plastic or bonding form, its dimensions can be decided according to length, width, the quantity of the largest stones specification of required processing: 4. sander: it is general stone polishing specific equipment, commercially available, for example can select 80M1-5 type rocking arm polishing machine for use.
Table 1:
Figure C9811338000071

Claims (1)

1. method of producing gold colored stone material with the natural granite processing of stone, it comprises the selection preparation of degreening liquid and look liquid and the processing step of processing gold colored stone material: the selection of (1) degreening liquid preparation: selecting transformer oil or automobile is that the automobile of 80%~90% transformer oil and 10%~20% stirs with lubricating oil and mixes degreening liquid with lubricating oil or with weight percent, is contained in container or the degreening liquid pond standby; (2) preparation of look liquid: its formulation weight per-cent is:
Iron nitrate: 30~50%
Methyl alcohol or ethanol: 3~5%
Water: 45~67%
Its blending process is: normal temperature adds the water of above-mentioned formulation weight per-cent in the corrosion-resistant container earlier down, again the iron nitrate of above-mentioned weight percent is added mix in the entry stir molten, add the methyl alcohol of above-mentioned weight percent or ethanol at last and mix to stir evenly and be prepared from look liquid, standby in pack at last corrosion-resistant container or the look liquid pool; (3) with the production craft step of natural granite processing of stone gold colored stone material: 1. the natural granite stone material is placed in the roaster and toasts, dry processing, storing temperature is 160~220 ℃, storing time is constant temperature insulation 1~2 hour, flame-out stop baking after, naturally cool to 30~40 ℃ (summer is for being cooled to normal temperature); 2. will dry cooled stone material and put into the degreening liquid pond, and degreening liquid be poured into again and carried out stone material in the degreening liquid pond and soak, soaking depth is flooded stone material with the degreening liquid pond and is advisable, and soak time is 4~8 hours, takes out the nature airing about 1 hour; The stone material that 3. will soak degreening liquid and natural airing is put in the roaster and is toasted, and storing temperature is 160~220 ℃, and storing time is constant temperature afterheat baking 2~3 hours, flame-out stop baking after, naturally cool to normal temperature and take out; 4. the above-mentioned stone material that soaked degreening liquid and drying is put in the look liquid pool at normal temperatures for the first time and soaked, soak time is 4~8 hours, extracts look liquid then from the look liquid pool out, and stone material stays that natural airing takes out after about 1 hour in the look liquid pool; The stone material that 5. will soak look liquid and natural airing is put into roaster again and is toasted, and the heated baking temperature is 160~220 ℃, constant temperature afterheat baking 2~3 hours, extinguish stop baking after, naturally cool to normal temperature and take out, just become golden yellow; 6. will produce yellow golden stone material and put into the look liquid pool for the second time and soaked 4~8 hours again, and then the look liquid in the look liquid pool is extracted out, stone material stays that natural airing took out after 1 hour in the look liquid pool; 7. will soak the stone material of look liquid for the second time, putting into roaster again carries out heated baking, and storing temperature is 160~220 ℃, constant temperature afterheat baking 2~3 hours, flame-out stop baking after, naturally cool to normal temperature and take out, just can make and protect the good gold colored stone material of look fixation; 8. to carrying out sanding and polishing, waxing cutting after the finished product gold colored stone material surface cleaning, just finished the technology of processing gold colored stone material.
CN98113380A 1998-10-14 1998-10-14 Method for processing golden stone by using natural granite Expired - Fee Related CN1067669C (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101274856B (en) * 2007-03-30 2012-01-18 曾志坚 Dyeing method for nature stone and product therefrom
CN102172873A (en) * 2010-12-30 2011-09-07 周其进 Production process for increasing gloss of stone lines
CN103144199A (en) * 2013-03-18 2013-06-12 陈松军 Processing process of jade

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4695487A (en) * 1986-04-14 1987-09-22 Cho Yu H Process for coloring granite
CN1117035A (en) * 1994-12-23 1996-02-21 余进 Granite coloring technique

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4695487A (en) * 1986-04-14 1987-09-22 Cho Yu H Process for coloring granite
CN1117035A (en) * 1994-12-23 1996-02-21 余进 Granite coloring technique

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