CN1157349C - Natural marble coloring method - Google Patents

Natural marble coloring method Download PDF

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Publication number
CN1157349C
CN1157349C CNB001168029A CN00116802A CN1157349C CN 1157349 C CN1157349 C CN 1157349C CN B001168029 A CNB001168029 A CN B001168029A CN 00116802 A CN00116802 A CN 00116802A CN 1157349 C CN1157349 C CN 1157349C
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CN
China
Prior art keywords
marble
natural
color
heating
natural marble
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Expired - Fee Related
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CNB001168029A
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Chinese (zh)
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CN1278489A (en
Inventor
阎忠林
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ZONGLIN INDUSTRY Co Ltd SHANGHAI
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ZONGLIN INDUSTRY Co Ltd SHANGHAI
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Priority to CNB001168029A priority Critical patent/CN1157349C/en
Publication of CN1278489A publication Critical patent/CN1278489A/en
Application granted granted Critical
Publication of CN1157349C publication Critical patent/CN1157349C/en
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Expired - Fee Related legal-status Critical Current

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Abstract

The present invention relates to a method for changing the color of natural marble. The present invention is characterized in that the method adopts heating treatment of which the heating temperature is 380 to 450 DEG C and the holding time is 3 to 5 hours, and then heating is stopped; natural cooling is performed in the air, and thereby, the color of the marble is changed; after the color of the marble is changed, the gloss and the hardness of the marble is free from damage, so that the decorative artistic quality of the marble is raised greatly and the grade of marble commercial products is also raised. The process of the present invention can cause low-grade marble to be applied to high-grade buildings in large quantities, can save a lot of foreign exchange, is broad in prospect of developing marble enterprises in China and utilizing low-value stones, and is obviously raised in economic effect.

Description

A kind of method of natural marble coloring
The present invention discloses a kind of method that changes the natural marble color, belongs to the processing class of chemical field lithotome.
China is natural marble big producing country, output ranks first in the world, the natural marble kind of having developed at present reaches kind more than 400, from the kind division dolomite is arranged, marble, limestone and lime precipitation rock etc., complicated and changeable for the marble cause condition, so color of natural marble, texture is ever-changing, form a kind of beauty of the Nature, therefore marble is used in the hotel, office building and assembly hall, on the decoration of palace building, obtain good artistic effect, decorateing on the engineering, wish that sometimes the natural marble color is more thin out, wish that perhaps texture is distinct, to decorating artistic effect is arranged more, in the production practice, once the someone invented granitic color change technology, for example Chinese patent application: 89105270.4, " a kind of method of dublicating colour for natural granite by phosphoric acid ", the complex color liquid that adopts anaerobic voltinism phosphoric acid to make is removed the brown spot in the white light granite decorative board, reverts to the natural granite tone.Or surperficial infusion method dyes, it is the stone surface change color that reacts, be unable to undergo the test of time, the structure of natural marble is tight, with the staining technique of chemical liquids, can be that effect is very little or do not have effect, know it is artificially colored at a glance, the sensation of " false making " is arranged, and commercial value is not obvious.
The objective of the invention is to disclose a kind of method that changes the natural marble color, make the marble all unified color that changes to the surface internally, and do not damage the glossiness and the hardness of natural marble, and make natural marble reach ideal and decorate requirement, improve the commodity grade of natural marble.
The object of the present invention is achieved like this, processing step is performed such, natural marble is divided into the sheet material of all size by the finishing material requirement, divide specification to stack, same specification sheet material is placed in the environment of sealing then, case for example, stove, kiln, it is characterized in that adopting heating treatment method to make natural marble change color, promptly is the confined chamber (stove that keeps natural marble sheet material, kiln) heating, 380 ℃~450 ℃ of Heating temperatures, soaking time 3-5 hour, stop heating after the insulation, naturally cooling in air is realized the natural marble color change, carry out the polishing technology of marble slabs then, natural marble is subjected in the thermal process in stove (kiln), and its interior molecules structure is aggravated by thermal motion, after for example the lime carbonate molecule is heated and moves, can change, take off can dividing of having some inner impurity, promote the variation of color, this variation from interior to table, the sheet material integral material takes place, and table all is consistent in the color after therefore changing.Facts have proved natural marble after above-mentioned condition adds thermo-color, its gloss and hardness remain unchanged.Below by embodiment the present invention is further set forth.
Colour contrast photo before and after accompanying drawing 1 Chinese beige natural marble is handled.
Color, texture contrast photo before and after accompanying drawing 2 Chinese beige natural marbles are handled.
Embodiment: Chinese beige natural marble is cut into same specification sheet material by decorating requirement, be placed in the carry out microwave radiation heating kiln and heat, 400 ℃ of Heating temperatures, soaking time 4 hours after the insulation, stops heating, naturally cooling in air.Natural marble color, texture before and after handling have very big variation, beige before handling, and brown macules is more, and color is muddy dark, and commercial value is low, sees the right half block photo of Fig. 1; The marble grain that has be cannot see or be unintelligible, sees accompanying drawing 2 right half block photos, handles the back color and becomes oyster white or milk yellow or white, and the depth of variable color adopts thermal conductance radiation related process to finish, and sees accompanying drawing 1 left half block photo; Handle the back clean mark, decorative pattern is vividly attractive in appearance, sees Fig. 2 left side half block photo.The left and right half block photo of Fig. 1, Fig. 2, former is a natural marble, it is widely different from color and texture, decorative pattern to handle the back, if do not distinguish that from the seam of left and right sides half block butt joint who does not see former in same block of sheet material.Other versicolor marbles are the same with the beige marble, on the basis of true qualities, produce the variation of light color, and the product after the variable color is the same with natural essence.
To make formerly do not have commercial value or the lower natural Dali of commercial value (marble coloring technology is simple with variable color technology of the present invention, cost is not high), but brought very big economic benefit, its commodity value is appreciated, improve marmorean commodity stone material utilization ratio, this technology can make low-grade marble be applied in large quantities can save a large amount of foreign exchanges on the top-grade building, to the development and the stone material utilization of China marble enterprise, application prospect is very wide.

Claims (3)

1. natural marble coloring method, step is earlier natural marble to be cut into sheet material by decorating requirement, carrying out variable color handles, after the variable color marble sheet material is polished, it is characterized in that: adopt heating treatment method to realize marble coloring, the marble sheet material of specification is placed in the environment of sealing, 380 ℃~450 ℃ of Heating temperatures, soaking time 3-5 hour, stop heating after the insulation, naturally cooling in air, realize marble coloring, the depth of variable color, or the variation requirement of decorative pattern adopt thermal conductance radiation related process to finish.
2. a kind of natural marble coloring method according to claim 1 is characterized in that adopting the thermal radiation mode to heat, and makes the natural marble color change.
3. natural marble coloring method according to claim 1 and 2, it is characterized in that using microwave heating method, 400 ℃ of Heating temperatures, soaking time 4 hours stops heating after the insulation, in air, cool off, with Chinese beige natural marble coloring oyster white, perhaps milk yellow, perhaps other versicolor marbles of white are the same with the beige marble, produce the variation of light color on the basis of true qualities, the product after the variable color is the same with natural essence.
CNB001168029A 2000-06-27 2000-06-27 Natural marble coloring method Expired - Fee Related CN1157349C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB001168029A CN1157349C (en) 2000-06-27 2000-06-27 Natural marble coloring method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB001168029A CN1157349C (en) 2000-06-27 2000-06-27 Natural marble coloring method

Publications (2)

Publication Number Publication Date
CN1278489A CN1278489A (en) 2001-01-03
CN1157349C true CN1157349C (en) 2004-07-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNB001168029A Expired - Fee Related CN1157349C (en) 2000-06-27 2000-06-27 Natural marble coloring method

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CN (1) CN1157349C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336586B (en) * 2010-07-23 2013-03-13 福建溪石股份有限公司 Preparation method for changing color of granite after electrolysis
CN101913206B (en) * 2010-08-31 2014-12-03 福建省南安市晋源石业有限公司 Natural stone decoloring process
EP3348943A1 (en) * 2017-01-11 2018-07-18 Wishing Star Marble Co. Ltd. Device and method for optimizing natural stone

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CN1278489A (en) 2001-01-03

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