CN106753932A - Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application - Google Patents
Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application Download PDFInfo
- Publication number
- CN106753932A CN106753932A CN201611134781.9A CN201611134781A CN106753932A CN 106753932 A CN106753932 A CN 106753932A CN 201611134781 A CN201611134781 A CN 201611134781A CN 106753932 A CN106753932 A CN 106753932A
- Authority
- CN
- China
- Prior art keywords
- clothing
- effervescent tablet
- sodium
- biology enzyme
- enzyme
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of degerming cleaning effervescent tablet of clothing biology enzyme, by weight, the degerming cleaning effervescent tablet of clothing biology enzyme is made up of following component：Basic effervescent agent 20% ~ 55%, surfactant 15%~40%, acidic effervescent agent 10%~30%, adhesive 2%~10%, complex enzyme formulation 1%~5%, bleaching agent 0.5%~3%, disintegrant 0.5%~5%, enzyme stabilizers 0.5%~2.5%.The cleaning performance of the degerming cleaning effervescent tablet of clothing biology enzyme of the invention is good, and the effervesce time is fast, sensorial effects heat-flash；For cleaning during clothing, each component synergy in the degerming cleaning effervescent tablet of clothing biology enzyme, particularly enzyme preparation and surfactant and the synergy of various auxiliary agents, can quickly remove the various stains in clothing, surfactant noresidue after cleaning, it is healthy and safe.
Description
Technical field
The invention belongs to detergent technical field, more particularly to a kind of degerming cleaning effervescent tablet and its system of clothing biology enzyme
Preparation Method and application.
Background technology
At present, the articles for washing source of goods of in the market is extremely abundant, comes in every shape, the washing class product that function is variant is
It is a feast for the eyes.Global laundry detergent market is increased with annual 4% speed, and washing powder, liquid detergent market are tended towards stability, and laundry sheet
Rapid development, is to develop most potential product type in clothing articles for washing.For various household washing articles for use, in life often
Laundry detergents mainly have three kinds of washing powder, liquid detergent and laundry soap.Washing powder easily makes moist after opening bag, lumps and influence its matter
Amount, and consumption is uncontrollable during taking.Liquid detergent is usually bottled, and measuring cup is needed when taking, and takes in addition
Liquid detergent spilling is easily caused in journey, further, liquid detergent more than 70% is water, it has not been convenient to packed and transported, logistics space is taken.
Laundry soap meeting residual moisture during washing by rubbing with the hands, after soap box is put into, moisture is retained for a long time can soften laundry soap, cause wave
Take；Solid soap blank is blocks of solid, packaging, transport and the low cost for storing, but dissolution velocity is slow in water due to it, therefore is difficult
For machine-washing, and soap product is high to washing water quality requirement, and, intolerant to the washing of hard water, the northern area of China water hardness is all for soaps
Than larger.
With the development of science and technology washing effervescent tablet enters the life of people, washing effervescent tablet is after washing powder, laundry
The new and high technology cleaning product of another different shape after liquid, laundry sheet.Washing effervescent tablet has easy to use, consumption essence
Really, aesthetic in appearance, effervesce sensorial effects are strong during washing, the features such as clean result is good, more and more welcomed by the people.Washing
Effervescent tablet requires quickly disintegrated performance and the short time in water in water in addition to the basic demand of washing force to be met, also
Dissolving is complete, that is, wash effervescent tablet should have strong hardness again can fater disintegration, this is the main feature for washing effervescent tablet, is also
Technological difficulties.At present, washing in the market does not occur the Betengent product that clothing biology enzyme washs effervescent tablet also.
The content of the invention
It is convenient for carrying the present invention solves the technical problem of one kind is provided, the strong Multifunctional clothes of instant and washability
Thing biology enzyme wash effervescent tablet, have the advantages that it is degerming, do not hurt hands, safe and efficient, environmental protection.
In order to solve the above technical problems, one aspect of the present invention is：There is provided a kind of clothing biology enzyme degerming
Cleaning effervescent tablet, by weight, the degerming cleaning effervescent tablet of clothing biology enzyme is made up of following component：
Basic effervescent agent 20% ~ 55%；
Surfactant 15%~40%；
Acidic effervescent agent 10%~30%；
Adhesive 2%~10%；
Complex enzyme formulation 1%~5%；
Bleaching agent 0.5%~3%；
Disintegrant 0.5%~5%；
Enzyme stabilizers 0.5%~2.5%.
Preferably, the basic effervescent agent be sodium carbonate, sodium acid carbonate in one or two.
Preferably, the surfactant is sodium n-alkylbenzenesulfonate, laruyl alcohol sodium sulfovinate, fatty acid methyl ester sulfonic acid
One or more in sodium, α-sodium olefin sulfonate, laureth sodium sulfovinate, natural soap powder, Tea Saponin.The surface
Activating agent source is healthy and safe, with effects such as cleaning, emulsification, infiltration, foamings, and enzyme preparation can be helped quickly to reach spot
Surface, promote enzyme preparation decompose spot, while, moreover it is possible to by enzyme preparation decompose spot after produce product quickly remove.
Preferably, the acidic effervescent agent be citric acid, tartaric acid in one or two.
Preferably, described adhesive is dextrin, polyethylene glycol, hydroxyethyl cellulose, polyvinylpyrrolidone, methylol fibre
One or more in the plain sodium of dimension.
It is further preferred that the molecular weight of the polyethylene glycol is 6000 ~ 10000.
Preferably, the complex enzyme formulation is lipase, protease, cellulase, amylase, hemicellulase, peroxide
Change two or more in hydrogen enzyme, lysozyme.Complex enzyme formulation is the principle active component of laundry effervescent tablet, with decontamination
And sterilization, biocidal efficacies.Specifically, lipase decomposes the grease type spot on clothing；Protide on proteases for decomposing clothing
Dirt, protease also has sterilizing function；Cellulase, amylase and hemicellulase decompose the carbohydrate spot on clothing；Cross
Hydrogen oxide enzyme and lysozyme have sterilization, bactericidal action.
Preferably, the bleaching agent be sodium hypochlorite, sodium dithionite, SODIUM PERCARBONATE, sodium perborate in one kind or
It is two or more.
Preferably, the disintegrant be sodium carboxymethyl starch, PVPP, sodium chloride in one or more.
Preferably, the enzyme stabilizers be borax, potassium sorbate, sorbierite in one or two.
In order to solve the above technical problems, another technical solution used in the present invention is：There is provided a kind of clothing biological
The preparation method of the degerming cleaning effervescent tablet of enzyme, comprises the following steps：
（1）During adhesive is dissolved in into absolute ethyl alcohol or acetone, 5% solution is made, obtains solution A；
（2）Dried being placed in baking oven after the sprinkling granulation of basic effervescent agent solution A, obtain A particles；
（3）Dried being placed in baking oven after the sprinkling granulation of acidic effervescent agent solution A, obtain B particles；
（4）Surfactant is granulated and dried, C particles are obtained；
（5）A particles, B particles, C particles, complex enzyme formulation, bleaching agent, disintegrant, enzyme stabilizers are mixed, is stirred,
Grain carries out compressing tablet after crossing 20 mesh sieves, and the degerming cleaning effervescent tablet of clothing biology enzyme is obtained.
Above-mentioned steps（2）、（3）, preferably use sponging granulator and granulated.Above-mentioned steps（4）, preferably taken out through granulation
Mechanism grain is simultaneously dried.
The preparation method of the degerming cleaning effervescent tablet of clothing biology enzyme, is that the effervesce chip technology in prepared by tablet is introduced
The preparation of laundry effervescent tablet.
In order to solve the above technical problems, the present invention also provides the application of the degerming cleaning effervescent tablet of the clothing biology enzyme, 2
1 effervescent tablet is added in~5 liters of water, appropriate laundry item is put into after effervesce is finished, routinely journey after immersion 5~10 minutes
Sequence is washed, and is finally rinsed well with clear water.
The beneficial effects of the invention are as follows：For lacking in the use of existing washing powder, liquid detergent and laundry soap, transport, storage
Fall into and in the market lacks the situation that clothing biology enzyme washs effervescent tablet, the degerming cleaning effervescent tablet of clothing biology enzyme of the invention
Cleaning performance is good, and the effervesce time is fast, sensorial effects heat-flash；For cleaning during clothing, in the degerming cleaning effervescent tablet of clothing biology enzyme
Each component synergy, the particularly synergy of enzyme preparation and surfactant and various auxiliary agents can quickly remove clothing
The microorganisms such as various stains and bacterium in thing, surfactant noresidue after cleaning is healthy and safe.
Additionally, the present invention has following remarkable advantage：
1st, using tartaric acid as acidic effervescent agent, contrast commonly used acid effervesce in medicine and health products technology of preparing
Agent, one is smaller hygroscopicity；Two is acidity strong compared with citric acid；Three is good effervesce great efforts, foaming effect, gives birth to clothing of the present invention
Product can be easier to disintegration to the degerming cleaning effervescent tablet of thing enzyme in use, and dissolution velocity is fast.
2nd, preparation method uses compressing dry granulation, it is to avoid bring moisture into, while using granulation film-coating technique, it is to avoid product tide
Solution, it is easy to long-term storage and use.
3rd, under sheet solid conditions, the storage of the biology enzyme in the degerming cleaning effervescent tablet of clothing biology enzyme of the invention is steady
It is qualitative more stable than in the liquid state.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
Embodiment 1~3
It is formulated according to table 1, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 1~3 is prepared respectively, its preparation method is：First will
Polyvinylpyrrolidone, PEG-4000 are dissolved in absolute ethyl alcohol, are made 5% solution, obtain solution A；Sodium acid carbonate is passed through
It is placed in baking oven after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains A particles；By DL- wine
Stone acid is placed in baking oven by after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；
By granulating knockout machine after laureth sodium sulfovinate, natural soap powder, sodium n-alkylbenzenesulfonate, Tea Saponin are well mixed
Granulation drying, obtains C particles；By A particles, B particles, C particles, complex enzyme formulation, SODIUM PERCARBONATE, sodium carboxymethyl starch, sorbic acid
Potassium mixes, and stirs, and particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, inspection is closed
Lattice can be prepared by the degerming cleaning effervescent tablet of clothing biology enzyme of the present invention.In embodiment 1 complex enzyme formulation by lipase, protease and
Lysozyme is constituted, and complex enzyme formulation is made up of lipase and protease in embodiment 2, and complex enzyme formulation is by fat in embodiment 3
Enzyme, protease and amylase composition.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 1~3 of table 1
Embodiment 4~6
It is formulated according to table 2, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 4~6 is prepared respectively, its preparation method is：First will
PEG-8 000 is dissolved in absolute ethyl alcohol, is made 5% solution, obtains solution A；By sodium carbonate by sponging granulator solution A
It is placed in baking oven after sprinkling granulation, by anhydrous ethanol solvent volatile dry, obtains A particles；By DL- tartaric acid by sponging granulator
It is placed in baking oven after spraying granulation with solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；By laruyl alcohol sodium sulfovinate,
By granulating knockout machine granulation drying after methyl sodiosul foaliphatate, α-sodium olefin sulfonate, Tea Saponin are well mixed, C particles are obtained；
A particles, B particles, C particles, complex enzyme formulation, sodium hypochlorite, PVPP, dextrin, sorbierite are mixed, are stirred,
Particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, inspection is qualified to can be prepared by the present invention
The degerming cleaning effervescent tablet of clothing enzyme.Complex enzyme formulation is made up of lipase, protease, cellulase and lysozyme in embodiment 4,
Complex enzyme formulation is made up of lipase, protease, amylase, hemicellulase and catalase in embodiment 5, embodiment 6
Middle complex enzyme formulation is made up of lipase, protease, cellulase, amylase and lysozyme.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 4~6 of table 2
Embodiment 7~9
It is formulated according to table 3, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 7~9 is prepared respectively, its preparation method is：First will
Polyvinylpyrrolidone, PEG-6000 0 are dissolved in absolute ethyl alcohol, are made 5% solution, obtain solution A；Sodium acid carbonate is passed through
It is placed in baking oven after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains A particles；By citric acid
It is placed in baking oven by after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；By the moon
Dried by granulating knockout machine granulation after laureth sodium sulfovinate, natural soap powder, α-sodium olefin sulfonate, Tea Saponin are well mixed
It is dry, obtain C particles；A particles, B particles, C particles, complex enzyme formulation, SODIUM PERCARBONATE, carboxyrnethyl starch sodium, borax are mixed, stirring is equal
Even, particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, check qualified can be prepared by originally
The degerming cleaning effervescent tablet of invention clothing biology enzyme.Complex enzyme formulation is by lipase, protease, cellulase, starch in embodiment 7
Enzyme, hemicellulase, catalase and lysozyme composition, complex enzyme formulation is by lipase, protease, starch in embodiment 8
Enzyme, catalase and lysozyme composition, in embodiment 9 complex enzyme formulation by lipase, protease, cellulase, amylase,
Hemicellulase, catalase and lysozyme composition.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 7~9 of table 3
Embodiment 10
The decontamination in measure by standard GB/T/T 1314-2008 dress materials with detergent detergency and circulation scourability is surveyed
Method for testing carries out detergency ability test, the results are shown in Table 4.
The detergency ability test result of table 4
The requirement of detergency national standard parameter index is as follows：Any two kinds of dirts in tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03
Cloth is more than or equal to standard liquid detergent.The degerming cleaning effervescent tablet of clothing biology enzyme of the invention, there is higher as can be seen from Table 4
Scourability.
Those skilled in the art do not depart from essence of the invention and spirit, can have various deformation scheme to realize the present invention,
Preferably feasible embodiment of the invention is the foregoing is only, not thereby limits to interest field of the invention, it is all with this
The equivalent structure change that description of the invention is made, is both contained within interest field of the invention.
Claims (12)
1. the degerming cleaning effervescent tablet of a kind of clothing biology enzyme, it is characterised in that by weight, the degerming cleaning of clothing biology enzyme
Effervescent tablet is made up of following component：
Basic effervescent agent 20% ~ 55%；
Surfactant 15%~40%；
Acidic effervescent agent 10%~30%；
Adhesive 2%~10%；
Complex enzyme formulation 1%~5%；
Bleaching agent 0.5%~3%；
Disintegrant 0.5%~5%；
Enzyme stabilizers 0.5%~2.5%.
2. the biological degerming enzyme cleaning effervescent tablet of clothing according to claim 1, it is characterised in that the basic effervescent agent is
One or two in sodium carbonate, sodium acid carbonate.
3. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the surfactant is
Sodium n-alkylbenzenesulfonate, laruyl alcohol sodium sulfovinate, methyl sodiosul foaliphatate, α-sodium olefin sulfonate, laureth sulfuric acid
One or more in ester sodium, natural soap powder, Tea Saponin.
4. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the acidic effervescent agent is
One or two in citric acid, tartaric acid.
5. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that described adhesive is paste
One or more in essence, polyethylene glycol, hydroxyethyl cellulose, polyvinylpyrrolidone, sodium cellulose glycolate.
6. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 5, it is characterised in that the polyethylene glycol point
Son amount is 6000 ~ 10000.
7. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the complex enzyme formulation is
Two or more in lipase, protease, cellulase, amylase, hemicellulase, catalase, lysozyme.
8. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the bleaching agent is time chlorine
One or more in sour sodium, sodium dithionite, SODIUM PERCARBONATE, sodium perborate.
9. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the disintegrant is carboxylic first
One or more in base sodium starch, PVPP, sodium chloride.
10. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the enzyme stabilizers are
One or two in borax, potassium sorbate, sorbierite.
The preparation method of the degerming cleaning effervescent tablet of clothing biology enzyme described in 11. any one of claim 1 ~ 10, it is characterised in that
Comprise the following steps：
（1）During adhesive is dissolved in into absolute ethyl alcohol or acetone, 5% solution is made, obtains solution A；
（2）Dried being placed in baking oven after the sprinkling granulation of basic effervescent agent solution A, obtain A particles；
（3）Dried being placed in baking oven after the sprinkling granulation of acidic effervescent agent solution A, obtain B particles；
（4）Surfactant is granulated and dried, C particles are obtained；
（5）A particles, B particles, C particles, complex enzyme formulation, bleaching agent, disintegrant, enzyme stabilizers are mixed, is stirred,
Grain carries out compressing tablet after crossing 20 mesh sieves, and the degerming cleaning effervescent tablet of clothing biology enzyme is obtained.
The application of the degerming cleaning effervescent tablet of clothing biology enzyme described in 12. any one of claim 1 ~ 11, it is characterised in that 2
1 effervescent tablet is added in~5 liters of water, laundry item is put into after effervesce is finished, routinely program is washed after soaking 5~10 minutes
Wash, rinsed well with clear water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134781.9A CN106753932A (en) | 2016-12-11 | 2016-12-11 | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134781.9A CN106753932A (en) | 2016-12-11 | 2016-12-11 | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106753932A true CN106753932A (en) | 2017-05-31 |
Family
ID=58875293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611134781.9A Pending CN106753932A (en) | 2016-12-11 | 2016-12-11 | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106753932A (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267322A (en) * | 2017-07-09 | 2017-10-20 | 深圳市美益洁生物科技有限公司 | Degerming cleaning effervescent tablet of feeding bottle biology enzyme and its preparation method and application |
| CN107312663A (en) * | 2017-07-12 | 2017-11-03 | 江苏卓尔美物联科技股份有限公司 | A kind of natural soap powder of environmentally friendly concentrated type and its preparation technology |
| CN107384602A (en) * | 2017-07-12 | 2017-11-24 | 江苏卓尔美物联科技股份有限公司 | A kind of submissive cocounut oil of environment-friendly type concentrates powder and its preparation technology |
| CN107400571A (en) * | 2017-07-12 | 2017-11-28 | 江苏卓尔美物联科技股份有限公司 | A kind of environment-friendly type concentration powder for specially washing white garments and its preparation technology |
| CN107488531A (en) * | 2017-08-29 | 2017-12-19 | 广州立白企业集团有限公司 | A kind of neutral Instant detergent bar composition and preparation method thereof |
| CN108149491A (en) * | 2017-12-19 | 2018-06-12 | 江苏新瑞贝科技股份有限公司 | A kind of fabric decontaminating finishing agent and preparation method thereof |
| CN108251239A (en) * | 2018-03-02 | 2018-07-06 | 胡小玲 | A kind of instant laundry sheet |
| CN108728258A (en) * | 2018-07-19 | 2018-11-02 | 杜永卫 | A kind of portable biometric enzyme stain removal agent and preparation method thereof |
| CN109234089A (en) * | 2018-11-06 | 2019-01-18 | 西安优露清科技股份有限公司 | A kind of antibacterial fabric effervescent table for cleaning and preparation method thereof |
| CN109897744A (en) * | 2019-03-22 | 2019-06-18 | 东莞市宏裕生物科技有限公司 | A kind of biological enzyme cleaning particle and its manufacture craft |
| CN110623249A (en) * | 2019-11-05 | 2019-12-31 | 泰兴市东圣生物科技有限公司 | Instant enzyme preparation and preparation method thereof |
| CN110684601A (en) * | 2018-07-05 | 2020-01-14 | 漳州甘净日用品有限公司 | Corrosion-free type washing machine tank decontamination sterilization effervescent tablet and preparation method thereof |
| CN111234943A (en) * | 2020-03-02 | 2020-06-05 | 惠州市多美日用品有限公司 | Aerobic laundry explosive ball and preparation method thereof |
| US20200261327A1 (en) * | 2019-02-20 | 2020-08-20 | One Home Brands, Inc. | Stable anhydrous foaming and gelling hand soap concentrate and method of making same |
| CN111748415A (en) * | 2020-07-24 | 2020-10-09 | 广州立白企业集团有限公司 | Toothbrush sterilizing and cleaning effervescent tablet and preparation method thereof |
| CN112522035A (en) * | 2020-12-22 | 2021-03-19 | 安徽克菱保健科技有限公司 | Antibacterial laundry effervescent swelling tablet and preparation method thereof |
| CN113249974A (en) * | 2021-06-16 | 2021-08-13 | 广东水卫仕生物科技有限公司 | Clothing fragrance-retaining effervescent tablet with softening effect and preparation method thereof |
| CN113403152A (en) * | 2021-07-10 | 2021-09-17 | 安徽克菱保健科技有限公司 | Effervescent laundry tablet |
| CN113430061A (en) * | 2021-06-11 | 2021-09-24 | 广东水卫仕生物科技有限公司 | Dish washing effervescent tablet with sterilization effect for dish washing machine and preparation method thereof |
| US11401488B2 (en) * | 2019-02-20 | 2022-08-02 | One Home Brands, Inc. | Stable anhydrous cleanser concentrate formulation and method of making same |
| CN116083178A (en) * | 2023-03-05 | 2023-05-09 | 余姚市德派日用品有限公司 | Floor cleaning effervescent tablet and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1137288A (en) * | 1993-10-14 | 1996-12-04 | 普罗格特-甘布尔公司 | Bleaching compositions comprising protease enzymes |
| CN102071111A (en) * | 2011-01-12 | 2011-05-25 | 广州立白企业集团有限公司 | Laundry liquid and preparation method thereof |
| CN104560470A (en) * | 2014-12-31 | 2015-04-29 | 鲁东大学 | Effervescent tablet for cleaning fruits and vegetables |
| CN105238604A (en) * | 2015-11-09 | 2016-01-13 | 云南健牛生物科技有限公司 | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof |
| CN105829519A (en) * | 2013-12-18 | 2016-08-03 | 阿科玛股份有限公司 | Stable liquid compositions containing enzymes and peroxides |
| CN105820888A (en) * | 2016-04-21 | 2016-08-03 | 刘爱华 | Decontaminating bactericidal clothing detergent |
-
2016
- 2016-12-11 CN CN201611134781.9A patent/CN106753932A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1137288A (en) * | 1993-10-14 | 1996-12-04 | 普罗格特-甘布尔公司 | Bleaching compositions comprising protease enzymes |
| CN102071111A (en) * | 2011-01-12 | 2011-05-25 | 广州立白企业集团有限公司 | Laundry liquid and preparation method thereof |
| CN105829519A (en) * | 2013-12-18 | 2016-08-03 | 阿科玛股份有限公司 | Stable liquid compositions containing enzymes and peroxides |
| CN104560470A (en) * | 2014-12-31 | 2015-04-29 | 鲁东大学 | Effervescent tablet for cleaning fruits and vegetables |
| CN105238604A (en) * | 2015-11-09 | 2016-01-13 | 云南健牛生物科技有限公司 | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof |
| CN105820888A (en) * | 2016-04-21 | 2016-08-03 | 刘爱华 | Decontaminating bactericidal clothing detergent |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267322A (en) * | 2017-07-09 | 2017-10-20 | 深圳市美益洁生物科技有限公司 | Degerming cleaning effervescent tablet of feeding bottle biology enzyme and its preparation method and application |
| CN107312663A (en) * | 2017-07-12 | 2017-11-03 | 江苏卓尔美物联科技股份有限公司 | A kind of natural soap powder of environmentally friendly concentrated type and its preparation technology |
| CN107384602A (en) * | 2017-07-12 | 2017-11-24 | 江苏卓尔美物联科技股份有限公司 | A kind of submissive cocounut oil of environment-friendly type concentrates powder and its preparation technology |
| CN107400571A (en) * | 2017-07-12 | 2017-11-28 | 江苏卓尔美物联科技股份有限公司 | A kind of environment-friendly type concentration powder for specially washing white garments and its preparation technology |
| CN107488531A (en) * | 2017-08-29 | 2017-12-19 | 广州立白企业集团有限公司 | A kind of neutral Instant detergent bar composition and preparation method thereof |
| CN108149491A (en) * | 2017-12-19 | 2018-06-12 | 江苏新瑞贝科技股份有限公司 | A kind of fabric decontaminating finishing agent and preparation method thereof |
| CN108251239A (en) * | 2018-03-02 | 2018-07-06 | 胡小玲 | A kind of instant laundry sheet |
| CN110684601A (en) * | 2018-07-05 | 2020-01-14 | 漳州甘净日用品有限公司 | Corrosion-free type washing machine tank decontamination sterilization effervescent tablet and preparation method thereof |
| CN108728258A (en) * | 2018-07-19 | 2018-11-02 | 杜永卫 | A kind of portable biometric enzyme stain removal agent and preparation method thereof |
| CN109234089A (en) * | 2018-11-06 | 2019-01-18 | 西安优露清科技股份有限公司 | A kind of antibacterial fabric effervescent table for cleaning and preparation method thereof |
| CN113748193A (en) * | 2019-02-20 | 2021-12-03 | 仅一居家品牌有限公司 | Stable anhydrous lathering and gelling hand soap concentrates and process for making same |
| US20200261327A1 (en) * | 2019-02-20 | 2020-08-20 | One Home Brands, Inc. | Stable anhydrous foaming and gelling hand soap concentrate and method of making same |
| US11401488B2 (en) * | 2019-02-20 | 2022-08-02 | One Home Brands, Inc. | Stable anhydrous cleanser concentrate formulation and method of making same |
| CN109897744A (en) * | 2019-03-22 | 2019-06-18 | 东莞市宏裕生物科技有限公司 | A kind of biological enzyme cleaning particle and its manufacture craft |
| CN110623249A (en) * | 2019-11-05 | 2019-12-31 | 泰兴市东圣生物科技有限公司 | Instant enzyme preparation and preparation method thereof |
| CN110623249B (en) * | 2019-11-05 | 2023-04-07 | 泰兴市东圣生物科技有限公司 | Instant enzyme preparation and preparation method thereof |
| CN111234943A (en) * | 2020-03-02 | 2020-06-05 | 惠州市多美日用品有限公司 | Aerobic laundry explosive ball and preparation method thereof |
| CN111748415B (en) * | 2020-07-24 | 2022-02-25 | 广州立白企业集团有限公司 | Toothbrush sterilizing and cleaning effervescent tablet and preparation method thereof |
| CN111748415A (en) * | 2020-07-24 | 2020-10-09 | 广州立白企业集团有限公司 | Toothbrush sterilizing and cleaning effervescent tablet and preparation method thereof |
| CN112522035A (en) * | 2020-12-22 | 2021-03-19 | 安徽克菱保健科技有限公司 | Antibacterial laundry effervescent swelling tablet and preparation method thereof |
| CN113430061A (en) * | 2021-06-11 | 2021-09-24 | 广东水卫仕生物科技有限公司 | Dish washing effervescent tablet with sterilization effect for dish washing machine and preparation method thereof |
| CN113249974A (en) * | 2021-06-16 | 2021-08-13 | 广东水卫仕生物科技有限公司 | Clothing fragrance-retaining effervescent tablet with softening effect and preparation method thereof |
| CN113403152A (en) * | 2021-07-10 | 2021-09-17 | 安徽克菱保健科技有限公司 | Effervescent laundry tablet |
| CN116083178A (en) * | 2023-03-05 | 2023-05-09 | 余姚市德派日用品有限公司 | Floor cleaning effervescent tablet and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106753932A (en) | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application | |
| US9828569B2 (en) | Granular laundry detergent | |
| JP6137741B2 (en) | Detergent containing carbamide and / or at least one derivative thereof | |
| CN102965223B (en) | Nano-multifunctional washing sheet | |
| CN105238604A (en) | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof | |
| CN102660401B (en) | Enzyme-containing detergent | |
| CN107267322A (en) | Degerming cleaning effervescent tablet of feeding bottle biology enzyme and its preparation method and application | |
| CN114250120B (en) | Clothes sterilizing detergent, clothes sterilizing cleaning mousse and preparation method | |
| CN111944622A (en) | Concentrated laundry detergent and preparation method thereof | |
| JP6449010B2 (en) | Washing method | |
| CN103923754A (en) | Household clothes-washing and dish-washing liquid | |
| WO2008040151A1 (en) | Synthetic detergent and its preparation method | |
| JPS6230198A (en) | Tablet detergent | |
| CN105886137A (en) | High-density low temperature quickly dissolved washing powder and preparation method thereof | |
| EP3008160A1 (en) | Granular laundry detergent | |
| CN106833946A (en) | Tableware biological enzyme cleaning fluid and its preparation method and application | |
| CN111171967B (en) | Effervescent washing product with high disintegration speed and easy rinsing and preparation method thereof | |
| KR101221115B1 (en) | 2 tablet-type detergent composition for kitchen with the excellent bleaching and deodorizing effect | |
| CN108410593B (en) | Multi-effect laundry detergent and preparation method thereof | |
| EP3790950B1 (en) | Detergent granule | |
| WO2008040152A1 (en) | A solid detergent and its preparation method | |
| CN108048225A (en) | A kind of environment friendly and pollution-free washing powder and preparation method thereof | |
| CN114806732A (en) | Effervescent tablet for cleaning clothes | |
| JP2015120849A (en) | Cleaning method | |
| CN108192778B (en) | Non-toxic and non-irritant washing gel bead and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |