CN112522035A - Antibacterial laundry effervescent swelling tablet and preparation method thereof - Google Patents
Antibacterial laundry effervescent swelling tablet and preparation method thereof Download PDFInfo
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- CN112522035A CN112522035A CN202011526831.4A CN202011526831A CN112522035A CN 112522035 A CN112522035 A CN 112522035A CN 202011526831 A CN202011526831 A CN 202011526831A CN 112522035 A CN112522035 A CN 112522035A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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Abstract
The invention relates to an antibacterial laundry effervescent swelling tablet and a preparation method thereof, and is characterized in that: 10 to 20 percent of citric acid, 20 to 30 percent of sodium bicarbonate, 15 to 35 percent of sodium percarbonate, 5 to 15 percent of sodium dodecyl benzene sulfonate, 10 to 15 percent of sodium dodecyl sulfate, 5 to 15 percent of anhydrous sodium sulfate, 1 to 3 percent of alkaline protease, 1 to 2 percent of lipase, 1 to 3 percent of crospovidone, 0.15 to 0.2 percent of triclosan, 0.1 to 0.3 percent of essence and 0.5 percent of coloring enzyme particles; (1) mixing sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, anhydrous sodium sulfate and sodium percarbonate, stirring, adding alkaline protease and polyvinylpolypyrrolidone, and mixing to obtain mixture A; (2) adding sodium bicarbonate and citric acid into a dry normal mixing reactor, uniformly mixing, adding the mixture A, the essence and the coloring enzyme particles, and uniformly mixing to obtain a mixture B; (3) the mixture B was subjected to high pressure tableting. The invention has the advantages that: the process is simple and the cost is low; products with different shapes, colors and fragrances can be produced; the using amount is accurate and controllable, no waste is caused, and the carrying is convenient; high dissolving speed and high washing and bacteriostasis effect.
Description
Technical Field
The invention belongs to the technical field of daily washing products, and relates to an antibacterial laundry effervescent swelling tablet and a preparation method thereof.
Background
Along with the use of washing machines and the improvement of water resource saving consciousness, people tend to use environment-friendly, low-foam, easy-to-rinse, no-residue after washing, healthy and environment-friendly washing articles. In order to meet the demands of consumers, enterprise products are in a position of being beneficial in intense market competition, and the development of new washing article types is one of the purposes of the invention.
With the rapid development of economy, the travel activities of business, travel, meeting and the like are increasing day by day, meanwhile, the life rhythm of people is accelerated, and the washing article which is convenient to carry and use and easy to control the dosage is needed by people. In recent years, researchers at home and abroad do a lot of work in the field of laundry sheet products, European and American laundry sheet markets are preliminarily formed, and several laundry sheet products are put into the markets at home. In various novel washing products, the laundry effervescent swelling tablets have high active matter content and are not diluted by water, so a large amount of energy can be saved in the production, transportation and storage processes, and meanwhile, the laundry effervescent swelling tablets have the advantages of convenience in use, small use amount, mild skin and the like, and are novel products with market potential.
Most of the patents on the preparation process of the laundry effervescent tablets published at present comprise a wet granulation process, in the wet granulation process, organic solvents such as ethanol and acetone are needed to be used as solutions, and the organic solvents are extremely volatile, flammable and explosive, are toxic to human bodies, pollute the environment, bring extremely strong potential safety hazards to the production process, and increase the production cost and management risks.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides an antibacterial laundry effervescent swelling tablet and a preparation method thereof.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
an antibacterial laundry effervescent swelling tablet comprises acidic effervescent agent, alkaline effervescent agent, surfactant, filler, complex enzyme preparation, and disintegrating agent; the feature is that it also contains bacteriostatic triclosan 0.15% -0.2% of the total weight of the mixture, in which the alkaline effervescent agent is the mixture of sodium bicarbonate and sodium percarbonate.
Further, the antibacterial laundry effervescent swelling tablet also contains essence which accounts for 0.1-0.3% of the total weight of the mixture.
Further, the bacteriostatic laundry effervescent swelling tablet also contains coloring enzyme particles accounting for 0.5-1.0% of the total weight of the mixture.
Further, the antibacterial laundry effervescent swelling tablet is characterized by being prepared from the following raw materials in percentage by weight: 10 to 20 percent of acidic effervescent agent (citric acid), 25 to 40 percent of alkaline effervescent agent (sodium bicarbonate and sodium percarbonate), 15 to 25 percent of surfactant (sodium dodecyl benzene sulfonate and sodium dodecyl sulfate), 5 to 15 percent of filler (anhydrous sodium sulfate), 1 to 5 percent of complex enzyme preparation, 1 to 3 percent of disintegrant (crospovidone) and 0.15 to 0.2 percent of bacteriostatic agent (triclosan).
Further, the antibacterial laundry effervescent swelling tablet is characterized by being prepared from the following raw materials in percentage by weight: 10 to 20 percent of citric acid, 20 to 30 percent of sodium bicarbonate, 15 to 35 percent of sodium percarbonate, 5 to 15 percent of sodium dodecyl benzene sulfonate, 10 to 15 percent of sodium dodecyl sulfate, 5 to 15 percent of anhydrous sodium sulfate, 1 to 3 percent of alkaline protease, 1 to 2 percent of lipase, 1 to 3 percent of crospovidone, 0.15 to 0.2 percent of triclosan, 0.1 to 0.3 percent of essence and 0.5 percent of coloring enzyme particles.
Further, the antibacterial laundry effervescent swelling tablet is characterized by being prepared from the following raw materials in percentage by weight: 13 to 18 percent of citric acid, 23 to 27 percent of sodium bicarbonate, 20 to 30 percent of sodium percarbonate, 10 to 20 percent of sodium dodecyl benzene sulfonate, 5 to 15 percent of sodium dodecyl sulfate, 10 to 15 percent of anhydrous sodium sulfate, 1.5 to 3 percent of alkaline protease, 0.5 to 1.5 percent of lipase, 1.0 to 3.0 percent of crospovidone, 0.1 to 0.2 percent of triclosan, 0.1 to 0.3 percent of essence and 0.5 percent of coloring enzyme particles.
Furthermore, the granularity of the sodium dodecyl benzene sulfonate, the sodium dodecyl sulfate, the anhydrous sodium sulfate and the sodium percarbonate is larger than 60 meshes. (if the particle size of the raw material is less than 60 meshes, the raw material is too fine and easily coheres and does not form during tabletting)
A preparation method of an antibacterial laundry effervescent swelling tablet is characterized by comprising the following steps:
(1) weighing the raw materials according to the weight percentage, mixing sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, anhydrous sodium sulfate and sodium percarbonate, uniformly stirring (30-60 min), sieving with a 60-mesh sieve, adding the complex enzyme preparation and the crospovidone, and uniformly mixing to obtain a mixture A;
(2) adding sodium bicarbonate and citric acid into a dry normal mixing reactor, uniformly mixing, adding the mixture A, the essence and the coloring enzyme particles, and uniformly mixing to obtain a mixture B;
(3) and tabletting the mixture B under high pressure (0.6 MPa) to obtain the antibacterial laundry effervescent swelling tablet.
The invention adopts triclosan as a bacteriostatic agent, which is dissolved in the solution, has general sterilization and bacteriostatic effects on escherichia coli, staphylococcus aureus, pathogenic gram-positive bacteria and the like, has extremely strong stability of triclosan, keeps stable in the tabletting process, has simple process requirements and wide application range.
The solid surfactant (sodium dodecyl benzene sulfonate and sodium dodecyl sulfate) which is easily obtained from the raw materials is easy to tablet, and is not bonded in the tabletting process; citric acid, sodium bicarbonate and sodium percarbonate are used as a buffer solution system and an effervescent system, and after the effervescence is finished, the whole pH value of the solution is neutral, so that the clothes and hands are not damaged;
in the invention, sodium percarbonate can release trace peroxy ions in the dissolving process, and the peroxy ions also have common sterilization and bacteriostasis effects on viruses, microorganisms and bacteria and a synergistic effect with a bacteriostat triclosan, so that the bacteriostasis effect is enhanced; meanwhile, the swelling agent crospovidone is added in the invention to accelerate the dissolution process of the tablet, so that the tablet is suitable for washing modes under various conditions, and meanwhile, the product is a low-foam formula, so that the washing effect is ensured and the tablet is easy to rinse.
The invention has the advantages that:
1. the invention has simple process and no wet granulation process, and the existing effervescent swelling tablet processing factory can meet the production requirements, thereby reducing the production cost; reduce the potential safety hazard in the production process
2. The bacteriostatic laundry effervescent swelling tablet can be used for producing products with different shapes according to different consumer demands, and can also be prepared into various colors and various fragrances according to needs;
3. the bacteriostatic laundry effervescent swelling tablet is convenient to use, corresponding tablets (15 g/tablet) are put in according to the kilogram number of laundry in each washing, and only one tablet is needed for each 8kg of clothes, so that the use amount is accurately controlled, the waste is avoided, and the bacteriostatic laundry effervescent swelling tablet is carried out according to the needs without occupying too much space and weight;
4. the antibacterial laundry effervescent swelling tablet provided by the invention adopts a dissolution mode of synergy of external effervescence and internal disintegration, can be quickly dissolved, has synergistic effect of active oxygen released in an effervescence process and a bacteriostatic agent triclosan, and has good antibacterial effect on various bacteria.
Detailed Description
A preparation method of an antibacterial laundry effervescent swelling tablet comprises the following specific implementation steps:
in the following embodiments, the mesh number of the sodium dodecyl benzene sulfonate, the sodium dodecyl sulfate, the anhydrous sodium sulfate and the sodium percarbonate is more than 60 meshes.
Examples
(1) Weighing the raw materials according to the weight percentage in the following table 1 for later use, mixing sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, anhydrous sodium sulfate and sodium percarbonate, stirring uniformly (30-60 min), sieving with a 60-mesh sieve, adding alkaline protease and crospovidone, and mixing uniformly to obtain a mixture A;
(2) adding sodium bicarbonate and citric acid into a dry normal mixing reactor, uniformly mixing, adding the mixture A, the essence and the coloring particles, and uniformly mixing to obtain a mixture B;
(3) tabletting the mixture B under high pressure (0.6 MPa) to obtain the antibacterial laundry effervescent swelling tablet;
(4) and (3) carrying out plastic packaging or sealing bag packaging treatment on the antibacterial laundry effervescent swelling tablets.
(5) The components are distributed as follows:
table 1: formulation tables for examples 1-5 and comparative examples 1-3
Claims (7)
1. An antibacterial laundry effervescent swelling tablet comprises acidic effervescent agent, alkaline effervescent agent, surfactant, filler, complex enzyme preparation, and disintegrating agent; the feature is that it also contains bacteriostatic triclosan 0.15% -0.2% of the total weight of the mixture, in which the alkaline effervescent agent is the mixture of sodium bicarbonate and sodium percarbonate.
2. A bacteriostatic laundry effervescent swelling tablet according to claim 1, characterized in that: the bacteriostatic laundry effervescent swelling tablet also contains essence which accounts for 0.1-0.3% of the total weight of the mixture and/or coloring enzyme particles which account for 0.5-1.0%.
3. An antibacterial laundry effervescent swelling tablet according to claim 1 or 2, characterized by being prepared from the following raw materials in percentage by weight: 10 to 20 percent of acidic effervescent agent, 25 to 40 percent of alkaline effervescent agent, 15 to 25 percent of surfactant, 5 to 15 percent of filler, 1 to 5 percent of complex enzyme preparation, 1 to 3 percent of disintegrant and 0.15 to 0.2 percent of triclosan; wherein the alkaline effervescent agent is a mixture of sodium bicarbonate and sodium percarbonate.
4. The bacteriostatic laundry effervescent swelling tablet according to claim 2, which is characterized by being prepared from the following raw materials in percentage by weight: 10 to 20 percent of citric acid, 20 to 30 percent of sodium bicarbonate, 15 to 35 percent of sodium percarbonate, 5 to 15 percent of sodium dodecyl benzene sulfonate, 10 to 15 percent of sodium dodecyl sulfate, 5 to 15 percent of anhydrous sodium sulfate, 1 to 3 percent of alkaline protease, 1 to 2 percent of lipase, 1 to 3 percent of crospovidone, 0.15 to 0.2 percent of triclosan, 0.1 to 0.3 percent of essence and 0.5 percent of coloring enzyme particles.
5. The bacteriostatic laundry effervescent swelling tablet according to claim 4, which is characterized by being prepared from the following raw materials in percentage by weight: 13 to 18 percent of citric acid, 23 to 27 percent of sodium bicarbonate, 20 to 30 percent of sodium percarbonate, 10 to 20 percent of sodium dodecyl benzene sulfonate, 5 to 15 percent of sodium dodecyl sulfate, 10 to 15 percent of anhydrous sodium sulfate, 1.5 to 3 percent of alkaline protease, 0.5 to 1.5 percent of lipase, 1.0 to 3.0 percent of crospovidone, 0.1 to 0.2 percent of triclosan, 0.1 to 0.3 percent of essence and 0.5 percent of coloring enzyme particles.
6. A bacteriostatic effervescent laundry swelling tablet according to any one of claims 4 or 5, wherein the particle sizes of the sodium dodecylbenzene sulfonate, sodium dodecyl sulfate, anhydrous sodium sulfate and sodium percarbonate are all larger than 60 mesh.
7. A process for the preparation of a bacteriostatic effervescent laundry swelling tablet according to claim 4 or 5, characterized in that it comprises the following steps:
(1) weighing the raw materials according to the weight percentage, mixing sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, anhydrous sodium sulfate and sodium percarbonate, uniformly stirring, sieving by a 60-mesh sieve, adding the complex enzyme preparation and the crospovidone, and uniformly mixing to obtain a mixture A;
(2) adding sodium bicarbonate and citric acid into a dry normal mixing reactor, uniformly mixing, adding the mixture A, the essence and the coloring enzyme particles, and uniformly mixing to obtain a mixture B;
(3) and tabletting the mixture B under high pressure to obtain the antibacterial laundry effervescent swelling tablet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011526831.4A CN112522035A (en) | 2020-12-22 | 2020-12-22 | Antibacterial laundry effervescent swelling tablet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011526831.4A CN112522035A (en) | 2020-12-22 | 2020-12-22 | Antibacterial laundry effervescent swelling tablet and preparation method thereof |
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| Publication Number | Publication Date |
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| CN112522035A true CN112522035A (en) | 2021-03-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011526831.4A Pending CN112522035A (en) | 2020-12-22 | 2020-12-22 | Antibacterial laundry effervescent swelling tablet and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113512476A (en) * | 2021-08-09 | 2021-10-19 | 浙江家至洁科技有限公司 | Multifunctional clothes, kitchen and household cleaning agent and preparation method thereof |
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| US20030059387A1 (en) * | 2001-09-13 | 2003-03-27 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Powdered composition for cosmetic effervescent cleansing pillow |
| US20030064042A1 (en) * | 2001-09-13 | 2003-04-03 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Cosmetic effervescent cleansing pillow |
| CN106635474A (en) * | 2016-10-12 | 2017-05-10 | 吉冠（上海）新材料科技有限公司 | Highly-concentrated neutral-washing zinc-ion antibacterial effervescent tablets and preparation method thereof |
| CN106753932A (en) * | 2016-12-11 | 2017-05-31 | 深圳市美益洁生物科技有限公司 | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application |
| CN109234089A (en) * | 2018-11-06 | 2019-01-18 | 西安优露清科技股份有限公司 | A kind of antibacterial fabric effervescent table for cleaning and preparation method thereof |
| CN111171967A (en) * | 2020-01-09 | 2020-05-19 | 广州市日用化学工业研究所有限公司 | Effervescent washing product with high disintegration speed and easy rinsing and preparation method thereof |
-
2020
- 2020-12-22 CN CN202011526831.4A patent/CN112522035A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030059387A1 (en) * | 2001-09-13 | 2003-03-27 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Powdered composition for cosmetic effervescent cleansing pillow |
| US20030064042A1 (en) * | 2001-09-13 | 2003-04-03 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Cosmetic effervescent cleansing pillow |
| CN106635474A (en) * | 2016-10-12 | 2017-05-10 | 吉冠（上海）新材料科技有限公司 | Highly-concentrated neutral-washing zinc-ion antibacterial effervescent tablets and preparation method thereof |
| CN106753932A (en) * | 2016-12-11 | 2017-05-31 | 深圳市美益洁生物科技有限公司 | Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application |
| CN109234089A (en) * | 2018-11-06 | 2019-01-18 | 西安优露清科技股份有限公司 | A kind of antibacterial fabric effervescent table for cleaning and preparation method thereof |
| CN111171967A (en) * | 2020-01-09 | 2020-05-19 | 广州市日用化学工业研究所有限公司 | Effervescent washing product with high disintegration speed and easy rinsing and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113512476A (en) * | 2021-08-09 | 2021-10-19 | 浙江家至洁科技有限公司 | Multifunctional clothes, kitchen and household cleaning agent and preparation method thereof |
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Application publication date: 20210319 |