CN106753728A - A kind of environment protection water-based cutting fluid and preparation method thereof - Google Patents

A kind of environment protection water-based cutting fluid and preparation method thereof Download PDF

Info

Publication number
CN106753728A
CN106753728A CN201611114856.7A CN201611114856A CN106753728A CN 106753728 A CN106753728 A CN 106753728A CN 201611114856 A CN201611114856 A CN 201611114856A CN 106753728 A CN106753728 A CN 106753728A
Authority
CN
China
Prior art keywords
stirring
cutting fluid
water
auxiliary agent
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611114856.7A
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deyang Li Long Yun Intellectual Property Operation Co Ltd
Original Assignee
Deyang Li Long Yun Intellectual Property Operation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deyang Li Long Yun Intellectual Property Operation Co Ltd filed Critical Deyang Li Long Yun Intellectual Property Operation Co Ltd
Priority to CN201611114856.7A priority Critical patent/CN106753728A/en
Publication of CN106753728A publication Critical patent/CN106753728A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/12—Oxidised hydrocarbons, i.e. oxidised subsequent to macromolecular formation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of environment protection water-based cutting fluid, it is made from the following raw materials in parts by weight：The alkenyl imidazoline 23 of 2 aminoethyl 17, nano imvite 46, polyether-modified dimethyl silicone polymer 13, salts of carboxylic acids 47, OPE 35, tall oil 24, butyl carbitol 13, Aerosol OT 12, auxiliary agent 9 12, water 120 150.The auxiliary agent of present invention addition enhances dispersion, lubrication, the filming performance of cutting fluid, the permeability and cooling performance of cutting fluid are improve simultaneously, cutting fluid of the invention has the advantages that good dispersion, stability be high, good cooling results, improve crudy, its is with low cost simultaneously, environmentally friendly, nontoxic to human body and biological degradability is good.

Description

A kind of environment protection water-based cutting fluid and preparation method thereof
Technical field
The present invention relates to cutting fluid field, more particularly to a kind of environment protection water-based cutting fluid and preparation method thereof.
Background technology
Environmental resource problem is the major issue that current mankind faces.It is exactly to realize money for green manufacturing Source is using maximization and environmental impact minimization.Cutting fluid is in manufacture plus serious consequence；The additive such as natrium nitrosum and sodium phosphate It is very big to environment and harm.Therefore, vital effect is played in the middle of the work for meeting processing characteristics, although dry type Cutting technology is succeeded application in the middle of some processing technologys, but by cooling performance is poor and the limitation of institute's technique for applying, The utilization of cutting fluid is still indispensable.In the middle of cutting process, in order to reduce the energy ezpenditure that friction belt is come, it is ensured that workpiece Quality and raising cutter life, cutting fluid must have good performance.Cutting fluid is widely used brings huge to us Economic benefit while, also threaten ecological environment and health：In the middle of undressed cutting fluid, due to antirust agent phosphorus The accumulation of sour sodium, can cause Water Eutrophication and then trigger red tide；The biological degradability of bactericide phenol is poor, to aquatic organism With very big harm；Some surfactants can make under conditions of human body skin degreasing, redness, or even cracking, suppuration, Research and development superior performance, environmentally friendly, nontoxic to the human body and good environment-friendlycutting cutting fluid of biological degradability have Very important realistic meaning.
The content of the invention
It is an object of the invention to overcome the above-mentioned deficiency in the presence of prior art, there is provided a kind of environment protection water-based cutting fluid And preparation method thereof.
In order to realize foregoing invention purpose, the invention provides following technical scheme：
A kind of environment protection water-based cutting fluid, is made from the following raw materials in parts by weight：The alkenyl imidazoline 2-3 of 2- aminoethyls 17, Nano imvite 4-6, polyether-modified dimethyl silicone polymer 1-3, salts of carboxylic acids 4-7, OPE 3-5, tall oil 2- 4th, butyl carbitol 1-3, Aerosol OT 1-2, auxiliary agent 9-12, water 120-150；
The auxiliary agent is to be made from the following raw materials in parts by weight：Rosin 1-3, potassium metaborate 1-2, pure-acrylic emulsion 5-8, different thiophene Oxazoline ketone 1-2, natrosol 1-2, boronation oleamide 3-6, polyethylene glycol 3-6, ethoxylated dodecyl alcohol sodium sulphate 1-2, defoamer 0.1-0.3, water 40-50；Preparation method is (1) by natrosol, polyethylene glycol, pure-acrylic emulsion, the moon Cinnamic alcohol polyethenoxy ether sodium sulfate is added in water, is heated to 55-65 DEG C, is stirring evenly and then adding into defoamer standby；(2) by pine Fragrant, boronation oleamide is mixed and heated to 60-70 DEG C, is slowly added to the product in step (1) after stirring, with 300-400 Rev/min rotating speed stirring, charging is heated to 75-85 DEG C after terminating, and at 2000-3000 revs/min of lower high-speed stirred 15-30 points Clock, adds remaining surplus materials and continues to stir 5-10 minutes.
Preparation method another object of the present invention is to provide above-mentioned water-base cutting fluid, comprises the following steps：
(1) tall oil, polyether-modified dimethyl silicone polymer and the alkenyl imidazoline of 2- aminoethyls 17 are mixed, is heated to 55-65 DEG C, mixture A is obtained after stirring reaction 30-40 minutes；
(2) 60-70 DEG C is rapidly cooled to after water is boiled, Aerosol OT and butyl carbitol is added Stir, it is lower stirring reaction 20-30 minutes with 1000-1400 revs/min to be stirring evenly and then adding into auxiliary agent, obtains mixture B；
(3) mixture B is slowly added while stirring in mixture A, by temperature control at 65-75 DEG C, is stirred After add remaining residual components, filtered after lower high-speed stirred 20-30 minutes at 1500-2000 revs/min.
Compared with prior art, beneficial effects of the present invention：
The auxiliary agent of present invention addition enhances dispersion, lubrication, the filming performance of cutting fluid, while improve oozing for cutting fluid Permeability and cooling performance, cutting fluid of the invention have the advantages that good dispersion, stability be high, good cooling results, improve plus Working medium amount, it is environmentally friendly, nontoxic to human body and biological degradability is good while its is with low cost.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood For the scope of above-mentioned theme of the invention is only limitted to following embodiment, all technologies realized based on present invention belong to this The scope of invention.
Embodiment 1
A kind of environment protection water-based cutting fluid, is made from the following raw materials in parts by weight：The alkenyl imidazoline 3 of 2- aminoethyls 17, receive Rice montmorillonite 5, polyether-modified dimethyl silicone polymer 2, salts of carboxylic acids 6, OPE 4, tall oil 3, butyl carbitol 2nd, Aerosol OT 1, auxiliary agent 10, water 140；
The auxiliary agent is to be made from the following raw materials in parts by weight：Rosin 2, potassium metaborate 1, pure-acrylic emulsion 7, OIT 1st, natrosol 2, boronation oleamide 5, polyethylene glycol 4, ethoxylated dodecyl alcohol sodium sulphate 2, defoamer 0.2, water 45；Preparation method is that be added to for natrosol, polyethylene glycol, pure-acrylic emulsion, ethoxylated dodecyl alcohol sodium sulphate by (1) In water, 60 DEG C are heated to, are stirring evenly and then adding into defoamer standby；(2) rosin, boronation oleamide are mixed and heated to 65 DEG C, The product in step (1) is slowly added to after stirring, is stirred with 360 revs/min of rotating speed, charging is heated to 80 after terminating DEG C, and in 2300 revs/min of lower high-speed stirreds 20 minutes, add remaining surplus materials and continue to stir 8 minutes.
The preparation method of above-mentioned environment protection water-based cutting fluid, comprises the following steps：
(1) tall oil, polyether-modified dimethyl silicone polymer and the alkenyl imidazoline of 2- aminoethyls 17 are mixed, is heated to 62 DEG C, stirring reaction obtains mixture A after 32 minutes；
(2) 67 DEG C are rapidly cooled to after water is boiled, Aerosol OT are added and butyl carbitol is stirred Mix uniform, be stirring evenly and then adding into auxiliary agent with 1200 revs/min of lower stirring reactions 25 minutes, obtain mixture B；
(3) mixture B is slowly added while stirring in mixture A, by temperature control at 70 DEG C, is added after stirring Enter remaining residual components, filtered after 25 minutes in 1600 revs/min of lower high-speed stirreds.
Cutting fluid performance indications manufactured in the present embodiment：5% emulsion stability experiment (15-30 DEG C, 24h)：Do not analyse Oil, not graining；Rust-preventing characteristic tests (35 ± 2 DEG C, steel monolithic 24h) >=54h, without rust staining；Rust-preventing characteristic tests (35 ± 2 DEG C, steel Lamination 8h) >=24h, without rust staining；Corrosion experiment (55 ± 2 DEG C, cast iron 24h) >=54h；Corrosion experiment (55 ± 2 DEG C, red copper 8h) >= 24h；Compatibility test is painted to lathe：It is non-foaming, do not ftracture, it is not tacky.

Claims (2)

1. a kind of environment protection water-based cutting fluid, it is characterised in that be made from the following raw materials in parts by weight：The alkenyl miaow of 2- aminoethyls 17 Oxazoline 2-3, nano imvite 4-6, polyether-modified dimethyl silicone polymer 1-3, salts of carboxylic acids 4-7, OPE 3-5, Tall oil 2-4, butyl carbitol 1-3, Aerosol OT 1-2, auxiliary agent 9-12, water 120-150；
The auxiliary agent is to be made from the following raw materials in parts by weight：Rosin 1-3, potassium metaborate 1-2, pure-acrylic emulsion 5-8, isothiazoline Ketone 1-2, natrosol 1-2, boronation oleamide 3-6, polyethylene glycol 3-6, ethoxylated dodecyl alcohol sodium sulphate 1-2, Defoamer 0.1-0.3, water 40-50；Preparation method is (1) by natrosol, polyethylene glycol, pure-acrylic emulsion, laruyl alcohol Polyethenoxy ether sodium sulfate is added in water, is heated to 55-65 DEG C, is stirring evenly and then adding into defoamer standby；(2) by rosin, boron Carburetion acid amides is mixed and heated to 60-70 DEG C, is slowly added to the product in step (1) after stirring, with 300-400 revs/min Rotating speed stirring, charging is heated to 75-85 DEG C after terminating, and lower high-speed stirred 15-30 minute at 2000-3000 revs/min, then plus Enter remaining surplus materials to continue to stir 5-10 minutes.
2. a kind of environment protection water-based cutting fluid according to claim 1, it is characterised in that be made up of step in detail below：
(1) tall oil, polyether-modified dimethyl silicone polymer and the alkenyl imidazoline of 2- aminoethyls 17 are mixed, is heated to 55- 65 DEG C, mixture A is obtained after stirring reaction 30-40 minutes；
(2) 60-70 DEG C is rapidly cooled to after water is boiled, Aerosol OT and butyl carbitol stirring is added Uniformly, it is stirring evenly and then adding into auxiliary agent lower stirring reaction 20-30 minutes with 1000-1400 revs/min, obtains mixture B；
(3) mixture B is slowly added while stirring in mixture A, by temperature control at 65-75 DEG C, is added after stirring Enter remaining residual components, filtered after lower high-speed stirred 20-30 minutes at 1500-2000 revs/min.
CN201611114856.7A 2016-12-07 2016-12-07 A kind of environment protection water-based cutting fluid and preparation method thereof Withdrawn CN106753728A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611114856.7A CN106753728A (en) 2016-12-07 2016-12-07 A kind of environment protection water-based cutting fluid and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611114856.7A CN106753728A (en) 2016-12-07 2016-12-07 A kind of environment protection water-based cutting fluid and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106753728A true CN106753728A (en) 2017-05-31

Family

ID=58878528

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611114856.7A Withdrawn CN106753728A (en) 2016-12-07 2016-12-07 A kind of environment protection water-based cutting fluid and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106753728A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115873654A (en) * 2022-12-01 2023-03-31 滁州默尔新材料科技有限公司 Preparation method of photovoltaic glass cutting fluid with good lubricating effect

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666721A (en) * 2013-12-05 2014-03-26 马鞍山市恒毅机械制造有限公司 Corrosion-free anti-wear semi-synthetic cutting fluid and preparation method thereof
CN104560352A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Water-based cutting fluid with remarkable rust prevention effect and good dispersity and preparation method of water-based cutting fluid
CN104560330A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Non-toxic, environment-friendly and deodorizing type metal cutting fluid and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666721A (en) * 2013-12-05 2014-03-26 马鞍山市恒毅机械制造有限公司 Corrosion-free anti-wear semi-synthetic cutting fluid and preparation method thereof
CN104560352A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Water-based cutting fluid with remarkable rust prevention effect and good dispersity and preparation method of water-based cutting fluid
CN104560330A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Non-toxic, environment-friendly and deodorizing type metal cutting fluid and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115873654A (en) * 2022-12-01 2023-03-31 滁州默尔新材料科技有限公司 Preparation method of photovoltaic glass cutting fluid with good lubricating effect
CN115873654B (en) * 2022-12-01 2023-12-15 滁州默尔新材料科技有限公司 Preparation method of photovoltaic glass cutting fluid with good lubricating effect

Similar Documents

Publication Publication Date Title
CN101659802B (en) Emulsified metal antirusting agent and preparation method thereof
CN103450762B (en) A kind of aqueous polyanion composite epoxy Corrosion resisting paint without need of cleaning rust and preparation method thereof
CN102153920A (en) Aqueous rusted anti-corrosive coating and preparation method thereof
CN107574429A (en) A kind of organic nigrescence oil and preparation method thereof
CN106590907A (en) Graphene-containing metal cutting fluid and preparation method thereof
CN105950268A (en) Metal processing multifunctional lubricating agent containing graphene additive and preparation method of metal processing multifunctional lubricating agent
CN107641418A (en) Watersoluble plumbago alkene anticorrosive paint and preparation method thereof
CN104560352A (en) Water-based cutting fluid with remarkable rust prevention effect and good dispersity and preparation method of water-based cutting fluid
CN104592853A (en) Preparation method for water-based phenolic red lead rusted antirust primer
CN103865623B (en) A kind of multi-functional nontoxic aqueous rustproof cutting liquid
CN104120017B (en) Water-base cutting fluid of the strong good antirust property of a kind of penetration and preparation method thereof
CN106753728A (en) A kind of environment protection water-based cutting fluid and preparation method thereof
CN106894023B (en) A kind of aluminium alloy corrosion-inhibiting composition and preparation method thereof
CN107746640A (en) A kind of acrylic acid antirust sealing wax and preparation method thereof
CN108948974A (en) A kind of water-based metal antirust paint lotion and preparation method thereof
CN104560336A (en) Long-acting environment-friendly type water-based cutting fluid and preparation method thereof
CN104263157A (en) Water-based acrylic red lead rust-proof paint and preparation method thereof
CN104775130B (en) A kind of environment-friendly metal skimmed milk and preparation method thereof
CN104560348A (en) Novel cutting fluid with good lubricating and cooling effects as well as preparation method thereof
CN113462455A (en) Water-based metal cutting fluid and preparation method thereof
CN104560327A (en) High-permeability metal cutting fluid with excellent corrosion resistance and preparation method of metal cutting fluid
CN106590902A (en) Anti-extreme pressure mould-proof cutting fluid and preparation method thereof
CN106590901A (en) Wearproof lubricating cutting fluid and preparation method thereof
CN104560333A (en) Extreme-pressure and lubricating emulsion type cutting fluid and preparation method thereof
CN104560330A (en) Non-toxic, environment-friendly and deodorizing type metal cutting fluid and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20170531

WW01 Invention patent application withdrawn after publication