CN106752581A - Magnesium imperial or royal seal prismatic crystal furniture anion spray and its preparation method and application - Google Patents
Magnesium imperial or royal seal prismatic crystal furniture anion spray and its preparation method and application Download PDFInfo
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- CN106752581A CN106752581A CN201611169091.7A CN201611169091A CN106752581A CN 106752581 A CN106752581 A CN 106752581A CN 201611169091 A CN201611169091 A CN 201611169091A CN 106752581 A CN106752581 A CN 106752581A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C08K2201/00—Specific properties of additives
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Abstract
The invention discloses a kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, following component is contained in parts by weight：Color stuffing：0.2 2 parts, negative ion powder：5 15 parts, paraffin：2 10 parts, synthetic resin emulsion：50 85 parts, thickener：0.2 1.5 parts, preservative：0.1 1.5 parts, silver ion：1 3.5 parts, 3 10 parts of nano mica scale.The invention also discloses the preparation method of magnesium imperial or royal seal prismatic crystal furniture anion spray.Magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by adding the materials such as silica, nano mica scale, synthetic resin emulsion, tourmaline powder, paraffin and silver ion so that anion spray has the performance of anion releasing, shielding neutron and reflection electromagnetic wave；When it is used for furniture protects, can continuously to anion releasing in space, and physical containment is carried out to furniture pollution sources using itself excellent impermeabilisation closure, slow down pollution sources and space volatilization is polluted, it is ensured that the safety and Health of people's living environment.
Description
Technical field
The invention belongs to technical field of air purification, and in particular to a kind of magnesium imperial or royal seal prismatic crystal furniture anion of energy purify air
Spray and its preparation method and application.
Background technology
In air purification field, because anion has splendid purifying and dedusting, the harm of reduction second-hand-cigarette, improvement prevention breathing
Tract disease, improve the health care of sleep, it is anti-oxidant, anti-aging, remove interior free yl and reduce blood viscosity effect, in medical field
Enjoy laudatory titles such as " tie up his oxygen ", " air vitamin ", " long-lived element " and " air vitamin ".
In physics, it is known that material is molecular, molecule be it is molecular by original, atom be by
The electronics composition that atomic nucleus and enclosing is rotated about, obtains aobvious elecrtonegativity during electronics, loses aobvious electropositive during electronics, and we are positive and negative
The motion artifacts of electronics are referred to as ionic phenomenon.In its natural state, the polarity of air molecule is in neutrality, i.e. neutral.But
Under the effects such as cosmic ray, ultraviolet, micro- radiation, Lightning strike, air molecule can lose a part around atomic nucleus
The outermost electron of rotation, ionizes air.The electronics of escape atomic nucleus constraint is referred to as free electron, negatively charged.When
After free electron is combined with other neutral gas molecules, negatively charged negative aeroion is just formed, above is in natural phenomena
The anion of generation.
With the generation and development of artificial anion generation technique.The technology of current artificially generated anion is mainly and passes through
The process of electric discharge manufacture negative oxygen ion is possible to produce ozone etc. in interior byproduct, and excessive ozone can accelerate cell old
Change, have a negative impact to health.Current state-of-the-art anion generation technique both at home and abroad, including Japan and the United States, English, method, moral
It is essentially all, using negative high voltage source, carbon fiber to be made sparking electrode (also having referred to as " discharging antenna ") Deng state, connects high
Carbon fiber electrode monopole is inserted into space after pressure, makes the peripherad space of electrode injection electronics at a high speed.Electronics is fast by air ion
Speed capture, forms negative aeroion, while being sensed using the potential of negative electric field, in cation and will reduce, to obtain a phase
To the anion for purifying.The negative high voltage of this technology must be in more than 8000V, and voltage is higher, electrode and air contact area
Bigger (electric discharge is extreme more), anion generation dosage is bigger, and the negative ion concentration of generation reaches 104/cm3~9 × 107/cm3,
But regrettably increasing with anion dosage, the growing amount of ozone also accordingly increases.This is to restrict artificial anion at present
Generation equipment urgent problem.
Furniture is the articles for use closely bound up with people's live and work, in order that furniture is durable attractive in appearance, by needing to family
Tool carries out spray painting protective treatment.At present, the paint for furniture on the market is wide in variety, purposes is wide, especially wood
Device paint, belongs to based on oil paint more, respectively has various functions, therefore when using all kinds of synthesis materials, typically all contain has to human body
Harmful material, sustained release goes out peculiar smell, such as formaldehyde, VOC (VOC), heavy metal, benzene during use
Deng causing a large amount of murders by poisoning to environment and health.
The content of the invention
For the defect of the presence of prior art, the pollution sources of inside of furniture can be closed the invention provides a kind of
The magnesium imperial or royal seal prismatic crystal furniture anion spray of the function of purified treatment and energy sustained release anion, shielding neutron and reflection electromagnetic wave
Agent.Present invention also offers the preparation method and application of the magnesium imperial or royal seal prismatic crystal furniture anion spray.
The purpose of the present invention is achieved through the following technical solutions：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, contains following component in parts by weight：Silica：0.2-2 parts, bear
Ion powder：5-15 parts, paraffin：2-10 parts, synthetic resin emulsion：50-85 parts, thickener：0.2-1.5 parts, preservative：0.1-
1.5 parts, silver ion：1-3.5 parts, nano mica scale：3-10 parts.
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, preferably, contains following component in parts by weight：Silica：1
Part, negative ion powder：10 parts, paraffin：5 parts, synthetic resin emulsion：76 parts, thickener：1 part, preservative：1 part, silver ion：1 part,
Nano mica scale：5 parts.
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, more preferably, contains following component in parts by weight：Titanium dioxide
Silicon：1 part, negative ion powder：15 parts, paraffin：8 parts, synthetic resin emulsion：70 parts, thickener：1.5 parts, preservative：0.5 part, silver
Ion：1 part, nano mica scale：3 parts.
Preferably, wherein the negative ion powder is the nano-tourmaline powder that mesh number is 6000-10000, the silica
It is porous silica.
Preferably, wherein the synthetic resin emulsion be silicone acrylic emulsion, polyaminoester emulsion and acrylic emulsion at least
One kind, and the viscosity of the synthetic resin emulsion is 300-1000cp, solid content is 20-40wt%, and pH value is 8-9, and acid number is
50-60。
Preferably, wherein during the thickener is hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite
It is at least one.
Preferably, wherein the silver ion is liquid nano silver ion, and the effective content of its silver ion is 3-8wt%.
Preferably, wherein the paraffin is Tissuemat E.
A kind of method for preparing above-mentioned magnesium imperial or royal seal prismatic crystal furniture anion spray, it is characterised in that comprise the following steps：
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the silica of formula ratio, negative ion powder and paraffin
Sequentially add high pressure to rush in mill apparatus, rush mill and be dispersed into suspension oar body；
(2) the nano mica scale of the synthetic resin emulsion and formula ratio that are uniformly added into surplus is rushed in mill apparatus to high pressure,
After high pressure punching mill dispersed with stirring, vibration filtering；
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, after dispersed with stirring is uniform, packing.
Field of the magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention in furniture protection, is conducive to in furniture
The pollution sources in portion carry out enclosed purification treatment, while can also anion releasing, purify air.
Compared with prior art, the present invention at least has advantages below：
(1) magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, constitution material is used as by using silica,
For the resistance to ag(e)ing of furniture anion spray, heat resistance, mechanical strength and chemical resistance etc. provide technical support；Using
The cementing agent of synthetic resin emulsion is used as filmogen so that anion spray can be perfectly adhered on base material, and VOC free
Discharge, safety and environmental protection；The materials such as tourmaline powder, paraffin and silver ion are added in system so that anion spray has
The performance of anion releasing, shielding neutron and reflection electromagnetic wave, the addition of paraffin, because the density ratio water of paraffin is low and paraffin
Surface tension is low, and during use, with the evaporation of moisture, the paraffin for being enclosed with negative ion powder is migrated to air surface,
So that increasing with the specific surface area of the negative ion powder of air contact, and then cause that negative ion powder can just discharge lasting releasing and bear
Ion；The addition of silver ion is easier to cause the electrical potential difference between negative ion powder crystal, so that air is ionized, is hit
The water that closes on of electron attachment and oxonium ion and it is converted into negative aeroion, improve the release of anion in negative ion powder
Amount；And nano mica scale is added in system, nano mica scale is in the film layer that furniture anion spray is formed in parallel
The palace formula structure of overlapping arrangement, so that the antiseepage Rotating fields of densification are formed, the harmful substance of inside of furniture film layer after hardening
In infiltration have to pass through without several tortuous approach；When it is used for furniture protects, not only will continuously in air
Conveying anion so that the entirely negative ion concentration more and more higher in space, and the harmful substance that furniture is had in itself is carried out
Physical containment, slows down it and is polluted to space volatilization, and is conducive to shielding neutron and transmitting electromagnetic wave, reduction neutron and electromagnetic wave pair
The influence of health.
(2) preparation method of a kind of magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, is rushed by using high pressure
Mill apparatus so that each material in system is well dispersed, form stabilization mixed slurry.
Specific embodiment
Below in conjunction with specific implementation, the present invention is described in detail.
When stated in the form of scope, preferred scope or preferred numerical upper limits and lower limit certain amount, concentration or its
It is worth or when parameter, it should be understood that equivalent to specifically disclose by by any pair range limit or preferred value with appoint
Any scope that meaning range lower limit or preferred value combine, without considering whether the scope specifically discloses.Unless referred in addition
Go out, number range value listed herein is in the end points including scope, and all integers and fraction within the scope of this.
Unless otherwise indicated, all of percentage, number, ratio etc. are by weight herein.
The material of this paper, method and embodiment are exemplary, and unless stated otherwise, be should not be construed as restricted
's.
Details are as follows for the present invention：A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, contains following component in parts by weight：Dioxy
SiClx：0.2-2 parts, negative ion powder：5-15 parts, paraffin：2-10 parts, synthetic resin emulsion：50-85 parts, thickener：0.2-1.5
Part, preservative：0.1-1.5 parts, silver ion：1-3.5 parts, nano mica scale：3-10 parts.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 0.2-2 parts two
Silica, the silica that uses of the present invention is porous silica, and the silica is incorporated as raising anion spray shape
Into the resistance to ag(e)ing of cured layer, mechanical strength and chemical resistance etc. provide technical support.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 5-15 parts bear from
Sub- powder, the negative ion powder that the present invention is used is the principle that human use's nature produces anion, artificial synthesized or proportioning
A kind of complex mineral, typically all tourmaline powder+lanthanide series or rare earth element, its main composition are as shown in the table：
| Composition | Al2O3 | SiO2 | B2O3 | MgO | Fe2O3 | Na2O |
| Content (%) | 35.10 | 34.81 | 11.02 | 4.70 | 10.18 | 0.91 |
| Composition | K2O | CaO | P2O5 | TiO2 | FeO | Other |
| Content (%) | 0.04 | It is micro | 0.22 | 0.26 | 1.35 | It is micro |
Its mesh number is 6000-10000, more preferably 2000-8000, and negative ion powder is that chemical general formula is XY3Z6
[Si6018](BO3)3(OH)4, the wherein position of X mainly occupies by Na, Ca, K, and the position of Y is mainly occupied by Mg, Fe, A1, Li, Z
Position mainly occupied by A1, due to X, Y, the displacement of Z location and formed environment difference, form numerous species, work as Y
Magnesium imperial or royal seal prismatic crystal powder when with Mg being main.Negative ion powder provides skill to be aided with the cured layer anion releasing of anion spray formation
Art is supported.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 2-10 parts of stone
Wax, the paraffin that the present invention is used melts also known as crystalline wax, typically white, tasteless waxy solid at 47-64 DEG C, and density is about
0.9g/cm3, it is dissolved in the class of gasoline, carbon disulfide, dimethylbenzene, ether, benzene, chloroform, carbon tetrachloride, naphtha etc. nonpolar molten
Agent, water insoluble and methyl alcohol polar solvent.Paraffin refined wax is good insulator, and its resistivity is 1013-1017Ohm meter,
Will be high than the most of materials in addition to some plastics (especially Teflon).Paraffin is also good heat accumulating, its specific heat
It is 2.14-2.9JgK to hold, and heat of fusion is 200-220Jg.Paraffin is as hydrogenous material to the neutron with strong γ backgrounds
Source (such as radium-beryllium neutron source), with the good effect for absorbing seed and then appropriateness shielding neutron, more preferably, paraffin
Using modified Tissuemat E, Tissuemat E has fusion temperature and the lower surface energy higher than paraffin, in anion spray
It is more beneficial for being migrated to air surface in agent system, transport efficiency is up to 30% than paraffin.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 50-85 parts of conjunction
Resin emulsion, as long as the various synthetic resin emulsions that the synthetic resin emulsion that the present invention is used can play cementation are equal
Can, in order to it is preferably supported the use with furniture, preferably in silicone acrylic emulsion, polyaminoester emulsion and acrylic emulsion at least one
Kind, the viscosity of the synthetic resin emulsion is 300-1000cp, and solid content is 20-40wt%, and pH value is 8-9, and acid number is 40-
60, the synthetic resin emulsion mainly plays cementation, and the other materials in anion spray are glued together, to be produced with base material
The firm adhesion of life.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 0.2-1.5 parts
Thickener, the thickener that the present invention is used with the system to have good thickening, suspension, dispersion, emulsification, bonding, film forming, guarantor
The characteristic such as shield moisture and offer protection adhesive tape, can specifically select hydroxyethyl cellulose type thickener, and alkali soluble is swollen, and propylene is acid-thickened
At least one in agent, sodium bentonite.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 0.1-1.5 parts
Preservative, the delay growth of microorganism that act as of the preservative that the present invention is used causes anion spray corrupt, can be hydroxyl
It is at least one or more of in benzoates, imidazolidinyl urea, KF88, bronopol, 1- phenoxy group propan-2-ols etc., plus
As long as entering amount no more than products standards regulation content.
Wherein, magnesium imperial or royal seal prismatic crystal furniture anion spray provided by the present invention, by weight, including 1-3.5 parts of silver
Ion, the silver ion that the present invention is used is the silver ion for losing more than one electronics, is existed with ionic condition, generally in positive electricity
Lotus, such as Ag1+、Ag2+、Ag3+Deng.Silver ion has oxidation, and sterilizing is usually used in daily life.It is in the present invention
Anion spray system in the not only effect with antisepsis and sterilization, also cause anion spray in air-conditioning, air purifier
During the cured film formed on air channel, the loop constituted using the silver ion in cured film produces induced current, by electricity of inducting
The reverse electromagnetic field of miscarriage life is shielded.Metal good conductor energy reflection electromagnetic wave, i.e., when wire netting aperture is less than electromagnetic wavelength
During (wavelength=light velocity/speed) 1/4, then electromagnetic wave can not be passed through, so as to substantially increase the antistatic of product, X-ray-preventing and
The functions such as ultraviolet.
Wherein, anion spray provided by the present invention, in parts by weight, also contains 3-10 parts of mica nanometer scale, cloud
Matrix is parallel to each other and laminates arrangement, forms fine and close impervious barrier female scale in the coating, according to surveying the scale in 1-2 millimeters of coating
Distribution up to tens of layers up to a hundred so that medium osmosis diffusion approach become it is tortuous, substantially prolongs medium osmosis expansion
The time of matrix is scattered to, the present invention uses nano mica scale so that the small-size effect of nano material, film layer is finer and close,
So that the impermeabilisation closure of film layer is more preferable.
A kind of method for preparing magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by the synthetic resin emulsion of formula ratio 1/2-2/3, and formula ratio color stuffing, bear from
Sub- powder and paraffin sequentially add high pressure and rush in mill apparatus, and rushing mill with the rotating speed stirring of 1000-3000r/min is dispersed into suspension oar
Body；
(2) the nano mica scale of the synthetic resin emulsion and formula ratio that are uniformly added into surplus is rushed in mill apparatus to high pressure,
After the rotating speed stirring punching mill dispersion of 1000-3000r/min, vibration filtering；
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, are stirred with the rotating speed of 1000-3000r/min
After being uniformly dispersed, packing.
Wherein, high pressure rushes the patented product that mill apparatus are our company, and its Patent No. " CN203842640U ", the equipment exists
Allow mixed slurry to circulate under the drive of high-pressure pump, and mixed slurry is fully contacted with wear-resistant ball, and in stainless steel ball
High-speed rotation, so that mixed slurry is sufficiently mixed uniformly.
Unless otherwise defined, all technologies used herein and scientific terminology have and those skilled in the art of the invention
The identical meanings being generally understood that.If there is contradiction, it is defined by the definition that the application is provided, wherein：
Magnesium imperial or royal seal prismatic crystal refers to chemical general formula as XY3Z6[Si6018](BO3)3(OH)4, wherein the position of X mainly by Na, Ca,
K is occupied, and the position of Y is mainly occupied by Mg, Fe, A1, Li, and the position of Z is mainly occupied by A1, due to X, Y, Z location displacement with
And the difference of formation environment, numerous species are formd, the tourmaline powder when Y is main with Mg.
Embodiment 1：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it contains following component by weight：Porous silica：2kg, bears
Ion powder：5kg, paraffin：3kg, synthetic resin emulsion：83.2kg, thickener：0.5kg, preservative：0.5kg, silver ion：
2.8kg, nano mica scale：3kg；The preparation method of the magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by 54kg synthetic resin emulsions, and 2kg porous silicas, 5kg negative ion powders,
3kg nano micas scale and 3kg paraffin sequentially add high pressure and rush in mill apparatus, with the rotating speed stirring punching mill dispersion of 1000r/min
Into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 29.2kg is rushed in mill apparatus to high pressure, is stirred with the rotating speed of 2000r/min
Rush after mill is uniformly dispersed, vibration filtering；
(3) 0.5kg thickeners, 0.5kg preservatives and 2.8kg silver ions are uniformly added into, are stirred with the rotating speed of 1800r/min
Mix after being uniformly dispersed, dispense.
Wherein, negative ion powder for mesh number be 8000 nano-tourmaline powder；Synthetic resin emulsion is silicone acrylic emulsion and the silicon
The viscosity of acrylic emulsion is 900cp, and solid content is 36wt%, and pH value is 8, and acid number is 52；Thickener is hydroxyethyl cellulose；Anti-corrosion
Agent is hydroxybenzoic acid esters；Silver ion is liquid nano silver ion, and the effective content of its silver ion is 3wt%.
Embodiment 2：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it contains following component by weight：Porous silica：2kg, bears
Ion powder：5kg, paraffin：3kg, synthetic resin emulsion：83.2kg, thickener：0.5kg, preservative：0.5kg, silver ion：
2.8kg, nano mica scale：3kg；The preparation method of the magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by 54kg synthetic resin emulsions, and 2kg porous silicas, 5kg negative ion powders,
3kg nano micas scale and 3kg paraffin sequentially add high pressure and rush in mill apparatus, with the rotating speed stirring punching mill dispersion of 1000r/min
Into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 29.2kg is rushed in mill apparatus to high pressure, is stirred with the rotating speed of 2000r/min
Rush after mill is uniformly dispersed, vibration filtering；
(3) 0.5kg thickeners, 0.5kg preservatives and 2.8kg silver ions are uniformly added into, are stirred with the rotating speed of 1800r/min
Mix after being uniformly dispersed, dispense.
Wherein, negative ion powder for mesh number be 8000 nano-tourmaline powder；Synthetic resin emulsion is silicone acrylic emulsion and the silicon
The viscosity of acrylic emulsion is 900cp, and solid content is 36wt%, and pH value is 8, and acid number is 52；Thickener is hydroxyethyl cellulose；Anti-corrosion
Agent is hydroxybenzoic acid esters；Silver ion is liquid nano silver ion, and the effective content of its silver ion is 3wt%, the stone
Wax is Tissuemat E.
Embodiment 3：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it contains following component by weight：Porous silica：1kg, bears
Ion powder：10kg, paraffin：5kg, synthetic resin emulsion：76kg, thickener：1kg, preservative：1kg, silver ion：1kg, nanometer
Mica flake：5kg；The preparation method of the magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by 54kg synthetic resin emulsions, and 1kg porous silicas, 10kg negative ion powders,
5kg nano micas scale and 5kg Tissuemat Es sequentially add high pressure and rush in mill apparatus, with the rotating speed punching mill dispersion of 1500r/min
Into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 26kg is rushed in mill apparatus to high pressure, punching is stirred with the rotating speed of 1000r/min
After mill is uniformly dispersed, vibration filtering；
(3) 1kg thickeners, 1kg preservatives and 1kg silver ions are uniformly added into, the rotating speed dispersed with stirring of 2000r/min is equal
After even, packing.
Wherein, negative ion powder for mesh number be 6000 nano-tourmaline powder；Synthetic resin emulsion is silicone acrylic emulsion and propylene
Yogurt liquid is 1 according to mass ratio:2 mixing, and the viscosity of the mixing synthetic resin emulsion is 750cp, solid content is 30wt%,
PH value is 8.2, and acid number is 55；Thickener is the swollen acrylic thickener of alkali soluble；Preservative is 1- phenoxy group propan-2-ols；Silver ion
It is liquid nano silver ion, and the effective content of its silver ion is 7wt%.
Embodiment 4：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it contains following component by weight：Porous silica：1kg, bears
Ion powder：15kg, paraffin：8kg, synthetic resin emulsion：70kg, thickener：1.5kg, preservative：0.5kg, silver ion：1kg,
Nano mica scale：3kg；The preparation method of the magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by 35kg synthetic resin emulsions, and 1kg porous silicas, 15kg negative ion powders,
3kg nano micas scale and 8kg paraffin sequentially add high pressure and rush in mill apparatus, with the rotating speed stirring punching mill dispersion of 1500r/min
Into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 35kg is rushed in mill apparatus to high pressure, punching is stirred with the rotating speed of 1000r/min
After mill is uniformly dispersed, vibration filtering；
(3) 1.5kg thickeners, 0.5kg preservatives and 1kg silver ions are uniformly added into, are stirred with the rotating speed of 2500r/min
After being uniformly dispersed, packing.
Wherein, negative ion powder for mesh number be 6000 nano-tourmaline powder and mesh number be 8500 nano-tourmaline powder according to
Mass ratio is 1:2 are well mixed；Synthetic resin emulsion is polyaminoester emulsion, and the viscosity of the polyaminoester emulsion is 600cp, admittedly contain
It is 26wt% to measure, and pH value is 8.7, and acid number is 56；Thickener is sodium bentonite；Preservative is bronopol；Silver ion is
Liquid nano silver ion, and the effective content of its silver ion is 6wt%.
Embodiment 5：
A kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it contains following component by weight：Porous silica：2kg, bears
Ion powder：12kg, paraffin：7kg, synthetic resin emulsion：68kg, thickener：0.2kg, preservative：1kg, silver ion：1.8kg,
Nano mica scale：8kg；The preparation method of the magnesium imperial or royal seal prismatic crystal furniture anion spray, comprises the following steps：
(1) at normal temperatures and pressures, by 42kg synthetic resin emulsions, and 2kg porous silicas, 12kg negative ion powders,
8kg nano micas scale and 7kg paraffin sequentially add high pressure and rush in mill apparatus, with the rotating speed stirring punching mill dispersion of 2500r/min
Into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 26kg is rushed in mill apparatus to high pressure, punching is stirred with the rotating speed of 1500r/min
After mill is uniformly dispersed, vibration filtering；
(3) 0.2kg thickeners, 1kg preservatives and 1.8kg silver ions are uniformly added into, are stirred with the rotating speed of 1200r/min
After being uniformly dispersed, packing.
Wherein, negative ion powder for mesh number be 7500 nano-tourmaline powder and mesh number be 10000 nano-tourmaline powder by
According to mass ratio 1:1 is well mixed；Synthetic resin emulsion is silicone acrylic emulsion, and it is 450cp to change the viscosity of silicone acrylic emulsion, and solid content is
23wt%, pH value is 8, and acid number is 50；Thickener is hydroxyethyl cellulose；Preservative is that hydroxybenzoic acid esters (are changed with KF88
Scientific name claims：The chloro- ketone of -4 isothiazoline of 2 methyl -3 of 5- and MIT (CMIT/MIT) (OIT
Isothiazolinones it is)) 1 according to mass ratio:1 is well mixed；Silver ion is liquid nano silver ion, and its silver ion
Effective content is 4.5wt%.
Performance test：
(1) each performance indications to the magnesium imperial or royal seal prismatic crystal home textile anion spray prepared by embodiment of the present invention 1-5 are carried out
Detection, concrete numerical value is as shown in table 1：
Table 1：Property indices
| Project | Standard requirement | Examination criteria |
| Condition in container | It is in uniform state without lump, after stirring | HG/T2458-1993 |
| Application property | Spraying | ----- |
| Drying time (surface drying) h | ≤2h | GB/T1728-1989 |
| Bin stability (1 year) | Never degenerate | HG/T2458-1993 |
| Radioactive material radionuclides limitation | Meet the index request of A class finishing materials | GB6566-2010 |
Remarks：Wherein radiological safety detection method is：50cm × 50cm × 1.2cm common white glass is taken, is entered with 5g products
Row even application, normal temperature 24h is pressed after drying《GB6566-2010 radioactive material radionuclides limitations》Detected.
(2) effect of magnesium imperial or royal seal prismatic crystal furniture anion spray anion releasing
In order to test the effect of the furniture anion spray anion releasing that embodiment of the present invention 1-5 is provided, and introduce 4
Group contrast groups, contrast groups 1 not spray anion spray, contrast groups 2 with when preparation method with embodiment 1, difference
It is that will be added without paraffinic components；With embodiment 1, difference is to be added without silver to the proportioning and preparation method of contrast groups 3
Ion；With embodiment 1, difference is to be added without paraffin and silver ion component to the proportioning and preparation method of contrast groups 4, and
We are measured using the method for anion static state emission measure and anion dynamic two kinds of test anions of generating capacity, wherein negative
Ion static state emission measure method of testing be：1L product 1L measuring cups splendid attire is taken, measuring cup is stretched into static anionic textiles instrument and is surveyed
Examination；The method of testing of anion dynamic emission amount is：5 50cm × 50cm × 1.2cm common white glass is taken, every common white glass is used
5g products carry out even application, and spraying is inward-facing to make cloche, is placed on simple glass table top, and 1L burettes are inverted in
Cloche center, after 15 minutes, the anion burst size in 15 minutes test burettes is continued with dynamic anionic textiles instrument.
The technical indicator of gained is as shown in table 2：
The anion emission amount situation test of the anion spray of table 2
As shown in Table 2, by comparing contrast groups 1 and embodiment 1, the release of magnesium imperial or royal seal prismatic crystal furniture anion spray is negative
Ion；By comparing contrast groups 2 and embodiment 1, the anion dynamic emission amount for having the anion spray for adding paraffinic components will
Greatly improve, it is relatively low that this is primarily due to paraffin density in itself, and surface tension is small, easily migrated to air surface, negative
During ion spray use, with the evaporation of moisture, paraffin drives negative ion powder to be migrated to air surface, increases system
The contact area of middle negative ion powder and air, so as to substantially increase the dynamic emission amount of negative ion powder；By comparing contrast groups 3
Understood with embodiment 1, add silver ion to also contribute to the raising of anion dynamic emission amount, this is primarily due in negative ion powder
The pyroelectricity and piezoelectricity having, when silver ion is added in components system, are even similar to the small changes such as air flow,
Be easier to cause the electrical potential difference between composition crystal so that air is ionized, the water that the electron attachment hit is closed on and
Oxonium ion simultaneously makes it be converted into negative aeroion；By comparing embodiment 1-5, the increasing of ratio is occupied with negative ion powder
Plus, anion static state emission measure and dynamic generating capacity are substantially improved, and this has widened the use scope of anion spray significantly, is
In large space technical support is provided rich in anion；In addition, by embodiment 1 and embodiment 2, Tissuemat E is in film layer
In migration effect greatly improved compared with paraffin, up to 30%.
(3) practical effect of magnesium imperial or royal seal prismatic crystal furniture anion spray
Lee has newly purchased a set of new house because marrying, and when finishing, Lee selects after furniture material is understood in depth
With the treated furniture of the magnesium imperial or royal seal prismatic crystal furniture anion spray prepared by the embodiment of the present invention 3, it is renovated after, peculiar smell is small,
And there is no any discomfort to body, and Lee is respectively when half a year, 1 year, 2 years, 3 years, 5 years, 7 years and 10 years are lived,
The anion concentration and content of formaldehyde at dynamic anionic textiles instrument detecting distance furniture 50cm are used in same test point, specifically
The result of test is as shown in Table 3 and Table 4：
The magnesium imperial or royal seal prismatic crystal furniture anion spray of table 3 is used for anion releasing effect during furniture
| Project name | Half a year | 1 year | 2 years | 3 years | 5 years | 7 years | 10 years |
| Negative ion amount (individual/cm3) | 12310 | 12106 | 11903 | 11705 | 11508 | 11305 | 11093 |
The magnesium imperial or royal seal prismatic crystal furniture anion spray of table 4 is used for content of formaldehyde situation during furniture
| Project name | Half a year | 1 year | 2 years | 3 years | 5 years | 7 years | 10 years |
| Content of formaldehyde (mg/m3) | 0.03 | 0.02 | 0.025 | 0.03 | 0.03 | 0.02 | 0.01 |
As shown in Table 3, when the magnesium imperial or royal seal prismatic crystal furniture anion spray that the embodiment of the present invention 3 is provided is used for furniture, only
Very thin one layer is sprayed, general thickness is 0.05-0.1mm, and from the point of view of test data, magnesium imperial or royal seal prismatic crystal furniture anion spray is used for
During treatment furniture, during using 10 years, decline is compared when negative ion amount near furniture is with beginning to use less than 10%, illustrate this hair
During use, the burst size of anion hardly declines the magnesium imperial or royal seal prismatic crystal furniture anion spray of bright embodiment 3, but may be used
With continuously anion releasing, purify air, it is ensured that the safety and Health of people's living environment；As shown in Table 4, formaldehyde
Content maintains 0.02-0.03mg/m always3Between, and it is understood that the release content of the formaldehyde in furniture be usually with when
Between extension slowly reduce, just started release content it is larger, it is possible to considerably beyond national standard requirement 0.08mg/m3, explanation
The pollution sources of inside of furniture effectively can be carried out by physics envelope using the magnesium imperial or royal seal prismatic crystal furniture anion spray of the embodiment of the present invention 3
Treatment is closed, is slowed down pollution sources and space volatilization is polluted, it is ensured that the safety and Health of people's living environment.
More than, the only present invention preferably specific embodiment, but the protection domain of invention is not limited thereto, any ripe
Know those skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in should all be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be defined by the protection domain of claims.
Claims (10)
1. a kind of magnesium imperial or royal seal prismatic crystal furniture anion spray, it is characterised in that contain following component in parts by weight：Silica：
0.2-2 parts, negative ion powder：5-15 parts, paraffin：2-10 parts, synthetic resin emulsion：50-85 parts, thickener：0.2-1.5 parts, prevent
Rotten agent：0.1-1.5 parts, silver ion：1-3.5 parts, nano mica scale：3-10 parts.
2. magnesium imperial or royal seal prismatic crystal furniture anion spray according to claim 1, it is characterised in that in parts by weight containing as follows
Component：Silica：1 part, negative ion powder：10 parts, paraffin：5 parts, synthetic resin emulsion：76 parts, thickener：1 part, preservative：
1 part, silver ion：1 part, nano mica scale：5 parts.
3. magnesium imperial or royal seal prismatic crystal furniture anion spray according to claim 1, it is characterised in that in parts by weight containing as follows
Component：Silica：1 part, negative ion powder：15 parts, paraffin：8 parts, synthetic resin emulsion：70 parts, thickener：1.5 parts, anti-corrosion
Agent：0.5 part, silver ion：1 part, nano mica scale：3 parts.
4. the magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of claims 1 to 3, it is characterised in that described negative
Ion powder is the nano-tourmaline powder that mesh number is 6000-10000, and the silica is porous silica.
5. the magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of Claims 1 to 4, it is characterised in that the conjunction
Resin emulsion is at least one in silicone acrylic emulsion, polyaminoester emulsion and acrylic emulsion, and the synthetic resin emulsion
Viscosity is 300-1000cp, and solid content is 20-40wt%, and pH value is 8-9, and acid number is 50-60.
6. the magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of Claims 1 to 5, it is characterised in that the increasing
Thick dose is at least one in hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite.
7. the magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of claim 1~6, it is characterised in that the silver
Ion is liquid nano silver ion, and the effective content of its silver ion is 3-8wt%.
8. the magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of claim 1~7, it is characterised in that the stone
Wax is Tissuemat E.
9. the preparation method of a kind of magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of claim 1~8, it is special
Levy and be, comprise the following steps：
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the silica of formula ratio, negative ion powder and paraffin are successively
Add high pressure to rush in mill apparatus, rush mill and be dispersed into suspension oar body；
(2) the nano mica scale of the synthetic resin emulsion and formula ratio that are uniformly added into surplus, high pressure are rushed in mill apparatus to high pressure
After punching mill dispersed with stirring, vibration filtering；
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, after dispersed with stirring is uniform, packing.
10. a kind of magnesium imperial or royal seal prismatic crystal furniture anion spray according to any one of claim 1~8 is in furniture protection
Using.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110227334A (en) * | 2019-06-21 | 2019-09-13 | 广州市纳能环保技术开发有限公司 | A kind of anion air purifying solution and preparation method thereof |
| CN114196313A (en) * | 2021-12-24 | 2022-03-18 | 广东百川化工有限公司 | Preparation method of negative ion sterilization antiviral furniture paint |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1648178A (en) * | 2004-01-19 | 2005-08-03 | 范存玉 | Long action negative ion antiseptic function paint |
| CN1899626A (en) * | 2005-07-21 | 2007-01-24 | 朱枫林 | Multifunction negative ion colorless spray agent |
| CN105295581A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Indoor multifunctional waterborne coating and preparation method thereof |
| CN105400408A (en) * | 2015-12-16 | 2016-03-16 | 深圳市宜丽家生态建材有限公司 | Transparent type water-borne woodenware coating capable of purifying indoor air quality |
| CN105462477A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne wood paint capable of releasing negative ions and production process thereof |
| CN105482567A (en) * | 2014-09-26 | 2016-04-13 | 王萍 | Heat-insulation antibacterial coating |
-
2016
- 2016-12-16 CN CN201611169091.7A patent/CN106752581A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1648178A (en) * | 2004-01-19 | 2005-08-03 | 范存玉 | Long action negative ion antiseptic function paint |
| CN1899626A (en) * | 2005-07-21 | 2007-01-24 | 朱枫林 | Multifunction negative ion colorless spray agent |
| CN105482567A (en) * | 2014-09-26 | 2016-04-13 | 王萍 | Heat-insulation antibacterial coating |
| CN105295581A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Indoor multifunctional waterborne coating and preparation method thereof |
| CN105462477A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne wood paint capable of releasing negative ions and production process thereof |
| CN105400408A (en) * | 2015-12-16 | 2016-03-16 | 深圳市宜丽家生态建材有限公司 | Transparent type water-borne woodenware coating capable of purifying indoor air quality |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110227334A (en) * | 2019-06-21 | 2019-09-13 | 广州市纳能环保技术开发有限公司 | A kind of anion air purifying solution and preparation method thereof |
| CN114196313A (en) * | 2021-12-24 | 2022-03-18 | 广东百川化工有限公司 | Preparation method of negative ion sterilization antiviral furniture paint |
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