CN106752472A - A kind of solar water container anticorrosive paint and preparation method thereof - Google Patents

A kind of solar water container anticorrosive paint and preparation method thereof Download PDF

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Publication number
CN106752472A
CN106752472A CN201611131431.7A CN201611131431A CN106752472A CN 106752472 A CN106752472 A CN 106752472A CN 201611131431 A CN201611131431 A CN 201611131431A CN 106752472 A CN106752472 A CN 106752472A
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China
Prior art keywords
parts
water container
solar water
anticorrosive paint
preparation
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Application number
CN201611131431.7A
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Chinese (zh)
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CN106752472B (en
Inventor
欧阳檐凤
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Huizhou Wei Di card Chemical Co., Ltd.
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QINZHOU PACIFIC ELECTRONIC TECHNOLOGY Co Ltd
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Priority to CN201611131431.7A priority Critical patent/CN106752472B/en
Publication of CN106752472A publication Critical patent/CN106752472A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/204Applications use in electrical or conductive gadgets use in solar cells
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The important component of solar energy --- water tank typically makes of color steel, not only economical and practical but also attractive in appearance, but the color steel surface lacquer of solar water container easily comes off and then have impact on the durability of water tank and attractive in appearance.Coating can protect tank shell, but most of coating all contains benzene currently on the market, and benzene is volatile, and toxic, has injury to humans and animals.Therefore a kind of nontoxic, adhesive force of research and development is strong, could meet needs to the etch-proof coating of color steel.The present invention relates to paint field, specifically a kind of solar water container anticorrosive paint and preparation method thereof, the anticorrosive paint raw material includes in parts by weight:Highly-chlorinated polyethylene, polyvinyl acetate resin, Ludox, iron powder, aluminium triphosphate, trbasic zinc phosphate, n-butanol, ethanol, tributyl phosphate, polyester-modified polysiloxanes, mica powder, blanc fixe, concrete.The present invention is anti-to have antiseptic property good, and adhesive force is strong, and film is fine and close and harder, and antipollution power is strong, and the advantage without benzene.

Description

A kind of solar water container anticorrosive paint and preparation method thereof
Technical field
The present invention relates to paint field, specifically a kind of solar water container anticorrosive paint and preparation method thereof.
Background technology
In recent years, with the improvement of people ' s living standards, everybody increasingly attaching importance to environmental protection problem, solar water heater Promoted therewith.The important component of solar energy --- water tank typically makes of color steel, not only economical and practical but also attractive in appearance, but The color steel surface lacquer of solar water container easily comes off and then have impact on the durability of water tank and attractive in appearance.And big portion currently on the market Coating is divided all to contain benzene, the People's Republic of China (PRC)《Dangerous cargo name of an article table》(GB12268-90)Regulation, it is dangerous that benzene belongs to the 3rd class Middle flash-point liquid in goods flammable liquid.And due to its volatility, steam localized clusters are likely to result in, exposed to air In be easy to diffusion, humans and animals suction or skin contact a large amount of benzene and enter and can cause acute and chronic benzene poisoning in vivo.Therefore The demand that a kind of nontoxic, adhesive force is strong, market is just adapted to the etch-proof coating of color steel is researched and developed, the need of people could be met Will.
The content of the invention
The invention provides a kind of solar water container anticorrosive paint and preparation method thereof, concrete technical scheme is as follows:
A kind of solar water container anticorrosive paint raw material includes in parts by weight:3~10 parts of highly-chlorinated polyethylene, polyvinyl acetate tree 9~15 parts of fat, 4~9 parts of Ludox, 5~9 parts of iron powder, 1~5 part of aluminium triphosphate, 1~5 part of trbasic zinc phosphate, n-butanol 6~10 Part, 2~10 parts of ethanol, 5~10 parts of tributyl phosphate, 3~8 parts of polyester-modified polysiloxanes, 2~8 parts of mica powder, sulfate precipitate 3~8 parts of barium, 6~12 parts of concrete.
Preferably, raw material includes in parts by weight:5~8 parts of highly-chlorinated polyethylene, 10~14 parts of polyvinyl acetate resin, 3~8 parts of Ludox, 4~6 parts of iron powder, 1~3 part of aluminium triphosphate, 1~4 part of trbasic zinc phosphate, 7~9 parts of n-butanol, ethanol 3~8 Part, 6~8 parts of tributyl phosphate, 4~6 parts of polyester-modified polysiloxanes, 3~6 parts of mica powder, 4~7 parts of blanc fixe, coagulation 8~10 parts of soil.
Further, the preparation method of the solar water container anticorrosive paint is comprised the following steps:
(1)Highly-chlorinated polyethylene, polyvinyl acetate resin, n-butanol are sufficiently stirred for, mixed liquor is obtained;
(2)Ludox, concrete, iron powder, tributyl phosphate, polyester-modified polysiloxanes are added into step(1)The mixing of gained Liquid, is sufficiently stirred for, is ground to fineness in 150 mesh, and then vacuum dehydration obtains mixture under conditions of 95~100 DEG C;
(3)Aluminium triphosphate, trbasic zinc phosphate, ethanol, mica powder, blanc fixe are added into step(2)The mixture of gained is gone forward side by side Row stirring, it is ground to fineness and reaches 100 mesh.
Preferably, the mixing speed is 350~450rpm;Mixing time is 25~35min.
Preferably, the vacuum of the vacuum dehydration is 0.07~0.12MPa;The time of vacuum dehydration is 2.5h.
Beneficial effects of the present invention are:
(1)The solar water container anticorrosive paint that the present invention is provided and preparation method thereof anticorrosive paint is free of benzene, nontoxic and environmental protection;
(2)The anticorrosion with coat performance is good, and adhesive force is strong, and brush is not allowed easy to fall off on color steel, and the water tank to solar energy is played very Good protective effect;
(3)Ludox has the characteristic of a certain amount of film forming dissolving, and its water resistance, heat resistance are substantially better than organic coating.Film It is fine and close and harder, electrostatic is not produced, the difficult adhesion of various dust in air, contamination resistance is stronger.
(4)Ludox has stronger penetration to basic unit, and calcium silicates is generated with the calcium hydroxide reaction in concrete, makes painting Material has stronger cohesive force.
Specific embodiment
In order to be better understood from the present invention, with reference to specific embodiment, the present invention will be further described:
Embodiment one:
A kind of solar water container anticorrosive paint raw material includes in parts by weight:5 parts of highly-chlorinated polyethylene, polyvinyl acetate resin 10 Part, 3 parts of Ludox, 4 parts of iron powder, 1 part of aluminium triphosphate, 1 part of trbasic zinc phosphate, 7 parts of n-butanol, 3 parts of ethanol, 6 parts of tributyl phosphate, 4 parts of polyester-modified polysiloxanes, 3 parts of mica powder, 4 parts of blanc fixe, concrete eight part.
Further, the preparation method of the solar water container anticorrosive paint is comprised the following steps:
((1)Highly-chlorinated polyethylene, polyvinyl acetate resin, n-butanol are obtained into mixed liquor with 350rpm stirrings 25min;
(2)Ludox, concrete, iron powder, tributyl phosphate, polyester-modified polysiloxanes are added into step(1)The mixing of gained Liquid, with 350rpm stirrings 25min, is ground to fineness in 150 mesh, then 95 DEG C, vacuum be 0.07MPa under conditions of vacuum Dehydration 2.5h obtains mixture;
(3)Aluminium triphosphate, trbasic zinc phosphate, ethanol, mica powder, blanc fixe are added into step(2)The mixture of gained and with 350rpm stirrings 25min, it is ground to fineness and reaches 100 mesh.
A kind of solar water container anticorrosive paint raw material includes in parts by weight:8 parts of highly-chlorinated polyethylene, polyvinyl acetate tree 14 parts of fat, 8 parts of Ludox, 6 parts of iron powder, 3 parts of aluminium triphosphate, 4 parts of trbasic zinc phosphate, 9 parts of n-butanol, 8 parts of ethanol, tributyl phosphate 8 parts, 6 parts of polyester-modified polysiloxanes, 6 parts of mica powder, 7 parts of blanc fixe, 10 parts of concrete.
Further, the preparation method of the solar water container anticorrosive paint is comprised the following steps:
(1)Highly-chlorinated polyethylene, polyvinyl acetate resin, n-butanol are obtained into mixed liquor with 450rpm stirrings 35min;
(2)Ludox, concrete, iron powder, tributyl phosphate, polyester-modified polysiloxanes are added into step(1)The mixing of gained Liquid, with 450rpm stirrings 35min, is ground to fineness in 150 mesh, then 100 DEG C, vacuum be 0.12MPa under conditions of it is true Sky dehydration 2.5h obtains mixture;
(3)Aluminium triphosphate, trbasic zinc phosphate, ethanol, mica powder, blanc fixe are added into step(2)The mixture of gained and with 450rpm stirrings 35min, it is ground to fineness and reaches 100 mesh.
The present invention is not limited to above-described specific embodiment, the foregoing is only preferable case study on implementation of the invention , it is not intended to limit the invention, all any modifications made within the spirit and principles in the present invention, equivalent and change Enter, should be included within the scope of the present invention.

Claims (5)

1. a kind of solar water container anticorrosive paint, it is characterised in that:Raw material includes in parts by weight:Highly-chlorinated polyethylene 3~10 Part, 9~15 parts of polyvinyl acetate resin, 4~9 parts of Ludox, 5~9 parts of iron powder, 1~5 part of aluminium triphosphate, trbasic zinc phosphate 1~5 Part, 6~10 parts of n-butanol, 2~10 parts of ethanol, 5~10 parts of tributyl phosphate, 3~8 parts of polyester-modified polysiloxanes, mica powder 2 ~8 parts, 3~8 parts of blanc fixe, 6~12 parts of concrete.
2. a kind of solar water container anticorrosive paint according to claim 1, it is characterised in that:Raw material is wrapped in parts by weight Include:5~8 parts of highly-chlorinated polyethylene, 10~14 parts of polyvinyl acetate resin, 3~8 parts of Ludox, 4~6 parts of iron powder, tripolyphosphate 1~3 part of aluminium, 1~4 part of trbasic zinc phosphate, 7~9 parts of n-butanol, 3~8 parts of ethanol, 6~8 parts of tributyl phosphate, the poly- silica of polyester modification 4~6 parts of alkane, 3~6 parts of mica powder, 4~7 parts of blanc fixe, concrete eight~10 part.
3. the preparation method of solar water container anticorrosive paint according to claim 1 and 2, it is characterised in that:Including following Step:
(1)Highly-chlorinated polyethylene, polyvinyl acetate resin, n-butanol are sufficiently stirred for, mixed liquor is obtained;
(2)Ludox, concrete, iron powder, tributyl phosphate, polyester-modified polysiloxanes are added into step(1)The mixing of gained Liquid, is sufficiently stirred for, is ground to fineness in 150 mesh, and then vacuum dehydration obtains mixture under conditions of 95~100 DEG C;
(3)Aluminium triphosphate, trbasic zinc phosphate, ethanol, mica powder, blanc fixe are added into step(2)The mixture of gained is gone forward side by side Row stirring, it is ground to fineness and reaches 100 mesh.
4. the preparation method of solar water container anticorrosive paint according to claim 3, it is characterised in that:The mixing speed It is 350~450rpm;Mixing time is 25~35min.
5. the preparation method of solar water container anticorrosive paint according to claim 3, it is characterised in that:The vacuum dehydration Vacuum be 0.07~0.12MPa;The time of vacuum dehydration is 2.5h.
CN201611131431.7A 2016-12-09 2016-12-09 A kind of solar water container anticorrosive paint and preparation method thereof Expired - Fee Related CN106752472B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108727911A (en) * 2018-05-21 2018-11-02 山东高强紧固件有限公司 A kind of bolt and nut surface conditioning agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694802A (en) * 2013-12-16 2014-04-02 青岛优维奥信息技术有限公司 Special coating for corrosion resistance
CN104130707A (en) * 2014-07-30 2014-11-05 苏州聚康新材料科技有限公司 Anticorrosion primer for steel structure and preparation method thereof
CN104559671A (en) * 2015-01-10 2015-04-29 安徽省东瑞装饰材料有限公司 Waterborne flame-retardant antirust noise reduction coating for multiple equipment shells and preparation method of coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694802A (en) * 2013-12-16 2014-04-02 青岛优维奥信息技术有限公司 Special coating for corrosion resistance
CN104130707A (en) * 2014-07-30 2014-11-05 苏州聚康新材料科技有限公司 Anticorrosion primer for steel structure and preparation method thereof
CN104559671A (en) * 2015-01-10 2015-04-29 安徽省东瑞装饰材料有限公司 Waterborne flame-retardant antirust noise reduction coating for multiple equipment shells and preparation method of coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108727911A (en) * 2018-05-21 2018-11-02 山东高强紧固件有限公司 A kind of bolt and nut surface conditioning agent

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Address after: 516200 room 523, 5 / F, executive office building, Hon Hai fine chemical base, Huiyang District, Huizhou, Guangdong

Applicant after: Huizhou Wei Di card Chemical Co., Ltd.

Address before: 535000 Qinzhou, the Guangxi Zhuang Autonomous Region Galaxy 2 Street East Paris District 2 2 units 203 rooms

Applicant before: QINZHOU PACIFIC ELECTRONIC TECHNOLOGY CO., LTD.

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