CN106751592A - A kind of spinning heating composite master batch and preparation method thereof - Google Patents
A kind of spinning heating composite master batch and preparation method thereof Download PDFInfo
- Publication number
- CN106751592A CN106751592A CN201710023383.8A CN201710023383A CN106751592A CN 106751592 A CN106751592 A CN 106751592A CN 201710023383 A CN201710023383 A CN 201710023383A CN 106751592 A CN106751592 A CN 106751592A
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- spinning
- master batch
- composite master
- heating composite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Multicomponent Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
The present invention relates to a kind of spinning heating master batch and preparation method thereof, belong to functional high polymer material field.A kind of spinning heating composite master batch, it is characterized in that being prepared from by polyethylene terephthalate (spinning-grade PET), polycaprolactam, zirconia powder, tourmaline, colour carbon black, graphene oxide, acrylic acid, antimony doped tin oxide powder, calcium stearate, mass percent shared by each raw material is respectively:Polyethylene terephthalate 45%~49%;Polycaprolactam 35%~40%;Zirconia powder 1%~3%;Tourmaline 1%~4%;Colour carbon black 0.1%~0.6%;Graphene oxide 1%~3%;Acrylic acid 0.1%~1%;Antimony doped tin oxide powder 0.1%~4.0%;Calcium stearate 0.1%~1.0%.The master batch is made spontaneous thermal fiber, its spontaneous heating effect is significant.
Description
Technical field
The present invention relates to a kind of spinning heating master batch and preparation method thereof, belong to functional high polymer material field.
Background technology
Heat generating fiber is a kind of brand-new material of self-heating and warm body.Heat generating fiber on the market mainly has at present
Far infrared heating fiber, hygroscopic heating fibers, phase change fiber.All of far infrared heating fiber is all in plus the method for type
Far-infared ceramic powder and master batch co-blended spinning are obtained.
There is not the hair of spinning polyethylene terephthalate (spinning-grade PET) and polycaprolactam in existing document
Hot functional form composite master batch, the spontaneous thermal effect of existing heat generating fiber is not also notable.
The content of the invention
It is an object of the invention to provide a kind of spinning heating composite master batch and preparation method thereof, the master batch is made spontaneous
Thermal fiber, its spontaneous heating effect is significant.
To achieve these goals, technical solution of the invention is:A kind of spinning heating composite master batch, its feature
It is by polyethylene terephthalate (spinning-grade PET), polycaprolactam, zirconia powder, tourmaline, colour carbon black, oxygen
Graphite alkene, acrylic acid, antimony doped tin oxide powder, calcium stearate are prepared from, and mass percent shared by each raw material is respectively:
Antimony and the molar ratio of tin are 1 in the antimony doped tin oxide powder:9.
Above-mentioned a kind of spinning preparation method of heating composite master batch, it is characterised in that it comprises the following steps:
1) raw material is chosen according to following mass percent,
2) above-mentioned raw materials are mixed, is stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning and use
Heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
The characteristics of there is the inorganic black particle of addition the energy that will can be absorbed in sunshine rapidly to change into heat energy.Add
Zirconia powder, enables fiber to produce electrical potential difference when the deformation such as being stretched, replying and bending so that when fiber is woven into
When loop and generation electrical potential difference, there is electric current to pass through;Electric energy is converted into by mechanical energy so as to complete, then heat energy is converted into by electric energy
Transformation;When application deformation heat generating fiber is made textile, energy-storage travelling wave tube, and temperature control element can be added by actual conditions,
Its unnecessary electric energy is set effectively to store.
The beneficial effects of the invention are as follows:Using zirconia powder, tourmaline, colour carbon black, acrylic acid and antimony doped tin oxide powder
Body collective effect, and the specific proportioning of the present invention;After the master batch is made spontaneous thermal fiber, its spontaneous heating effect is significant.
Specific embodiment
For a better understanding of the present invention, it is with reference to the embodiment content that the present invention is furture elucidated but of the invention
Content is not limited solely to the following examples.
In following embodiments, antimony and the molar ratio of tin are 1 in the antimony doped tin oxide powder:9, the antimony doped tin oxide powder
Between 40 nanometers to 100 nanometers, the far infrared irradiation rate of the antimony doped tin oxide powder is 0.94 to the particle diameter of body, and this is mixed
Antimony oxidation tin powder has the characteristic of the near infrared ray that absorbable wavelength is 0.7 micron to 2 microns.
Embodiment 1:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio,
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
Embodiment 2:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio;
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
Embodiment 3:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio;
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
Embodiment 4:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio;
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
Embodiment 5:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio;
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
Embodiment 6:
A kind of spinning heating composite master batch, is prepared from the following materials, and mass percent shared by each raw material is respectively:
A kind of above-mentioned spinning preparation method of heating composite master batch, it comprises the following steps:
1) raw material is chosen by said ratio;
2) above-mentioned raw materials are sufficiently mixed, are stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning
Silk heating composite master batch.
The processing temperature of described double screw extruder is 270 DEG C -280 DEG C (spinning the temperature inside the box is 280 DEG C -285 DEG C).
A kind of preparation method of spontaneous thermal fiber, comprises the following steps:1) the spinning preparation of heating composite master batch;2) will
Spinning is put into melt spinning machine with heating composite master batch and carries out melt spinning and obtains precursor, by filament surfaces carry out drawing-off winding,
Stretching, sizing, obtain spontaneous thermal fiber.
By the polyester fiber of spontaneous thermal fiber obtained in embodiment 1-6 and comparative example, { masterbatch is pure polyester (poly- terephthaldehyde
Sour glycol ester) } test comparison is carried out, characterized with infrared thermoviewer, heating effect, gained test effect are weighed with temperature
Fruit such as table 1 below.
Table 1
Table 1 shows, master batch of the present invention is made into spontaneous thermal fiber, its spontaneous heating effect is significant.
Claims (4)
1. a kind of spinning heating composite master batch, it is characterised in that by polyethylene terephthalate (spinning-grade PET), gather oneself
It is prepared by lactams, zirconia powder, tourmaline, colour carbon black, graphene oxide, acrylic acid, antimony doped tin oxide powder, calcium stearate
Form, mass percent shared by each raw material is respectively:
2. a kind of spinning according to claim 1 heating composite master batch, it is characterised in that:The antimony doped tin oxide powder
Middle antimony is 1 with the molar ratio of tin:9.
3. a kind of spinning as claimed in claim 1 preparation method of heating composite master batch, it is characterised in that it includes as follows
Step:
1) raw material is chosen according to following mass percent,
2) above-mentioned raw materials are mixed, is stirred, through twin-screw extrusion machining, granulation, obtained a kind of spinning heating
Composite master batch.
4. a kind of spinning according to claim 3 preparation method of heating composite master batch, it is characterised in that described is double
The processing temperature of screw extruder is 270 DEG C -280 DEG C.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108486710A (en) * | 2018-01-17 | 2018-09-04 | 南通富尊纺织科技有限公司 | A kind of production technology of high energy jewel bio wave health yarn |
CN108950717A (en) * | 2018-05-17 | 2018-12-07 | 无锡恒诺纺织科技有限公司 | A kind of extinction heat generating fiber and its spinning processing technology |
CN111593433A (en) * | 2020-05-25 | 2020-08-28 | 中国科学技术大学先进技术研究院 | Energy-storage heating fiber and preparation method thereof |
CN114507930A (en) * | 2022-01-27 | 2022-05-17 | 青岛上雅家居用品股份有限公司 | Moisture absorption and heat accumulation plush fabric that generates heat |
CN115074859A (en) * | 2022-05-27 | 2022-09-20 | 厦门欣思源新材料科技股份有限公司 | Efficient heating and warming composite fiber and preparation method thereof |
CN117683348A (en) * | 2024-01-30 | 2024-03-12 | 广州傲群刷业科技有限公司 | Wear-resistant industrial bristle material and production process thereof |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108486710A (en) * | 2018-01-17 | 2018-09-04 | 南通富尊纺织科技有限公司 | A kind of production technology of high energy jewel bio wave health yarn |
CN108950717A (en) * | 2018-05-17 | 2018-12-07 | 无锡恒诺纺织科技有限公司 | A kind of extinction heat generating fiber and its spinning processing technology |
CN111593433A (en) * | 2020-05-25 | 2020-08-28 | 中国科学技术大学先进技术研究院 | Energy-storage heating fiber and preparation method thereof |
CN114507930A (en) * | 2022-01-27 | 2022-05-17 | 青岛上雅家居用品股份有限公司 | Moisture absorption and heat accumulation plush fabric that generates heat |
CN115074859A (en) * | 2022-05-27 | 2022-09-20 | 厦门欣思源新材料科技股份有限公司 | Efficient heating and warming composite fiber and preparation method thereof |
CN117683348A (en) * | 2024-01-30 | 2024-03-12 | 广州傲群刷业科技有限公司 | Wear-resistant industrial bristle material and production process thereof |
CN117683348B (en) * | 2024-01-30 | 2024-04-09 | 广州傲群刷业科技有限公司 | Wear-resistant industrial bristle material and production process thereof |
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Application publication date: 20170531 |