CN106757439A - A kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof - Google Patents

A kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof Download PDF

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Publication number
CN106757439A
CN106757439A CN201611174796.8A CN201611174796A CN106757439A CN 106757439 A CN106757439 A CN 106757439A CN 201611174796 A CN201611174796 A CN 201611174796A CN 106757439 A CN106757439 A CN 106757439A
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CN
China
Prior art keywords
heating
moisture absorbing
sweat releasing
particle
fiber
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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CN201611174796.8A
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Chinese (zh)
Inventor
王栋
郭启浩
赵青华
梅涛
蒋海青
吴永智
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Wuhan Textile University
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Wuhan Textile University
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Priority to CN201611174796.8A priority Critical patent/CN106757439A/en
Publication of CN106757439A publication Critical patent/CN106757439A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof, belong to functional fibre material technical field.Functional fibre of the invention includes fiber bodies, the cross sectional shape of fiber bodies is circle, several raised polymorphic structures are outwards formed uniformly on circumference, the inside of fiber bodies offers circular cavity, and fiber bodies are made up of together heat generating fiber monofilament juxtaposed beaming.It is inner hollow that the present invention uses spinneret, cross sectional shape is the twin-screw spinning-drawing machine that several raised polymorphic structures are outwards formed uniformly on circular periphery, inorganic heating powder is carried out into melt spinning with polyester according to certain mass percent, functional fibre is prepared.Functional fibre of the invention has the fiber of moisture absorbing and sweat releasing, heating and heat insulation function concurrently, can be used for intelligent clothing field.

Description

A kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof
Technical field
The present invention relates to functional fibre material technical field, more particularly to a kind of moisture absorbing and sweat releasing, generate heat and be incubated many work( Energy fiber and preparation method thereof.
Background technology
Functional fibre refers in addition to the physical and mechanical properties that general fiber has, also with the new of certain specific function Fiber type, such as has healthcare function (antibacterial, mite killing, physiotherapy and eliminate the unusual smell);Safeguard function (radiation proof, antistatic, uvioresistant Line etc.);Medical treatment and environment-friendly function (biocompatibility and biological degradability) etc.;The development of functional fibre is that modern fiber science enters The symbol of step, the technological innovation for developing into traditional textile industry of functional fibre, creates favorably to the conversion of high-tech industry Condition, is that mankind's growth in the living standard contributes.
Chinese invention patent application (application publication number:CN104213242A, Shen Qing Publication day:2014-12-17) disclose A kind of extinction heating function fiber and its spinning processing technology and fabric, the extinction heating function of the application for a patent for invention are fine Dimension is polyester slice, the inorganic black particle that parts by weight are 1 part~10 parts and the weight by parts by weight no less than 90 parts Number is that the melt spinning processing after dry mixed of 0 part~9 parts of Masterbatch is prepared, and extinction heating function fiber Eventually pass through circular knitting machine weaving, it is overboard sizing and be made the fabric with extinction heating function, the application for a patent for invention is carried A kind of extinction heating function fiber and its spinning processing technology and fabric are supplied, it is fine that it can solve existing thermal isolation and heat storage feature Also without being dyeed again after dimension or the poor problem of fabric heat absorption efficiency, and its weaving such that it is able to reach energy-conservation and subtract The purpose of row.
Chinese utility model patent (Authorization Notice No.:CN204825149U, Authorization Notice No.:2015-12-02) disclose Terylene profiled filament, including section is circular body, and manhole is provided with body central, and the outer rim of manhole is circumferential Some first grooves of cloth, the circumferential uniform some ellipse holes in periphery and kidney ellipsoid through hole of manhole, ellipse hole The quantity of quantity and the first groove is equal, and the first groove, ellipse hole are stretched into one of major axis end of ellipse hole Two stud ends be provided with the second groove, the kidney ellipsoid through hole of arc, kidney ellipsoid are provided between two neighboring ellipse hole The both ends of through hole are respectively protruding into the second groove of corresponding two ellipse holes, the circumferential uniform some and waist of body outer rim The 3rd relative groove of manhole, the quantity of the 3rd groove and the quantity of kidney ellipsoid through hole are equal.The terylene profiled filament bullet Property is high, and intensity is high, good hygroscopicity, and anti pilling ability is strong.
Not yet there is the report of the multifunctional fibre for having moisture absorbing and sweat releasing, heating and heat insulation function concurrently at present.
The content of the invention
It is an object of the invention to disclose a kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof. Functional fibre of the invention includes fiber bodies, and the cross sectional shape of fiber bodies is outwards to be formed uniformly several on circular periphery Raised polymorphic structure so that fiber surface forms several grooves, therefore possess the function of moisture absorbing and sweat releasing, the inside of fiber bodies Circular cavity is offered, low-fiber rate of heat dispation can drop in hollow structure so that fiber has certain heat-insulating property, and Fiber bodies are made up of together heat generating fiber monofilament juxtaposed beaming, impart the functional fibre heating property, therefore the present invention Fiber bodies have concurrently moisture absorbing and sweat releasing and heating and heat insulation function, can be used for intelligent clothing field.
To achieve the above object, the invention discloses a kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre, including fiber Body, the cross sectional shape of the fiber bodies is described to be outwards formed uniformly several raised polymorphic structures on circular periphery The inside of fiber bodies offers circular cavity, and fiber bodies are made up of together heat generating fiber monofilament juxtaposed beaming.
Further, the projection in the polymorphic structure is the one kind in arc convex, rectangular preiection, zigzag projection.
Yet further, the heat generating fiber monofilament is the inorganic particle modified monofilament polyester of heating, the inorganic heating grain Sub- modified poly ester monofilament is 60%~99.9% by mass percent:It is prepared by 0.1%~40% polyester and inorganic heating particle Form.
Further, the polyester be PET, PBT, PTT in one or more by any proportioning mixture; The inorganic heating particle is one kind or one kind in far-infared ceramic powder, Graphene, CNT, the carbide of transition metal Above by the mixture of any proportioning.
Further, the particle diameter of the inorganic heating particle is 1000~15000 mesh.
To realize the purpose of the present invention, the invention also discloses a kind of technical scheme, i.e., a kind of moisture absorbing and sweat releasing, heat preservation The preparation method of multifunctional fibre, comprises the following steps:
1) inorganic heating particle and polyester are carried out being sufficiently mixed drying according to corresponding mass percent, after stirring Granulated through double screw extruder, prepare the powder-modified polyester master particle of heating;
2) by the step 1) the powder-modified polyester master particle of heating that obtains is placed in and melting spinning carried out in twin-screw spinning-drawing machine Silk, prepares moisture absorbing and sweat releasing, heat preservation multifunctional fibre, and the spinneret of the twin-screw spinning-drawing machine is inner hollow, Cross sectional shape is outwards to be formed uniformly several raised polymorphic structures on circular periphery.
Further, the step 2) in, the temperature of melt spinning is 200~300 DEG C.
Yet further, the step 1) in, the temperature of double screw extruder granulation is 200~270 DEG C.
Beneficial effect:
1st, the cross sectional shape of fiber bodies of the invention is the abnormity that several projections are outwards formed uniformly on circular periphery Structure so that fiber surface forms several grooves, not only makes the surface area of fiber increase compared with the surface area of circular fiber, And wet structure is led in the wicking by groove, fiber is reached the function of rapid moisture absorbing and sweat releasing, keep skin dry and comfortable with it is pleasantly cool; The inside of fiber bodies offers circular cavity, and low-fiber rate of heat dispation can drop in hollow structure so that fiber has one Fixed heat-insulating property;
2nd, fiber bodies of the present invention are made up of together heat generating fiber monofilament juxtaposed beaming, and heat generating fiber monofilament is inorganic hair Hot particle modified poly ester monofilament, is blended using polyester and inorganic heating particle, assigns material certain heating function;
3rd, moisture absorbing and sweat releasing, heating and the insulation multifunctional fibre prepared using the present invention, infrared ray can penetrate fiber sheet The surface of body, absorbs the infrared ray from extraneous and human body, and photothermal deformation phenomenon occurs, and raises fiber surface temperature, human body Feel at low ambient temperatures warm;Low-fiber coefficient of heat transfer can drop in the hollow structure of fiber, with insulation work(function, reduce Human body thermal loss at low ambient temperatures;The polymorphic structure of fiber bodies cross sectional shape makes fiber surface form groove, by Wet structure is led in the wicking of groove, rapid to absorb skin surface moisture and sweat, and moment excretes, so as to reach moisture absorption row Sweat, regulation body temperature purpose, make skin keep it is dry and comfortable with it is pleasantly cool, therefore functional fibre of the invention can be used for intelligent clothing neck Domain.
Brief description of the drawings
Fig. 1 to Fig. 6 is the structural representation of the cross sectional shape of embodiment of the present invention fiber bodies.
Specific embodiment
In order to preferably explain the present invention, below in conjunction with specific embodiments and the drawings the present invention is furture elucidated it is main in Hold, but present disclosure is not limited solely to following examples.
Embodiment 1
The carbon nanotube dust that 99.9kg PET and 0.1kg mesh numbers are 5000 mesh is sufficiently mixed, through double after stirring Screw extruder is granulated, and the operating temperature of double screw extruder is 200 DEG C, prepares the powder-modified polyester master particle of heating;Again The 100kg powder-modified polyester master particles that generate heat are placed in melt spinning is carried out in twin-screw spinning-drawing machine, it is 220 to control spinning temperature DEG C, and the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is convex to be outwards formed uniformly several on circular periphery The polymorphic structure for rising, the present embodiment is preferably projection in polymorphic structure for arc convex, petal-shaped as shown in Figure 1, finally Prepare moisture absorbing and sweat releasing, heating and insulation multifunctional fibre.
Embodiment 2
The graphene powder that 99.9kg PET and 0.1kg mesh numbers are 3000 mesh is sufficiently mixed, through double spiral shells after stirring Bar extruder is granulated, and the operating temperature of double screw extruder is 250 DEG C, prepares the powder-modified polyester master particle of heating;Again will The powder-modified polyester master particle of 100kg heatings is placed in and melt spinning is carried out in twin-screw spinning-drawing machine, controls spinning temperature for 270 DEG C, And the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is outwards to be formed uniformly several projections on circular periphery Polymorphic structure, the projection that the present embodiment is preferably in polymorphic structure is arc convex, bunge bedstraw herb shape as shown in Figure 2, final system It is standby to obtain moisture absorbing and sweat releasing, heating and insulation multifunctional fibre.
Embodiment 3
The far-infrared ceramic powder that 99.9kg PTT and 0.1kg mesh numbers are 2000 mesh is sufficiently mixed, is passed through after stirring Double screw extruder is granulated, and the operating temperature of double screw extruder is 250 DEG C, prepares the powder-modified polyester master particle of heating; The 100kg powder-modified polyester master particles that generate heat are placed in melt spinning is carried out in twin-screw spinning-drawing machine again, it is 280 to control spinning temperature DEG C, and the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is convex to be outwards formed uniformly several on circular periphery The polymorphic structure for rising, the present embodiment is preferably projection in polymorphic structure for arc convex, peach blossom shape as shown in Figure 3, finally Prepare moisture absorbing and sweat releasing, heating and insulation multifunctional fibre.
Embodiment 4
The graphene powder that 99.9kg PET and 0.1kg mesh numbers are 1000 mesh is sufficiently mixed, through double spiral shells after stirring Bar extruder is granulated, and the operating temperature of double screw extruder is 250 DEG C, prepares the powder-modified polyester master particle of heating;Again will The powder-modified polyester master particle of 100kg heatings is placed in and melt spinning is carried out in twin-screw spinning-drawing machine, controls spinning temperature for 300 DEG C, And the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is outwards to be formed uniformly several projections on circular periphery Polymorphic structure, the projection that the present embodiment is preferably in polymorphic structure is arc convex, trilobes as shown in Figure 4, final system It is standby to obtain moisture absorbing and sweat releasing, heating and insulation multifunctional fibre.
Embodiment 5
The titanium carbide powder that 65kg PBT and 35kg mesh numbers are 15000 mesh is sufficiently mixed, through twin-screw after stirring Extruder is granulated, and the operating temperature of double screw extruder is 250 DEG C, prepares the powder-modified polyester master particle of heating;Again will The powder-modified polyester master particle of 100kg heatings is placed in and melt spinning is carried out in twin-screw spinning-drawing machine, controls spinning temperature for 270 DEG C, And the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is outwards to be formed uniformly several projections on circular periphery Polymorphic structure, the projection that the present embodiment is preferably in polymorphic structure is rectangular preiection, as shown in figure 5, finally preparing moisture absorption Perspire, generate heat and be incubated multifunctional fibre.
Embodiment 6
The far-infrared ceramic powder that 90kg PTT and 10kg mesh numbers are 2000 mesh is sufficiently mixed, through double spiral shells after stirring Bar extruder is granulated, and the operating temperature of double screw extruder is 250 DEG C, prepares the powder-modified polyester master particle of heating;Again will The powder-modified polyester master particle of 100kg heatings is placed in and melt spinning is carried out in twin-screw spinning-drawing machine, controls spinning temperature for 270 DEG C, And the spinneret of twin-screw spinning-drawing machine is inner hollow, cross sectional shape is outwards to be formed uniformly several projections on circular periphery Polymorphic structure, the projection that the present embodiment is preferably in polymorphic structure is zigzag projection, as shown in fig. 6, finally preparing suction It is wet to perspire, generate heat and be incubated multifunctional fibre.
Above example is only optimal citing, and is not the restriction to embodiments of the present invention.Except above-described embodiment Outward, the present invention also has other embodiment.The technical scheme that all use equivalents or equivalent transformation are formed, all falls within the present invention It is required that protection domain.

Claims (8)

1. a kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre, it is characterised in that:Including fiber bodies, the fiber bodies Cross sectional shape to be outwards formed uniformly several raised polymorphic structures on circular periphery, the inside of the fiber bodies opens up There is circular cavity, and fiber bodies are made up of together heat generating fiber monofilament juxtaposed beaming.
2. moisture absorbing and sweat releasing according to claim 1, heating and insulation multifunctional fibre, it is characterised in that:The abnormity knot Projection in structure is the one kind in arc convex, rectangular preiection, zigzag projection.
3. moisture absorbing and sweat releasing according to claim 1, heating and insulation multifunctional fibre, it is characterised in that:The heating is fine Dimension monofilament is the inorganic particle modified monofilament polyester of heating, and the inorganic particle modified monofilament polyester of heating is by mass percent 60%~99.9%:0.1%~40% polyester and inorganic heating particle are prepared from.
4. moisture absorbing and sweat releasing according to claim 3, heating and insulation multifunctional fibre, it is characterised in that:The polyester is In PET, PBT, PTT one or more by any proportioning mixture;The inorganic heating particle is far-infrared ceramic In powder, Graphene, CNT, the carbide of transition metal one or more by any proportioning mixture.
5. moisture absorbing and sweat releasing according to claim 4, heating and insulation multifunctional fibre, it is characterised in that:The inorganic hair The particle diameter of hot particle is 1000~15000 mesh.
6. the preparation method of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre described in a kind of claim 1, it is characterised in that: Comprise the following steps:
1) inorganic heating particle and polyester are carried out being sufficiently mixed drying according to corresponding mass percent, through double after stirring Screw extruder is granulated, and prepares the powder-modified polyester master particle of heating;
2) by the step 1) the powder-modified polyester master particle of heating that obtains is placed in and melt spinning carried out in twin-screw spinning-drawing machine, make It is standby to obtain moisture absorbing and sweat releasing, heating and insulation multifunctional fibre, and the spinneret of the twin-screw spinning-drawing machine is inner hollow, section It is shaped as outwards being formed uniformly several raised polymorphic structures on circular periphery.
7. moisture absorbing and sweat releasing according to claim 6, heating and insulation multifunctional fibre preparation method, it is characterised in that: The step 2) in, the temperature of melt spinning is 200~300 DEG C.
8. moisture absorbing and sweat releasing according to claim 6, heating and insulation multifunctional fibre preparation method, it is characterised in that: The step 1) in, the temperature of double screw extruder granulation is 200~270 DEG C.
CN201611174796.8A 2016-12-19 2016-12-19 A kind of moisture absorbing and sweat releasing, heating and insulation multifunctional fibre and preparation method thereof Pending CN106757439A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107815770A (en) * 2017-12-13 2018-03-20 苏州东胜化纤纺织有限公司 A kind of compound cotton fiber of accumulation of heat health care
CN109364379A (en) * 2018-08-03 2019-02-22 广东丰森第五能源科技有限公司 A kind of nanometer new material radiating resonance wave frequency function with far infrared energy-saving
CN109385688A (en) * 2017-08-10 2019-02-26 中国石化仪征化纤有限责任公司 A kind of abnormity thermal polyester fibers and preparation method thereof
CN111663199A (en) * 2020-05-15 2020-09-15 浙江双兔新材料有限公司 Preparation method of graphene modified PET (polyethylene terephthalate) blend fiber
CN115012049A (en) * 2022-05-19 2022-09-06 张家港江苏科技大学产业技术研究院 Hollow fiber and processing equipment and processing method thereof
CN118082308A (en) * 2024-04-17 2024-05-28 石狮市波威兰服饰有限公司 Breathable fabric and preparation process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10195716A (en) * 1996-12-25 1998-07-28 Unitika Ltd Sunlight selectively absorbing heat-retaining yarn excellent in lightweight
JP2002061025A (en) * 2000-08-10 2002-02-28 Teijin Ltd Polyester fiber
CN102912466A (en) * 2012-05-14 2013-02-06 毛盈军 Fiber for warming and heat accumulation and preparation method of fiber and textile
CN103556282A (en) * 2013-10-24 2014-02-05 东华大学 Preparation method for novel warm-keeping type polyacrylonitrile hollow fiber
CN103866405A (en) * 2012-12-18 2014-06-18 中国纺织科学研究院 High-orifice-density profiled filaments and preparation method thereof
CN204265898U (en) * 2014-11-13 2015-04-15 江苏菲霖纤维科技有限公司 A kind of six lobe regeneration hollow polyester staple fibre spinneretss
CN105908269A (en) * 2016-06-12 2016-08-31 福建百宏聚纤科技实业有限公司 Manufacturing method of special-shaped hollow warmth keeping polyester drawn textured yarn

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10195716A (en) * 1996-12-25 1998-07-28 Unitika Ltd Sunlight selectively absorbing heat-retaining yarn excellent in lightweight
JP2002061025A (en) * 2000-08-10 2002-02-28 Teijin Ltd Polyester fiber
CN102912466A (en) * 2012-05-14 2013-02-06 毛盈军 Fiber for warming and heat accumulation and preparation method of fiber and textile
CN103866405A (en) * 2012-12-18 2014-06-18 中国纺织科学研究院 High-orifice-density profiled filaments and preparation method thereof
CN103556282A (en) * 2013-10-24 2014-02-05 东华大学 Preparation method for novel warm-keeping type polyacrylonitrile hollow fiber
CN204265898U (en) * 2014-11-13 2015-04-15 江苏菲霖纤维科技有限公司 A kind of six lobe regeneration hollow polyester staple fibre spinneretss
CN105908269A (en) * 2016-06-12 2016-08-31 福建百宏聚纤科技实业有限公司 Manufacturing method of special-shaped hollow warmth keeping polyester drawn textured yarn

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109385688A (en) * 2017-08-10 2019-02-26 中国石化仪征化纤有限责任公司 A kind of abnormity thermal polyester fibers and preparation method thereof
CN107815770A (en) * 2017-12-13 2018-03-20 苏州东胜化纤纺织有限公司 A kind of compound cotton fiber of accumulation of heat health care
CN109364379A (en) * 2018-08-03 2019-02-22 广东丰森第五能源科技有限公司 A kind of nanometer new material radiating resonance wave frequency function with far infrared energy-saving
CN111663199A (en) * 2020-05-15 2020-09-15 浙江双兔新材料有限公司 Preparation method of graphene modified PET (polyethylene terephthalate) blend fiber
CN111663199B (en) * 2020-05-15 2022-12-09 浙江双兔新材料有限公司 Preparation method of graphene modified PET (polyethylene terephthalate) blend fiber
CN115012049A (en) * 2022-05-19 2022-09-06 张家港江苏科技大学产业技术研究院 Hollow fiber and processing equipment and processing method thereof
CN118082308A (en) * 2024-04-17 2024-05-28 石狮市波威兰服饰有限公司 Breathable fabric and preparation process thereof
CN118082308B (en) * 2024-04-17 2024-06-21 石狮市波威兰服饰有限公司 Breathable fabric and preparation process thereof

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