CN106750801A - A kind of antibacterial waterproof polyethylene cable material - Google Patents
A kind of antibacterial waterproof polyethylene cable material Download PDFInfo
- Publication number
- CN106750801A CN106750801A CN201611184101.4A CN201611184101A CN106750801A CN 106750801 A CN106750801 A CN 106750801A CN 201611184101 A CN201611184101 A CN 201611184101A CN 106750801 A CN106750801 A CN 106750801A
- Authority
- CN
- China
- Prior art keywords
- parts
- clay
- stirring
- pretreatment
- cable material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antibacterial waterproof polyethylene cable material, its raw material includes by weight：Polyethylene 25 35, polytrifluorochloroethylene 5 12, ethylene-vinyl acetate copolymer 10 18, polyacrylonitrile-based carbon fibre 2 10, aluminum oxide 28, aluminium borate whisker 38, sodium antimonate 27, diethylenetriamines 0.2 0.6, cyanoethylation diethylentriamine 0.4 0.8, p-phenylenediamine 0.1 0.6, haloflex wax 12, dioctyl adipate 0.4 0.9, modified clay 14, chitosan polysaccharide 13, chlorinated paraffin 12, lanthana 0.1 0.16, cerium oxide 0.4 0.9, stabilizer 0.4 0.8, Masterbatch 12.Good waterproof performance of the present invention, heat endurance is good, excellent in mechanical performance, and anti-microbial property is excellent, not easy oxidation discoloration.
Description
Technical field
The present invention relates to plastics arts, more particularly to a kind of antibacterial waterproof polyethylene cable material.
Background technology
Polyethylene is the maximum general-purpose plastics of usage amount, is widely used in cable material field.Experiment shows, poly- second
Alkene is easier bacterial growth, and simple polythene material can not meet the use requirement of cable material.Silver-series antibacterial agent
It is the most frequently used antiseptic, but applies in polyethylene products in the presence of limitation：Easy oxidation stain and decline antibacterial ability；Power
Especially tensile strength and elongation at break significantly decline to learn performance, greatly limit its application on cable material；And
Organic antibacterial agent there is also poor heat resistance, be separated out in easy solvent environment, the poisonous problem of catabolite.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of antibacterial waterproof polyethylene cable material, prevents
Aqueous good, heat endurance is good, excellent in mechanical performance, and anti-microbial property is excellent, not easy oxidation discoloration, can effectively reduce the present invention
Bending phenomenon is susceptible to when being impacted, the application on cable material is effectively enhanced.
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：Polyethylene 25-35
Part, polytrifluorochloroethylene 5-12 parts, ethylene-vinyl acetate copolymer 10-18 parts, polyacrylonitrile-based carbon fibre 2-10 parts, oxidation
Aluminium 2-8 parts, aluminium borate whisker 3-8 parts, sodium antimonate 2-7 parts, diethylenetriamines 0.2-0.6 parts, cyanoethylation diethylentriamine
0.4-0.8 parts, p-phenylenediamine 0.1-0.6 parts, 1-2 parts of haloflex wax, dioctyl adipate 0.4-0.9 parts, modified clay
1-4 parts, 1-3 parts of chitosan polysaccharide, chlorinated paraffin 1-2 parts, lanthana 0.1-0.16 parts, cerium oxide 0.4-0.9 parts, surely
Determine agent 0.4-0.8 parts, Masterbatch 1-2 parts.
Preferably, modified clay is prepared using following technique：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, 12 are added
Alkyl trimethoxysilane, intensification stirring obtains pre-processing dodecyltrimethoxysilane；Clay, toluene are mixed equal
It is even, pretreatment dodecyltrimethoxysilane is added dropwise, after being added dropwise completely, heat up, it is refluxed, filter, filter cake is washed with toluene
Wash, dry, pulverize and obtain pre-processing clay；By nano silicon add silver nitrate solution in, regulation system pH value to neutrality,
Heat up stirring, centrifugation, and washing obtains pre-processing nano silicon extremely without silver ion；By silane resin acceptor kh-550, in advance
Treatment clay, ethylene glycol, water ultrasonic vibration, add pretreatment nano silicon stirring, dry, pulverize and obtain modified clay.
Preferably, modified clay is prepared using following technique：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, 12 are added
Alkyl trimethoxysilane, is warming up to 55-65 DEG C of stirring 20-40min, obtains pre-processing dodecyltrimethoxysilane；Will
Clay, toluene mixing and stirring, are added dropwise pretreatment dodecyltrimethoxysilane, after being added dropwise completely, are warming up to 115-125
DEG C 2-6h is refluxed, filtered, filter cake wash with toluene, 65-75 DEG C dry, pulverize and obtain pretreatment clay；By nano-silica
SiClx is added in silver nitrate solution, and regulation system pH value is warming up to 60-70 DEG C of stirring 20-40min to neutrality, and centrifugation is washed
Wash to without silver ion, obtain pre-process nano silicon；Silane resin acceptor kh-550, pretreatment clay, ethylene glycol, water are surpassed
30-40min is swung in acoustic shock, adds pretreatment nano silicon stirring 70-100min, and whipping temp is 75-85 DEG C, is dried, powder
It is broken to obtain modified clay.
Preferably, modified clay is prepared using following technique：By weight by 25-35 parts of water, 30-40 parts of absolute ethyl alcohol,
2-8 parts of glacial acetic acid is well mixed, and adds 2-4 parts of dodecyltrimethoxysilane, is warming up to 55-65 DEG C of stirring 20-40min,
Obtain pre-processing dodecyltrimethoxysilane；By weight by 10-20 parts of clay, 50-80 parts of toluene mixing and stirring,
2-7 parts of pretreatment dodecyltrimethoxysilane is added dropwise, after being added dropwise completely, is warming up to 115-125 DEG C and is refluxed 2-6h, mistake
Filter, filter cake wash with toluene, and 65-75 DEG C dry, pulverize and obtain pretreatment clay；By weight by 30-40 parts of nanometer titanium dioxide
During silicon adds 80-120 parts of concentration for the silver nitrate solution of 0.5-1.2mol/L, regulation system pH value is warming up to 60-70 to neutrality
DEG C stirring 20-40min, centrifugation, washing obtains pre-processing nano silicon to without silver ion；By weight by 0.5-
1.5 parts of silane resin acceptor kh-550s, 10-20 parts of pretreatment clay, 30-40 parts of ethylene glycol, 40-50 parts of water ultrasonic vibration 30-
40min, adds 5-18 parts of pretreatment nano silicon stirring 70-100min, and whipping temp is 75-85 DEG C, be dry, pulverize
To modified clay.
Preferably, polyethylene, polytrifluorochloroethylene, the weight ratio of ethylene-vinyl acetate copolymer are 28-32：6-10：
12-16。
Preferably, diethylenetriamines, cyanoethylation diethylentriamine, the weight ratio of p-phenylenediamine are 0.3-0.5：0.5-
0.7：0.2-0.4.
Preferably, modified clay, chlorinated paraffin, polyacrylonitrile-based carbon fibre, aluminum oxide, aluminium borate whisker, sodium antimonate
Weight ratio is 2-3：1.2-1.8：4-8：4-6：5-7：3-5.
The present invention is obtained using conventional fabrication process.
Because ethylene-vinyl acetate copolymer has good filler pardon and a cross linkable, the present invention using its with
Polyethylene, polytrifluorochloroethylene coordinate, and intersolubility is good, using diethylenetriamines, cyanoethylation diethylentriamine, p-phenylenediamine
The cross-linking system of composition is crosslinked, and is crosslinked good evenness, good waterproof performance, and heat endurance is good, excellent in mechanical performance；This hair
In bright modified clay, clay by pretreatment dodecyltrimethoxysilane treatment after, by dodecyl trimethoxy silicon
Alkane is grafted on clay, not only eliminates reactive hydroxyl on clay silicate lamella, and its dispersibility is strong, peels off degree of scatter
Height, heat endurance is good, excellent in mechanical performance；Again with nano silicon as carrier, make gained pretreatment nano silicon be
Impalpable structure, particle spherical in shape, particle diameter is minimum；By each reaction condition of Grain size controlling, the structure of nano silicon passes through
Adsorption reaction is not changed after carrying silver, and because substantial amounts of hydroxyl is contained on resulting structures surface, itself and pretreatment clay are acted on,
It is modified to above-mentioned surface of material through ethylene glycol, silane resin acceptor kh-550 again, can not only prevent from reuniting, dispersibility is good, and
Heat endurance is further enhanced with mechanical property, and anti-microbial property is excellent；Further assisted with chitosan polysaccharide, chlorinated paraffin
Same-action, three not only mixes good dispersion, and anti-microbial property is further enhanced；And the collaboration of chlorinated paraffin, modified clay can be effective
RPP itrile group carbon fiber, aluminum oxide, aluminium borate whisker, sodium antimonate are in polyethylene, polytrifluorochloroethylene, ethyl vinyl acetate
The degree that is uniformly dispersed of ethylene copolymer, on the basis of reduces cost, filling effect is good, makes tensile strength of the invention and breaks
Elongation is split to greatly improve；Other lanthana, the chlorine atom of the replaceable polytrifluorochloroethylene of cation of cerium oxide, can effectively subtract
The radical reaction speed of slow polytrifluorochloroethylene, makes the present invention not easy oxidation discoloration, and haloflex wax, adipic acid two are pungent
Ester is acted on, and can effectively be reduced when the present invention is impacted and is susceptible to bending phenomenon, effectively enhances the application on cable material.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：25 parts of polyethylene,
12 parts of polytrifluorochloroethylene, 10 parts of ethylene-vinyl acetate copolymer, 10 parts of polyacrylonitrile-based carbon fibre, 2 parts of aluminum oxide, boric acid
8 parts of al whisker, 2 parts of sodium antimonate, 0.6 part of diethylenetriamines, 0.4 part of cyanoethylation diethylentriamine, 0.6 part of p-phenylenediamine,
1 part of haloflex wax, 0.9 part of dioctyl adipate, 1 part of modified clay, 3 parts of chitosan polysaccharide, chlorinated paraffin 1
Part, 0.16 part of lanthana, 0.4 part of cerium oxide, 0.8 part of stabilizer, 1 part of Masterbatch.
Embodiment 2
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：35 parts of polyethylene,
5 parts of polytrifluorochloroethylene, 18 parts of ethylene-vinyl acetate copolymer, 2 parts of polyacrylonitrile-based carbon fibre, 8 parts of aluminum oxide, aluminium borate
3 parts of whisker, 7 parts of sodium antimonate, 0.2 part of diethylenetriamines, 0.8 part of cyanoethylation diethylentriamine, 0.1 part of p-phenylenediamine, chlorine
2 parts of Tissuemat E of change, 0.4 part of dioctyl adipate, 4 parts of modified clay, 1 part of chitosan polysaccharide, 2 parts of chlorinated paraffin,
0.1 part of lanthana, 0.9 part of cerium oxide, 0.4 part of stabilizer, 2 parts of Masterbatch.
Modified clay is prepared using following technique：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, dodecyl three is added
Methoxy silane, intensification stirring obtains pre-processing dodecyltrimethoxysilane；By clay, toluene mixing and stirring, drop
Plus pretreatment dodecyltrimethoxysilane, after being added dropwise completely, heat up, it is refluxed, filter, filter cake is washed with toluene, is done
Dry, crushing obtains pre-processing clay；By in nano silicon addition silver nitrate solution, regulation system pH value to neutrality heats up
Stirring, centrifugation, washing obtains pre-processing nano silicon extremely without silver ion；By silane resin acceptor kh-550, pretreatment
Clay, ethylene glycol, water ultrasonic vibration, add pretreatment nano silicon stirring, dry, pulverize and obtain modified clay.
Embodiment 3
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：28 parts of polyethylene,
10 parts of polytrifluorochloroethylene, 12 parts of ethylene-vinyl acetate copolymer, 8 parts of polyacrylonitrile-based carbon fibre, 4 parts of aluminum oxide, aluminium borate
7 parts of whisker, 3 parts of sodium antimonate, 0.5 part of diethylenetriamines, 0.5 part of cyanoethylation diethylentriamine, 0.4 part of p-phenylenediamine, chlorine
Change 1.2 parts of Tissuemat E, 0.7 part of dioctyl adipate, 2 parts of modified clay, 2.5 parts of chitosan polysaccharide, chlorinated paraffin
1.2 parts, 0.14 part of lanthana, 0.5 part of cerium oxide, 0.7 part of stabilizer, 1.4 parts of Masterbatch.
Modified clay is prepared using following technique：25 parts of water, 40 parts of absolute ethyl alcohols, 2 parts of glacial acetic acid are mixed by weight
Uniformly, 4 parts of dodecyltrimethoxysilanes are added, 55 DEG C of stirring 40min are warming up to, obtains pre-processing dodecyl trimethoxy
Base silane；By weight by 10 parts of clays, 80 parts of toluene mixing and stirrings, 2 parts of pretreatment dodecyl trimethoxies are added dropwise
Silane, after being added dropwise completely, is warming up to 125 DEG C and is refluxed 2h, filters, and filter cake washs with toluene, and 75 DEG C dry, pulverize and obtain pre-
Treatment clay；During 30 parts of nano silicons are added into 120 parts of concentration for the silver nitrate solution of 0.5mol/L by weight, adjust
System pH is warming up to 70 DEG C of stirring 20min to neutrality, and centrifugation, washing obtains pre-processing nano-silica extremely without silver ion
SiClx；By weight by 1.5 parts of silane resin acceptor kh-550s, 10 parts of pretreatment clays, 40 parts of ethylene glycol, 40 parts of water ultrasonic vibrations
40min, adds 5 parts of pretreatment nano silicon stirring 100min, and whipping temp is 75 DEG C, dry, pulverize and obtains modified glutinous
Soil.
Embodiment 4
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：32 parts of polyethylene,
6 parts of polytrifluorochloroethylene, 16 parts of ethylene-vinyl acetate copolymer, 4 parts of polyacrylonitrile-based carbon fibre, 6 parts of aluminum oxide, aluminium borate
5 parts of whisker, 5 parts of sodium antimonate, 0.3 part of diethylenetriamines, 0.7 part of cyanoethylation diethylentriamine, 0.2 part of p-phenylenediamine, chlorine
Change 1.7 parts of Tissuemat E, 0.5 part of dioctyl adipate, 3 parts of modified clay, 1.5 parts of chitosan polysaccharide, chlorinated paraffin
1.8 parts, 0.12 part of lanthana, 0.8 part of cerium oxide, 0.5 part of stabilizer, 1.8 parts of Masterbatch.
Modified clay is prepared using following technique：35 parts of water, 30 parts of absolute ethyl alcohols, 8 parts of glacial acetic acid are mixed by weight
Uniformly, 2 parts of dodecyltrimethoxysilanes are added, 65 DEG C of stirring 20min are warming up to, obtains pre-processing dodecyl trimethoxy
Base silane；By weight by 20 parts of clays, 50 parts of toluene mixing and stirrings, 7 parts of pretreatment dodecyl trimethoxies are added dropwise
Silane, after being added dropwise completely, is warming up to 115 DEG C and is refluxed 6h, filters, and filter cake washs with toluene, and 65 DEG C dry, pulverize and obtain pre-
Treatment clay；During 40 parts of nano silicons are added into 80 parts of concentration for the silver nitrate solution of 1.2mol/L by weight, adjust
System pH is warming up to 60 DEG C of stirring 40min to neutrality, and centrifugation, washing obtains pre-processing nano-silica extremely without silver ion
SiClx；By weight by 0.5 part of silane resin acceptor kh-550,20 parts of pretreatment clays, 30 parts of ethylene glycol, 50 parts of water ultrasonic vibrations
30min, adds 18 parts of pretreatment nano silicon stirring 70min, and whipping temp is 85 DEG C, dry, pulverize and obtains modified glutinous
Soil.
Embodiment 5
A kind of antibacterial waterproof polyethylene cable material proposed by the present invention, its raw material includes by weight：30 parts of polyethylene,
8 parts of polytrifluorochloroethylene, 14 parts of ethylene-vinyl acetate copolymer, 6 parts of polyacrylonitrile-based carbon fibre, 5 parts of aluminum oxide, aluminium borate
6 parts of whisker, 4 parts of sodium antimonate, 0.4 part of diethylenetriamines, 0.6 part of cyanoethylation diethylentriamine, 0.3 part of p-phenylenediamine, chlorine
Change 1.5 parts of Tissuemat E, 0.6 part of dioctyl adipate, 2.5 parts of modified clay, 2 parts of chitosan polysaccharide, chlorinated paraffin
1.5 parts, 0.13 part of lanthana, 0.7 part of cerium oxide, 0.6 part of stabilizer, 1.6 parts of Masterbatch.
Modified clay is prepared using following technique：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, dodecyl three is added
Methoxy silane, is warming up to 60 DEG C of stirring 30min, obtains pre-processing dodecyltrimethoxysilane；Clay, toluene are mixed
Stir, pretreatment dodecyltrimethoxysilane is added dropwise, after being added dropwise completely, be warming up to 120 DEG C and be refluxed 4h, mistake
Filter, filter cake wash with toluene, and 70 DEG C dry, pulverize and obtain pretreatment clay；By nano silicon add silver nitrate solution in,
Regulation system pH value is warming up to 65 DEG C of stirring 30min to neutrality, and centrifugation, washing obtains pre-processing nanometer extremely without silver ion
Silica；By silane resin acceptor kh-550, pretreatment clay, ethylene glycol, water ultrasonic vibration 35min, pretreatment nanometer is added
Silica stirs 80min, and whipping temp is 80 DEG C, dry, pulverize and obtains modified clay.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of antibacterial waterproof polyethylene cable material, it is characterised in that its raw material includes by weight：Polyethylene 25-35 parts,
Polytrifluorochloroethylene 5-12 parts, ethylene-vinyl acetate copolymer 10-18 parts, polyacrylonitrile-based carbon fibre 2-10 parts, aluminum oxide 2-
8 parts, aluminium borate whisker 3-8 parts, sodium antimonate 2-7 parts, diethylenetriamines 0.2-0.6 parts, cyanoethylation diethylentriamine 0.4-
0.8 part, p-phenylenediamine 0.1-0.6 parts, 1-2 parts of haloflex wax, dioctyl adipate 0.4-0.9 parts, modified clay 1-4
Part, 1-3 parts of chitosan polysaccharide, chlorinated paraffin 1-2 parts, lanthana 0.1-0.16 parts, cerium oxide 0.4-0.9 parts, stabilization
Agent 0.4-0.8 parts, Masterbatch 1-2 parts.
2. antibacterial waterproof polyethylene cable material according to claim 1, it is characterised in that modified clay uses following technique
Prepare：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, dodecyltrimethoxysilane is added, intensification stirring is pre-processed
Dodecyltrimethoxysilane；By clay, toluene mixing and stirring, pretreatment dodecyltrimethoxysilane is added dropwise,
After being added dropwise completely, heat up, be refluxed, filter, filter cake is washed with toluene, dry, pulverize and obtain pre-processing clay；By nanometer two
Silica is added in silver nitrate solution, regulation system pH value to neutrality, and heat up stirring, and centrifugation, washing is obtained to without silver ion
To pretreatment nano silicon；By silane resin acceptor kh-550, pretreatment clay, ethylene glycol, water ultrasonic vibration, pre- place is added
Reason nano silicon stirring, dry, pulverize and obtain modified clay.
3. antibacterial waterproof polyethylene cable material according to claim 1 or claim 2, it is characterised in that modified clay is using as follows
It is prepared by technique：Water, absolute ethyl alcohol, glacial acetic acid are well mixed, dodecyltrimethoxysilane is added, 55-65 DEG C is warming up to
Stirring 20-40min, obtains pre-processing dodecyltrimethoxysilane；By clay, toluene mixing and stirring, pre- place is added dropwise
Reason dodecyltrimethoxysilane, after being added dropwise completely, is warming up to 115-125 DEG C and is refluxed 2-6h, filters, filter cake toluene
Washing, 65-75 DEG C dry, pulverize obtain pre-process clay；By nano silicon add silver nitrate solution in, regulation system pH
Value is warming up to 60-70 DEG C of stirring 20-40min to neutrality, and centrifugation, washing obtains pre-processing nano-silica extremely without silver ion
SiClx；By silane resin acceptor kh-550, pretreatment clay, ethylene glycol, water ultrasonic vibration 30-40min, pretreatment nanometer two is added
Silica stirs 70-100min, and whipping temp is 75-85 DEG C, dry, pulverize and obtains modified clay.
4. the antibacterial waterproof polyethylene cable material according to claim any one of 1-3, it is characterised in that modified clay is used
It is prepared by following technique：25-35 parts of water, 30-40 parts of absolute ethyl alcohol, 2-8 parts of glacial acetic acid are well mixed by weight, add 2-4
Part dodecyltrimethoxysilane, is warming up to 55-65 DEG C of stirring 20-40min, obtains pre-processing dodecyl trimethoxy silicon
Alkane；By weight by 10-20 parts of clay, 50-80 parts of toluene mixing and stirring, 2-7 parts of pretreatment dodecyl front three is added dropwise
TMOS, after being added dropwise completely, is warming up to 115-125 DEG C and is refluxed 2-6h, filters, and filter cake is washed with toluene, and 65-75 DEG C is done
Dry, crushing obtains pre-processing clay；It is 0.5- that 30-40 parts of nano silicon is added into 80-120 parts of concentration by weight
In the silver nitrate solution of 1.2mol/L, regulation system pH value to neutrality, be warming up to 60-70 DEG C stirring 20-40min, centrifugation,
Washing obtains pre-processing nano silicon extremely without silver ion；By weight by 0.5-1.5 parts of silane resin acceptor kh-550,10-
20 parts of pretreatment clays, 30-40 parts of ethylene glycol, 40-50 parts of water ultrasonic vibration 30-40min, add 5-18 parts of pretreatment nanometer two
Silica stirs 70-100min, and whipping temp is 75-85 DEG C, dry, pulverize and obtains modified clay.
5. the antibacterial waterproof polyethylene cable material according to claim any one of 1-4, it is characterised in that polyethylene, poly- three
Fluorine vinyl chloride, the weight ratio of ethylene-vinyl acetate copolymer are 28-32：6-10：12-16.
6. the antibacterial waterproof polyethylene cable material according to claim any one of 1-5, it is characterised in that diethylidene three
Amine, cyanoethylation diethylentriamine, the weight ratio of p-phenylenediamine are 0.3-0.5：0.5-0.7：0.2-0.4.
7. the antibacterial waterproof polyethylene cable material according to claim any one of 1-6, it is characterised in that modified clay, chlorine
Fossil waxes, polyacrylonitrile-based carbon fibre, aluminum oxide, aluminium borate whisker, the weight ratio of sodium antimonate are 2-3：1.2-1.8：4-8：4-
6：5-7：3-5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611184101.4A CN106750801A (en) | 2016-12-20 | 2016-12-20 | A kind of antibacterial waterproof polyethylene cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611184101.4A CN106750801A (en) | 2016-12-20 | 2016-12-20 | A kind of antibacterial waterproof polyethylene cable material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106750801A true CN106750801A (en) | 2017-05-31 |
Family
ID=58894280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611184101.4A Withdrawn CN106750801A (en) | 2016-12-20 | 2016-12-20 | A kind of antibacterial waterproof polyethylene cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106750801A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250520A (en) * | 2017-12-01 | 2018-07-06 | 安徽渡江电缆集团有限公司 | A kind of environment friendly cable jacket material |
| CN111534275A (en) * | 2020-05-26 | 2020-08-14 | 黄振星 | Low-density heat-insulation pouring sealant for new energy power battery module |
| CN117511032A (en) * | 2023-11-10 | 2024-02-06 | 云南春城线缆制造有限公司 | High-flame-retardance low-smoke electric wire and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009214A (en) * | 2016-06-03 | 2016-10-12 | 繁昌县菲德通讯材料设计有限公司 | Heat-resistant aging-resistant insulation material for coal mine |
| CN106084658A (en) * | 2016-06-21 | 2016-11-09 | 安徽酷米智能科技有限公司 | A kind of wear-resisting composite plastic of phone housing |
| CN106084802A (en) * | 2016-06-21 | 2016-11-09 | 安徽酷米智能科技有限公司 | A kind of protective casing of cell phone shock resistance fluoroplastics |
-
2016
- 2016-12-20 CN CN201611184101.4A patent/CN106750801A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009214A (en) * | 2016-06-03 | 2016-10-12 | 繁昌县菲德通讯材料设计有限公司 | Heat-resistant aging-resistant insulation material for coal mine |
| CN106084658A (en) * | 2016-06-21 | 2016-11-09 | 安徽酷米智能科技有限公司 | A kind of wear-resisting composite plastic of phone housing |
| CN106084802A (en) * | 2016-06-21 | 2016-11-09 | 安徽酷米智能科技有限公司 | A kind of protective casing of cell phone shock resistance fluoroplastics |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250520A (en) * | 2017-12-01 | 2018-07-06 | 安徽渡江电缆集团有限公司 | A kind of environment friendly cable jacket material |
| CN111534275A (en) * | 2020-05-26 | 2020-08-14 | 黄振星 | Low-density heat-insulation pouring sealant for new energy power battery module |
| CN117511032A (en) * | 2023-11-10 | 2024-02-06 | 云南春城线缆制造有限公司 | High-flame-retardance low-smoke electric wire and preparation process thereof |
| CN117511032B (en) * | 2023-11-10 | 2024-05-14 | 云南春城线缆制造有限公司 | High-flame-retardance low-smoke electric wire and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106750801A (en) | A kind of antibacterial waterproof polyethylene cable material | |
| JP6370913B2 (en) | Treated filler, composition containing it and article prepared therefrom | |
| CN106752119B (en) | A kind of preparation method of carbon black nano material | |
| US9321909B2 (en) | Rubber composition for tire tread and tire manufactured by using the same | |
| CN101914311B (en) | Calcium carbonate surface modifying method | |
| CN103554704A (en) | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof | |
| CN106117644A (en) | A kind of high-strength impact-resistant natural rubber cable sheath material | |
| CN107415862A (en) | Automotive wire bundle rubber sheath | |
| CN103265742A (en) | Oil-resistant cable sheath material | |
| CN103173135B (en) | High temperature resistant epoxy resin adhesive | |
| CN106349519A (en) | Cable sheathing material of heat resistance flame retardant natural rubber | |
| CN106315596B (en) | A kind of production technology of low CTAB specific surface areas low-heat-generation white carbon | |
| CN105733111A (en) | Anti-aging marine power cable | |
| CN109666149B (en) | Preparation method of graphene-based polysiloxane with silicon-oxygen six-membered ring structure | |
| CN107286889A (en) | A kind of high temperature resistant environment-protective adhesive and preparation method thereof | |
| CN106800694A (en) | A kind of antibacterial PE cable material not easy to change | |
| CN105255044A (en) | Weather-proof and flame-retardant PVC (polyvinyl chloride)-sheathed cable | |
| CN108178992A (en) | A kind of composition for being used to prepare anticorrosive heat insulating automobile adhesive film and preparation method thereof | |
| CN107312261A (en) | A kind of polyvinyl chloride cable sheathing compound for automotive wire bundle | |
| CN109401584B (en) | Aldehyde-free antibacterial water-based diatom coating for children and preparation method thereof | |
| CN103059750A (en) | Epoxy resin and nitrile rubber adhesive and preparing method thereof | |
| CN106046218A (en) | Method for preparing uvioresistant polyvinyl chloride master batch | |
| CN109456564A (en) | A kind of ageing-resistant rubber and preparation method thereof | |
| CN107312255A (en) | A kind of electric wire for automobile | |
| KR20130077212A (en) | Rubber composition for tire tread and tire manufactured by using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170531 |