CN106750596A - A kind of fire resisting oil resistant high-low temperature resistant technically classified rubber - Google Patents

A kind of fire resisting oil resistant high-low temperature resistant technically classified rubber Download PDF

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Publication number
CN106750596A
CN106750596A CN201611165358.5A CN201611165358A CN106750596A CN 106750596 A CN106750596 A CN 106750596A CN 201611165358 A CN201611165358 A CN 201611165358A CN 106750596 A CN106750596 A CN 106750596A
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CN
China
Prior art keywords
parts
rubber
fire resisting
oil
low temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611165358.5A
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Chinese (zh)
Inventor
周春毅
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Wuzhong District Dome High Polymer Material Technology Research Institute
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Wuzhong District Dome High Polymer Material Technology Research Institute
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Application filed by Wuzhong District Dome High Polymer Material Technology Research Institute filed Critical Wuzhong District Dome High Polymer Material Technology Research Institute
Priority to CN201611165358.5A priority Critical patent/CN106750596A/en
Publication of CN106750596A publication Critical patent/CN106750596A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K2003/1034Materials or components characterised by specific properties
    • C09K2003/1078Fire-resistant, heat-resistant materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of fire resisting oil resistant high-low temperature resistant technically classified rubber, it is made up of following components raw material:Natural rubber, neoprene, nitrile rubber, ceramic, palm oil, adhesive, dimethicone, polyurethane, oleic acid, softening agent, zinc oxide, PEG4000, age resistor.Technically classified rubber of the present invention is had an enormous advantage in the aspect performance such as fire resisting, oil resistant, high temperature resistant, and abrasion rupture, long service life are not susceptible in use, instant component proportioning is scientific and reasonable, safely and effectively, preparation method is easily operated, is adapted to industrially large-scale promotion.

Description

A kind of fire resisting oil resistant high-low temperature resistant technically classified rubber
Technical field
The present invention relates to technically classified rubber field, and in particular to a kind of fire resisting oil resistant high-low temperature resistant technically classified rubber.
Background technology
The rubber of early stage is taken from the latex of the plants such as rubber tree, Russian dandelion, be made after processing with elasticity, insulation Property, the material of impermeable water and air.Elastomeric macromolecular compound.It is divided into two kinds of natural rubber and synthetic rubber.Natural rubber Glue is made of the extraction colloid post-processing from the plants such as rubber tree, Russian dandelion;Synthetic rubber is then by the aggregated reaction of various monomers And obtain.Rubber is widely used in industry or life each side.
, with common rubber as main raw material(s), its formula design is often with tear resistance for technically classified rubber in the market Energy, anti-wear performance and crush resistance can not fully take into account it and use Jie as important considerations in design process is formulated Matter and working condition, causing existing oil sealing to meet use at aspects such as fire resisting, oil resistant, high-low temperature resistants will Ask, performance occurs very big change in industrial production use, service life is short.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of fire resisting oil resistant high-low temperature resistant technically classified rubber so that institute Performance very big change, long service life to the sealing ring of production will not occur in use.
To realize object above, the present invention is achieved by the following technical programs:
The invention provides a kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, it is prepared from the following raw materials in parts by weight: Natural rubber:30-70 parts, neoprene:15-35 parts, nitrile rubber:15-35 parts, ceramic 5-15 parts, palm oil 1-8 Part, adhesive 1-8 parts, dimethicone 1-5 parts, polyurethane 1-8 parts, oleic acid:0.05-0.2 parts, softening agent:6-15 parts, oxidation Zinc:1-5 parts, PEG4000:1-6 parts, age resistor:1-4.5 parts..
Preferably, it is prepared from the following raw materials in parts by weight:Natural rubber:35-68 parts, neoprene:16-33 parts, fourth Nitrile rubber:18-33 parts, ceramic 6-12 parts, palm oil 4-6 parts, adhesive 2-6 parts, dimethicone 2-3 parts, polyurethane 2-6 parts, oleic acid:0.08-0.15 parts, softening agent:7-13 parts, zinc oxide:2-4 parts, PEG4000:2-5 parts, age resistor:2-4 parts.
Preferably, it is prepared from the following raw materials in parts by weight:Natural rubber:36 parts, neoprene:16 parts, nitrile rubber: 18 parts, 6 parts of ceramic, 4 parts of palm oil, 3 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.1 part, softening Agent:9 parts, zinc oxide:3 parts, PEG4000:3 parts, age resistor:3 parts.
Preferably, it is prepared from the following raw materials in parts by weight:Natural rubber:40 parts, neoprene:20 parts, nitrile rubber: 22 parts, 8 parts of ceramic, 5 parts of palm oil, 4 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.1 part, softening Agent:9 parts, zinc oxide:4 parts, PEG4000:4 parts, age resistor:4 parts.
Preferably, described softening agent is sulfonated oil, carbon number aliphatic acid emulsion high, one kind of silicone oil.
Preferably, described age resistor is N- PBNAs, one kind of p-phenylenediamine.
Beneficial effect of the present invention:
Neoprene has oil resistant, high temperature resistant, resistance to combustion, resistance to daylight, resistance to ozone, acid and alkali-resistance, chemical-resistant reagent etc. good Physical and mechanical properties, nitrile rubber oil resistivity is fabulous, and wearability is higher, and preferably, bonding force is strong for heat-resisting quantity, and the present invention will be natural Rubber, neoprene, three kinds of rubber of nitrile rubber cooperate with shared according to a certain percentage can meet synthesized technically classified rubber tool There is an oil resistant, resistance to combustion, the superperformance of resistance to oxidation, PEG4000 is used as additive, by increasing capacitance it is possible to increase the lubrication of technically classified rubber product Property and plasticity, the power consumption in process can also be reduced, so as to extend the service life of sealing ring, dimethicone tool Have excellent antioxidative stabilizer, heat decomposition temperature is high, the small advantage of evaporation loss, by increasing capacitance it is possible to increase technically classified rubber product it is anti- Oxidisability, ceramic is a kind of lightweight non-metallic multifunctional material, and main component is SiO2 and Al2O3, chemical stability is good, It is plasticity is good, heat resisting temperature is high, density is small, can improve technically classified rubber product oil resistant, resistance to combustion, resistance to oxidation, corrosion-resistant and resistance to It is high temperatures.Instant component proportioning is scientific and reasonable, and safely and effectively, preparation method is easily operated, is adapted to industrially push away on a large scale Extensively.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with implementation of the invention Example, is clearly and completely described to the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to protection of the present invention Scope.
Embodiment 1:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:36 Part, neoprene:16 parts, nitrile rubber:18 parts, 4 parts of palm oil, 3 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oil Acid:0.1 part, softening agent:9 parts, zinc oxide:3 parts, PEG4000:3 parts, age resistor:3 parts.
Embodiment 2:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:36 Part, neoprene:20 parts, nitrile rubber:18 parts, 4 parts of palm oil, 3 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oil Acid:0.1 part, softening agent:9 parts, zinc oxide:3 parts, PEG4000:3 parts, age resistor:3 parts.
Embodiment 3:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:40 Part, neoprene:18 parts, nitrile rubber:20 parts, 8 parts of ceramic, 5 parts of palm oil, 4 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.08 part, softening agent:8 parts, zinc oxide:4 parts, PEG4000:4 parts, age resistor:3 parts.
Embodiment 4:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:50 Part, neoprene:30 parts, nitrile rubber:20 parts, 8 parts of ceramic, 5 parts of palm oil, 3 parts of adhesive, 2 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.08 part, softening agent:10 parts, zinc oxide:4 parts, PEG4000:5 parts, age resistor:4 parts.
Embodiment 5:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:60 Part, neoprene:33 parts, nitrile rubber:30 parts, 8 parts of ceramic, 4 parts of palm oil, 3 parts of adhesive, 2 parts of dimethicone, 3 parts of polyurethane, oleic acid:0.01 part, softening agent:8 parts, zinc oxide:2 parts, PEG4000:2 parts, age resistor:2 parts.
Embodiment 6:
A kind of oil-resistant high-temperature resistance to oxidation technically classified rubber, is prepared from the following raw materials in parts by weight:Natural rubber:38 Part, neoprene:8 parts, nitrile rubber:20 parts, 8 parts of ceramic, 6 parts of palm oil, 4 parts of adhesive, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.01 part, softening agent:9 parts, zinc oxide:4 parts, PEG4000:3 parts, age resistor:3 parts.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention has been described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.

Claims (6)

1. a kind of fire resisting oil resistant high-low temperature resistant technically classified rubber, it is characterised in that be prepared from the following raw materials in parts by weight:Naturally Rubber:30-70 parts, neoprene:15-35 parts, nitrile rubber:15-35 parts, ceramic 5-15 parts, palm oil 1-8 parts, glue Glutinous 1-8 parts of agent, dimethicone 1-5 parts, polyurethane 1-8 parts, oleic acid:0.05-0.2 parts, softening agent:6-15 parts, zinc oxide:1- 5 parts, PEG4000:1-6 parts, age resistor:1-4.5 parts.
2. fire resisting oil resistant high-low temperature resistant technically classified rubber as claimed in claim 1, it is characterised in that by following parts by weight Raw material is made:Natural rubber:35-68 parts, neoprene:16-33 parts, nitrile rubber:18-33 parts, ceramic 6-12 parts, palm fibre 4-6 parts of palmitic acid oil, adhesive 2-6 parts, dimethicone 2-3 parts, polyurethane 2-6 parts, oleic acid:0.08-0.15 parts, softening agent:7- 13 parts, zinc oxide:2-4 parts, PEG4000:2-5 parts, age resistor:2-4 parts.
3. fire resisting oil resistant high-low temperature resistant technically classified rubber as claimed in claim 2, it is characterised in that by following parts by weight Raw material is made:Natural rubber:36 parts, neoprene:16 parts, nitrile rubber:18 parts, 6 parts of ceramic, 4 parts of palm oil, gluing 3 parts of agent, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.1 part, softening agent:9 parts, zinc oxide:3 parts, PEG4000:3 parts, it is anti- Old agent:3 parts.
4. fire resisting oil resistant high-low temperature resistant technically classified rubber as claimed in claim 2, it is characterised in that by following parts by weight Raw material is made:Natural rubber:40 parts, neoprene:20 parts, nitrile rubber:22 parts, 8 parts of ceramic, 5 parts of palm oil, gluing 4 parts of agent, 3 parts of dimethicone, 4 parts of polyurethane, oleic acid:0.1 part, softening agent:9 parts, zinc oxide:4 parts, PEG4000:4 parts, it is anti- Old agent:4 parts.
5. fire resisting oil resistant high-low temperature resistant technically classified rubber as claimed in claim 1, it is characterised in that described softening agent is sulphur Carburetion, carbon number aliphatic acid emulsion high, one kind of silicone oil.
6. fire resisting oil resistant high-low temperature resistant technically classified rubber as claimed in claim 1, it is characterised in that described age resistor is N- PBNA, one kind of p-phenylenediamine.
CN201611165358.5A 2016-12-16 2016-12-16 A kind of fire resisting oil resistant high-low temperature resistant technically classified rubber Pending CN106750596A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112210132A (en) * 2020-07-27 2021-01-12 浙江中瑞橡胶高分子材料股份有限公司 Oil-resistant corrosion-resistant heel mark material and preparation method thereof
CN113354940A (en) * 2021-08-10 2021-09-07 佛山市湘聚新材料有限公司 High-elasticity thermoplastic rubber and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654530A (en) * 2009-09-18 2010-02-24 清华大学 Negative temperature coefficient polymer composite material for temperature sensing cable and preparation method
CN104592576A (en) * 2015-01-30 2015-05-06 柳州市颖航汽配有限公司 Rubber material for sealing automobile window and preparation method of rubber material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654530A (en) * 2009-09-18 2010-02-24 清华大学 Negative temperature coefficient polymer composite material for temperature sensing cable and preparation method
CN104592576A (en) * 2015-01-30 2015-05-06 柳州市颖航汽配有限公司 Rubber material for sealing automobile window and preparation method of rubber material

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
王正远: "《化工产品购销手册》", 2 February 2002 *
胡岳飞: "《现代有机合成试剂 性质、制备和反应》", 31 January 2011 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112210132A (en) * 2020-07-27 2021-01-12 浙江中瑞橡胶高分子材料股份有限公司 Oil-resistant corrosion-resistant heel mark material and preparation method thereof
CN113354940A (en) * 2021-08-10 2021-09-07 佛山市湘聚新材料有限公司 High-elasticity thermoplastic rubber and preparation method thereof
CN113354940B (en) * 2021-08-10 2021-11-05 佛山市湘聚新材料有限公司 High-elasticity thermoplastic rubber and preparation method thereof

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