PL423484A1 - Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor - Google Patents

Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor

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Publication number
PL423484A1
PL423484A1 PL423484A PL42348417A PL423484A1 PL 423484 A1 PL423484 A1 PL 423484A1 PL 423484 A PL423484 A PL 423484A PL 42348417 A PL42348417 A PL 42348417A PL 423484 A1 PL423484 A1 PL 423484A1
Authority
PL
Poland
Prior art keywords
aniline
paper
cu6i6
aminophosphine
triaza
Prior art date
Application number
PL423484A
Other languages
Polish (pl)
Inventor
Sabina Weronika Jaros
Jerzy Sokolnicki
Piotr Smoleński
Original Assignee
Univ Wroclawski
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Wroclawski filed Critical Univ Wroclawski
Priority to PL423484A priority Critical patent/PL423484A1/en
Publication of PL423484A1 publication Critical patent/PL423484A1/en

Links

Abstract

Przedmiotem zgłoszenia jest nowy polimer koordynacyjny typu 2D zbudowany z klasterów heksamiedziowych [Cu6I6] i klatkowej aminofosfiny 1,3,5-triaza-7-fosfaadamantanu oraz jego materiał kompozytowy [Cu6(µ3-I)6(µ3-PTA=O)]n@paper, sposób ich wytwarzania, zastosowanie jako efektywny sensor aniliny w ciele stałym oraz oddziaływanie aniliny z [Cu6(µ3-I)6(µ3-PTA=O)]n i [Cu6(µ3-I)6(µ3-PTA=O)]n@paper przejawiające się zmianą emisji z żółtozielonej na pomarańczowo-czerwoną i przesunięciem emisji w kierunku dłuższych fal.The subject of the application is a new 2D coordination polymer built from hexamino clusters [Cu6I6] and caged aminophosphine 1,3,5-triaza-7-phosphadadamantane and its composite material [Cu6 (µ3-I) 6 (µ3-PTA = O)] n @paper, method of their production, use as an effective sensor for aniline in a solid body and interaction of aniline with [Cu6 (µ3-I) 6 (µ3-PTA = O)] than [Cu6 (µ3-I) 6 (µ3-PTA = O )] n @ paper manifested by a change in yellow-green emissions to orange-red and shifting emissions towards longer waves.

PL423484A 2017-11-17 2017-11-17 Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor PL423484A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL423484A PL423484A1 (en) 2017-11-17 2017-11-17 Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL423484A PL423484A1 (en) 2017-11-17 2017-11-17 Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor

Publications (1)

Publication Number Publication Date
PL423484A1 true PL423484A1 (en) 2019-05-20

Family

ID=66519034

Family Applications (1)

Application Number Title Priority Date Filing Date
PL423484A PL423484A1 (en) 2017-11-17 2017-11-17 Coordination polymer of 2D type, built from hexacopper clusters [Cu₆I₆] and the 1,3,5-triaza-7-phosphaadamantane oxide cagelike aminophosphine, its composite material [Cu₆(µ₃-I)₆(µ₃PTA=O)]n@paper, method for obtaining and the application as the effective aniline sensor

Country Status (1)

Country Link
PL (1) PL423484A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154115A (en) * 2020-01-03 2020-05-15 大连理工大学 Preparation method and application of binuclear Ir (III) metal-organic supermolecular cage-like compound

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ALEXANDER M. KIRILLOV, COPPER(I) IODIDE COMPLEXES DERIVED FROM N-ALKYL-1 ,3,5- TRIAZA- 7-PHOSPHAADAMANTANES: SYNTHESIS, CRYSTAL STRUCTURES, PHOTOLUMINESCE, AND IDENTIFICATION OF THE UNPRECEDENTED {CU3I5}2- CLUSTER, 2009 *
FRANCESCO ENDRIZZI, CU(I) AND AG(I) COMPLEX FORMATION WITH THE HYDROPHILIC PHOSPHINE 1,3,5-TRIAZA-7-PHOSPHADAMANTANE IN DIFFERENT IONIC MEDIA. HOW TO ESTIMATE THE EFFECT OF A COMPLEXING MEDIUM, 2017 *
P. SMOLENSKI, UNIQUE MIXED-VALENCE CU(L)/CU(II) COORDINATION POLYMER WITH NEW TOPOLOGY OF BITUBULAR 1 D CHAINS DRIVEN BY 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PT A), 2012 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154115A (en) * 2020-01-03 2020-05-15 大连理工大学 Preparation method and application of binuclear Ir (III) metal-organic supermolecular cage-like compound

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