Rubber seal and preparation method thereof for a kind of novel capacitor
Technical field
The present invention relates to rubber composite manufacture field, particularly rubber seal and preparation method thereof for a kind of novel capacitor.
Background technology
Electrical condenser is conventionally referred to as electric capacity, is one of a large amount of electronic components that use in electronics, be widely used in circuit every aspects such as straight-through friendship, coupling, bypass, filtering, resonant tank, energy transformation, controls.Electrical condenser is comprised of housing, capacitor core, end cap and connection terminal, steeping medium is housed in capacitor casing, steeping medium is generally vegetables oil or mineral oil, the sealing position of electrical condenser is equipped with gasket or sealing-ring, because the Working environment of electrical condenser varies, some electrical condensers need to be worked under rugged environment, and that electrical condenser gasket needs is high temperature resistant, cold-resistant, acid and alkali-resistance, salt spray resistance etc. have different requirements.
Summary of the invention
The object of this invention is to provide rubber seal and preparation method thereof for a kind of novel capacitor.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of novel capacitor rubber seal, raw material by following weight part is made: chloroprene rubber (CR121) 55-60, nylon PA664-6, clay powders 3-5, mica powder 10-12, butoxy ethyl phosphate 5-7, nonylphenol 1-2, Phenylsulfonic acid 1-2, emery dust 2-3, trimethylsilyl dimethyl methyl phosphonate 1-2, melamine cyanurate 3-4, nanometer potter's clay 30-40, tributyl citrate 4-5, sulphur 1-2, zinc oxide 2-3, captax 1-2, silane resin acceptor kh-550 1-2, epoxy tetrahydro-2-ethylhexyl phthalate 1-2, attapulgite modified 10-12,
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, tolylene diisocyanate 3-4, double pentaerythritol methacrylate 2-3, diatomite 3-4, Union carbide A-162 2-3, sepiolite 10-12, Zirconium tetrafluoride 1-2, Syzygium aromaticum stem oil 2-3, xitix 1-2, kaolin 3-4,2-hydroxypropyl acrylate 2-3, lapis amiridis 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into attapulgite, diatomite, sepiolite, kaolin mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
Novel capacitor rubber seal of the present invention, by following concrete steps, made: chloroprene rubber (CR121), nylon PA66, oxygen base triethyl phosphate, trimethylsilyl dimethyl methyl phosphonate are added in Banbury mixer, be heated to 80-85 ℃, mixing 3-5min; Then be warming up to 90-110 ℃, add again clay powders, mica powder, nonylphenol, Phenylsulfonic acid, emery dust, melamine cyanurate, nanometer potter's clay, mixing 6-8min, add again tributyl citrate, sulphur, zinc oxide, captax, silane resin acceptor kh-550 to continue mixing 4-6min, add the mixing 5-6min of all the other remaining components, obtain rubber mass of the present invention.
Excellent effect of the present invention is: the present invention adds attapulgite modified, has improved the processing performance of sizing material, uses environment-friendly type Synergist S-421 95, reduces its toxic side effect and the pollution to environment; The present invention is cheap for manufacturing cost, and technique is simple, and has good oil resistance and insulating property, and application prospect is extensive.
Embodiment
Below by specific examples, the present invention is described in detail.
A novel capacitor rubber seal, by following weight part (kilogram) raw material make: chloroprene rubber (CR121) 55, nylon PA664, clay powders 3, mica powder 10, butoxy ethyl phosphate 5, nonylphenol 1, Phenylsulfonic acid 1, emery dust 2, trimethylsilyl dimethyl methyl phosphonate 1, melamine cyanurate 3, nanometer potter's clay 30, tributyl citrate 4, sulphur 1, zinc oxide 2, captax 1, silane resin acceptor kh-550 1, epoxy tetrahydro-2-ethylhexyl phthalate 1, attapulgite modified 10;
Described attapulgite modified by following weight part (kilogram) raw material make: attapulgite 20, tolylene diisocyanate 3, double pentaerythritol methacrylate 2, diatomite 3, Union carbide A-162 2, sepiolite 10, Zirconium tetrafluoride 1, Syzygium aromaticum stem oil 2, xitix 1, kaolin 3,2-hydroxypropyl acrylate 2, lapis amiridis 2, Fructus Zanthoxyli oil 1; Preparation method puts into attapulgite, diatomite, sepiolite, kaolin mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
Novel capacitor rubber seal of the present invention, by following concrete steps, made: chloroprene rubber (CR121), nylon PA66, oxygen base triethyl phosphate, trimethylsilyl dimethyl methyl phosphonate are added in Banbury mixer, be heated to 80-85 ℃, mixing 3-5min; Then be warming up to 90-110 ℃, add again clay powders, mica powder, nonylphenol, Phenylsulfonic acid, emery dust, melamine cyanurate, nanometer potter's clay, mixing 6-8min, add again tributyl citrate, sulphur, zinc oxide, captax, silane resin acceptor kh-550 to continue mixing 4-6min, add the mixing 5-6min of all the other remaining components, obtain rubber mass of the present invention.
By anti-corrosive rubber sealing-ring of the present invention and common sizing material physicals, contrast as following table.
Use as can be seen from the table rubber seal product of the present invention, comprehensive comparison is good.