Mixed rubber electrical condenser sealing-ring and preparation method thereof
Technical field
The present invention relates to rubber composite manufacture field, particularly a kind of mixed rubber electrical condenser sealing-ring and preparation method thereof.
Background technology
Electrical condenser, usually referred to as electric capacity, is one of a large amount of electronic component used in electronics, be widely used in circuit every aspects such as straight-through friendship, coupling, bypass, filtering, resonant tank, energy transformation, controls.Electrical condenser is made up of housing, capacitor core, end cap and connection terminal, capacitor casing is built with steeping medium, steeping medium is generally vegetables oil or mineral oil, the sealing position of electrical condenser is equipped with gasket or sealing-ring, because the Working environment of electrical condenser varies, some electrical condensers need to work under rugged environment, and electrical condenser gasket needs are high temperature resistant, cold-resistant, acid and alkali-resistance, salt spray resistance etc. have different requirement.
Summary of the invention
The object of this invention is to provide a kind of mixed rubber electrical condenser sealing-ring and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of mixed rubber electrical condenser sealing-ring, is made up of the raw material of following weight part: urethanes 8-12, silicon rubber 27-29, viton 64-70, aluminium hydroxide 15-20, Vulcanization accelerator TMTD 1-2, diaminodiphenylmethane 3-4, Secondary ammonium phosphate 2-3, borax 6-8, magnesium chloride 3-4, vulcanizing agent TRA1.4-1.6, dioctyl ester 8-12, paraffin 3-4, calcinated argil 30-40, carbon black 45-55, captax 1.0-2.0, attapulgite modified 12-15;
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, tolylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, clay 12-15, nano titanium oxide 3-4, Zirconium tetrafluoride 1-2, Union carbide A-162 1-2, ferrocene 1-2, Vulcanization accelerator TMTD 1-2, aluminium hydroxide 8-10,2-amino-2-methyl-1-propanol 2-3, Fructus Zanthoxyli oil 1-2; Attapulgite, clay mixing are put into calcining furnace and calcine 3-4 hour at 700-720 DEG C by preparation method, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, to obtain final product.
Mixed rubber electrical condenser sealing-ring of the present invention, be made up of following concrete steps: urethanes, aluminium hydroxide, Vulcanization accelerator TMTD, diaminodiphenylmethane, Secondary ammonium phosphate, dioctyl ester are added in Banbury mixer, be heated to 80-90 DEG C, mixing 3-5min; Then be warming up to 110-130 DEG C, then add borax, magnesium chloride, vulcanizing agent TRA, mixing 6-8min, then add paraffin, calcinated argil, carbon black continue mixing 4-6min, add the mixing 6-8min of all the other remaining components, obtain rubber mass of the present invention.
Excellent effect of the present invention is: the present invention adds attapulgite modified, improves the processing performance of sizing material, uses environment-friendly type Synergist S-421 95, reduces its toxic side effect and the pollution to environment; Sealing-ring of the present invention has good wear-resisting, oil resistance, and elasticity is suitable for, and duration of service is long, and the cost of material is low simultaneously.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of mixed rubber electrical condenser sealing-ring, is made up of the raw material of following weight part (kilogram): urethanes 8, silicon rubber 27, viton 64, aluminium hydroxide 15, Vulcanization accelerator TMTD 1, diaminodiphenylmethane 3, Secondary ammonium phosphate 2, borax 6, magnesium chloride 3, vulcanizing agent TRA1.4, dioctyl ester 8, paraffin 3, calcinated argil 30, carbon black 45, captax 1.0, attapulgite modified 12;
The described attapulgite modified raw material by following weight part (kilogram) is made: attapulgite 20, tolylene diisocyanate 3, tri (propylene glycol) diacrylate 2, clay 12, nano titanium oxide 3, Zirconium tetrafluoride 1, Union carbide A-162 1, ferrocene 1, Vulcanization accelerator TMTD 1, aluminium hydroxide 8,2-amino-2-methyl-1-propanol 2, Fructus Zanthoxyli oil 1; Attapulgite, clay mixing are put into calcining furnace and calcine 3-4 hour at 700-720 DEG C by preparation method, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, to obtain final product.
Mixed rubber electrical condenser sealing-ring of the present invention, be made up of following concrete steps: urethanes, aluminium hydroxide, Vulcanization accelerator TMTD, diaminodiphenylmethane, Secondary ammonium phosphate, dioctyl ester are added in Banbury mixer, be heated to 80-90 DEG C, mixing 3-5min; Then be warming up to 110-130 DEG C, then add borax, magnesium chloride, vulcanizing agent TRA, mixing 6-8min, then add paraffin, calcinated argil, carbon black continue mixing 4-6min, add the mixing 6-8min of all the other remaining components, obtain rubber mass of the present invention.
By anti-corrosive rubber sealing-ring of the present invention and common compound physical performance comparison as following table.
As can be seen from the table with rubber seal product of the present invention, comprehensive comparison is good.