CN106747242A - The fire-proof board and its manufacture method of a kind of energy waterproof - Google Patents
The fire-proof board and its manufacture method of a kind of energy waterproof Download PDFInfo
- Publication number
- CN106747242A CN106747242A CN201710003615.3A CN201710003615A CN106747242A CN 106747242 A CN106747242 A CN 106747242A CN 201710003615 A CN201710003615 A CN 201710003615A CN 106747242 A CN106747242 A CN 106747242A
- Authority
- CN
- China
- Prior art keywords
- mine tailing
- binding material
- grain slag
- fire
- proof board
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
- B28B1/522—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement for producing multi-layered articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B23/00—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
- B28B23/02—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects wherein the elements are reinforcing members
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses the fire-proof board and its manufacture method of a kind of energy waterproof, including plate body, it is this color surface layer, mine tailing grain slag fiber magnesite binding material that the plate body sets gradually from bottom to up, at least layer glass fibrous mesh cloth is provided with the mine tailing grain slag fiber magnesite binding material, true qualities starch adhesive material is filled between the bottom glass fibrous mesh cloth, mine tailing grain slag fiber magnesite binding material upper surface is sanding face, and organic silicon water-proofing layer is coated with outside plate body.A kind of fire-proof board of energy waterproof of the invention, product water absorption rate < 5%, coefficient of softing 1, compression strength > 40Mpa, high-strength light is widely used in interior decoration PLASTIC LAMINATED, is widely used in interior decoration PLASTIC LAMINATED.
Description
Technical field
The present invention relates to building material field, the fire-proof board and its manufacture method of a kind of energy waterproof are related specifically to.
Background technology
China's building materials industry resources and energy consumption is high, gross contamination emission big, at present, mainly takes and is cheated in surrounding city
The mode that depression band is set up interim eliminate-incorporate-land and simply fill is disposed, and causes serious environmental pollution and land resource wave
Take.
In long-term Mining Development, a large amount of the storing up of the industrial solid wastes such as mine tailing and metallurgical slag not only wastes preciousness
Land resource, return regional environment and bring huge pollution, cause great ecological environment problem.Currently, carry forward vigorously
Ecological Civilization Construction, intensive utilization of promoting energy conservation, it has also become the new normality of China " 13 " economic development.Such
Under background, how the industrial solid wastes such as propulsion mine tailing and metallurgical slag developed using technology and comprehensive utilization efficiently, energy-conservation dress
While standby device upgrade, promote financial capital and comprehensive utilization industry depth integration, explore cities with resource-based economies and resources-type enterprise
The road of the Transformation Development of industry turns into the important issue of this seminar.Industrial residue, mine tailing " turning waste into wealth ", make it " harmless
Change, resource, minimizing ", improves human settlement, promotes a conservation culture, and is green building material and the development of green building Industrial Convergence
In the urgent need to.
Existing PLASTIC LAMINATED is with substantial amounts of sawdust as inserts, it is necessary to substantial amounts of timber, destroys ecological environment, Er Qiefang
The product water absorption rate > 10% of fiery sheet material, coefficient of softing 0.85, compression strength is low.In the large-scale frame structure building such as exhibition meeting-place
, it is necessary to water absorption rate is small in thing, compression strength is high and lightweight PLASTIC LAMINATED.
The content of the invention
The technical problem to be solved in the present invention is:One kind is provided with magnesite material as gelling agent, a large amount of blast furnace granulated slags are added
It is inserts, overcomes the shortcomings of existing PLASTIC LAMINATED, the fire-proof board of light weight, compression strength a kind of energy waterproof high and its manufacture
Method.
The technical solution adopted for the present invention to solve the technical problems:A kind of fire-proof board of energy waterproof, including plate body, institute
It is this color surface layer, mine tailing grain slag fiber magnesite binding material, the mine tailing grain slag fiber water chestnut to state plate body and set gradually from bottom to up
At least layer glass fibrous mesh cloth is provided with magnesium Binder Materials, true qualities face is filled between the bottom glass fibrous mesh cloth
Slurry, mine tailing grain slag fiber magnesite binding material upper surface is sanding face, and organic silicon water-proofing layer is coated with outside plate body.
Further, the weight of every layer described of fiber/glass fiber grid cloth is between every square metre of 50g to 200g.
Further, the outer surface of described color surface layer is uniformly arranged latticed lines;Described sanding face inner surface with
And the inner surface of this color surface layer is provided with enhancement layer.
Further, the thickness of this described color surface layer is between 0.1mm to 1.2mm.
Further, the sanding face is every square metre of 35g to 68g.
Further, described mine tailing grain slag fiber magnesite binding material is to include mine tailing, grain slag, fiber, magnesite gelling
The mixture of material.Wherein described fiber is one or a combination set of the short silk of organic fiber, the short silk of inorfil, and the quality of fiber
Scope is 1-2kg, and the thickness of whole sheet material is 10-40mm.
Present invention has the advantages that:The fire-proof board of a kind of energy waterproof of the invention, by mine tailing grain slag fiber magnesite glue
The cooperation in gel material, fiberglass gridding cloth, this color surface layer and sanding face, compared with common fire prevention panel products water absorption rate <
5%, coefficient of softing 1, compression strength > 40Mpa, high-strength light is widely used in interior decoration.It is worth noting that, a kind of energy
The fire-proof board of waterproof consumes a large amount of blast furnace granulated slags, reduces pollution, improves human settlement.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the fire-proof board of energy waterproof of the invention;
Fig. 2 is schematic cross-sectional views of the Fig. 1 along A-A;
In figure, 1-mine tailing grain slag fiber magnesite binding material, 2-fiberglass gridding cloth, 3-this color surface layer, 4-sand
Smooth surface, 5-organic silicon water-proofing layer, 6-true qualities starch adhesive material.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1:
As shown in Figure 1 and Figure 2, a kind of fire-proof board of energy waterproof of the invention, including plate body, the plate body is from bottom to up
It is this color surface layer 3, mine tailing grain slag fiber magnesite binding material 1 to set gradually, in the mine tailing grain slag fiber magnesite binding material 1
At least layer glass fibrous mesh cloth 2 is provided with, true qualities starch adhesive material 6, mine tailing are filled between the bottom glass fibrous mesh cloth 2
The upper surface of grain slag fiber magnesite binding material 1 is sanding face 4, and organic silicon water-proofing layer 5 is coated with outside plate body.Wherein described glass
Glass fibrous mesh cloth 2 is equipped with two-layer.And the weight of every layer described of fiberglass gridding cloth 2 is every square metre of 50g to 200g
Between.
The fire-proof board of a kind of energy waterproof of the invention, by mine tailing grain slag fiber magnesite binding material 1, glass fiber mesh
The cooperation of lattice cloth 2, this color surface layer 3 and sanding face 4, compared with common fire prevention panel products water absorption rate < 5%, coefficient of softing 1 resists
Compressive Strength > 40Mpa, quality mitigates, but intensity improves, and is widely used in interior decoration, particularly office building decoration.Value
It is noted that it is a kind of can the fire-proof board of waterproof consume a large amount of blast furnace granulated slags, reduce pollution, improve human settlement.
Embodiment 2:
Used as preferred, the outer surface of described color surface layer 3 is uniformly arranged latticed lines;Table in described sanding face 4
The inner surface of face and this color surface layer is provided with enhancement layer.
It is worth noting that, the enhancement layer can make for organic fiber, inorfil etc..Latticed lines improves suction
Attached power, can facilitate a kind of installation of the fire-proof board of whole energy waterproof, prevent from dropping.
Embodiment 3:
As the thickness of this preferred, described color surface layer between 0.1mm to 1.2mm.
When a kind of fire-proof board gross thickness of energy waterproof is 9mm, layer glass fibrous mesh cloth 2, rupture strength >
11Mpa, when a kind of fire-proof board gross thickness of energy waterproof is 9mm, four-layer glass fibrous mesh cloth 2, rupture strength >
24Mpa, when a kind of fire-proof board gross thickness of energy waterproof is 10mm, four-layer glass fibrous mesh cloth 2, rupture strength >
24Mpa, when a kind of fire-proof board gross thickness of energy waterproof is 12mm, four-layer glass fibrous mesh cloth 2, rupture strength >
20Mpa, six layers of fiberglass gridding cloth 2, rupture strength > when a kind of fire-proof board gross thickness of energy waterproof is 16mm
25Mpa, six layers of fiberglass gridding cloth when a kind of fire-proof board gross thickness of energy waterproof is 20mm, rupture strength > 30Mpa,
Seven layers of fiberglass gridding cloth, rupture strength > 35Mpa, when a kind of energy when a kind of fire-proof board thickness of energy waterproof is 20mm
Seven layers of fiberglass gridding cloth, rupture strength > 25Mpa when the fire-proof board thickness of waterproof is 40mm.A kind of fire prevention of energy waterproof
Sheet metal thickness is different, and two to seven layers of fiberglass gridding cloth 2 may be selected.
Embodiment 5:
Used as preferred, the sanding face 4 is every square metre of 35g to 68g.
Embodiment 6:
Described mine tailing grain slag fiber magnesite binding material 1 be include mine tailing, grain slag, fiber, magnesite binding material it is mixed
Compound.The mixture is not related to component.
The preparation method of this PLASTIC LAMINATED is:
1) 29.4 ° of B é magnesium sulfate waters are made:The epsom salt of 850kg is taken, the water for then taking 1000kg is molten by magnesium sulfate
Solution is into 29.4 ° of B é magnesium sulfate waters;
2) way of 6 layer 6 of true qualities starch adhesive material:Take 29.4 ° of B é magnesium sulfate waters of 130kg, the magnesia light burnt powder of 150kg,
The dolomite dust of 8kg, the mine tailing of 85kg, the modifying agent of a weight, mixer stirs;
3) way of mine tailing grain slag fiber magnesite binding material 1:Take 29.4 ° of B é magnesium sulfate waters of 125kg, the oxygen of 100kg
Change magnesium light burnt powder, the dolomite dust of 4kg, the mine tailing of 125kg, 180kg grain slags, fiber 1kg, the modifying agent of a weight are stirred
The machine of mixing stirs;
4) PLASTIC LAMINATED is made:One mixer stirs out true qualities starch adhesive material 6, and two mixers stir out mine tailing grain slag fiber
The slurry of magnesite binding material 1, is then molded on fire prevention board assembly line, and true qualities starch adhesive material 6 is paved on PVC or ABS substrates, glass
In the press-in true qualities starch adhesive of glass fibrous mesh cloth 2 material 6, the slurry of mine tailing grain slag fiber magnesite binding material 1 is paved in true qualities starch adhesive material 6
On, fiberglass gridding cloth 2 is laid again, the slurry of mine tailing grain slag fiber magnesite binding material 1 is laid again, then lay nonwoven
Cloth, cleaved, leveling, maintenance, solidification, form removal, sanding, four side Length-fixing cuttings, maintenance, spraying waterproofing agent of organosilicon, drying.
It is worth noting that, a kind of proportioning of mine tailing grain slag fiber magnesite binding material 1:29.4 ° of B é magnesium sulfate of 135kg
Water, the magnesia light burnt powder of 100kg, the grain slag powder of 150kg, the mine tailing of 200kg, haydite 90kg, the fiber of a weight is a
The modifying agent of weight, product density 1.4.
Another proportioning of mine tailing grain slag fiber magnesite binding material 1:29.4 ° of B é magnesium sulfate waters of 155kg, 100kg's
Magnesia light burnt powder, the grain slag powder of 150kg, the mine tailing of 200kg, perlite 13kg, the fiber of a weight, a weight changes
Property agent, product density 1.25.
Another proportioning of mine tailing grain slag fiber magnesite binding material 1:29.4 ° of B é magnesium sulfate waters of 145kg, 100kg's
Magnesia light burnt powder, the grain slag powder of 150kg, the mine tailing of 200kg, eps foam pearl 1.5kg, perlite 6.5kg, a weight
Fiber, the modifying agent of a weight, product density 1.25.
Another proportioning of mine tailing grain slag fiber magnesite binding material 1:29.4 ° of B é magnesium sulfate waters of 155kg, 100kg's
Magnesia light burnt powder, the grain slag powder of 150kg, the mine tailing of 200kg, eps foam pearl 1.5kg, glass bead 6.5kg, a weight
Fiber, the modifying agent of a weight, product density 1.25.
The proportioning of this color surface layer 3:29.4 ° of B é magnesium sulfate waters of 125kg, the magnesia light burnt powder of 100kg, the water of 150kg
Ground-slag or 150kg dolomite dusts, the modifying agent of a weight, 25 DEG C to 30 DEG C of room temperature, its drying shrinkage value is minimum, and stability is most
It is good.
According to a kind of every square metre of fire-proof board thickness different choice 35g to 68g of energy waterproof, it is mainly made in sanding face 4
With product surface porosity is reduced, facilitate vacuum cup product offline.
Semi-finished product through leveling, maintenance, solidification, form removal, reach intensity after by production line enter four side sizing cutting machines, enter
Row Length-fixing cutting, product is offline.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that:Its in specification still can be right
Technical scheme described in foregoing embodiments is modified, or carries out equivalent to which part technical characteristic, not
Make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (6)
1. it is a kind of can waterproof fire-proof board, it is characterised in that:Including plate body, it is true qualities that the plate body sets gradually from bottom to up
It is provided with least in surface layer (3), mine tailing grain slag fiber magnesite binding material (1), the mine tailing grain slag fiber magnesite binding material (1)
Layer glass fibrous mesh cloth (2), is filled with true qualities starch adhesive material (6), tailing water between the bottom glass fibrous mesh cloth (2)
Slag fiber magnesite binding material (1) upper surface is sanding face (4), and organic silicon water-proofing layer (5) is coated with outside plate body.
2. it is according to claim 1 it is a kind of can waterproof fire-proof board, it is characterised in that:Described fiber/glass fiber grid
The weight of every layer of cloth (2) is between every square metre of 50g to 200g.
3. it is according to claim 1 and 2 it is a kind of can waterproof fire-proof board, it is characterised in that:Described color surface layer (3)
Outer surface is uniformly arranged latticed lines;Described sanding face (4) inner surface and the inner surface of this color surface layer (3) are provided with
Organic silicon water-proofing layer (5).
4. it is according to claim 1 and 2 it is a kind of can waterproof fire-proof board, it is characterised in that:Described this color surface layer (3)
Thickness between 0.1mm to 1.2mm.
5. it is according to claim 1 and 2 it is a kind of can waterproof fire-proof board, it is characterised in that:Described mine tailing grain slag is fine
Dimension magnesite binding material (1) is the mixture for including mine tailing, grain slag, fiber, magnesite binding material.
6. a kind of fire-proof board of the energy waterproof described in claim 1-5 is prepared, it is characterised in that:
Manufacture method is:
(1) 29.4 ° of B é magnesium sulfate waters are made:The epsom salt of 850kg is taken, be dissolved into for magnesium sulfate by the water for then taking 1000kg
29.4 ° of B é magnesium sulfate waters;
(2) way of the true qualities starch adhesive bed of material (6):Take 29.4 ° of B é magnesium sulfate waters of 130kg, the magnesia light burnt powder of 150kg, 8kg
Dolomite dust, the mine tailing of 85kg, the modifying agent of a weight, mixer stirs;
(3) way of mine tailing grain slag fiber magnesite binding material (1):Take 29.4 ° of B é magnesium sulfate waters of 125kg, the oxidation of 100kg
Magnesium light burnt powder, the dolomite dust of 4kg, the mine tailing of 125kg, 180kg grain slags, fiber 1kg, the modifying agent of a weight, stirring
Machine stirs;
(4) PLASTIC LAMINATED is made:One mixer stirs out true qualities starch adhesive material (6), and two mixers stir out mine tailing grain slag fiber
Magnesite binding material slurry (1), is then molded on fire prevention board assembly line, and true qualities starch adhesive material is paved on PVC or ABS substrates,
Fiberglass gridding cloth (2) is pressed into true qualities starch adhesive material (6), and mine tailing grain slag fiber magnesite binding material (1) slurry is paved at this
On color starch adhesive material (6), fiberglass gridding cloth (2) is laid again, mine tailing grain slag fiber magnesite binding material (2) slurry is laid again
Material, then lays non-woven fabrics, cleaved, leveling, maintenance, solidification, form removal, sanding, four side Length-fixing cuttings, conserve, spray it is organic
Silicon waterproofing agent, drying.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107386477A (en) * | 2017-06-28 | 2017-11-24 | 无锡市京锡冶金液压机电有限公司 | A kind of corridor special fireproof plate and preparation method thereof |
CN107471781A (en) * | 2017-06-16 | 2017-12-15 | 无锡市京锡冶金液压机电有限公司 | A kind of indoor suspended ceiling sheet material and preparation method thereof |
CN108585755A (en) * | 2018-06-07 | 2018-09-28 | 黄志贵 | A kind of phase transformation anion glass magnesium artificial stone plate and its manufacturing method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107471781A (en) * | 2017-06-16 | 2017-12-15 | 无锡市京锡冶金液压机电有限公司 | A kind of indoor suspended ceiling sheet material and preparation method thereof |
CN107386477A (en) * | 2017-06-28 | 2017-11-24 | 无锡市京锡冶金液压机电有限公司 | A kind of corridor special fireproof plate and preparation method thereof |
CN108585755A (en) * | 2018-06-07 | 2018-09-28 | 黄志贵 | A kind of phase transformation anion glass magnesium artificial stone plate and its manufacturing method |
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Application publication date: 20170531 |