CN106747226A - One kind has excellent water penetration Ceramic water-permeable brick - Google Patents

One kind has excellent water penetration Ceramic water-permeable brick Download PDF

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Publication number
CN106747226A
CN106747226A CN201611261483.6A CN201611261483A CN106747226A CN 106747226 A CN106747226 A CN 106747226A CN 201611261483 A CN201611261483 A CN 201611261483A CN 106747226 A CN106747226 A CN 106747226A
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CN
China
Prior art keywords
parts
permeable brick
water
whisker
excellent water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611261483.6A
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Chinese (zh)
Inventor
薛念念
汤俊怀
李青松
王军
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Anhui city clean environment Technology Co., Ltd.
Original Assignee
Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Anhui Huapu Environmental Remediation Mstar Technology Ltd filed Critical Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority to CN201611261483.6A priority Critical patent/CN106747226A/en
Publication of CN106747226A publication Critical patent/CN106747226A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

There is excellent water penetration Ceramic water-permeable brick the invention discloses one kind, its raw material includes by weight:5 10 parts of silicon carbide whisker, 10 20 parts of magnesium borate crystal whisker, 5 12 parts of glass microballoon, 28 parts of concrete, 30 50 parts of cinder, 28 parts of silicon powder, 10 20 parts of gangue, 28 parts of calcium nitrate, 3 10 parts of limestone, 26 parts of calcite, 16 parts of gypsum fiber, 27 parts of sodium metasilicate, 3 12 parts of bentonite, 5 10 parts of nano-cellulose whisker, 5 12 parts of porous konilite, 0.2 0.8 parts of water reducer, 12 parts of adhesive, 30 60 parts of shraff, 50 100 parts of loess compound.Not only low cost of the invention, and good water permeability, it is economic and environment-friendly.

Description

One kind has excellent water penetration Ceramic water-permeable brick
Technical field
There is excellent water penetration Ceramic water-permeable brick the present invention relates to seepage brick technical field, more particularly to one kind.
Background technology
With the construction of modern city, building and concrete in city etc. more and more cover city ground Face, prevents the precipitation in city from swimmingly permeating the ground, and is formed city " tropical island effect ", and formed in city when heavy rain is run into Flood, very big ten are brought just to city people's lives.Because ceramic water-permeable brick is used as a kind of environmentally conscious materialses, possess good pressure resistance Degree, can be applicable to urban road and square water-permeable brick, and a kind of good water permeability, economic and environment-friendly ceramic water-permeable brick how are prepared at present As the current technical issues that need to address.
The content of the invention
The present invention proposes a kind of with excellent water penetration Ceramic water-permeable brick, not only low cost, and good water permeability, economic ring Protect.
Proposed by the present invention a kind of with excellent water penetration Ceramic water-permeable brick, its raw material includes by weight:Silicon carbide whisker Must 5-10 parts, magnesium borate crystal whisker 10-20 parts, glass microballoon 5-12 parts, concrete 2-8 parts, cinder 30-50 parts, silicon powder 2-8 Part, gangue 10-20 parts, calcium nitrate 2-8 parts, limestone 3-10 parts, calcite 2-6 parts, gypsum fiber 1-6 parts, sodium metasilicate 2-7 Part, bentonite 3-12 parts, 5-10 parts of nano-cellulose whisker, porous konilite 5-12 parts, water reducer 0.2-0.8 parts, adhesive 1-2 parts, shraff 30-60 parts, 50-100 parts of loess compound.
Preferably, loess compound is prepared using following technique:Beta-schardinger dextrin, NaOH, pyridine are mixed, is stirred Speed is mixed for 400-480r/min, succinyl oxide is added, in 55-62 DEG C of stirring of temperature, dimethylformamide crystallization is added, done It is dry, add sand yellow soil, phosphate aqueous solution to mix, mixing speed is 450-520r/min, adds sodium tetraborate to continue to stir, Dry, pulverize, obtain loess compound.
Preferably, beta-schardinger dextrin, NaOH, the weight ratio of pyridine are 4-12:1-3:70-100.
Preferably, beta-schardinger dextrin, the weight ratio of succinyl oxide are 4-12:1-4.
Preferably, phosphate aqueous solution concentration is 2-6%;Sand yellow soil, the weight ratio of phosphate aqueous solution are 15-35:60-100.
Preferably, sodium tetraborate, the weight ratio of sand yellow soil are 0.5-2.5:15-35.
Preferably, loess compound is prepared using following technique:By weight by 4-12 parts of beta-schardinger dextrin, 1-3 parts of hydrogen-oxygen Change sodium, 70-100 parts of pyridine and mix 2-4h, mixing speed is 400-480r/min, 1-4 parts of succinyl oxide is added, in temperature 55-62 DEG C of stirring 10-20min, adds dimethylformamide crystallization, dries, and adds 15-35 parts of sand yellow soil, 60-100 parts of concentration For 2-6% phosphate aqueous solutions mix 20-60min, mixing speed is 450-520r/min, adds 0.5-2.5 parts of tetraboric acid Sodium continues to stir 20-35min, dry, pulverize, and obtains loess compound.
Preferably, described with excellent water penetration Ceramic water-permeable brick, its raw material includes by weight:Silicon carbide whisker 6- 8 parts, magnesium borate crystal whisker 14-17 parts, glass microballoon 6-8 parts, concrete 4-6 parts, cinder 42-46 parts, silicon powder 5-7 parts, bastard coal Stone 14-16 parts, calcium nitrate 5-7 parts, limestone 6-8 parts, calcite 3-5 parts, gypsum fiber 2-4 parts, sodium metasilicate 4-5 parts, swelling It is native 8-10 parts, 6-8 parts of nano-cellulose whisker, porous konilite 6-8 parts, water reducer 0.4-0.6 parts, adhesive 1.2-1.5 parts, Shraff 50-55 parts, 60-80 parts of loess compound.
In loess compound of the invention, beta-schardinger dextrin molecular shape is outer hydrophilic slightly in the cavity of cone cylinder shape for interior hydrophobic Structure, it contains substantial amounts of primary hydroxyl and secondary hydroxyl, is acted on succinyl oxide under certain condition, water-soluble fabulous, can be effective Promote sand yellow soil to be acidified in phosphate aqueous solution and destroy the granular built on stilts micro-structural of sand yellow soil, combined with sodium tetraborate, and lead to Matched between crossing rationally control each component, on the premise of guarantee is excellent in cushion effect, seepage of water is fabulous, matches somebody with somebody with shraff for product Not only low cost is closed, and innoxious and resource utilization can be realized;Remaining sand material, can be in brick structure in sintering process The structure with certain porosity is formed, both ensure that fragment of brick had certain mechanical strength, formation can be saturating between also making fragment of brick The space of water, improves its permeability performance, coordinates its compression strength to can reach more than 24MPa with loess compound, while infiltration Coefficient is up to 1.58 × 10-2More than cm/s.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
One kind has excellent water penetration Ceramic water-permeable brick, and its raw material includes by weight:5 parts of silicon carbide whisker, antifungin 20 parts of whisker, 5 parts of glass microballoon, concrete eight part, 30 parts of cinder, 8 parts of silicon powder, 10 parts of gangue, 8 parts of calcium nitrate, limestone 3 parts, 6 parts of calcite, 1 part of gypsum fiber, 7 parts of sodium metasilicate, 3 parts of bentonite, 10 parts of nano-cellulose whisker, porous konilite 5 Part, 0.8 part of water reducer, 1 part of adhesive, 60 parts of shraff, 50 parts of loess compound.
Embodiment 2
One kind has excellent water penetration Ceramic water-permeable brick, and its raw material includes by weight:10 parts of silicon carbide whisker, antifungin 10 parts of whisker, 12 parts of glass microballoon, 2 parts of concrete, 50 parts of cinder, 2 parts of silicon powder, 20 parts of gangue, 2 parts of calcium nitrate, lime 10 parts of rock, 2 parts of calcite, 6 parts of gypsum fiber, 2 parts of sodium metasilicate, 12 parts of bentonite, 5 parts of nano-cellulose whisker, periporate stone 12 parts of English, 0.2 part of water reducer, 2 parts of adhesive, 30 parts of shraff, 100 parts of loess compound.
Embodiment 3
One kind has excellent water penetration Ceramic water-permeable brick, and its raw material includes by weight:8 parts of silicon carbide whisker, antifungin 14 parts of whisker, 8 parts of glass microballoon, 4 parts of concrete, 46 parts of cinder, 5 parts of silicon powder, 16 parts of gangue, 5 parts of calcium nitrate, limestone 8 parts, 3 parts of calcite, 4 parts of gypsum fiber, 4 parts of sodium metasilicate, 10 parts of bentonite, 6 parts of nano-cellulose whisker, porous konilite 8 Part, 0.4 part of water reducer, 1.5 parts of adhesive, 50 parts of shraff, 80 parts of loess compound.
Loess compound is prepared using following technique:By weight by 4 parts of beta-schardinger dextrins, 3 parts of NaOH, 70 parts of pyridines 4h is mixed, mixing speed is 400r/min, add 4 parts of succinyl oxides, in 55 DEG C of stirring 20min of temperature, add dimethyl Formamide is crystallized, and is dried, and it is that 2% phosphate aqueous solution mixes 60min, mixing speed to add 15 parts of sand yellow soil, 100 parts of concentration It is 450r/min, adds 2.5 parts of sodium tetraborates to continue to stir 20min, dry, pulverize, obtains loess compound.
Embodiment 4
One kind has excellent water penetration Ceramic water-permeable brick, and its raw material includes by weight:6 parts of silicon carbide whisker, antifungin 17 parts of whisker, 6 parts of glass microballoon, 6 parts of concrete, 42 parts of cinder, 7 parts of silicon powder, 14 parts of gangue, 7 parts of calcium nitrate, limestone 6 parts, 5 parts of calcite, 2 parts of gypsum fiber, 5 parts of sodium metasilicate, 8 parts of bentonite, 8 parts of nano-cellulose whisker, porous konilite 6 Part, 0.6 part of water reducer, 1.2 parts of adhesive, 55 parts of shraff, 60 parts of loess compound.
Loess compound is prepared using following technique:By weight by 12 parts of beta-schardinger dextrins, 1 part of NaOH, 100 parts of pyrroles Pyridine mixes 2h, and mixing speed is 480r/min, adds 1 part of succinyl oxide, in 62 DEG C of stirring 10min of temperature, adds diformazan Base formamide is crystallized, and is dried, and it is that 6% phosphate aqueous solution mixes 20min, stirring speed to add 35 parts of sand yellow soil, 60 parts of concentration It is 520r/min to spend, and adds 0.5 part of sodium tetraborate to continue to stir 35min, be dry, pulverize, and obtains loess compound.
Embodiment 5
One kind has excellent water penetration Ceramic water-permeable brick, and its raw material includes by weight:7 parts of silicon carbide whisker, antifungin 15 parts of whisker, 7 parts of glass microballoon, 5 parts of concrete, 43 parts of cinder, 6 parts of silicon powder, 15 parts of gangue, 6 parts of calcium nitrate, limestone 7 parts, 4 parts of calcite, 3 parts of gypsum fiber, 4.2 parts of sodium metasilicate, 8 parts of bentonite, 7 parts of nano-cellulose whisker, porous konilite 7 Part, 0.5 part of water reducer, 1.4 parts of adhesive, 52 parts of shraff, 72 parts of loess compound.
Loess compound is prepared using following technique:By weight by 8 parts of beta-schardinger dextrins, 1.5 parts of NaOH, 85 parts of pyrroles Pyridine mixes 3h, and mixing speed is 440r/min, adds 1.5 parts of succinyl oxides, in 58 DEG C of stirring 16min of temperature, adds two NMF is crystallized, and is dried, and it is that 3.5% phosphate aqueous solution mixes 40min to add 22 parts of sand yellow soil, 85 parts of concentration, is stirred Speed is mixed for 485r/min, adds 2.1 parts of sodium tetraborates to continue to stir 32min, dry, pulverize, obtain loess compound.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (8)

1. it is a kind of that there is excellent water penetration Ceramic water-permeable brick, it is characterised in that its raw material includes by weight:Silicon carbide whisker 5- 10 parts, magnesium borate crystal whisker 10-20 parts, glass microballoon 5-12 parts, concrete 2-8 parts, cinder 30-50 parts, silicon powder 2-8 parts, coal It is spoil 10-20 parts, calcium nitrate 2-8 parts, limestone 3-10 parts, calcite 2-6 parts, gypsum fiber 1-6 parts, sodium metasilicate 2-7 parts, swollen 3-12 parts of soil of profit, 5-10 parts of nano-cellulose whisker, porous konilite 5-12 parts, water reducer 0.2-0.8 parts, adhesive 1-2 parts, Shraff 30-60 parts, 50-100 parts of loess compound.
2. it is according to claim 1 with excellent water penetration Ceramic water-permeable brick, it is characterised in that loess compound is using such as It is prepared by lower technique:Beta-schardinger dextrin, NaOH, pyridine are mixed, mixing speed is 400-480r/min, add butanedioic acid Acid anhydride, in 55-62 DEG C of stirring of temperature, adds dimethylformamide crystallization, dries, and adds sand yellow soil, phosphate aqueous solution to mix, Mixing speed is 450-520r/min, adds sodium tetraborate to continue to stir, and be dry, pulverize, and obtains loess compound.
3. it is according to claim 2 with excellent water penetration Ceramic water-permeable brick, it is characterised in that beta-schardinger dextrin, hydroxide Sodium, the weight ratio of pyridine are 4-12:1-3:70-100.
4. it is according to claim 2 with excellent water penetration Ceramic water-permeable brick, it is characterised in that beta-schardinger dextrin, butanedioic acid The weight ratio of acid anhydride is 4-12:1-4.
5. it is according to claim 2 with excellent water penetration Ceramic water-permeable brick, it is characterised in that phosphate aqueous solution concentration is 2-6%;Sand yellow soil, the weight ratio of phosphate aqueous solution are 15-35:60-100.
6. it is according to claim 2 with excellent water penetration Ceramic water-permeable brick, it is characterised in that sodium tetraborate, sand yellow soil Weight ratio be 0.5-2.5:15-35.
7. according to claim any one of 1-6 with excellent water penetration Ceramic water-permeable brick, it is characterised in that loess be combined Thing is prepared using following technique:4-12 parts of beta-schardinger dextrin, 1-3 parts of NaOH, 70-100 parts of pyridine are mixed by weight is stirred 2-4h is mixed, mixing speed is 400-480r/min, add 1-4 parts of succinyl oxide, in 55-62 DEG C of stirring 10-20min of temperature, plus Enter dimethylformamide crystallization, dry, it is that the mixing of 2-6% phosphate aqueous solutions is stirred to add 15-35 parts of sand yellow soil, 60-100 parts of concentration 20-60min is mixed, mixing speed is 450-520r/min, adds 0.5-2.5 parts of sodium tetraborate to continue to stir 20-35min, dried, Crush, obtain loess compound.
8. according to claim any one of 1-7 with excellent water penetration Ceramic water-permeable brick, it is characterised in that its raw material is pressed Weight portion includes:Silicon carbide whisker 6-8 parts, magnesium borate crystal whisker 14-17 parts, glass microballoon 6-8 parts, concrete 4-6 parts, cinder 42-46 parts, silicon powder 5-7 parts, gangue 14-16 parts, calcium nitrate 5-7 parts, limestone 6-8 parts, calcite 3-5 parts, gypsum is fine 2-4 parts of dimension, sodium metasilicate 4-5 parts, bentonite 8-10 parts, 6-8 parts of nano-cellulose whisker, porous konilite 6-8 parts, water reducer 0.4-0.6 parts, adhesive 1.2-1.5 parts, shraff 50-55 parts, 60-80 parts of loess compound.
CN201611261483.6A 2016-12-30 2016-12-30 One kind has excellent water penetration Ceramic water-permeable brick Pending CN106747226A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675759A (en) * 2018-06-22 2018-10-19 郑州秉同立智电子科技有限公司 A kind of high stability ceramic material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850038A (en) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 Ceramic water-permeable brick
CN104781210A (en) * 2012-10-30 2015-07-15 乐金华奥斯有限公司 Antibacterial porous ceramic tile, and preparation method therefor
CN104860663A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Waterproof mould-proof ceramic tile and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850038A (en) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 Ceramic water-permeable brick
CN104781210A (en) * 2012-10-30 2015-07-15 乐金华奥斯有限公司 Antibacterial porous ceramic tile, and preparation method therefor
CN104860663A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Waterproof mould-proof ceramic tile and production method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675759A (en) * 2018-06-22 2018-10-19 郑州秉同立智电子科技有限公司 A kind of high stability ceramic material and preparation method thereof
CN108675759B (en) * 2018-06-22 2020-04-24 福建省德化县腾艺陶瓷有限公司 High-stability ceramic material and preparation method thereof

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Effective date of registration: 20181112

Address after: 242300 No. 102 outer ring road, Ningguo, Xuancheng, Anhui.

Applicant after: Anhui city clean environment Technology Co., Ltd.

Address before: 242300 Anhui Ningguo Xuancheng port eco industrial park passes two way.

Applicant before: Anhui Huapu environmental remediation Mstar Technology Ltd

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531