CN106882943A - A kind of strength cement-based grouting material suitable for chlorion hyposmosis - Google Patents

A kind of strength cement-based grouting material suitable for chlorion hyposmosis Download PDF

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Publication number
CN106882943A
CN106882943A CN201710202430.5A CN201710202430A CN106882943A CN 106882943 A CN106882943 A CN 106882943A CN 201710202430 A CN201710202430 A CN 201710202430A CN 106882943 A CN106882943 A CN 106882943A
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CN
China
Prior art keywords
grouting material
chlorion
hyposmosis
strength cement
based grouting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710202430.5A
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Chinese (zh)
Inventor
朱燕
陈佳佳
宋玲
徐广舒
宋健
王伟
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Nantong Vocational College
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Nantong Vocational College
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Vocational College filed Critical Nantong Vocational College
Priority to CN201710202430.5A priority Critical patent/CN106882943A/en
Publication of CN106882943A publication Critical patent/CN106882943A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/24Sea water resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Present invention is disclosed a kind of strength cement-based grouting material suitable for chlorion hyposmosis, 42.5R Portland cements:39.7%~40.7%;River sand:39.7%~40.7%;Flyash:3.2%~3.3%;Silicon ash:2%;Water reducer:0.28%;Retarder:0.04%;Swelling agent:3.18%~3.28%;Water:9.7%~11.9%.Strength cement-based grouting material of the present invention is based on Portland cement, the admixtures such as optimum organization river sand, flyash, silicon ash, and it is aided with the additives such as water reducer, retarder, swelling agent, and the rational ratio of mud, so that the strength cement-based grouting material except having the advantages that early strength is high, later strength is high, Workable, microdilatancy, not in addition to bleeding, also there is the characteristics of total chloridion content is low, electric flux value is low, and resistance of chloride ion penetration is high.

Description

A kind of strength cement-based grouting material suitable for chlorion hyposmosis
Technical field
The invention belongs to strength cement-based grouting material field, and in particular to filled to a kind of cement base with chlorion hypotonicity Slurry.
Background technology
Strength cement-based grouting material is by cement, additive(Water reducer, swelling agent, retarder etc.), gather materials and mineral admixture Deng the dry blend that material is bound together, adding water has the advantages that intensity high, Workable, not microdilatancy, bleeding after mixing and stirring, and Such grouting material is nontoxic, cheap, is applied to the anchoring of the back-grouting, foundation bolt of mechanical equipment installation more, mixes Xtah Crude Clay structure is transformed and the field such as is connected with reinforcing, the grouting of assembled architecture.
As coastal economy develops on a large scale, high-rise building and Large-Scale Equipment emerge in an endless stream, especially the Sheng of assembled architecture OK, but these buildings or the equipment long-term seepage failure by chlorion in use, building or equipment are shortened Service life, and the resistance of chloride ion penetration of strength cement-based grouting material of the prior art is low, therefore coastal engineering pair can not be met The requirement of basic material.
The content of the invention
A kind of defect it is an object of the invention to overcome prior art, there is provided cement base suitable for chlorion hyposmosis Grouting material, except having the advantages that early strength is high, later strength is high, Workable, microdilatancy, not in addition to bleeding, also with total chlorine Ion concentration is low, electric flux value is low, the characteristics of resistance of chloride ion penetration is high.
To achieve the above object, the present invention proposes following technical scheme:A kind of cement base suitable for chlorion hyposmosis Grouting material, is constituted and mass percent with following material:
42.5R Portland cements: 39.7%~40.7%;
River sand: 39.7%~40.7%;
Flyash: 3.2%~3.3%
Silicon ash: 2%;
Water reducer: 0.28%;
Retarder: 0.04%;
Swelling agent: 3.18%~3.28%;
Water: 9.7%~11.9%.
Preferably, the portland cement density is 3.21g/cm3, specific surface area is 355m2/ kg, fineness is 0.85%, Consumptive use of water normal consistence 31%, alkali content 0.67%, loss on ignition 4.11%, volume stability and pressure-proof and snap-resistent intensity are qualified.
Preferably, the flyash is I grade of flyash, density 2.78g/cm3, water demand ratio 93.5%, loss on ignition 2.7%, 45 μm of screen over-sizes 4.47%.
Preferably, described silicon ash is SILICA FUME.
Preferably, the river sand is washed more than 20 times and dries dry, particle diameter≤2.36mm, modulus of fineness Mf=in advance 2.78。
Preferably, the water reducer is Polycarboxylic Superplasticizer, diminishing efficiency is 25%;
Preferably, described retarder is tartaric acid.
Preferably, described swelling agent is CMA high performance expansion admixtures.
The present invention provide chlorion hyposmosis strength cement-based grouting material in, flyash improve grouting material microstructure and The composition of hydrated product, reduces transmittability of the chlorion in the middle of grouting material, improves the chloride-penetration resistance of grouting material Performance, additionally, flyash has preferable water-retaining property, can improve the intensity and workability of grouting material;Silicon ash is preferably filled out The space of cement particle is filled, increases the mobility of grouting material, while improving the packing and intensity of grouting material;River sand maximum particle diameter 2.36mm, had both met the requirement of fluidity, and the intensity of grouting material is can ensure that again;High efficiency water reducing agent effectively reduces the ratio of mud, reduces The quantity and size of macropore, improve the Anti-Chloride Ion Penetration of hardened paste;The hydration rate and water of retarder reduction cement The mud heat of hydration, reduces the gradual loss of grouting material fluidity;Swelling agent is filled out by the secondary hydration with hydrolysis product of cement Fill, cut off big continuous pore, increased the packing of grouting material, improve its resistance of concrete to chloride ion penetration, further, since Swell increment is more than aquation amount of contraction, and the anti-crack ability of grouting material is improved, it is ensured that its good anti-permeability performance.
Compared with prior art, a kind of strength cement-based grouting material suitable for chlorion hyposmosis that the present invention is disclosed, uses Common low-grade cement, it is cheap, using extensive;The strength cement-based grouting material of chlorion hyposmosis prepared by the present invention is removed to be had Early strength is high, later strength is high, Workable, microdilatancy, not bleeding the advantages of outside, also with total chloridion content is low, electricity Amount of flux is low, the characteristics of resistance of chloride ion penetration is high, can be widely applied to the back-grouting of mechanical equipment installation, foundation bolt Anchoring, concrete structure transformation the field such as are connected with reinforcing, the grouting of assembled architecture, especially meet coastal engineering to basis The requirement of property material.
Specific embodiment
Below in conjunction with specific embodiment of the invention, the technical scheme of the embodiment of the present invention is carried out clear, complete Description.
Embodiment 1
Using 42.5R Portland cements 40.7%, the river sand 40.7% of maximum particle diameter 2.36mm, I grade of flyash 3.3%, silicon ash 2.0%, Polycarboxylic Superplasticizer 0.28%, tartaric acid retarder 0.04%, CMA high performance expansion admixtures 3.28% add 9.7% Water mix, stirred with glue sand agitator.
Embodiment 2
Using 42.5R Portland cements 40.4%, the river sand 40.4% of maximum particle diameter 2.36mm, I grade of flyash 3.2%, silicon ash 2.0%, Polycarboxylic Superplasticizer 0.28%, tartaric acid retarder 0.04%, CMA high performance expansion admixtures 3.28% add 10.4% Water mix, stirred with glue sand agitator.
Embodiment 3
Using 42.5R Portland cements 40%, the river sand 40% of maximum particle diameter 2.36mm, I grade of flyash 3.2%, silicon ash 2.0%, Polycarboxylic Superplasticizer 0.28%, tartaric acid retarder 0.04%, CMA high performance expansion admixtures 3.18% add 11.3% Water mix, stirred with glue sand agitator.
Embodiment 4
Using 42.5R Portland cements 39.7%, the river sand 39.7% of maximum particle diameter 2.36mm, I grade of flyash 3.2%, silicon ash 2.0%, Polycarboxylic Superplasticizer 0.28%, tartaric acid retarder 0.04%, CMA high performance expansion admixtures 3.18% add 11.9% Water mix, stirred with glue sand agitator.
By the grouting material that example is produced, its technical indicator is listed in the table below interior.
Technology contents of the invention and technical characteristic have revealed that as above, but those of ordinary skill in the art still may base Make a variety of replacements and modification without departing substantially from spirit of the present invention in teachings of the present invention and announcement, therefore, the scope of the present invention Should be not limited to the content disclosed in embodiment, and should include various without departing substantially from replacement of the invention and modification, and be this patent Shen Please claim covered.

Claims (8)

1. a kind of strength cement-based grouting material suitable for chlorion hyposmosis, it is characterised in that:Constituted with following material and matter Amount percentage:
42.5R Portland cements: 39.7%~40.7%;
River sand: 39.7%~40.7%;
Flyash: 3.2%~3.3%
Silicon ash: 2%;
Water reducer: 0.28%;
Retarder: 0.04%;
Swelling agent: 3.18%~3.28%;
Water: 9.7%~11.9%.
2. the strength cement-based grouting material suitable for chlorion hyposmosis according to claim 1, it is characterised in that:The silicon Acid salt cement density is 3.21g/cm3, and specific surface area is 355m2/kg, and fineness is 0.85%, consumptive use of water normal consistence 31%, alkali Content 0.67%, loss on ignition 4.11%, volume stability and pressure-proof and snap-resistent intensity are qualified.
3. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:The flyash is I Level flyash, density 2.78g/cm3, water demand ratio 93.5%, loss on ignition 2.7%, 45 μm of screen over-sizes 4.47%.
4. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:Described silicon ash is micro- Silica flour.
5. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:River sand water in advance Wash more than 20 times and dry dry, particle diameter≤2.36mm, modulus of fineness Mf=2.78.
6. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:The water reducer is poly- Carboxylic acid analog high efficiency water reducing agent, diminishing efficiency is 25%;
The strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:Described retarder is wine Stone acid.
7. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:Described swelling agent is CMA high performance expansion admixtures.
8. the strength cement-based grouting material of chlorion hyposmosis according to claim 1, it is characterised in that:Described water is originally Water.
CN201710202430.5A 2017-03-30 2017-03-30 A kind of strength cement-based grouting material suitable for chlorion hyposmosis Pending CN106882943A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107265977A (en) * 2017-06-28 2017-10-20 徐州市龙山水泥有限公司 A kind of hypotonic cement base-material
CN110156402A (en) * 2019-06-04 2019-08-23 江南大学 A kind of cement base new-old concrete interfacial adhesion strengthening material and preparation method
CN112919869A (en) * 2021-03-30 2021-06-08 中交上海港湾工程设计研究院有限公司 Low-density grouting material and preparation method thereof
CN115504735A (en) * 2022-09-13 2022-12-23 长江师范学院 Cement-based grouting material for steel bar sleeve

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269935A (en) * 2008-04-29 2008-09-24 水利部交通部电力工业部南京水利科学研究院 Conduit pipe joint sealing perfusion mortar and manufacturing method thereof
CN101602589A (en) * 2009-06-30 2009-12-16 中国地质大学(武汉) Post-tensioned prestressing pipeline vacuum grouting or mud jacking preformed material and preparation method thereof
CN101798208A (en) * 2010-02-22 2010-08-11 湖北中桥科技有限公司 High fluidity grouting material and production method thereof
CN102351503A (en) * 2011-07-12 2012-02-15 安徽中铁工程材料科技有限公司 High speed railway bridge bearing anchoring mortar material
CN104671719A (en) * 2015-03-06 2015-06-03 建研建材有限公司 Cement-based reinforced grouting material with strong acid resistance

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269935A (en) * 2008-04-29 2008-09-24 水利部交通部电力工业部南京水利科学研究院 Conduit pipe joint sealing perfusion mortar and manufacturing method thereof
CN101602589A (en) * 2009-06-30 2009-12-16 中国地质大学(武汉) Post-tensioned prestressing pipeline vacuum grouting or mud jacking preformed material and preparation method thereof
CN101798208A (en) * 2010-02-22 2010-08-11 湖北中桥科技有限公司 High fluidity grouting material and production method thereof
CN102351503A (en) * 2011-07-12 2012-02-15 安徽中铁工程材料科技有限公司 High speed railway bridge bearing anchoring mortar material
CN104671719A (en) * 2015-03-06 2015-06-03 建研建材有限公司 Cement-based reinforced grouting material with strong acid resistance

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107265977A (en) * 2017-06-28 2017-10-20 徐州市龙山水泥有限公司 A kind of hypotonic cement base-material
CN110156402A (en) * 2019-06-04 2019-08-23 江南大学 A kind of cement base new-old concrete interfacial adhesion strengthening material and preparation method
CN112919869A (en) * 2021-03-30 2021-06-08 中交上海港湾工程设计研究院有限公司 Low-density grouting material and preparation method thereof
CN115504735A (en) * 2022-09-13 2022-12-23 长江师范学院 Cement-based grouting material for steel bar sleeve

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Application publication date: 20170623

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