CN106702418B - Photocatalytic hydrogen production equipment and photocatalytic water treatment device - Google Patents
Photocatalytic hydrogen production equipment and photocatalytic water treatment device Download PDFInfo
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- CN106702418B CN106702418B CN201611237006.6A CN201611237006A CN106702418B CN 106702418 B CN106702418 B CN 106702418B CN 201611237006 A CN201611237006 A CN 201611237006A CN 106702418 B CN106702418 B CN 106702418B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Catalysts (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The photocatalyst catalytic hydrogen production equipment comprises a photolysis module; the electromagnetic valve driving module is further included. The photocatalytic water treatment device has the technical scheme. The invention has the advantages of low cost, flexible application, long service life, convenient use, safety and reliability.
Description
Technical field
The invention belongs to hydrogen preparation field technical fields, at photocatalyst catalyzing manufacturing of hydrogen equipment, photocatalysis water
Manage device.
Technical background
The problems such as that there are efficiency is low, of high cost for photolysis water hydrogen system, electrode life is short, cause it to be difficult to actually answer
With.
Invention content
In order to solve the above technical problems, the present invention proposes photocatalyst catalyzing manufacturing of hydrogen equipment, photocatalytic water treatment device,
Specific solution has following technical solution.
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
It further include solenoid valve driving module；
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode
(DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；One end of 5th capacitance and microcontroller
Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；The electricity of one end and microcontroller of the 6th capacitance
Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller；The supply pin of one end and microcontroller of the 7th capacitance
It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place (GND), the microcontroller of control unit
Supply pin with control power supply (VCC) be connected；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode
(D1), the second diode (D2), first resistor (R1), the 8th resistance (R8), the first capacitance (C1), the second capacitance (C2), the 4th
Capacitance (C4), the first inductance (L1), power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor (Q1) has input, output end, control terminal；First
The output end of metal-oxide-semiconductor (Q1) is connected with the cathode of the first diode (D1)；The input terminal of first metal-oxide-semiconductor (Q1) is via first resistor
(R1) it is connected to the control terminal of the first metal-oxide-semiconductor (Q1)；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode (Q6) has input, output end, control terminal；The
The input terminal of six triodes (Q6) is connected to the control terminal of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5)；6th triode
(Q6) output end is connected with the anode of the first diode (D1)；The input terminal of 6th triode (Q6) and power power-supply access point
It is connected；The control terminal of 6th triode (Q6) is connected to pwm signal access point via the 8th resistance (R8)；
In the VRM Voltage Regulator Module of photocatalytic water module：The output end phase of one end of the first capacitance (C1) and the first inductance (L1)
Even, the other end of the first capacitance (C1) is connected with the anode of the first diode (D1)；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance (C2) is in parallel with the first capacitance (C1)；8th resistance
(R8) in parallel with the 4th capacitance (C4)；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC)；
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit
Even；
The anode of the first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND)；
The output end of the first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), third capacitance (C3)；
In the voltage feedback module of photocatalytic water module：4th resistance (R4) has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance (R9) has input, output end；9th resistance (R9)
Input terminal be connected with the input terminal of the 4th resistance (R4)；
In the voltage feedback module of photocatalytic water module：Third capacitance (C3) is in parallel with the 9th resistance (R9)；
The output of the input terminal of 4th resistance (R4) of voltage feedback module and the first inductance (L1) of VRM Voltage Regulator Module
End is connected；The output end of 9th resistance (R9) of voltage feedback module is connected with place (GND)；9th electricity of voltage feedback module
The input terminal of resistance (R9) is connected with an IO foot of the microcontroller of control unit；
In photocatalytic water module：First electrode (DJ1) is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：Second electrode (DJ2) is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid
Body channel (S10)；
In the first electrode of photocatalytic water module：Conversion zone (S2) is located at the connection path of isolation layer (S1) and ventilative liquid-proof
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer and the through ventilative liquid-proof of conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or liquid is accelerated to become gas is anti-
It answers or chemically reacts；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Production
Object gas is appeared via channel in ventilative liquid-proof under buoyancy, to anti-when reducing bubble (S99) by reacting layer surface
It answers layer surface and liquid to contact the adverse effect generated, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble
The scale and quantity for merging explosion reduce bubble and merge impact of the explosion to electrode, increase the service life of electrolysis electrode；
Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid
Body channel (S10)；
In the second electrode of photocatalytic water module：Conversion zone (S2) is located at the connection path of isolation layer (S1) and ventilative liquid-proof
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer and the through ventilative liquid-proof of conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or liquid is accelerated to become gas is anti-
It answers or chemically reacts；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Every
Exhausted layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
In photocatalytic water module：The conversion zone (S2) of first electrode (DJ1) and the first inductance (L1) of VRM Voltage Regulator Module
Output end is in be electrically connected；
In photocatalytic water module：The place (GND) of the conversion zone (S2) of second electrode (DJ2) and the power supply of VRM Voltage Regulator Module
In being electrically connected；
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th electricity
It hinders (R17)；In solenoid valve driving module：9th triode (Q9) has input, output end, control terminal, the 9th triode (Q9
Input terminal be connected with the anode of the 4th diode (D4)；
In solenoid valve driving module：Coil interface (P5) has the first foot, crus secunda；First foot of coil interface (P5) with
The cathode of 4th diode (D4) is connected；The crus secunda of coil interface (P5) is connected with the anode of the 4th diode (D4)；
The control terminal of 9th triode (Q9) of solenoid valve driving module via solenoid valve driving module the 17th resistance
(R17) it is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module；
The cathode of the 9th triode (Q9) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module；
The output end of the 4th diode (D4) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module.
Further：In photocatalytic water module：The thickness of the conversion zone of first electrode (DJ1) is less than 1 micron.
Further：Solenoid valve driving module has LED lamp bead, the break-make situation for reflecting solenoid valve.
Further：In photocatalytic water module：The thickness of the conversion zone of second electrode (DJ2) is less than 1 micron.
Further：Solenoid valve driving module has PCB circuit board.
Further：In photocatalytic water module：The making material of the conversion zone of first electrode (DJ1) includes titanium dioxide.
Further：Solenoid valve driving module has the plastic shell of insulation.
Further：In photocatalytic water module：The making material of the conversion zone of second electrode (DJ2) is platinum.
Further：The interface of solenoid valve driving module has foolproof function.
Further：In photocatalytic water module：Control unit includes that LED display is used to that Voltage Feedback mould to be presented for operator
The data of block feedback.
Further：There is solenoid valve driving module sound-producing device, term to make a sound prompt message.
Photocatalytic water treatment device, it is characterised in that：With any one of aforementioned photocatalyst catalyzing manufacturing of hydrogen equipment.
Advantageous effect.
The present invention it is of low cost, using flexible, service life is long, esy to use, safe and reliable.
Description of the drawings
Fig. 1 is the electricity block schematic illustration of the photocatalytic water module of embodiment 1.
Fig. 2 is the circuit diagram of the photocatalytic water module of embodiment 1.
Fig. 3 is the structural schematic diagram of the electrode of the photocatalytic water module of embodiment 1.
Fig. 4 is the schematic diagram of the circuit of the solenoid valve driving module of embodiment 1.
Fig. 5 is the schematic diagram of 2 preparing hydrogen, generating power modules of embodiment.
Fig. 6 is the schematic diagram of the anti-mixing arrangement of 2 preparing hydrogen, generating power modules of embodiment, and wherein a is longitudinal sectional figure, and b is cross
The schematic diagram of cut section N1-N1.
Specific implementation mode
1. photocatalyst catalyzing manufacturing of hydrogen equipment of embodiment, it is characterised in that：
Including photocatalytic water module；
It further include solenoid valve driving module；
Photocatalytic water module includes control power supply VCC, power power-supply TCC, place GND, control unit, first electrode DJ1, the
Two electrode DJ2, VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；One end of 5th capacitance and microcontroller
Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；The electricity of one end and microcontroller of the 6th capacitance
Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller；The supply pin of one end and microcontroller of the 7th capacitance
It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place GND, the microcontroller of control unit
Supply pin is connected with control power supply VCC；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor Q1, the 6th triode Q6, the first diode D1, the
Two diode D2, first resistor R1, the 8th resistance R8, the first capacitance C1, the second capacitance C2, the 4th capacitance C4, the first inductance L1,
Power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor Q1 has input, output end, control terminal；First
The output end of metal-oxide-semiconductor Q1 is connected with the cathode of the first diode D1；The input terminal of first metal-oxide-semiconductor Q1 is through being connected to by first resistor
The control terminal of the first metal-oxide-semiconductors of R1 Q1；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode Q6 has input, output end, control terminal；6th
The input terminal of triode Q6 is connected to the control terminal of the first metal-oxide-semiconductor Q1 via the 5th resistance R5；The output end of 6th triode Q6
It is connected with the anode of the first diode D1；The input terminal of 6th triode Q6 is connected with power power-supply access point；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first capacitance C1 is connected with the output end of the first inductance L1,
The other end of first capacitance C1 is connected with the anode of the first diode D1；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance C2 is in parallel with the first capacitance C1；8th resistance R8 and
Four capacitance C4 are in parallel；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply TCC；
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit
Even；
The anode of first diode D1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with place GND；
The output end of first inductance L1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance R4, the 9th resistance R9, third capacitance C3；
In the voltage feedback module of photocatalytic water module：4th resistance R4 has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance R9 has input, output end；9th resistance R9's is defeated
Enter end with the input terminal of the 9th resistance R9 to be connected；
In the voltage feedback module of photocatalytic water module：Third capacitance C3 is in parallel with the 9th resistance R9；
The output end phase of the input terminal of 4th resistance R4 of voltage feedback module and the first inductance L1 of VRM Voltage Regulator Module
Even；The output end of 9th resistance R9 of voltage feedback module is connected with place GND；9th resistance R9's of voltage feedback module is defeated
Enter end with an IO foot of the microcontroller of control unit to be connected；
In photocatalytic water module：First electrode DJ1 is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：Second electrode DJ2 is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：First electrode DJ1 includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the first electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof connection path it
Between；Conversion zone S2 is between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 runs through isolation layer and reacts
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or the chemical reaction that conversion zone S2 can be participated in or liquid is accelerated to become gas；Isolation
Physical reactions or the chemical reaction that layer S1 is not involved in or liquid is accelerated to become gas；The highest of the arrival end S11 of fluid passage S10
The peak S129 of end S12s of the point S119 less than fluid passage S10；Product gas is having under buoyancy via channel
Gas liquid-proof appears, the adverse effect generated to reaction layer surface and liquid contact when reducing bubble S99 by reacting layer surface,
The efficiency that photodissociation liquid air-generating reaction can be increased decreases scale and quantity that bubble merges explosion, reduces bubble conjunction
And the impact to burst to electrode, increase the service life of electrolysis electrode；Isolation layer S1 is transparent；Conversion zone S2 be suitable for
The electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone
S2, ventilative liquid-proof S3 are in multilayer barrel-like structure, distribution sequence from inside to outside be successively ventilative liquid-proof S3, conversion zone S2,
Isolation layer S1；
The second electrode DJ2 of photocatalytic water module includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the second electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof connection path it
Between；Conversion zone S2 is between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 runs through isolation layer and reacts
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or the chemical reaction that conversion zone S2 can be participated in or liquid is accelerated to become gas；Isolation
Physical reactions or the chemical reaction that layer S1 is not involved in or liquid is accelerated to become gas；The highest of the arrival end S11 of fluid passage S10
The peak S129 of end S12s of the point S119 less than fluid passage S10；Isolation layer S1 is transparent；Conversion zone S2 be suitable for
The electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone
S2, ventilative liquid-proof S3 are in multilayer barrel-like structure, distribution sequence from inside to outside be successively ventilative liquid-proof S3, conversion zone S2,
Isolation layer S1；
In photocatalytic water module：The output end of the conversion zone S2 of first electrode DJ1 and the first inductance L1 of VRM Voltage Regulator Module
In being electrically connected；
In photocatalytic water module：The place GND of the conversion zone S2 of second electrode DJ2 and the power supply of VRM Voltage Regulator Module is in electricity
Connection；Solenoid valve driving module includes the 4th diode D4, coil interface P5, the 9th triode Q9, the 17th resistance R17；
In solenoid valve driving module：4th diode D4 has input, output end, control terminal, the 4th diode D4's
Input terminal is connected with the anode of the 4th diode D4；
In solenoid valve driving module：Coil interface P5 has the first foot, crus secunda；The first foot of coil interface P5 and the 4th
The cathode of diode D4 is connected；The crus secunda of coil interface P5 is connected with the anode of the 4th diode D4；
The control terminal of 4th diode D4 of solenoid valve driving module via solenoid valve driving module the 17th resistance R17
It is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module；
The cathode of 4th diode D4 of solenoid valve driving module is connected with the control power supply VCC of photocatalytic water module；
The output end of the 4th diode D4 of solenoid valve driving module is connected with the place GND of photocatalytic water module.
Embodiment 2, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of two electrode DJ2 is made using micropore glass.
Embodiment 3, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With pedestal for carrying solenoid valve driving module.
Embodiment 4, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of one electrode DJ1 is made using micropore ceramics.
Embodiment 5, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module has
There is fuse that can prevent critical piece from burning.
Embodiment 6, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The isolation layer S1 of two electrode DJ2 is made using glass.
Embodiment 7, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module with
The connecting elements being electrically connected between control unit is fine copper conducting wire.
Embodiment 8, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The isolation layer S1 of one electrode DJ1 is made using glass.
Embodiment 9, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With sound-producing device, term makes a sound prompt message.
Embodiment 10, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：Control
Unit processed includes the data that LED display is used to present voltage feedback module feedback for operator.
Embodiment 11, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
Interface have foolproof function.
Embodiment 12, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The making material of the conversion zone of two electrode DJ2 is platinum.
Embodiment 13, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
Plastic shell with insulation.
Embodiment 14, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The making material of the conversion zone of one electrode DJ1 includes titanium dioxide.
Embodiment 15, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With PCB circuit board.
Embodiment 16, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The thickness of the conversion zone of two electrode DJ2 is less than 1 micron.
Embodiment 17, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With LED lamp bead, the break-make situation for reacting solenoid valve.
Embodiment 18, on the basis of embodiment 1, increase preparing hydrogen, generating power module, preparing hydrogen, generating power module includes anti-mixed
It attaches together and sets LXQ, the first container L1, second container L2, filling opening, filling valve F3, first electrode DJ1, second electrode DJ2, first
Pipeline GD1, second pipe GD2, the first air pump B1, the second air pump B2, the first check valve DF1, the second check valve DF2, the first gas
Tank Q1, the second gas tank Q2, first entrance air valve F1, second entrance air valve F2, the first pressure maintaining valve W1, the second pressure maintaining valve W2, hydrogen combustion
Expect battery BAT1, third pipeline GD3, the 4th pipeline GD4, circulating valve F4, degasification container YLG；
The anti-mixing arrangement LXQ of preparing hydrogen, generating power module includes shell, spiral tube chamber LXG, the first tube chamber ZG1, the second tube chamber
ZG2；Spiral tube chamber LXG is helical form, and spiral tube chamber LXG has a first end and a second end；The axis direction of first tube chamber ZG1 with
The axis of screw direction of spiral tube chamber LXG is identical, and the first tube chamber ZG1 is located within the helix of spiral tube chamber LXG, the first tube chamber
At a distance from the face vertical with spiral tube chamber LXG axis where two endpoints of the length of ZG1 more than spiral tube chamber LXG；First
Tube chamber ZG1 has connecting pin and open end JK1；The connecting pin of first tube chamber ZG1 is communicated with the first end of spiral tube chamber LXG；The
One tube chamber ZG1 is through LXG sections of entire spiral tube chamber, and the open end JK1 of the first tube chamber ZG1 exceeds the second of spiral tube chamber LXG
End；The axis direction of second tube chamber ZG2 is identical as the axis of screw direction of spiral tube chamber LXG, and the second tube chamber ZG2 is located at helix tube
Within the helix of chamber LXG, where two endpoints of the length of the second tube chamber ZG2 more than spiral tube chamber LXG with spiral tube chamber
The distance in the vertical face of LXG axis；Second tube chamber ZG2 has connecting pin and open end JK2；The connecting pin of second tube chamber ZG2 with
The second end of spiral tube chamber LXG communicates；Second tube chamber ZG2 is through LXG sections of entire spiral tube chamber, and the opening of the second tube chamber ZG2
JK2 is held to exceed the first end of spiral tube chamber LXG.
In preparing hydrogen, generating power module：The first container L1 is transparent, the bottom of the first container L1 and the one of anti-mixing arrangement LXQ
End communicates, and the bottom of second container L2 is communicated with the other end of anti-mixing arrangement LXQ；That is the bottom of the first container L1,
The bottom of second container L2 is communicated by anti-mixing arrangement LXQ；
In preparing hydrogen, generating power module：The top of the first container L1 is by first pipe GD1 via the first air pump B1, first unidirectional
Valve DF1 is communicated with the first gas tank Q1, and for the first air pump B1 by the gas-powered in the first container L1 to the first gas tank Q1, first is single
Allowing the gas in the first container L1 to flow to the first gas tank Q1, the first check valve DF1 to valve DF1 does not allow the first gas tank Q1 streams
It moves in the first container L1；
In preparing hydrogen, generating power module：Second container L2 be it is transparent, the top of second container L2 by second pipe GD2 via
Second air pump B2, the second check valve DF2 are communicated with the second gas tank Q2, and the second air pump B2 arrives the gas-powered in second container L2
In second gas tank Q2, the second check valve DF2 allows the gas in second container L2 to flow to the second gas tank Q2, the second check valve
DF2 does not allow the second gas tank Q2 to flow in second container L2；
In preparing hydrogen, generating power module：First gas tank Q1 is connected with an inlet channel of hydrogen fuel cell BAT1, the first gas tank
There is the first pressure maintaining valve W1, the first pressure maintaining valve W1 to allow fluid from the first gas tank on the communication path of Q1 and hydrogen fuel cell BAT1
Q1, which flows to hydrogen fuel cell BAT1, the first pressure maintaining valve W1, does not allow fluid to flow to the first gas tank Q1 from hydrogen fuel cell BAT1, the
One pressure maintaining valve W1 can control the air pressure of the inlet channel for the hydrogen fuel cell BAT1 that the first gas tank Q1 is connected；
In preparing hydrogen, generating power module：Second gas tank Q2 is connected with an inlet channel of hydrogen fuel cell BAT1, the second gas tank
There is the second pressure maintaining valve W2, the second pressure maintaining valve W2 to allow fluid from the second gas tank on the communication path of Q2 and hydrogen fuel cell BAT1
Q2, which flows to hydrogen fuel cell BAT1, the second pressure maintaining valve W2, does not allow fluid to flow to the second gas tank Q2 from hydrogen fuel cell BAT1, the
Two pressure maintaining valve W2 can control the air pressure of the inlet channel for the hydrogen fuel cell BAT1 that the second gas tank Q2 is connected；
In preparing hydrogen, generating power module：The upper end of third pipeline GD3 is communicated with the discharge outlet of hydrogen fuel cell BAT1, third pipeline
The lower end of GD3 is communicated with the vessel of degasification container YLG；The upper end of 4th pipeline GD4 is communicated with the vessel of degasification container YLG, the
The lower end of four pipeline GD4 is communicated via circulating valve F4 with the first container L1 so that the product water of hydrogen fuel cell BAT1 can weigh
It is new to flow into the first container L1, the electrolysis vessel that second container L2 is constituted, it recycles；The lower ending opening of third pipeline GD3
The horizontal position of upper end opening of the horizontal position less than the 4th pipeline GD4 can prevent gas from entering the first container L1, the second appearance
In the electrolysis vessel that device L2 is constituted；
In preparing hydrogen, generating power module：Also there is supersonic generator C1, supersonic generator C1 to be located in degasification container YLG
Portion；Also there is exhaust outlet, degasification container YLG to be communicated with gas vent by the 5th pipeline GD5, the fluid path of the 5th pipeline GD5
In also have the 5th pump B5, air bleeding valve F5；When by controlling degasification container YLG degasification operation while supersonic generator C1
Open air bleeding valve F5 and the air pressure for opening the 5th pump B5 reduction degasification containers YLG, so that the product water of hydrogen fuel cell BAT1
The gas of middle dissolving is deviate from, and the design that the air pressure of degasification container YLG is reduced while supersonic generator C1 deaerates to deaerate
Hardware cost is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell BAT1 has power supply output point VCC1, power supply place GND1；
The first electrode DJ1 of photocatalytic water module is installed in the vessel of the first container L1 of preparing hydrogen, generating power module, photocatalytic water
The first container L1 and preparing hydrogen, generating power module of the lowermost horizontal position of the first electrode DJ1 of module higher than preparing hydrogen, generating power module
Anti- mixing arrangement LXQ communicate the horizontal position of interface；
The second electrode DJ2 of photocatalytic water module is installed in the vessel of second container L2, the second electrode of photocatalytic water module
Anti- mixing arrangement of the lowermost horizontal position of DJ2 higher than the second container L2 and preparing hydrogen, generating power module of preparing hydrogen, generating power module
LXQ communicates the horizontal position of interface；When the second container L2 electrolysis of the first container L1, preparing hydrogen, generating power module of preparing hydrogen, generating power module
When draught head it is too big when can due to liquid be detached from electrode and terminate cell reaction.
It is embodiment 19, further on the basis of embodiment 18：The material of the first container L1 of preparing hydrogen, generating power module
Matter is glass.
It is embodiment 20, further on the basis of embodiment 18：The material of the second container L2 of preparing hydrogen, generating power module
Matter is glass.
The above embodiment is not to the legal scope of the present invention, and protection scope of the present invention is please according to claim
Book content is judged.
Claims (10)
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
It further include solenoid valve driving module；
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode
(DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；5th one end of capacitance and connecing for microcontroller
Lower margin is connected, and the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；The supply pin of one end and microcontroller of the 6th capacitance
It is connected, the other end of the 6th capacitance is connected with the grounding leg of microcontroller；One end of 7th capacitance is connected with the supply pin of microcontroller,
The other end of 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place (GND), the electricity of the microcontroller of control unit
Source foot is connected with control power supply (VCC)；
The VRM Voltage Regulator Module of photocatalytic water module include the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode (D1),
Second diode (D2), first resistor (R1), the 8th resistance (R8), the first capacitance (C1), the second capacitance (C2), the 4th capacitance
(C4), the first inductance (L1), power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor (Q1) has input, output end, control terminal；First MOS
The output end of pipe (Q1) is connected with the cathode of the first diode (D1)；The input terminal of first metal-oxide-semiconductor (Q1) is via first resistor
(R1) it is connected to the control terminal of the first metal-oxide-semiconductor (Q1)；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode (Q6) has input, output end, control terminal；Six or three
The input terminal of pole pipe (Q6) is connected to the control terminal of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5)；6th triode (Q6)
Output end is connected with the anode of the first diode (D1)；The input terminal of 6th triode (Q6) is connected with power power-supply access point；
The control terminal of 6th triode (Q6) is connected to pwm signal access point via the 8th resistance (R8)；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first capacitance (C1) is connected with the output end of the first inductance (L1),
The other end of first capacitance (C1) is connected with the anode of the first diode (D1)；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance (C2) is in parallel with the first capacitance (C1)；8th resistance (R8) with
4th capacitance (C4) is in parallel；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC)；
The pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with an IO foot of microcontroller in control unit；
The anode of the first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND)；
The output end of the first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), third capacitance (C3)；
In the voltage feedback module of photocatalytic water module：4th resistance (R4) has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance (R9) has input, output end；9th resistance (R9) it is defeated
Enter end with the input terminal of the 4th resistance (R4) to be connected；
In the voltage feedback module of photocatalytic water module：Third capacitance (C3) is in parallel with the 9th resistance (R9)；
The output end phase of the input terminal and the first inductance (L1) of VRM Voltage Regulator Module of 4th resistance (R4) of voltage feedback module
Even；The output end of 9th resistance (R9) of voltage feedback module is connected with place (GND)；9th resistance of voltage feedback module
(R9) input terminal is connected with an IO foot of the microcontroller of control unit；
In photocatalytic water module：First electrode (DJ1) is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：Second electrode (DJ2) is the electrode suitable for photolysis water hydrogen；
In photocatalytic water module：First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), breathe freely liquid-proof (S3), liquid are logical
Road (S10)；
In the first electrode of photocatalytic water module：Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof connection path it
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) runs through isolation layer
With the through ventilative liquid-proof of conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or liquid is accelerated to become gas is anti-
It answers or chemically reacts；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Production
Object gas is appeared via channel in ventilative liquid-proof under buoyancy, to anti-when reducing bubble (S99) by reacting layer surface
It answers layer surface and liquid to contact the adverse effect generated, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble
The scale and quantity for merging explosion reduce bubble and merge impact of the explosion to electrode, increase the service life of electrolysis electrode；
Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), breathe freely liquid-proof (S3), liquid are logical
Road (S10)；
In the second electrode of photocatalytic water module：Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof connection path it
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) runs through isolation layer
With the through ventilative liquid-proof of conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or liquid is accelerated to become gas is anti-
It answers or chemically reacts；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Every
Exhausted layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
In photocatalytic water module：The output of the conversion zone (S2) of first electrode (DJ1) and the first inductance (L1) of VRM Voltage Regulator Module
End is in be electrically connected；
In photocatalytic water module：The place (GND) of the conversion zone (S2) of second electrode (DJ2) and the power supply of VRM Voltage Regulator Module is in electricity
Learn connection；
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th resistance
(R17)；
In solenoid valve driving module：9th triode (Q9) has input, output end, control terminal, and (Q9's is defeated for the 9th triode
Enter end with the anode of the 4th diode (D4) to be connected；
In solenoid valve driving module：Coil interface (P5) has the first foot, crus secunda；The first foot and the 4th of coil interface (P5)
The cathode of diode (D4) is connected；The crus secunda of coil interface (P5) is connected with the anode of the 4th diode (D4)；
The control terminal of 9th triode (Q9) of solenoid valve driving module via solenoid valve driving module the 17th resistance (R17)
It is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module；
The cathode of the 4th diode (D4) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module；
The output end of the 9th triode (Q9) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module.
2. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：First electrode
(DJ1) thickness of conversion zone is less than 1 micron.
3. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：Solenoid valve driving module has LED light
Pearl, the break-make situation for reflecting solenoid valve.
4. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
(DJ2) thickness of conversion zone is less than 1 micron.
5. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：Solenoid valve driving module has PCB electricity
Road plate.
6. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：First electrode
(DJ1) making material of conversion zone includes titanium dioxide.
7. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：Solenoid valve driving module has insulation
Plastic shell.
8. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
(DJ2) making material of conversion zone is platinum.
9. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：The interface of solenoid valve driving module has
Foolproof function.
10. photocatalytic water treatment device, it is characterised in that：With photocatalyst catalyzing manufacturing of hydrogen equipment described in claim 1.
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| JP3655349B2 (en) * | 1995-04-28 | 2005-06-02 | 株式会社日立製作所 | Carbon dioxide converter |
| KR20010079672A (en) * | 1998-08-21 | 2001-08-22 | 추후제출 | Visible radiation type photocatalyst and production method thereof |
| CN100487164C (en) * | 2005-09-28 | 2009-05-13 | 中国船舶重工集团公司第七一八研究所 | Uses of magnetic valve in hydrogen production plant |
| KR100806168B1 (en) * | 2007-02-12 | 2008-02-21 | 재단법인서울대학교산학협력재단 | Preparation method of hydrogen energy by photocatalytic water splitting using electric field of solar cells |
| CN102713010B (en) * | 2010-01-22 | 2015-10-07 | 松下知识产权经营株式会社 | Hydrogen generation apparatus |
| JP5628928B2 (en) * | 2010-09-07 | 2014-11-19 | パナソニック株式会社 | Hydrogen generation device |
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