CN106676566B - Photocatalyst catalytic hydrogen production equipment and photocatalyst catalyst environmental protection system - Google Patents
Photocatalyst catalytic hydrogen production equipment and photocatalyst catalyst environmental protection system Download PDFInfo
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- CN106676566B CN106676566B CN201611235042.9A CN201611235042A CN106676566B CN 106676566 B CN106676566 B CN 106676566B CN 201611235042 A CN201611235042 A CN 201611235042A CN 106676566 B CN106676566 B CN 106676566B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
- C25B11/031—Porous electrodes
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Catalysts (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The photocatalyst catalytic hydrogen production equipment comprises a photolysis module; an indication module is also included. The photocatalyst catalyst environmental protection system has the technical scheme. The invention has the advantages of low cost, flexible application, long service life, convenient use, safety and reliability.
Description
Technical field
The invention belongs to electricity field technical field, more particularly to photocatalyst catalyzing manufacturing of hydrogen equipment, photocatalyst catalyst ring
Insurance system.
Technical background
Photolysis water hydrogen system there are the problems such as efficiency is low, of high cost, electrode life is short, cause its be difficult to it is practical should
With.
Invention content
In order to solve the above technical problems, the present invention proposes photocatalyst catalyzing manufacturing of hydrogen equipment, the environmental protection of photocatalyst catalyst
System, specific solution have following technical solution.
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
Further include indicating module；
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode
(DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；One end of 5th capacitance and microcontroller
Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；One end of 6th capacitance and the electricity of microcontroller
Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller；One end of 7th capacitance and the supply pin of microcontroller
It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place (GND), the microcontroller of control unit
Supply pin with control power supply (VCC) be connected；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode
(D1), first resistor (R1), the 8th resistance (R8), the first capacitance (C1), the second capacitance (C2), the 4th capacitance (C4), the first electricity
Feel (L1), power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor (Q1) has input, output end, control terminal；First
The output terminal of MOS pipes (Q1) is connected with the cathode of the first diode (D1)；The input terminal of first metal-oxide-semiconductor (Q1) is via the first electricity
Resistance (R1) is connected to the control terminal of the first metal-oxide-semiconductor (Q1)；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode (Q6) has input, output end, control terminal；The
The input terminal of six triodes (Q6) is connected to the control terminal of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5)；6th triode
(Q6) output terminal is connected with the anode of the first diode (D1)；The input terminal of 6th triode (Q6) and power power-supply access point
It is connected；The control terminal of 6th triode (Q6) is connected to pwm signal access point via the 8th resistance (R8)；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first capacitance (C1) and the output terminal phase of the first inductance (L1)
Even, the other end of the first capacitance (C1) is connected with the anode of the first diode (D1)；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance (C2) is in parallel with the first capacitance (C1)；8th resistance
(R8) it is in parallel with the 4th capacitance (C4)；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC)；
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit
Even；
The anode of the first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND)；
The output terminal of the first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), third capacitance (C3)；
In the voltage feedback module of photocatalytic water module：4th resistance (R4) has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance (R9) has input, output end；9th resistance (R9)
Input terminal be connected with the output terminal of the 4th resistance (R4)；
In the voltage feedback module of photocatalytic water module：Third capacitance (C3) is in parallel with the 9th resistance (R9)；
The output of the input terminal of 4th resistance (R4) of voltage feedback module and the first inductance (L1) of VRM Voltage Regulator Module
End is connected；The output terminal of 9th resistance (R9) of voltage feedback module is connected with place (GND)；9th electricity of voltage feedback module
The input terminal of resistance (R9) is connected with an IO foot of the microcontroller of control unit；
In photocatalytic water module：First electrode (DJ1) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode (DJ2) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid
Body channel (S10)；
In the first electrode of photocatalytic water module：Conversion zone (S2) is positioned at isolation layer (S1) and the connection path of ventilative liquid-proof
Between；Conversion zone (S2) is between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer goes directly ventilative liquid-proof with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or accelerate liquid to become gas is anti-
It should or chemically react；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of end (S12) of the peak (S119) of arrival end (S11) less than fluid passage (S10)；
Product gas is appeared by ventilative liquid-proof again under buoyancy via fluid passage, reduces bubble (S99) by conversion zone table
The adverse effect generated during face to reaction layer surface and liquid contact, can increase the efficiency of photodissociation liquid air-generating reaction, also subtract
Scale and quantity that bubble merges explosion are lacked, have reduced bubble and merge impact of the explosion to electrode, increase electrolysis electrode
Service life；Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer
(S1), conversion zone (S2), ventilative liquid-proof (S3) are cylindrical shape, isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3)
In multilayer barrel-like structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), fluid passage
(S10)；
In the second electrode of photocatalytic water module：Conversion zone (S2) is positioned at isolation layer (S1) and the connection path of ventilative liquid-proof
Between；Conversion zone (S2) is between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer goes directly ventilative liquid-proof with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；The physics that conversion zone (S2) can participate in or accelerate liquid to become gas is anti-
It should or chemically react；Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or liquid is accelerated to become gas；Fluid passage
(S10) peak (S129) of end (S12) of the peak (S119) of arrival end (S11) less than fluid passage (S10)；
Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively；
In photocatalytic water module：The conversion zone (S2) of first electrode (DJ1) and the first inductance (L1) of VRM Voltage Regulator Module
Output terminal is in be electrically connected；
In photocatalytic water module：The conversion zone (S2) of second electrode (DJ2) and the place (GND) of the power supply of VRM Voltage Regulator Module
In being electrically connected；
Indicating module includes the 2nd No. ten resistance (R20), the second ride on Bus No. 11 resistance (R21), No. four light emitting diode
(D4), No. five light emitting diode (D5)；
The cathode of No. four light emitting diode (D4) of indicating module is connected with the place (GND) of photocatalytic water module；
The cathode of No. five light emitting diode (D5) of indicating module is connected with the place (GND) of photocatalytic water module；
The anode of No. four light emitting diode (D4) of indicating module is connected to photocatalytic water via the 2nd No. ten resistance (R20)
One IO foot of the microcontroller of the control unit of module；
The anode of No. five light emitting diode (D5) of indicating module is connected to photodissociation via the second ride on Bus No. 11 resistance (R21)
One IO foot of the microcontroller of the control unit of water module.
Further：In photocatalytic water module：The thickness of the conversion zone of first electrode (DJ1) is less than 1 micron.
Further：The nominal value of 2nd No. ten resistance (R20) of indicating module is 4.70 kilohms.
Further：In photocatalytic water module：The thickness of the conversion zone of second electrode (DJ2) is less than 1 micron.
Photocatalyst catalyst environment friendly system, it is characterised in that：With any one in preceding solution.
Advantageous effect.
The present invention it is of low cost, using it is flexible, service life is long, esy to use, safe and reliable.
Description of the drawings
Fig. 1 is the electricity block schematic illustration of the photocatalytic water module of embodiment 1.
Fig. 2 is the circuit diagram of the photocatalytic water module of embodiment 1.
Fig. 3 is the structure diagram of the electrode of the photocatalytic water module of embodiment 1.
Fig. 4 is the schematic diagram of the circuit of the indicating module of embodiment 1.
Fig. 5 is the schematic diagram of 2 preparing hydrogen, generating power modules of embodiment.
Fig. 6 is the schematic diagram of the anti-mixing arrangement of 2 preparing hydrogen, generating power modules of embodiment, and wherein a is rip cutting figure, and b is horizontal stroke
The schematic diagram of cut section N1-N1.
Specific embodiment
1. photocatalyst catalyzing manufacturing of hydrogen equipment of embodiment, it is characterised in that：
Including photocatalytic water module；
Further include indicating module；
Photocatalytic water module includes control power supply VCC, power power-supply TCC, place GND, control unit, first electrode DJ1, the
Two electrode DJ2, VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；One end of 5th capacitance and microcontroller
Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；One end of 6th capacitance and the electricity of microcontroller
Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller；One end of 7th capacitance and the supply pin of microcontroller
It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place GND, the microcontroller of control unit
Supply pin is connected with control power supply VCC；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor Q1, the 6th triode Q6, the first diode D1, the
One resistance R1, the 8th resistance R8, the first capacitance C1, the second capacitance C2, the 4th capacitance C4, the first inductance L1, power power-supply access
Point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor Q1 has input, output end, control terminal；First
The output terminal of metal-oxide-semiconductor Q1 is connected with the cathode of the first diode D1；The input terminal of first metal-oxide-semiconductor Q1 is through being connected to by first resistor
The control terminal of the first metal-oxide-semiconductors of R1 Q1；The input terminal of first metal-oxide-semiconductor Q1 is connected to the control of the first metal-oxide-semiconductor Q1 via first resistor R1
End processed；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode Q6 has input, output end, control terminal；6th
The input terminal of triode Q6 is connected to the control terminal of the first metal-oxide-semiconductor Q1 via the 5th resistance R5；The output terminal of 6th triode Q6
It is connected with the anode of the first diode D1；The input terminal of 6th triode Q6 is connected with power power-supply access point；6th triode
The control terminal of Q6 is connected to pwm signal access point via the 8th resistance R8；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first capacitance C1 is connected with the output terminal of the first inductance L1,
The other end of first capacitance C1 is connected with the anode of the first diode D1；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance C2 is in parallel with the first capacitance C1；8th resistance R8 and
Four capacitance C4 are in parallel；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply TCC；
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit
Even；
The anode of first diode D1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with place GND；
The output terminal of first inductance L1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance R4, the 9th resistance R9, third capacitance C3；
In the voltage feedback module of photocatalytic water module：4th resistance R4 has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance R9 has input, output end；9th resistance R9's is defeated
Enter end with the output terminal of the 4th resistance R4 to be connected；
In the voltage feedback module of photocatalytic water module：Third capacitance C3 is in parallel with the 9th resistance R9；
The output terminal phase of the input terminal of 4th resistance R4 of voltage feedback module and the first inductance L1 of VRM Voltage Regulator Module
Even；The output terminal of 9th resistance R9 of voltage feedback module is connected with place GND；9th resistance R9's of voltage feedback module is defeated
Enter end with an IO foot of the microcontroller of control unit to be connected；
In photocatalytic water module：First electrode DJ1 applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode DJ2 applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode DJ1 includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the first electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof connection path it
Between；Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 is through isolation layer with reacting
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or the chemical reaction that conversion zone S2 can be participated in or liquid is accelerated to become gas；Isolation
Physical reactions or the chemical reaction that layer S1 is not involved in or liquid is accelerated to become gas；The arrival end S11 of fluid passage S10 is most
The peak S129 of end S12s of the high point S119 less than fluid passage S10；Product gas under buoyancy via channel again
It is appeared by ventilative liquid-proof, it is unfavorable by being generated during reaction layer surface to reaction layer surface and liquid contact to reduce bubble S99
It influences, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease scale and quantity that bubble merges explosion, reduce gas
Bubble merges impact of the explosion to electrode, increases the service life of electrolysis electrode；Isolation layer S1 is transparent；Conversion zone S2 is suitable
For the electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, anti-
Answering layer S2, ventilative liquid-proof S3, distribution sequence from inside to outside is ventilative liquid-proof S3, conversion zone successively in multilayer barrel-like structure
S2, isolation layer S1；
The second electrode DJ2 of photocatalytic water module includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the second electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof connection path it
Between；Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 is through isolation layer with reacting
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or the chemical reaction that conversion zone S2 can be participated in or liquid is accelerated to become gas；Isolation
Physical reactions or the chemical reaction that layer S1 is not involved in or liquid is accelerated to become gas；The arrival end S11 of fluid passage S10 is most
The peak S129 of end S12s of the high point S119 less than fluid passage S10；Isolation layer S1 is transparent；Conversion zone S2 is applicable
In the electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, are reacted
In multilayer barrel-like structure, distribution sequence from inside to outside is ventilative liquid-proof S3, conversion zone successively by layer S2, ventilative liquid-proof S3
S2, isolation layer S1；
In photocatalytic water module：The output terminal of the conversion zone S2 of first electrode DJ1 and the first inductance L1 of VRM Voltage Regulator Module
In being electrically connected；
In photocatalytic water module：The place GND of the conversion zone S2 of second electrode DJ2 and the power supply of VRM Voltage Regulator Module is in electricity
Connection；Indicating module include the 2nd No. ten resistance R20, the second ride on Bus No. 11 resistance R21, No. four light emitting diode D4, No. five
Light emitting diode D5；
The cathode of No. four light emitting diode D4 of indicating module is connected with the place GND of photocatalytic water module；
The cathode of No. five light emitting diode D5 of indicating module is connected with the place GND of photocatalytic water module；
The anode of No. four light emitting diode D4 of indicating module is connected to photocatalytic water module via the 2nd No. ten resistance R20
Control unit microcontroller an IO foot；
The anode of No. five light emitting diode D5 of indicating module is connected to photocatalytic water mould via the second ride on Bus No. 11 resistance R21
One IO foot of the microcontroller of the control unit of block.
Embodiment 2, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of two electrode DJ2 is made using micropore glass.
Embodiment 3, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：No. five of indicating module
The color of the light of light emitting diode D5 is white.
Embodiment 4, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of one electrode DJ1 is made using micropore ceramics.
Embodiment 5, on the basis of embodiment 1, increase preparing hydrogen, generating power module, preparing hydrogen, generating power module include anti-mixing
Device LXQ, the first container L1, second container L2, filling opening, filling valve F3, first electrode DJ1, second electrode DJ2, the first pipe
Road GD1, second pipe GD2, the first air pump B1, the second air pump B2, the first check valve DF1, the second check valve DF2, the first gas tank
Q1, the second gas tank Q2, first entrance air valve F1, second entrance air valve F2, the first pressure maintaining valve W1, the second pressure maintaining valve W2, hydrogen fuel
Battery BAT1, third pipeline GD3, the 4th pipeline GD4, circulating valve F4, degasification container YLG；
The anti-mixing arrangement LXQ of preparing hydrogen, generating power module includes housing, spiral tube chamber LXG, the first tube chamber ZG1, the second tube chamber
ZG2；Spiral tube chamber LXG is helical form, and spiral tube chamber LXG has a first end and a second end；The axis direction of first tube chamber ZG1 with
The axis of screw direction of spiral tube chamber LXG is identical, and the first tube chamber ZG1 is located within the helix of spiral tube chamber LXG, the first tube chamber
The distance in the face vertical with spiral tube chamber LXG axis where two endpoints of the length of ZG1 more than spiral tube chamber LXG；First
Tube chamber ZG1 has connecting pin and openend JK1；The connecting pin of first tube chamber ZG1 is communicated with the first end of spiral tube chamber LXG；The
One tube chamber ZG1 is through entire LXG sections of spiral tube chamber, and the openend JK1 of the first tube chamber ZG1 exceeds the second of spiral tube chamber LXG
End；The axis direction of second tube chamber ZG2 is identical with the axis of screw direction of spiral tube chamber LXG, and the second tube chamber ZG2 is located at helix tube
Within the helix of chamber LXG, where two endpoints of the length of the second tube chamber ZG2 more than spiral tube chamber LXG with spiral tube chamber
The distance in the vertical face of LXG axis；Second tube chamber ZG2 has connecting pin and openend JK1；The connecting pin of second tube chamber ZG2 with
The second end of spiral tube chamber LXG communicates；Second tube chamber ZG2 is through entire LXG sections of spiral tube chamber, and the opening of the second tube chamber ZG2
The first end that JK1 is held to exceed spiral tube chamber LXG.
In preparing hydrogen, generating power module：The first container L1 is transparent, the bottom of the first container L1 and the one of anti-mixing arrangement LXQ
End communicates, and the bottom of second container L2 is communicated with the other end of anti-mixing arrangement LXQ；That is the bottom of the first container L1
Portion, second container L2 bottom communicated by anti-mixing arrangement LXQ；
In preparing hydrogen, generating power module：The top of the first container L1 is by first pipe GD1 via the first air pump B1, first unidirectional
Valve DF1 is communicated with the first gas tank Q1, and the first air pump B1 is by the gas-powered in the first container L1 to the first gas tank Q1, and first
Check valve DF1, which allows the gas in the first container L1 to flow to the first gas tank Q1, the first check valve DF1, does not allow the first gas tank
Q1 is flow in the first container L1；
In preparing hydrogen, generating power module：Second container L2 be it is transparent, the top of second container L2 by second pipe GD2 via
Second air pump B2, the second check valve DF2 are communicated with the second gas tank Q2, and the second air pump B2 arrives the gas-powered in second container L2
In second gas tank Q2, the second check valve DF2 allows the gas in second container L2 to flow to the second gas tank Q2, the second check valve
DF2 does not allow the second gas tank Q2 to flow in second container L2；
In preparing hydrogen, generating power module：First gas tank Q1 is connected with an inlet channel of hydrogen fuel cell BAT1, the first gas tank
There is the first pressure maintaining valve W1, the first pressure maintaining valve W1 to allow fluid from the first gas on the communication path of Q1 and hydrogen fuel cell BAT1
Tank Q1, which flows to hydrogen fuel cell BAT1, the first pressure maintaining valve W1, does not allow fluid to flow to the first gas tank Q1 from hydrogen fuel cell BAT1,
First pressure maintaining valve W1 can control the air pressure of hydrogen fuel cell BAT1 inlet channel that the first gas tank Q1 is connected；
In preparing hydrogen, generating power module：Second gas tank Q2 is connected with an inlet channel of hydrogen fuel cell BAT1, the second gas tank
There is the second pressure maintaining valve W2, the second pressure maintaining valve W2 to allow fluid from the second gas on the communication path of Q2 and hydrogen fuel cell BAT1
Tank Q2, which flows to hydrogen fuel cell BAT1, the second pressure maintaining valve W2, does not allow fluid to flow to the second gas tank Q2 from hydrogen fuel cell BAT1,
Second pressure maintaining valve W2 can control the air pressure of hydrogen fuel cell BAT1 inlet channel that the second gas tank Q2 is connected；
In preparing hydrogen, generating power module：The upper end of third pipeline GD3 is communicated with the discharge outlet of hydrogen fuel cell BAT1, third pipeline
The lower end of GD3 is communicated with the cavity volume of degasification container YLG；The upper end of 4th pipeline GD4 is communicated with the cavity volume of degasification container YLG, the
The lower end of four pipeline GD4 is communicated via circulating valve F4 with the first container L1 so that the product water of hydrogen fuel cell BAT1 can weigh
In the new electrolysis cavity volume for flowing into the first container L1, second container L2 and forming, recycle；The lower ending opening of third pipeline GD3
The horizontal position of upper end opening of the horizontal position less than the 4th pipeline GD4 can prevent gas from entering the first container L1, the second appearance
In the electrolysis cavity volume that device L2 is formed；
In preparing hydrogen, generating power module：Also there is supersonic generator C1, supersonic generator C1 to be located in degasification container YLG
Portion；Also there is exhaust outlet, degasification container YLG is communicated by the 5th pipeline GD5 with gas vent, the fluid path of the 5th pipeline GD5
In also have the 5th pump B5, air bleeding valve F5；When being operated by controlling degasification container YLG degasification while supersonic generator C1
Open air bleeding valve F5 and the air pressure for opening the 5th pump B5 reduction degasification containers YLG, so that the product water of hydrogen fuel cell BAT1
The gas abjection of middle dissolving, the design that the air pressure of degasification container YLG is reduced while supersonic generator C1 deaerates to deaerate
Hardware cost is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell BAT1 has power supply output point VCC1, power supply place GND1；
The first electrode DJ1 of photocatalytic water module is installed in the cavity volume of the first container L1 of preparing hydrogen, generating power module, photocatalytic water
The lowermost horizontal position of the first electrode DJ1 of module is higher than the first container L1 of preparing hydrogen, generating power module and preparing hydrogen, generating power module
Anti- mixing arrangement LXQ communicate the horizontal position of interface；
The second electrode DJ2 of photocatalytic water module is installed in the cavity volume of second container L2, the second electrode of photocatalytic water module
The lowermost horizontal position of DJ2 is higher than the second container L2 of preparing hydrogen, generating power module and the anti-mixing arrangement of preparing hydrogen, generating power module
LXQ communicates the horizontal position of interface；The second container L2 electrolysis of the first container L1, preparing hydrogen, generating power module when preparing hydrogen, generating power module
When draught head it is too big when can due to liquid be detached from electrode and terminate cell reaction.
It is embodiment 6, further on the basis of embodiment 5：The material of the first container L1 of preparing hydrogen, generating power module
It is glass.It is embodiment 7, further on the basis of embodiment 5：The material of the second container L2 of preparing hydrogen, generating power module is
Glass.
More than embodiment is not the legal scope to the present invention, and protection scope of the present invention is please according to claim
Book content is judged.
Claims (10)
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
Further include indicating module；
Photocatalytic water module includes control power supply（VCC）, power power-supply（TCC）, place（GND）, control unit, first electrode
（DJ1）, second electrode（DJ2）, VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance；
In the control unit of photocatalytic water module：The model STM8S103 of microcontroller；5th one end of capacitance and connecing for microcontroller
Lower margin is connected, and the other end of the 5th capacitance is connected with the VCAP feet of microcontroller；One end of 6th capacitance and the supply pin of microcontroller
It is connected, the other end of the 6th capacitance is connected with the grounding leg of microcontroller；One end of 7th capacitance is connected with the supply pin of microcontroller,
The other end of 7th capacitance is connected with the grounding leg of microcontroller；
The grounding leg of the microcontroller of the control unit of photocatalytic water module and place（GND）It is connected, the electricity of the microcontroller of control unit
Source foot and control power supply（VCC）It is connected；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor（Q1）, the 6th triode（Q6）, the first diode（D1）、
First resistor（R1）, the 8th resistance（R8）, the first capacitance（C1）, the second capacitance（C2）, the 4th capacitance（C4）, the first inductance
（L1）, power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor（Q1）With input, output end, control terminal；First MOS
Pipe（Q1）Output terminal and the first diode（D1）Cathode be connected；First metal-oxide-semiconductor（Q1）Input terminal via first resistor
（R1）It is connected to the first metal-oxide-semiconductor（Q1）Control terminal；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode（Q6）With input, output end, control terminal；Six or three
Pole pipe（Q6）Input terminal via the 5th resistance（R5）It is connected to the first metal-oxide-semiconductor（Q1）Control terminal；6th triode（Q6）'s
Output terminal and the first diode（D1）Anode be connected；6th triode（Q6）Input terminal be connected with power power-supply access point；
6th triode（Q6）Control terminal via the 8th resistance（R8）It is connected to pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First capacitance（C1）One end and the first inductance（L1）Output terminal be connected,
First capacitance（C1）The other end and the first diode（D1）Anode be connected；
In the VRM Voltage Regulator Module of photocatalytic water module：Second capacitance（C2）With the first capacitance（C1）It is in parallel；8th resistance（R8）With
4th capacitance（C4）It is in parallel；
The power power-supply access point and power power-supply of the VRM Voltage Regulator Module of photocatalytic water module（TCC）It is connected；
The pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with an IO foot of microcontroller in control unit；
First diode of the VRM Voltage Regulator Module of photocatalytic water module（D1）Anode and place（GND）It is connected；
First inductance of the VRM Voltage Regulator Module of photocatalytic water module（L1）Output terminal be connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance（R4）, the 9th resistance（R9）, third capacitance（C3）；
In the voltage feedback module of photocatalytic water module：4th resistance（R4）With input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance（R9）With input, output end；9th resistance（R9）It is defeated
Enter end and the 4th resistance（R4）Output terminal be connected；
In the voltage feedback module of photocatalytic water module：Third capacitance（C3）With the 9th resistance（R9）It is in parallel；
4th resistance of voltage feedback module（R4）Input terminal and VRM Voltage Regulator Module the first inductance（L1）Output terminal phase
Even；9th resistance of voltage feedback module（R9）Output terminal and place（GND）It is connected；9th resistance of voltage feedback module
（R9）Input terminal be connected with an IO foot of the microcontroller of control unit；
In photocatalytic water module：First electrode（DJ1）Apply to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode（DJ2）Apply to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode（DJ1）Including isolation layer（S1）, conversion zone（S2）, ventilative liquid-proof（S3）, liquid leads to
Road（S10）；In the first electrode of photocatalytic water module：Conversion zone（S2）Positioned at isolation layer（S1）With the link road of ventilative liquid-proof
Between diameter；Conversion zone（S2）Positioned at isolation layer（S1）Between the space path of ventilative liquid-proof；Fluid passage（S10）Through every
Exhausted layer and conversion zone are gone directly ventilative liquid-proof；Fluid passage（S10）End by ventilative liquid-proof（S3）It is closed, fluid passage
（S10）Arrival end be opened on the outside of isolation layer；Conversion zone（S2）It can participate in or accelerate the physics that liquid becomes gas anti-
It should or chemically react；Isolation layer（S1）Physical reactions or the chemical reaction for being not involved in or liquid being accelerated to become gas；Fluid passage
（S10）Arrival end（S11）Peak（S119）Less than fluid passage（S10）End（S12）Peak（S129）；Production
Object gas is appeared by ventilative liquid-proof again under buoyancy via fluid passage, reduces bubble（S99）By reacting layer surface
When to reaction layer surface and liquid contact generate adverse effect, the efficiency of photodissociation liquid air-generating reaction can be increased, also reduced
Bubble merges the scale and quantity of explosion, reduces bubble and merges impact of the explosion to electrode, increases making for electrolysis electrode
Use the service life；Isolation layer（S1）It is transparent；Conversion zone（S2）To be suitable for the electrode material of photolysis water hydrogen；Isolation layer（S1）、
Conversion zone（S2）, ventilative liquid-proof（S3）It is cylindrical shape, isolation layer（S1）, conversion zone（S2）, ventilative liquid-proof（S3）In more
Layer barrel-like structure, distribution sequence from inside to outside is ventilative liquid-proof successively（S3）, conversion zone（S2）, isolation layer（S1）；
The second electrode of photocatalytic water module（DJ2）Including isolation layer（S1）, conversion zone（S2）, ventilative liquid-proof（S3）, liquid leads to
Road（S10）；
In the second electrode of photocatalytic water module：Conversion zone（S2）Positioned at isolation layer（S1）With the connection path of ventilative liquid-proof it
Between；Conversion zone（S2）Positioned at isolation layer（S1）Between the space path of ventilative liquid-proof；Fluid passage（S10）Through isolation layer
It goes directly ventilative liquid-proof with conversion zone；Fluid passage（S10）End by ventilative liquid-proof（S3）It is closed, fluid passage
（S10）Arrival end be opened on the outside of isolation layer；Conversion zone（S2）It can participate in or accelerate the physics that liquid becomes gas anti-
It should or chemically react；Isolation layer（S1）Physical reactions or the chemical reaction for being not involved in or liquid being accelerated to become gas；Fluid passage
（S10）Arrival end（S11）Peak（S119）Less than fluid passage（S10）End（S12）Peak（S129）；Every
Exhausted layer（S1）It is transparent；Conversion zone（S2）To be suitable for the electrode material of photolysis water hydrogen；Isolation layer（S1）, conversion zone
（S2）, ventilative liquid-proof（S3）It is cylindrical shape, isolation layer（S1）, conversion zone（S2）, ventilative liquid-proof（S3）In multilayer tubbiness
Structure, distribution sequence from inside to outside is ventilative liquid-proof successively（S3）, conversion zone（S2）, isolation layer（S1）；
In photocatalytic water module：First electrode（DJ1）Conversion zone（S2）With the first inductance of VRM Voltage Regulator Module（L1）Output
End is in be electrically connected；
In photocatalytic water module：Second electrode（DJ2）Conversion zone（S2）With the place of the power supply of VRM Voltage Regulator Module（GND）In electricity
Learn connection；
Indicating module includes the 2nd No. ten resistance（R20）, the second ride on Bus No. 11 resistance（R21）, No. four light emitting diode（D4）,
No. five light emitting diodes（D5）；
No. four light emitting diode of indicating module（D4）Cathode and photocatalytic water module place（GND）It is connected；
No. five light emitting diode of indicating module（D5）Cathode and photocatalytic water module place（GND）It is connected；
No. four light emitting diode of indicating module（D4）Anode via the 2nd No. ten resistance（R20）It is connected to photocatalytic water module
Control unit microcontroller an IO foot；
No. five light emitting diode of indicating module（D5）Anode via the second ride on Bus No. 11 resistance（R21）It is connected to photocatalytic water mould
One IO foot of the microcontroller of the control unit of block.
2. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：First electrode
（DJ1）Conversion zone thickness be less than 1 micron.
3. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：2nd No. ten resistance of indicating module
（R20）Nominal value be 4.70 kilohms.
4. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
（DJ2）Conversion zone thickness be less than 1 micron.
5. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：Second ride on Bus No. 11 resistance of indicating module
（R21）Nominal value be 4.70 kilohms.
6. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：First electrode
（DJ1）Conversion zone making material include titanium dioxide.
7. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：No. four light-emitting diodes of indicating module
Pipe（D4）Light color for red.
8. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
（DJ2）Conversion zone making material be platinum.
9. photocatalyst catalyzing manufacturing of hydrogen equipment as described in claim 1, it is characterised in that：No. four light-emitting diodes of indicating module
Pipe（D4）Light color for green.
10. photocatalyst catalyst environment friendly system, it is characterised in that：With photocatalyst catalyzing manufacturing of hydrogen equipment described in claim 1.
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|---|---|---|---|---|
| JPH08296077A (en) * | 1995-04-28 | 1996-11-12 | Hitachi Ltd | Gaseous carbon dioxide converting device |
| EP1125636A1 (en) * | 1998-08-21 | 2001-08-22 | Ecodevice Laboratory Co., Ltd | Visible radiation type photocatalyst and production method thereof |
| CN1769532A (en) * | 2005-09-28 | 2006-05-10 | 中国船舶重工集团公司第七一八研究所 | Uses of magnetic valve in hydrogen production plant |
| KR100806168B1 (en) * | 2007-02-12 | 2008-02-21 | 재단법인서울대학교산학협력재단 | Preparation method of hydrogen energy by photocatalytic water splitting using electric field of solar cells |
| CN102713010A (en) * | 2010-01-22 | 2012-10-03 | 松下电器产业株式会社 | Hydrogen generation device |
| CN102933487A (en) * | 2010-09-07 | 2013-02-13 | 松下电器产业株式会社 | Hydrogen production device |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08296077A (en) * | 1995-04-28 | 1996-11-12 | Hitachi Ltd | Gaseous carbon dioxide converting device |
| EP1125636A1 (en) * | 1998-08-21 | 2001-08-22 | Ecodevice Laboratory Co., Ltd | Visible radiation type photocatalyst and production method thereof |
| CN1769532A (en) * | 2005-09-28 | 2006-05-10 | 中国船舶重工集团公司第七一八研究所 | Uses of magnetic valve in hydrogen production plant |
| KR100806168B1 (en) * | 2007-02-12 | 2008-02-21 | 재단법인서울대학교산학협력재단 | Preparation method of hydrogen energy by photocatalytic water splitting using electric field of solar cells |
| CN102713010A (en) * | 2010-01-22 | 2012-10-03 | 松下电器产业株式会社 | Hydrogen generation device |
| CN102933487A (en) * | 2010-09-07 | 2013-02-13 | 松下电器产业株式会社 | Hydrogen production device |
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