CN106637278B - Photocatalyst catalytic water decomposing system with electromagnetic valve driving module and photocatalytic environment-friendly device - Google Patents

Photocatalyst catalytic water decomposing system with electromagnetic valve driving module and photocatalytic environment-friendly device Download PDF

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CN106637278B
CN106637278B CN201611237086.5A CN201611237086A CN106637278B CN 106637278 B CN106637278 B CN 106637278B CN 201611237086 A CN201611237086 A CN 201611237086A CN 106637278 B CN106637278 B CN 106637278B
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module
resistance
air pressure
pressure sensing
capacitance
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CN106637278A (en
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聂新明
田亚平
乔学斌
万巧云
蒋少杰
李建伟
肖雄
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Xuzhou Bochuang Construction Development Group Co ltd
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Jiangsu Normal University
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/50Processes
    • C25B1/55Photoelectrolysis
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/02Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B19/00Programme-control systems
    • G05B19/02Programme-control systems electric
    • G05B19/04Programme control other than numerical control, i.e. in sequence controllers or logic controllers
    • G05B19/042Programme control other than numerical control, i.e. in sequence controllers or logic controllers using digital processors
    • G05B19/0423Input/output
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The photocatalyst catalytic water splitting system with the electromagnetic valve driving module comprises a water splitting module; the electromagnetic valve driving module is also included; the air pressure sensing device also comprises an air pressure sensing module. The photocatalytic environment-friendly device has the technical scheme. The invention has the advantages of low cost, flexible application, long service life, convenient use, safety and reliability.

Description

Photocatalyst catalysis solution water system with solenoid valve driving module, photocatalytic environmental-protection Device
Technical field
The invention belongs to energy storage domain technology field, and Xie Shui is catalyzed more particularly to the photocatalyst with solenoid valve driving module System, photocatalytic environmental-protection device.
Background technology
Photolysis water hydrogen system there are the problems such as efficiency is low, of high cost, electrode life is short, cause its be difficult to it is actual should With.
The content of the invention
In order to solve the above technical problems, the present invention proposes the photocatalyst catalysis solution water system with solenoid valve driving module System, photocatalytic environmental-protection device, specific solution have following technical solution.
1. the photocatalyst catalysis solution water system with solenoid valve driving module, it is characterised in that:
Including photocatalytic water module;
Further include solenoid valve driving module;
Further include air pressure sensing module;
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode (DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module;
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance;
In the control unit of photocatalytic water module:The model STM8S103 of microcontroller;One end of 5th capacitance and microcontroller Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller;One end of 6th capacitance and the electricity of microcontroller Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller;One end of 7th capacitance and the supply pin of microcontroller It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller;
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place (GND), the microcontroller of control unit Supply pin with control power supply (VCC) be connected;
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode (D1), first resistor (R1), the 8th resistance (R8), the first capacitance (C1), the second capacitance (C2), the 4th capacitance (C4), the first electricity Feel (L1), power power-supply access point, pwm signal access point;
In the VRM Voltage Regulator Module of photocatalytic water module:First metal-oxide-semiconductor (Q1) has input, output end, control terminal;First The output terminal of metal-oxide-semiconductor (Q1) is connected with the anode of the first diode (D1);The input terminal of first metal-oxide-semiconductor (Q1) is via first resistor (R1) it is connected to the control terminal of the first metal-oxide-semiconductor (Q1);
In the VRM Voltage Regulator Module of photocatalytic water module:6th triode (Q6) has input, output end, control terminal;The The input terminal of six triodes (Q6) is connected to the control terminal of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5);6th triode (Q6) output terminal is connected with the cathode of the first diode (D1);The input terminal of 6th triode (Q6) and power power-supply access point It is connected;The control terminal of 6th triode (Q6) is connected to pwm signal access point via the 8th resistance (R8);
In the VRM Voltage Regulator Module of photocatalytic water module:One end of first capacitance (C1) and the output terminal phase of the first inductance (L1) Even, the other end of the first capacitance (C1) is connected with the cathode of the first diode (D1);
In the VRM Voltage Regulator Module of photocatalytic water module:Second capacitance (C2) is in parallel with the first capacitance (C1);8th resistance (R8) it is in parallel with the 4th capacitance (C4);
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC);
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit Even;
The cathode of the first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND);
The output terminal of the first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode;
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), the 3rd capacitance (C3);
In the voltage feedback module of photocatalytic water module:4th resistance (R4) has input, output end;
In the voltage feedback module of photocatalytic water module:9th resistance (R9) has input, output end;9th resistance (R9) Input terminal be connected with the output terminal of the 4th resistance (R4);
In the voltage feedback module of photocatalytic water module:3rd capacitance (C3) is in parallel with the 9th resistance (R9);
The output of the input terminal of 4th resistance (R4) of voltage feedback module and the first inductance (L1) of VRM Voltage Regulator Module End is connected;The output terminal of 9th resistance (R9) of voltage feedback module is connected with place (GND);9th electricity of voltage feedback module The input terminal of resistance (R9) is connected with an IO foot of the microcontroller of control unit;
In photocatalytic water module:First electrode (DJ1) applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:Second electrode (DJ2) applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid Body passage (S10);
In the first electrode of photocatalytic water module:Conversion zone (S2) is located at the access path of isolation layer (S1) and ventilative liquid-proof Between;Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof;Fluid passage (S10) is through isolation Layer goes directly ventilative liquid-proof with conversion zone;The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage (S10) arrival end is opened on the outside of isolation layer;The physics that conversion zone (S2) can participate in or accelerate liquid to be changed into gas is anti- Should or it chemically react;Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas;Fluid passage (S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10);Production Thing gas is having ventilative liquid-proof to appear under buoyancy via passage, to anti-when reducing bubble S99 by reacting layer surface Answer layer surface and liquid to contact the adverse effect produced, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble Merge the scale and quantity of explosion, reduce bubble and merge impact of the explosion to electrode, add the service life of electrolysis electrode; Isolation layer (S1) is transparent;Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen;Isolation layer (S1), conversion zone (S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively;
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid Body passage (S10);
In the second electrode of photocatalytic water module:Conversion zone (S2) is located at the access path of isolation layer (S1) and ventilative liquid-proof Between;Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof;Fluid passage (S10) is through isolation Layer goes directly ventilative liquid-proof with conversion zone;The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage (S10) arrival end is opened on the outside of isolation layer;The physics that conversion zone (S2) can participate in or accelerate liquid to be changed into gas is anti- Should or it chemically react;Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas;Fluid passage (S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10);Every Exhausted layer (S1) is transparent;Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen;Isolation layer (S1), conversion zone (S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively;
In photocatalytic water module:The conversion zone (S2) of first electrode (DJ1) and the first inductance (L1) of VRM Voltage Regulator Module Output terminal is in be electrically connected;
In photocatalytic water module:The conversion zone (S2) of second electrode (DJ2) and the place (GND) of the power supply of VRM Voltage Regulator Module In being electrically connected;
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th electricity Hinder (R17);In solenoid valve driving module:9th triode (Q9) has input, output end, control terminal, the 4th diode (D4) input terminal is connected with the cathode of the 4th diode (D4);
In solenoid valve driving module:Coil interface (P5) has the first foot, crus secunda;First foot of coil interface (P5) with The anode of 4th diode (D4) is connected;The crus secunda of coil interface (P5) is connected with the cathode of the 4th diode (D4);
The control terminal of 9th triode (Q9) of solenoid valve driving module via solenoid valve driving module the 17th resistance (R17) it is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module;
The anode of the 4th diode (D4) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module;
The output terminal of the 9th triode (Q9) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module;
Air pressure sensing module, air pressure sensing module include air pressure sensing signal processing module, baroceptor;
In air pressure sensing module:Baroceptor has the first output pin and the second output pin;
The air pressure sensing signal processing module of air pressure sensing module include operational amplifier (U2), the 11st resistance (R11), 12nd resistance (R12), the 13rd resistance (R13), the 14th resistance (R14), the 15th resistance (R15), the 8th capacitance (C8), 9th capacitance (C9);
In air pressure sensing module:Air pressure sensing signal processing module in:13rd resistance (R13) has input terminal, defeated Outlet;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal of 12nd resistance (R12) is put with computing The inverting input of big device (U2) is connected;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal of 14th resistance (R14) is put with computing The in-phase input end of big device (U2) is connected;
In the air pressure sensing signal processing module of air pressure sensing module:One end of 8th capacitance (C8) and operational amplifier (U2) in-phase input end is connected, and the other end of the 8th capacitance (C8) is connected with the inverting input of operational amplifier (U2);
In the air pressure sensing signal processing module of air pressure sensing module:The inverting input of operational amplifier (U2) is via 11 resistance (R11) are connected to the output terminal of operational amplifier (U2);The output terminal and the 13rd resistance of operational amplifier (U2) (R13) input terminal is connected;
In the pressure sensing signal processing module of gas air pressure sensing module:The output terminal of 13rd resistance (R13) successively via 9th capacitance (C9), the 15th resistance (R15) are connected to the in-phase input end of operational amplifier (U2);
In the air pressure sensing signal processing module of air pressure sensing module:The input terminal and the 14th of 15th resistance (R15) The output terminal of resistance (R14) is connected;
In air pressure sensing module:First output pin of baroceptor is via the 12nd of air pressure sensing signal processing module Resistance (R12) is connected to the inverting input of the operational amplifier (U2) of air pressure sensing signal processing module;
In air pressure sensing module:Second output pin of baroceptor is via the 14th of air pressure sensing signal processing module Resistance (R14) is connected to the inverting input of the operational amplifier (U2) of air pressure sensing signal processing module;
15th resistance (R15) of the air pressure sensing signal processing module of air pressure sensing module and the public affairs of the 9th capacitance (C9) Concurrent is connected with the place (GND) of photocatalytic water module;
The output terminal of 13rd resistance (R13) of the air pressure sensing signal processing module of air pressure sensing module and photocatalytic water mould One IO foot of the microcontroller of the control unit of block is connected in signal, with to the pressure of gas obtained by photocatalytic water module feedback photocatalytic water Force data.
Further:In photocatalytic water module:The thickness of the conversion zone of first electrode (DJ1) is less than 1 micron.
Further:Solenoid valve driving module has LED lamp bead, for reacting the break-make situation of solenoid valve.
Further:The resistance value of 11st resistance (R11) of the air pressure sensing signal processing module of air pressure sensing module is 470K ohm.
Further:In photocatalytic water module:The thickness of the conversion zone of second electrode (DJ2) is less than 1 micron.
Further:Solenoid valve driving module has PCB circuit board.
Further:The resistance value of 12nd resistance (R12) of the air pressure sensing signal processing module of air pressure sensing module is 10K ohm.
Further:In photocatalytic water module:The making material of the conversion zone of first electrode (DJ1) includes titanium dioxide.
Further:Solenoid valve driving module has the plastic shell of insulation.
Further:The resistance value of 14th resistance (R14) of the air pressure sensing signal processing module of air pressure sensing module is 10K ohm.
Further:In photocatalytic water module:The making material of the conversion zone of second electrode (DJ2) is platinum.
Further:The interface of solenoid valve driving module has foolproof function.
Further:The model ceramics of 8th capacitance (C8) of the air pressure sensing signal processing module of air pressure sensing module Capacitance.
Further:In photocatalytic water module:Control unit includes LED display and is used to Voltage Feedback mould be presented for operator The data of block feedback.
Further:Solenoid valve driving module has sound-producing device, and term makes a sound prompt message.
Further:The resistance value of 15th resistance (R15) of the air pressure sensing signal processing module of air pressure sensing module is 470K ohm.
Further:In photocatalytic water module:The isolation layer (S1) of first electrode (DJ1) is made using glass.
Further:The connecting elements being electrically connected between solenoid valve driving module and control unit is fine copper conducting wire.
Further:The model of the operational amplifier (U2) of the air pressure sensing signal processing module of air pressure sensing module LM324。
Photocatalytic environmental-protection device, it is characterised in that:With any one in preceding solution.
Beneficial effect.
The present invention it is of low cost, using it is flexible, service life is long, esy to use, safe and reliable.
Brief description of the drawings
Fig. 1 is the electricity block schematic illustration of the photocatalytic water module of embodiment 1.
Fig. 2 is the circuit diagram of the photocatalytic water module of embodiment 1.
Fig. 3 is the structure diagram of the electrode of the photocatalytic water module of embodiment 1.
Fig. 4 is the schematic diagram of the circuit of the solenoid valve driving module of embodiment 1.
Fig. 5 is the schematic diagram of the circuit of the air pressure sensing module of embodiment 1.
Fig. 6 is the schematic diagram of 2 preparing hydrogen, generating power modules of embodiment.
Fig. 7 is the schematic diagram of the anti-mixing arrangement of 2 preparing hydrogen, generating power modules of embodiment, and wherein a is rip cutting figure, and b is horizontal stroke The schematic diagram of cut section N1-N1.
Embodiment
Embodiment 1. has the photocatalyst catalysis solution water system of solenoid valve driving module, it is characterised in that:
Including photocatalytic water module;
Further include solenoid valve driving module;
Further include air pressure sensing module;
Photocatalytic water module includes control power supply VCC, power power-supply TCC, place GND, control unit, first electrode DJ1, the Two electrode DJ2, VRM Voltage Regulator Module, voltage feedback module;
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance;
In the control unit of photocatalytic water module:The model STM8S103 of microcontroller;One end of 5th capacitance and microcontroller Grounding leg be connected, the other end of the 5th capacitance is connected with the VCAP feet of microcontroller;One end of 6th capacitance and the electricity of microcontroller Source foot is connected, and the other end of the 6th capacitance is connected with the grounding leg of microcontroller;One end of 7th capacitance and the supply pin of microcontroller It is connected, the other end of the 7th capacitance is connected with the grounding leg of microcontroller;
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place GND, the microcontroller of control unit Supply pin is connected with control power supply VCC;
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor Q1, the 6th triode Q6, the first diode D1, the One resistance R1, the 8th resistance R8, the first capacitance C1, the second capacitance C2, the 4th capacitance C4, the first inductance L1, power power-supply access Point, pwm signal access point;
In the VRM Voltage Regulator Module of photocatalytic water module:First metal-oxide-semiconductor Q1 has input, output end, control terminal;First The output terminal of metal-oxide-semiconductor Q1 is connected with the anode of the first diode D1;The input terminal of first metal-oxide-semiconductor Q1 is via first resistor R1 connections To the control terminal of the first metal-oxide-semiconductor Q1;;
In the VRM Voltage Regulator Module of photocatalytic water module:6th triode Q6 has input, output end, control terminal;6th The input terminal of triode Q6 is connected to the control terminal of the first metal-oxide-semiconductor Q1 via the 5th resistance R5;The output terminal of 6th triode Q6 It is connected with the cathode of the first diode D1;The input terminal of 6th triode Q6 is connected with power power-supply access point;6th triode The control terminal of Q6 is connected to pwm signal access point via the 8th resistance R8;
In the VRM Voltage Regulator Module of photocatalytic water module:One end of first capacitance C1 is connected with the output terminal of the first inductance L1, The other end of first capacitance C1 is connected with the cathode of the first diode D1;
In the VRM Voltage Regulator Module of photocatalytic water module:Second capacitance C2 is in parallel with the first capacitance C1;8th resistance R8 and Four capacitance C4 are in parallel;
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply TCC;
One IO foot phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and microcontroller in control unit Even;
The cathode of first diode D1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with place GND;
The output terminal of first inductance L1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode;
The voltage feedback module of photocatalytic water module includes the 4th resistance R4, the 9th resistance R9, the 3rd capacitance C3;
In the voltage feedback module of photocatalytic water module:4th resistance R4 has input, output end;
In the voltage feedback module of photocatalytic water module:9th resistance R9 has input, output end;9th resistance R9's is defeated Enter end with the output terminal of the 4th resistance R4 to be connected;
In the voltage feedback module of photocatalytic water module:3rd capacitance C3 is in parallel with the 9th resistance R9;
The output terminal phase of the input terminal of 4th resistance R4 of voltage feedback module and the first inductance L1 of VRM Voltage Regulator Module Even;The output terminal of 9th resistance R9 of voltage feedback module is connected with place GND;9th resistance R9's of voltage feedback module is defeated Enter end with an IO foot of the microcontroller of control unit to be connected;
In photocatalytic water module:First electrode DJ1 applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:Second electrode DJ2 applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:First electrode DJ1 includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage S10;
In the first electrode of photocatalytic water module:Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof access path it Between;Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof;Fluid passage S10 is through isolation layer and reaction The through ventilative liquid-proof of layer;The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened Mouth is in the outside of isolation layer;Physical reactions or the chemical reaction that conversion zone S2 can be participated in or be accelerated liquid to be changed into gas;Isolation Physical reactions or the chemical reaction that layer S1 is not involved in or accelerates liquid to be changed into gas;The highest of the arrival end S11 of fluid passage S10 The peak S129 of end S12s of the point S119 less than fluid passage S10;Product gas is having under buoyancy via passage Gas liquid-proof appears, and reduces bubble S99 by contacting the adverse effect produced to reaction layer surface and liquid during reaction layer surface, The efficiency of photodissociation liquid air-generating reaction can be increased, decrease scale and quantity that bubble merges explosion, reduce bubble conjunction And the impact to electrode of bursting, add the service life of electrolysis electrode;Isolation layer S1 is transparent;Conversion zone S2 be suitable for The electrode material of photolysis water hydrogen;Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone S2, ventilative liquid-proof S3 be in multilayer barrel-like structure, distribution sequence from inside to outside be successively breathe freely liquid-proof S3, conversion zone S2, Isolation layer S1;
The second electrode DJ2 of photocatalytic water module includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage S10;
In the second electrode of photocatalytic water module:Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof access path it Between;Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof;Fluid passage S10 is through isolation layer and reaction The through ventilative liquid-proof of layer;The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened Mouth is in the outside of isolation layer;Physical reactions or the chemical reaction that conversion zone S2 can be participated in or be accelerated liquid to be changed into gas;Isolation Physical reactions or the chemical reaction that layer S1 is not involved in or accelerates liquid to be changed into gas;The highest of the arrival end S11 of fluid passage S10 The peak S129 of end S12s of the point S119 less than fluid passage S10;Isolation layer S1 is transparent;Conversion zone S2 be suitable for The electrode material of photolysis water hydrogen;Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone S2, ventilative liquid-proof S3 be in multilayer barrel-like structure, distribution sequence from inside to outside be successively breathe freely liquid-proof S3, conversion zone S2, Isolation layer S1;
In photocatalytic water module:The output terminal of the conversion zone S2 of first electrode DJ1 and the first inductance L1 of VRM Voltage Regulator Module In being electrically connected;
In photocatalytic water module:The place GND of the conversion zone S2 of second electrode DJ2 and the power supply of VRM Voltage Regulator Module is in electricity Connection;
Solenoid valve driving module includes the 4th diode D4, coil interface P5, the 9th triode Q9, the 17th resistance R17;
In solenoid valve driving module:9th triode Q9 has input, output end, control terminal, the 9th triode Q9's Input terminal is connected with the cathode of the 4th diode D4;
In solenoid valve driving module:Coil interface P5 has the first foot, crus secunda;The first foot of coil interface P5 and the 4th The anode of diode D4 is connected;The crus secunda of coil interface P5 is connected with the cathode of the 4th diode D4;
The control terminal of 9th triode Q9 of solenoid valve driving module via solenoid valve driving module the 17th resistance R17 It is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module;
The anode of 4th diode D4 of solenoid valve driving module is connected with the control power supply VCC of photocatalytic water module;
The output terminal of the 9th triode Q9 of solenoid valve driving module is connected with the place GND of photocatalytic water module;
Air pressure sensing module, air pressure sensing module include air pressure sensing signal processing module, baroceptor;
In air pressure sensing module:Baroceptor has the first output pin and the second output pin;
The air pressure sensing signal processing module of air pressure sensing module includes operational amplifier U2, the 11st resistance R11, the tenth Two resistance R12, the 13rd resistance R13, the 14th resistance R14, the 15th resistance R15, the 8th capacitance C8, the 9th capacitance C9;
In air pressure sensing module:Air pressure sensing signal processing module in:13rd resistance R13 has input terminal, output End;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal and operation amplifier of 12nd resistance R12 The inverting input of device U2 is connected;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal and operation amplifier of 14th resistance R14 The in-phase input end of device U2 is connected;
In the air pressure sensing signal processing module of air pressure sensing module:One end of 8th capacitance C8 is with operational amplifier U2's In-phase input end is connected, and the other end of the 8th capacitance C8 is connected with the inverting input of operational amplifier U2;
In the air pressure sensing signal processing module of air pressure sensing module:The inverting input of operational amplifier U2 is via the tenth One resistance R11 is connected to the output terminal of operational amplifier U2;The input of the output terminal of operational amplifier U2 and the 13rd resistance R13 End is connected;
In the pressure sensing signal processing module of gas air pressure sensing module:The output terminal of 13rd resistance R13 is successively via Nine capacitance C9, the 15th resistance R15 are connected to the in-phase input end of operational amplifier U2;
In the air pressure sensing signal processing module of air pressure sensing module:The input terminal of 15th resistance R15 and the 14th electricity The output terminal of resistance R14 is connected;
In air pressure sensing module:First output pin of baroceptor is via the 12nd of air pressure sensing signal processing module Resistance R12 is connected to the inverting input of the operational amplifier U2 of air pressure sensing signal processing module;
In air pressure sensing module:Second output pin of baroceptor is via the 14th of air pressure sensing signal processing module Resistance R14 is connected to the inverting input of the operational amplifier U2 of air pressure sensing signal processing module;
The 15th resistance R15 of air pressure sensing signal processing module and the common point of the 9th capacitance C9 of air pressure sensing module It is connected with the place GND of photocatalytic water module;
The output terminal of 13rd resistance R13 of the air pressure sensing signal processing module of air pressure sensing module and photocatalytic water module The IO foot of microcontroller of control unit connected in signal, with to the pressure of gas obtained by photocatalytic water module feedback photocatalytic water Data.
Embodiment 2, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:The ventilative liquid-proof S3 of second electrode DJ2 is made using micropore glass.
Embodiment 3, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:There is solenoid valve driving module base to be used to carry solenoid valve driving module.
Embodiment 4, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:The ventilative liquid-proof S3 of first electrode DJ1 is made using micropore ceramics.
Embodiment 5, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The model nominal value of 9th capacitance C9 of the air pressure sensing signal processing module of air pressure sensing module is 1000 pico farads.
Embodiment 6, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:There is solenoid valve driving module fuse can prevent critical piece from burning.
Embodiment 7, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:The isolation layer S1 of second electrode DJ2 is made using glass.
Embodiment 8, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The model LM324 of the operational amplifier U2 of the air pressure sensing signal processing module of air pressure sensing module.
Embodiment 9, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The connecting elements being electrically connected between solenoid valve driving module and control unit is fine copper conducting wire.
Embodiment 10, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:The isolation layer S1 of first electrode DJ1 is made using glass.
Embodiment 11, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The resistance value of 15th resistance R15 of the air pressure sensing signal processing module of air pressure sensing module is 470K ohm.
Embodiment 12, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:Solenoid valve driving module has sound-producing device, and term makes a sound prompt message.
Embodiment 13, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:Control unit includes the number that LED display is used to voltage feedback module feedback be presented for operator According to.
Embodiment 14, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The model ceramic condenser of 8th capacitance C8 of the air pressure sensing signal processing module of air pressure sensing module.
Embodiment 15, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The interface of solenoid valve driving module has foolproof function.
Embodiment 16, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:In photocatalytic water module:The making material of the conversion zone of second electrode DJ2 is platinum.
Embodiment 17, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:The resistance value of 14th resistance R14 of the air pressure sensing signal processing module of air pressure sensing module is 10K ohm.
Embodiment 18, the catalysis solution water system of the photocatalyst with solenoid valve driving module based on embodiment 1, into one Step ground:Solenoid valve driving module has the plastic shell of insulation.
Embodiment 19, on the basis of embodiment 1, increase preparing hydrogen, generating power module, preparing hydrogen, generating power module includes anti-mixed Attach together and put LXQ, the first container L1, second container L2, filling opening, filling valve F3, first electrode DJ1, second electrode DJ2, first Pipeline GD1, second pipe GD2, the first air pump B1, the second air pump B2, the first check valve DF1, the second check valve DF2, the first gas Tank Q1, the second gas tank Q2, first entrance air valve F1, second entrance air valve F2, the first pressure maintaining valve W1, the second pressure maintaining valve W2, hydrogen combustion Expect battery BAT1, the 3rd pipeline GD3, the 4th pipeline GD4, circulating valve F4, degasification container YLG;
The anti-mixing arrangement LXQ of preparing hydrogen, generating power module includes housing, spiral tube chamber LXG, the first tube chamber ZG1, the second tube chamber ZG2;Spiral tube chamber LXG is helical form, and spiral tube chamber LXG has a first end and a second end;The axis direction of first tube chamber ZG1 with The axis of screw direction of spiral tube chamber LXG is identical, and the first tube chamber ZG1 is located within the helix of spiral tube chamber LXG, the first tube chamber The distance in the face vertical with spiral tube chamber LXG axis where two endpoints of the length of ZG1 more than spiral tube chamber LXG;First Tube chamber ZG1 has connecting pin and openend JK1;The connecting pin of first tube chamber ZG1 is communicated with the first end of spiral tube chamber LXG;The One tube chamber ZG1 is through entirely spiral tube chamber LXG sections, and the openend JK1 of the first tube chamber ZG1 exceeds the second of spiral tube chamber LXG End;The axis direction of second tube chamber ZG2 is identical with the axis of screw direction of spiral tube chamber LXG, and the second tube chamber ZG2 is located at helix tube Within the helix of chamber LXG, where two endpoints of the length of the second tube chamber ZG2 more than spiral tube chamber LXG with spiral tube chamber The distance in the vertical face of LXG axis;Second tube chamber ZG2 has connecting pin and openend JK1;The connecting pin of second tube chamber ZG2 with The second end of spiral tube chamber LXG communicates;Second tube chamber ZG2 is through entirely spiral tube chamber LXG sections, and the opening of the second tube chamber ZG2 The first end for holding JK1 to exceed spiral tube chamber LXG.
In preparing hydrogen, generating power module:The first container L1 is transparent, the bottom of the first container L1 and the one of anti-mixing arrangement LXQ End communicates, and the bottom of second container L2 is communicated with the other end of anti-mixing arrangement LXQ;That is the bottom of the first container L1 Portion, the bottom of second container L2 are communicated by anti-mixing arrangement LXQ;
In preparing hydrogen, generating power module:The top of the first container L1 is by the first pipeline GD1 via the first air pump B1, first unidirectional Valve DF1 is communicated with the first gas tank Q1, and for the first air pump B1 by the gas-powered in the first container L1 to the first gas tank Q1, first is single Allowing the gas in the first container L1 to flow to the first gas tank Q1, the first check valve DF1 to valve DF1 does not allow the first gas tank Q1 to flow Move in the first container L1;
In preparing hydrogen, generating power module:Second container L2 be it is transparent, the top of second container L2 by second pipe GD2 via Second air pump B2, the second check valve DF2 are communicated with the second gas tank Q2, and the second air pump B2 arrives the gas-powered in second container L2 In second gas tank Q2, the second check valve DF2 allows the gas in second container L2 to flow to the second gas tank Q2, the second check valve DF2 does not allow the second gas tank Q2 to flow in second container L2;
In preparing hydrogen, generating power module:First gas tank Q1 is connected with an inlet channel of hydrogen fuel cell BAT1, the first gas tank There is the first pressure maintaining valve W1, the first pressure maintaining valve W1 to allow fluid from the first gas tank on the communication path of Q1 and hydrogen fuel cell BAT1 Q1, which flows to hydrogen fuel cell BAT1, the first pressure maintaining valve W1, does not allow fluid to flow to the first gas tank Q1 from hydrogen fuel cell BAT1, the One pressure maintaining valve W1 can control the air pressure of the inlet channel for the hydrogen fuel cell BAT1 that the first gas tank Q1 connected;
In preparing hydrogen, generating power module:Second gas tank Q2 is connected with an inlet channel of hydrogen fuel cell BAT1, the second gas tank There is the second pressure maintaining valve W2, the second pressure maintaining valve W2 to allow fluid from the second gas tank on the communication path of Q2 and hydrogen fuel cell BAT1 Q2, which flows to hydrogen fuel cell BAT1, the second pressure maintaining valve W2, does not allow fluid to flow to the second gas tank Q2 from hydrogen fuel cell BAT1, the Two pressure maintaining valve W2 can control the air pressure of the inlet channel for the hydrogen fuel cell BAT1 that the second gas tank Q2 connected;
In preparing hydrogen, generating power module:The upper end of 3rd pipeline GD3 is communicated with the discharge outlet of hydrogen fuel cell BAT1, the 3rd pipeline The lower end of GD3 is communicated with the cavity volume of degasification container YLG;The upper end of 4th pipeline GD4 is communicated with the cavity volume of degasification container YLG, the The lower end of four pipeline GD4 is communicated via circulating valve F4 with the first container L1 so that the product water of hydrogen fuel cell BAT1 can weigh In the new electrolysis cavity volume for flowing into the first container L1, second container L2 and forming, recycle;The lower ending opening of 3rd pipeline GD3 The horizontal level of upper end opening of the horizontal level less than the 4th pipeline GD4, can prevent gas from entering the first container L1, the second appearance In the electrolysis cavity volume that device L2 is formed;
In preparing hydrogen, generating power module:Also there is supersonic generator C1, supersonic generator C1 to be located in degasification container YLG Portion;Also there is exhaust outlet, degasification container YLG is communicated by the 5th pipeline GD5 with exhausting-gas hole, the fluid path of the 5th pipeline GD5 In also have the 5th pump B5, air bleeding valve F5;When being operated by controlling degasification container YLG degasification while supersonic generator C1 Open air bleeding valve F5 and the air pressure for opening the 5th pump B5 reduction degasification containers YLG, so that the product water of hydrogen fuel cell BAT1 The gas abjection of middle dissolving, the design that the air pressure of degasification container YLG is reduced while supersonic generator C1 deaerates to deaerate Hardware cost is very low and effect is fine;
In preparing hydrogen, generating power module:Hydrogen fuel cell BAT1 has power supply output point VCC1, power supply place GND1;
The first electrode DJ1 of photocatalytic water module is installed in the cavity volume of the first container L1 of preparing hydrogen, generating power module, photocatalytic water The first container L1 and preparing hydrogen, generating power module of the lowermost horizontal level of the first electrode DJ1 of module higher than preparing hydrogen, generating power module Anti- mixing arrangement LXQ communicate the horizontal level of interface;
The second electrode DJ2 of photocatalytic water module is installed in the cavity volume of second container L2, the second electrode of photocatalytic water module The lowermost horizontal level of DJ2 is higher than the second container L2 of preparing hydrogen, generating power module and the anti-mixing arrangement of preparing hydrogen, generating power module LXQ communicates the horizontal level of interface;The second container L2 electrolysis of the first container L1, preparing hydrogen, generating power module when preparing hydrogen, generating power module When draught head it is too big when can due to liquid depart from electrode and terminate cell reaction.
It is embodiment 20, further on the basis of embodiment 19:The material of the first container L1 of preparing hydrogen, generating power module Matter is glass.
It is embodiment 21, further on the basis of embodiment 19:The material of the second container L2 of preparing hydrogen, generating power module Matter is glass.
Above embodiment is not the legal scope to the present invention, and protection scope of the present invention is please according to claim Book content is judged.

Claims (7)

1. the photocatalyst catalysis solution water system with solenoid valve driving module, it is characterised in that:
Including photocatalytic water module;
Further include solenoid valve driving module;
Further include air pressure sensing module;
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode (DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module;
The control unit of photocatalytic water module includes microcontroller, the 6th capacitance, the 7th capacitance, the 5th capacitance;
In the control unit of photocatalytic water module:The model STM8S103 of microcontroller;5th one end of capacitance and connecing for microcontroller Lower margin is connected, and the other end of the 5th capacitance is connected with the VCAP feet of microcontroller;One end of 6th capacitance and the supply pin of microcontroller It is connected, the other end of the 6th capacitance is connected with the grounding leg of microcontroller;One end of 7th capacitance is connected with the supply pin of microcontroller, The other end of 7th capacitance is connected with the grounding leg of microcontroller;
The grounding leg of the microcontroller of the control unit of photocatalytic water module is connected with place (GND), the electricity of the microcontroller of control unit Source foot is connected with control power supply (VCC);
The VRM Voltage Regulator Module of photocatalytic water module include the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode (D1), First resistor (R1), the 8th resistance (R8), the first capacitance (C1), the second capacitance (C2), the 4th capacitance (C4), the first inductance (L1), power power-supply access point, pwm signal access point;
In the VRM Voltage Regulator Module of photocatalytic water module:First metal-oxide-semiconductor (Q1) has input, output end, control terminal;First MOS The output terminal of pipe (Q1) is connected with the anode of the first diode (D1);The input terminal of first metal-oxide-semiconductor (Q1) is via first resistor (R1) it is connected to the control terminal of the first metal-oxide-semiconductor (Q1);
In the VRM Voltage Regulator Module of photocatalytic water module:6th triode (Q6) has input, output end, control terminal;Six or three The input terminal of pole pipe (Q6) is connected to the control terminal of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5);6th triode (Q6) Output terminal is connected with the cathode of the first diode (D1);The input terminal of 6th triode (Q6) is connected with power power-supply access point; The control terminal of 6th triode (Q6) is connected to pwm signal access point via the 8th resistance (R8);
In the VRM Voltage Regulator Module of photocatalytic water module:One end of first capacitance (C1) is connected with the output terminal of the first inductance (L1), The other end of first capacitance (C1) is connected with the cathode of the first diode (D1);
In the VRM Voltage Regulator Module of photocatalytic water module:Second capacitance (C2) is in parallel with the first capacitance (C1);8th resistance (R8) with 4th capacitance (C4) is in parallel;
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC);
The pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with an IO foot of microcontroller in control unit;
The cathode of the first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND);
The output terminal of the first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode;
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), the 3rd capacitance (C3);
In the voltage feedback module of photocatalytic water module:4th resistance (R4) has input, output end;
In the voltage feedback module of photocatalytic water module:9th resistance (R9) has input, output end;9th resistance (R9) it is defeated Enter end with the output terminal of the 4th resistance (R4) to be connected;
In the voltage feedback module of photocatalytic water module:3rd capacitance (C3) is in parallel with the 9th resistance (R9);
The output terminal phase of the input terminal and the first inductance (L1) of VRM Voltage Regulator Module of 4th resistance (R4) of voltage feedback module Even;The output terminal of 9th resistance (R9) of voltage feedback module is connected with place (GND);9th resistance of voltage feedback module (R9) input terminal is connected with an IO foot of the microcontroller of control unit;
In photocatalytic water module:First electrode (DJ1) applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:Second electrode (DJ2) applies to the electrode of photolysis water hydrogen;
In photocatalytic water module:First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid and leads to Road (S10);
In the first electrode of photocatalytic water module:Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof access path it Between;Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof;Fluid passage (S10) runs through isolation layer Go directly ventilative liquid-proof with conversion zone;The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage (S10) arrival end is opened on the outside of isolation layer;The physics that conversion zone (S2) can participate in or accelerate liquid to be changed into gas is anti- Should or it chemically react;Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas;Fluid passage (S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10);Production Thing gas is having ventilative liquid-proof to appear under buoyancy via passage, to anti-when reducing bubble S99 by reacting layer surface Answer layer surface and liquid to contact the adverse effect produced, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble Merge the scale and quantity of explosion, reduce bubble and merge impact of the explosion to electrode, add the service life of electrolysis electrode; Isolation layer (S1) is transparent;Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen;Isolation layer (S1), conversion zone (S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively;
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid and leads to Road (S10);
In the second electrode of photocatalytic water module:Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof access path it Between;Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof;Fluid passage (S10) runs through isolation layer Go directly ventilative liquid-proof with conversion zone;The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage (S10) arrival end is opened on the outside of isolation layer;The physics that conversion zone (S2) can participate in or accelerate liquid to be changed into gas is anti- Should or it chemically react;Physical reactions or the chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas;Fluid passage (S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10);Every Exhausted layer (S1) is transparent;Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen;Isolation layer (S1), conversion zone (S2), liquid-proof (S3) of breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness Structure, distribution sequence from inside to outside is ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1) successively;
In photocatalytic water module:The conversion zone (S2) of first electrode (DJ1) and the output of the first inductance (L1) of VRM Voltage Regulator Module End is in be electrically connected;
In photocatalytic water module:The place (GND) of the conversion zone (S2) of second electrode (DJ2) and the power supply of VRM Voltage Regulator Module is in electricity Learn connection;
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th resistance (R17);
In solenoid valve driving module:9th triode (Q9) has input, output end, control terminal, the 9th triode (Q9) Input terminal is connected with the cathode of the 4th diode (D4);
In solenoid valve driving module:Coil interface (P5) has the first foot, crus secunda;The first foot and the 4th of coil interface (P5) The anode of diode (D4) is connected;The crus secunda of coil interface (P5) is connected with the cathode of the 4th diode (D4);
The control terminal of 9th triode (Q9) of solenoid valve driving module via solenoid valve driving module the 17th resistance (R17) It is connected to an IO foot of the microcontroller of the control unit of photocatalytic water module;
The anode of the 4th diode (D4) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module;
The output terminal of the 9th triode (Q9) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module;
Air pressure sensing module, air pressure sensing module include air pressure sensing signal processing module, baroceptor;
In air pressure sensing module:Baroceptor has the first output pin and the second output pin;
The air pressure sensing signal processing module of air pressure sensing module includes operational amplifier (U2), the 11st resistance (R11), the tenth Two resistance (R12), the 13rd resistance (R13), the 14th resistance (R14), the 15th resistance (R15), the 8th capacitance (C8), the 9th Capacitance (C9);
In air pressure sensing module:Air pressure sensing signal processing module in:13rd resistance (R13) has input, output end;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal and operational amplifier of 12nd resistance (R12) (U2) inverting input is connected;
In the air pressure sensing signal processing module of air pressure sensing module:The output terminal and operational amplifier of 14th resistance (R14) (U2) in-phase input end is connected;
In the air pressure sensing signal processing module of air pressure sensing module:One end of 8th capacitance (C8) and operational amplifier (U2) In-phase input end is connected, and the other end of the 8th capacitance (C8) is connected with the inverting input of operational amplifier (U2);
In the air pressure sensing signal processing module of air pressure sensing module:The inverting input of operational amplifier (U2) is via the 11st Resistance (R11) is connected to the output terminal of operational amplifier (U2);The output terminal of operational amplifier (U2) and the 13rd resistance (R13) Input terminal be connected;
In the pressure sensing signal processing module of gas air pressure sensing module:The output terminal of 13rd resistance (R13) is successively via the 9th Capacitance (C9), the 15th resistance (R15) are connected to the in-phase input end of operational amplifier (U2);
In the air pressure sensing signal processing module of air pressure sensing module:The input terminal and the 14th resistance of 15th resistance (R15) (R14) output terminal is connected;
In air pressure sensing module:First output pin of baroceptor via air pressure sensing signal processing module the 12nd resistance (R12) it is connected to the inverting input of the operational amplifier (U2) of air pressure sensing signal processing module;
In air pressure sensing module:Second output pin of baroceptor via air pressure sensing signal processing module the 14th resistance (R14) it is connected to the inverting input of the operational amplifier (U2) of air pressure sensing signal processing module;
15th resistance (R15) of the air pressure sensing signal processing module of air pressure sensing module and the common point of the 9th capacitance (C9) It is connected with the place (GND) of photocatalytic water module;
The output terminal of 13rd resistance (R13) of the air pressure sensing signal processing module of air pressure sensing module and photocatalytic water module One IO foot of the microcontroller of control unit is connected in signal, with to the number pressure of gas obtained by photocatalytic water module feedback photocatalytic water According to.
2. the photocatalyst catalysis solution water system with solenoid valve driving module as claimed in claim 1, it is characterised in that:Photodissociation In water module:The thickness of the conversion zone of first electrode (DJ1) is less than 1 micron.
3. the photocatalyst catalysis solution water system with solenoid valve driving module as claimed in claim 1, it is characterised in that:Electromagnetism Valve drive module has LED lamp bead, for reacting the break-make situation of solenoid valve.
4. the photocatalyst catalysis solution water system with solenoid valve driving module as claimed in claim 1, it is characterised in that:Air pressure The resistance value of 11st resistance (R11) of the air pressure sensing signal processing module of sensing module is 470K ohm.
5. the photocatalyst catalysis solution water system with solenoid valve driving module as claimed in claim 1, it is characterised in that:Photodissociation In water module:The thickness of the conversion zone of second electrode (DJ2) is less than 1 micron.
6. the photocatalyst catalysis solution water system with solenoid valve driving module as claimed in claim 1, it is characterised in that:Electromagnetism Valve drive module has PCB circuit board.
7. photocatalytic environmental-protection device, it is characterised in that:With the photocatalyst with solenoid valve driving module described in claim 1 Catalysis solution water system.
CN201611237086.5A 2016-08-29 2016-12-28 Photocatalyst catalytic water decomposing system with electromagnetic valve driving module and photocatalytic environment-friendly device Active CN106637278B (en)

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