CN106702418A - Photocatalytic hydrogen production equipment and photocatalytic water treatment device - Google Patents
Photocatalytic hydrogen production equipment and photocatalytic water treatment device Download PDFInfo
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- CN106702418A CN106702418A CN201611237006.6A CN201611237006A CN106702418A CN 106702418 A CN106702418 A CN 106702418A CN 201611237006 A CN201611237006 A CN 201611237006A CN 106702418 A CN106702418 A CN 106702418A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Catalysts (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The photocatalyst catalytic hydrogen production equipment comprises a photolysis module; the electromagnetic valve driving module is further included. The photocatalytic water treatment device has the technical scheme. The invention has the advantages of low cost, flexible application, long service life, convenient use, safety and reliability.
Description
Technical field
The invention belongs to hydrogen preparation field technical field, specifically related at photocatalyst catalyzing manufacturing of hydrogen equipment, photocatalysis water
Reason device.
Technical background
There are the problems such as low efficiency, high cost, electrode life be short in photolysis water hydrogen system, cause its be difficult to it is actual should
With.
The content of the invention
In order to solve the above technical problems, the present invention proposes photocatalyst catalyzing manufacturing of hydrogen equipment, photocatalytic water treatment device,
Specific solution has following technical scheme.
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
Also include solenoid valve driving module；
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode
(DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes single-chip microcomputer, the 6th electric capacity, the 7th electric capacity, the 5th electric capacity；
In the control unit of photocatalytic water module：The model STM8S103 of single-chip microcomputer；One end of 5th electric capacity and single-chip microcomputer
Grounding leg be connected, the other end of the 5th electric capacity is connected with the VCAP pin of single-chip microcomputer；One end of 6th electric capacity and the electricity of single-chip microcomputer
Source pin is connected, and the other end of the 6th electric capacity is connected with the grounding leg of single-chip microcomputer；One end of 7th electric capacity and the supply pin of single-chip microcomputer
It is connected, the other end of the 7th electric capacity is connected with the grounding leg of single-chip microcomputer；
The grounding leg of the single-chip microcomputer of the control unit of photocatalytic water module is connected with place (GND), the single-chip microcomputer of control unit
Supply pin with control power supply (VCC) be connected；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode
(D1), the second diode (D2), first resistor (R1), the 8th resistance (R8), the first electric capacity (C1), the second electric capacity (C2), the 4th
Electric capacity (C4), the first inductance (L1), power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor (Q1) has input, output end, control end；First
The output end of metal-oxide-semiconductor (Q1) is connected with the negative pole of the first diode (D1)；The input of the first metal-oxide-semiconductor (Q1) is through being connected to by
The control end of the first metal-oxide-semiconductor of one resistance (R1) (Q1)；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode (Q6) has input, output end, control end；The
The input of six triodes (Q6) is connected to the control end of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5)；6th triode
(Q6) output end is connected with the positive pole of the first diode (D1)；The input of the 6th triode (Q6) and power power-supply access point
It is connected；
In the VRM Voltage Regulator Module of photocatalytic water module：The output end phase of one end of the first electric capacity (C1) and the first inductance (L1)
Even, the other end of the first electric capacity (C1) is connected with the positive pole of the first diode (D1)；
In the VRM Voltage Regulator Module of photocatalytic water module：Second electric capacity (C2) is in parallel with the first electric capacity (C1)；8th resistance
(R8) it is in parallel with the 4th electric capacity (C4)；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC)；
One IO pin phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and single-chip microcomputer in control unit
Even；
The positive pole of first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND)；
The output end of first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), the 3rd electric capacity (C3)；
In the voltage feedback module of photocatalytic water module：4th resistance (R4) has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance (R9) has input, output end；9th resistance (R9)
Input be connected with the input of the 9th resistance (R9)；
In the voltage feedback module of photocatalytic water module：3rd electric capacity (C3) is in parallel with the 9th resistance (R9)；
The output of the input of the 4th resistance (R4) of voltage feedback module and first inductance (L1) of VRM Voltage Regulator Module
End is connected；
The output end of the 9th resistance (R9) of voltage feedback module is connected with place (GND)；The 9th of voltage feedback module
The input of resistance (R9) is connected with an IO pin of the single-chip microcomputer of control unit；
In photocatalytic water module：First electrode (DJ1) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode (DJ2) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode (DJ1) includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid
Body passage (S10)；
In the first electrode of photocatalytic water module：Conversion zone (S2) is located at the access path of isolation layer (S1) and ventilative liquid-proof
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer ventilative liquid-proof through with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；Conversion zone (S2) can participate in or accelerate liquid be changed into gas physics it is anti-
Should or chemically react；Physical reactions or chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Produce
Thing gas is having ventilative liquid-proof to appear under buoyancy via passage, to anti-when reducing bubble S99 by reaction layer surface
The adverse effect that layer surface and liquid contact are produced is answered, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble
Merge the scale and quantity of explosion, reduce bubble and merge impact of the explosion to electrode, increased the service life of electrolysis electrode；
Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2) liquid-proof (S3) of, breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is successively ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1)；
The second electrode (DJ2) of photocatalytic water module includes isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid
Body passage (S10)；
In the second electrode of photocatalytic water module：Conversion zone (S2) is located at the access path of isolation layer (S1) and ventilative liquid-proof
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) is through isolation
Layer ventilative liquid-proof through with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；Conversion zone (S2) can participate in or accelerate liquid be changed into gas physics it is anti-
Should or chemically react；Physical reactions or chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Every
Exhausted layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2) liquid-proof (S3) of, breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is successively ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1)；
In photocatalytic water module：The conversion zone (S2) of first electrode (DJ1) and first inductance (L1) of VRM Voltage Regulator Module
Output end is in be electrically connected；
In photocatalytic water module：The place (GND) of the conversion zone (S2) of second electrode (DJ2) and the power supply of VRM Voltage Regulator Module
In being electrically connected；
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th electricity
Resistance (R17)；
In solenoid valve driving module：4th diode (D4) has input, output end, control end, the 4th diode
(D4) input is connected with the positive pole of the 4th diode (D4)；
In solenoid valve driving module：Coil interface (P5) has the first pin, crus secunda；First pin of coil interface (P5) with
The negative pole of the 4th diode (D4) is connected；The crus secunda of coil interface (P5) is connected with the positive pole of the 4th diode (D4)；
The control end of the 4th diode (D4) of solenoid valve driving module via solenoid valve driving module the 17th resistance
(R17) it is connected to an IO pin of the single-chip microcomputer of the control unit of photocatalytic water module；
The negative pole of the 4th diode (D4) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module；
The output end of the 4th diode (D4) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module.
Further：In photocatalytic water module：The thickness of the conversion zone of first electrode (DJ1) is less than 1 micron.
Further：Solenoid valve driving module has LED lamp bead, the break-make situation for reacting magnetic valve.
Further：In photocatalytic water module：The thickness of the conversion zone of second electrode (DJ2) is less than 1 micron.
Further：Solenoid valve driving module has PCB.
Further：In photocatalytic water module：The making material of the conversion zone of first electrode (DJ1) includes titanium dioxide.
Further：Solenoid valve driving module has the plastic casing of insulation.
Further：In photocatalytic water module：The making material of the conversion zone of second electrode (DJ2) is platinum.
Further：The interface of solenoid valve driving module has foolproof function.
Further：In photocatalytic water module：Control unit is used to that Voltage Feedback mould to be presented for operator comprising LED display
The data of block feedback.
Further：Solenoid valve driving module with sound-producing device, term sends auditory tone cues information.
Photocatalytic water treatment device, it is characterised in that：With any one in preceding solution.
Beneficial effect.
The present invention is with low cost, using flexible, long service life, esy to use, safe and reliable.
Brief description of the drawings
Fig. 1 is the electricity block schematic illustration of the photocatalytic water module of embodiment 1.
Fig. 2 is the circuit diagram of the photocatalytic water module of embodiment 1.
Fig. 3 is the structural representation of the electrode of the photocatalytic water module of embodiment 1.
Fig. 4 is the schematic diagram of the circuit of the solenoid valve driving module of embodiment 1.
Fig. 5 is the schematic diagram of 2 preparing hydrogen, generating power modules of embodiment.
Fig. 6 is the schematic diagram of the anti-mixing arrangement of 2 preparing hydrogen, generating power modules of embodiment, and wherein a is rip cutting figure, and b is horizontal stroke
The schematic diagram of cut section N1-N1.
Specific embodiment
The photocatalyst catalyzing manufacturing of hydrogen equipment of embodiment 1., it is characterised in that：
Including photocatalytic water module；
Also include solenoid valve driving module；
Photocatalytic water module includes control power supply VCC, power power-supply TCC, place GND, control unit, first electrode DJ1, the
Two electrode DJ2, VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes single-chip microcomputer, the 6th electric capacity, the 7th electric capacity, the 5th electric capacity；
In the control unit of photocatalytic water module：The model STM8S103 of single-chip microcomputer；One end of 5th electric capacity and single-chip microcomputer
Grounding leg be connected, the other end of the 5th electric capacity is connected with the VCAP pin of single-chip microcomputer；One end of 6th electric capacity and the electricity of single-chip microcomputer
Source pin is connected, and the other end of the 6th electric capacity is connected with the grounding leg of single-chip microcomputer；One end of 7th electric capacity and the supply pin of single-chip microcomputer
It is connected, the other end of the 7th electric capacity is connected with the grounding leg of single-chip microcomputer；
The grounding leg of the single-chip microcomputer of the control unit of photocatalytic water module is connected with place GND, the single-chip microcomputer of control unit
Supply pin is connected with control power supply VCC；
The VRM Voltage Regulator Module of photocatalytic water module includes the first metal-oxide-semiconductor Q1, the 6th triode Q6, the first diode D1, the
Two diode D2, first resistor R1, the 8th resistance R8, the first electric capacity C1, the second electric capacity C2, the 4th electric capacity C4, the first inductance L1,
Power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor Q1 has input, output end, control end；First
The output end of metal-oxide-semiconductor Q1 is connected with the negative pole of the first diode D1；The input of the first metal-oxide-semiconductor Q1 is through being connected to by first resistor
The control end of the first metal-oxide-semiconductors of R1 Q1；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode Q6 has input, output end, control end；6th
The input of triode Q6 is connected to the control end of the first metal-oxide-semiconductor Q1 via the 5th resistance R5；The output end of the 6th triode Q6
Positive pole with the first diode D1 is connected；The input of the 6th triode Q6 is connected with power power-supply access point；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first electric capacity C1 is connected with the output end of the first inductance L1,
The other end of the first electric capacity C1 is connected with the positive pole of the first diode D1；
In the VRM Voltage Regulator Module of photocatalytic water module：Second electric capacity C2 is in parallel with the first electric capacity C1；8th resistance R8 and
Four electric capacity C4 are in parallel；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply TCC；
One IO pin phase of the pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module and single-chip microcomputer in control unit
Even；
The positive pole of the first diode D1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with place GND；
The output end of the first inductance L1 of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance R4, the 9th resistance R9, the 3rd electric capacity C3；
In the voltage feedback module of photocatalytic water module：4th resistance R4 has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance R9 has input, output end；9th resistance R9's is defeated
Enter end to be connected with the input of the 9th resistance R9；
In the voltage feedback module of photocatalytic water module：3rd electric capacity C3 is in parallel with the 9th resistance R9；
The output end phase of the input of the 4th resistance R4 of voltage feedback module and the first inductance L1 of VRM Voltage Regulator Module
Even；The output end of the 9th resistance R9 of voltage feedback module is connected with place GND；9th resistance R9's of voltage feedback module is defeated
Enter end to be connected with an IO pin of the single-chip microcomputer of control unit；
In photocatalytic water module：First electrode DJ1 applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode DJ2 applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode DJ1 includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the first electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof access path it
Between；Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 is through isolation layer and reaction
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or chemical reaction that conversion zone S2 can be participated in or be accelerated liquid to be changed into gas；Isolation
Physical reactions or chemical reaction that layer S1 is not involved in or accelerates liquid to be changed into gas；The highest of the arrival end S11 of fluid passage S10
The peak S129 of end S12s of the point S119 less than fluid passage S10；Product gas are having under buoyancy via passage
Gas liquid-proof is appeared, the adverse effect produced to reaction layer surface and liquid contact when reducing bubble S99 by reaction layer surface,
The efficiency of photodissociation liquid air-generating reaction can be increased, scale and quantity that bubble merges explosion is decreased, bubble conjunction is reduced
And the impact burst to electrode, increased the service life of electrolysis electrode；Isolation layer S1 is transparent；Conversion zone S2 be suitable for
The electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone
S2, ventilative liquid-proof S3 are in multilayer barrel-like structure, distribution sequence from inside to outside be successively ventilative liquid-proof S3, conversion zone S2,
Isolation layer S1；
The second electrode DJ2 of photocatalytic water module includes isolation layer S1, conversion zone S2, ventilative liquid-proof S3, fluid passage
S10；
In the second electrode of photocatalytic water module：Conversion zone S2 be located at isolation layer S1 and ventilative liquid-proof access path it
Between；Conversion zone S2 is located between isolation layer S1 and the space path of ventilative liquid-proof；Fluid passage S10 is through isolation layer and reaction
The through ventilative liquid-proof of layer；The end of fluid passage S10 is closed by ventilative liquid-proof S3, and the arrival end of fluid passage S10 is opened
Mouth is in the outside of isolation layer；Physical reactions or chemical reaction that conversion zone S2 can be participated in or be accelerated liquid to be changed into gas；Isolation
Physical reactions or chemical reaction that layer S1 is not involved in or accelerates liquid to be changed into gas；The highest of the arrival end S11 of fluid passage S10
The peak S129 of end S12s of the point S119 less than fluid passage S10；Isolation layer S1 is transparent；Conversion zone S2 be suitable for
The electrode material of photolysis water hydrogen；Isolation layer S1, conversion zone S2, ventilative liquid-proof S3 are cylindrical shape, isolation layer S1, conversion zone
S2, ventilative liquid-proof S3 are in multilayer barrel-like structure, distribution sequence from inside to outside be successively ventilative liquid-proof S3, conversion zone S2,
Isolation layer S1；
In photocatalytic water module：The output end of the conversion zone S2 of first electrode DJ1 and the first inductance L1 of VRM Voltage Regulator Module
In being electrically connected；
In photocatalytic water module：The conversion zone S2 of second electrode DJ2 is in electricity with the place GND of the power supply of VRM Voltage Regulator Module
Connection；
Solenoid valve driving module includes the 4th diode D4, coil interface P5, the 9th triode Q9, the 17th resistance R17；
In solenoid valve driving module：4th diode D4 has input, output end, control end, the 4th diode D4's
Input is connected with the positive pole of the 4th diode D4；
In solenoid valve driving module：Coil interface P5 has the first pin, crus secunda；First pin of coil interface P5 and the 4th
The negative pole of diode D4 is connected；The crus secunda of coil interface P5 is connected with the positive pole of the 4th diode D4；
The control end of the 4th diode D4 of solenoid valve driving module via solenoid valve driving module the 17th resistance R17
It is connected to an IO pin of the single-chip microcomputer of the control unit of photocatalytic water module；
The negative pole of the 4th diode D4 of solenoid valve driving module is connected with the control power supply VCC of photocatalytic water module；
The output end of the 4th diode D4 of solenoid valve driving module is connected with the place GND of photocatalytic water module.
Embodiment 2, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of two electrode DJ2 is made using micropore glass.
Embodiment 3, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
It is used to carry solenoid valve driving module with base.
Embodiment 4, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The ventilative liquid-proof S3 of one electrode DJ1 is made using micropore ceramics.
Embodiment 5, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module has
There is fuse to be prevented from critical piece to burn.
Embodiment 6, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The isolation layer S1 of two electrode DJ2 is made using glass.
Embodiment 7, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module with
The connecting elements being electrically connected between control unit is fine copper wire.
Embodiment 8, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The isolation layer S1 of one electrode DJ1 is made using glass.
Embodiment 9, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With sound-producing device, term sends auditory tone cues information.
Embodiment 10, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：Control
Unit processed is used to be presented for operator the data of voltage feedback module feedback comprising LED display.
Embodiment 11, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
Interface there is foolproof function.
Embodiment 12, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The making material of the conversion zone of two electrode DJ2 is platinum.
Embodiment 13, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
Plastic casing with insulation.
Embodiment 14, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The making material of the conversion zone of one electrode DJ1 includes titanium dioxide.
Embodiment 15, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With PCB.
Embodiment 16, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：In photocatalytic water module：The
The thickness of the conversion zone of two electrode DJ2 is less than 1 micron.
Embodiment 17, the photocatalyst catalyzing manufacturing of hydrogen equipment based on embodiment 1, further：Solenoid valve driving module
With LED lamp bead, the break-make situation for reacting magnetic valve.
Embodiment 18, on the basis of embodiment 1, increase preparing hydrogen, generating power module, preparing hydrogen, generating power module includes anti-mixed
Attach together and put LXQ, the first container L1, second container L2, filling opening, filling valve F3, first electrode DJ1, second electrode DJ2, first
Pipeline GD1, second pipe GD2, the first air pump B1, the second air pump B2, the first check valve DF1, the second check valve DF2, the first gas
Tank Q1, the second gas tank Q2, first entrance air valve F1, second entrance air valve F2, the first pressure maintaining valve W1, the second pressure maintaining valve W2, hydrogen combustion
Material battery BAT1, the 3rd pipeline GD3, the 4th pipeline GD4, circulating valve F4, degasification container YLG；
The anti-mixing arrangement LXQ of preparing hydrogen, generating power module includes housing, spiral tube chamber LXG, the first tube chamber ZG1, the second tube chamber
ZG2；Spiral tube chamber LXG is helical form, and spiral tube chamber LXG has first end and the second end；The axis direction of the first tube chamber ZG1 with
The axis of screw direction of spiral tube chamber LXG is identical, and the first tube chamber ZG1 is located within the helix of spiral tube chamber LXG, the first tube chamber
The distance in the face vertical with spiral tube chamber LXG axis where two end points of the length of ZG1 more than spiral tube chamber LXG；First
Tube chamber ZG1 has connection end and openend JK1；The connection end of the first tube chamber ZG1 communicates with the first end of spiral tube chamber LXG；The
One tube chamber ZG1 is through LXG sections of whole spiral tube chamber, and the openend JK1 of the first tube chamber ZG1 exceeds the second of spiral tube chamber LXG
End；The axis direction of the second tube chamber ZG2 is identical with the axis of screw direction of spiral tube chamber LXG, and the second tube chamber ZG2 is located at helix tube
Within the helix of chamber LXG, where two end points of the length of the second tube chamber ZG2 more than spiral tube chamber LXG with spiral tube chamber
The distance in the vertical face of LXG axis；Second tube chamber ZG2 has connection end and openend JK1；The connection end of the second tube chamber ZG2 with
Second end of spiral tube chamber LXG communicates；Second tube chamber ZG2 is through LXG sections of whole spiral tube chamber, and the second tube chamber ZG2 opening
First ends of the end JK1 beyond spiral tube chamber LXG.
In preparing hydrogen, generating power module：First container L1 is transparent, the bottom of the first container L1 and the one of anti-mixing arrangement LXQ
End communicates, and the bottom of second container L2 communicates with the other end of anti-mixing arrangement LXQ；That is the bottom of the first container L1
Portion, the bottom of second container L2 are communicated by anti-mixing arrangement LXQ；
In preparing hydrogen, generating power module：The top of the first container L1 is by the first pipeline GD1 via the first air pump B1, first unidirectional
Valve DF1 is communicated with the first gas tank Q1, and the first air pump B1 is by the gas-powered in the first container L1 to the first gas tank Q1, and first is single
Allowing the gas in the first container L1 to flow to the first gas tank Q1, the first check valve DF1 to valve DF1 does not allow the first gas tank Q1 to flow
Move in the first container L1；
In preparing hydrogen, generating power module：Second container L2 be it is transparent, the top of second container L2 by second pipe GD2 via
Second air pump B2, the second check valve DF2 are communicated with the second gas tank Q2, and the second air pump B2 arrives the gas-powered in second container L2
In second gas tank Q2, the second check valve DF2 allows the gas in second container L2 to flow to the second gas tank Q2, the second check valve
DF2 does not allow the second gas tank Q2 to flow in second container L2；
In preparing hydrogen, generating power module：First gas tank Q1 is connected with an inlet channel of hydrogen fuel cell BAT1, the first gas tank
Having the first pressure maintaining valve W1, the first pressure maintaining valve W1 on the communication path of Q1 and hydrogen fuel cell BAT1 allows fluid from the first gas tank
Q1 flows to hydrogen fuel cell BAT1, the first pressure maintaining valve W1 does not allow fluid to flow to the first gas tank Q1 from hydrogen fuel cell BAT1, the
One pressure maintaining valve W1 can control an air pressure for inlet channel of the hydrogen fuel cell BAT1 that the first gas tank Q1 connected；
In preparing hydrogen, generating power module：Second gas tank Q2 is connected with an inlet channel of hydrogen fuel cell BAT1, the second gas tank
Having the second pressure maintaining valve W2, the second pressure maintaining valve W2 on the communication path of Q2 and hydrogen fuel cell BAT1 allows fluid from the second gas tank
Q2 flows to hydrogen fuel cell BAT1, the second pressure maintaining valve W2 does not allow fluid to flow to the second gas tank Q2 from hydrogen fuel cell BAT1, the
Two pressure maintaining valve W2 can control an air pressure for inlet channel of the hydrogen fuel cell BAT1 that the second gas tank Q2 connected；
In preparing hydrogen, generating power module：The upper end of the 3rd pipeline GD3 communicates with the discharge outlet of hydrogen fuel cell BAT1, the 3rd pipeline
The lower end of GD3 communicates with the cavity volume of degasification container YLG；The upper end of the 4th pipeline GD4 communicates with the cavity volume of degasification container YLG, the
The lower end of four pipeline GD4 communicates via circulating valve F4 with the first container L1 so that the product water of hydrogen fuel cell BAT1 can be again
In the new electrolysis cavity volume for flowing into the first container L1, second container L2 composition, recycle；The lower ending opening of the 3rd pipeline GD3
The horizontal level of upper end open of the horizontal level less than the 4th pipeline GD4, can prevent gas from entering the first container L1, the second appearance
In the electrolysis cavity volume that device L2 is constituted；
In preparing hydrogen, generating power module：Also there is supersonic generator C1, supersonic generator C1 to be located in degasification container YLG
Portion；Also there is exhaust outlet, degasification container YLG is communicated by the 5th pipeline GD5 with steam vent, the fluid path of the 5th pipeline GD5
In also have the 5th pump B5, air bleeding valve F5；When being operated by controlling degasification container YLG degasification while supersonic generator C1
The air pressure of open air bleeding valve F5 and opening the 5th pump B5 reduction degasification containers YLG, causes the product water of hydrogen fuel cell BAT1
The gas abjection of middle dissolving, the design that the air pressure of degasification container YLG is reduced while supersonic generator C1 deaerates causes degassing
Hardware cost is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell BAT1 has power supply output point VCC1, power supply place GND1；
The first electrode DJ1 of photocatalytic water module is installed in the cavity volume of the first container L1 of preparing hydrogen, generating power module, photocatalytic water
First container L1 and preparing hydrogen, generating power module of the horizontal level of the bottom of the first electrode DJ1 of module higher than preparing hydrogen, generating power module
Anti- mixing arrangement LXQ communicate the horizontal level of interface；
The second electrode DJ2 of photocatalytic water module is installed in the cavity volume of second container L2, the second electrode of photocatalytic water module
The horizontal level of the bottom of DJ2 is higher than the second container L2 of preparing hydrogen, generating power module and the anti-mixing arrangement of preparing hydrogen, generating power module
LXQ communicates the horizontal level of interface；The second container L2 electrolysis of the first container L1, preparing hydrogen, generating power module when preparing hydrogen, generating power module
When draught head it is too big when can due to liquid depart from electrode and terminate cell reaction.
It is embodiment 19, further on the basis of embodiment 18：The material of the first container L1 of preparing hydrogen, generating power module
Matter is glass.
It is embodiment 20, further on the basis of embodiment 18：The material of the second container L2 of preparing hydrogen, generating power module
Matter is glass.
Above embodiment is not that protection scope of the present invention is please according to claim to legal scope of the invention
Book content is judged.
Claims (10)
1. photocatalyst catalyzing manufacturing of hydrogen equipment, it is characterised in that：
Including photocatalytic water module；
Also include solenoid valve driving module；
Photocatalytic water module includes control power supply (VCC), power power-supply (TCC), place (GND), control unit, first electrode
(DJ1), second electrode (DJ2), VRM Voltage Regulator Module, voltage feedback module；
The control unit of photocatalytic water module includes single-chip microcomputer, the 6th electric capacity, the 7th electric capacity, the 5th electric capacity；
In the control unit of photocatalytic water module：The model STM8S103 of single-chip microcomputer；5th one end of electric capacity and connecing for single-chip microcomputer
Lower margin is connected, and the other end of the 5th electric capacity is connected with the VCAP pin of single-chip microcomputer；One end of 6th electric capacity and the supply pin of single-chip microcomputer
It is connected, the other end of the 6th electric capacity is connected with the grounding leg of single-chip microcomputer；One end of 7th electric capacity is connected with the supply pin of single-chip microcomputer,
The other end of the 7th electric capacity is connected with the grounding leg of single-chip microcomputer；
The grounding leg of the single-chip microcomputer of the control unit of photocatalytic water module is connected with place (GND), the electricity of the single-chip microcomputer of control unit
Source pin is connected with control power supply (VCC)；
The VRM Voltage Regulator Module of photocatalytic water module include the first metal-oxide-semiconductor (Q1), the 6th triode (Q6), the first diode (D1),
Second diode (D2), first resistor (R1), the 8th resistance (R8), the first electric capacity (C1), the second electric capacity (C2), the 4th electric capacity
(C4), the first inductance (L1), power power-supply access point, pwm signal access point；
In the VRM Voltage Regulator Module of photocatalytic water module：First metal-oxide-semiconductor (Q1) has input, output end, control end；First MOS
The output end for managing (Q1) is connected with the negative pole of the first diode (D1)；The input of the first metal-oxide-semiconductor (Q1) is through being connected to by first
The control end of the first metal-oxide-semiconductor of resistance (R1) (Q1)；
In the VRM Voltage Regulator Module of photocatalytic water module：6th triode (Q6) has input, output end, control end；Six or three
The input of pole pipe (Q6) is connected to the control end of the first metal-oxide-semiconductor (Q1) via the 5th resistance (R5)；6th triode (Q6)
Output end is connected with the positive pole of the first diode (D1)；The input of the 6th triode (Q6) is connected with power power-supply access point；
In the VRM Voltage Regulator Module of photocatalytic water module：One end of first electric capacity (C1) is connected with the output end of the first inductance (L1),
The other end of the first electric capacity (C1) is connected with the positive pole of the first diode (D1)；
In the VRM Voltage Regulator Module of photocatalytic water module：Second electric capacity (C2) is in parallel with the first electric capacity (C1)；8th resistance (R8) with
4th electric capacity (C4) is in parallel；
The power power-supply access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with power power-supply (TCC)；
The pwm signal access point of the VRM Voltage Regulator Module of photocatalytic water module is connected with an IO pin of single-chip microcomputer in control unit；
The positive pole of first diode (D1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with place (GND)；
The output end of first inductance (L1) of the VRM Voltage Regulator Module of photocatalytic water module is connected with first electrode；
The voltage feedback module of photocatalytic water module includes the 4th resistance (R4), the 9th resistance (R9), the 3rd electric capacity (C3)；
In the voltage feedback module of photocatalytic water module：4th resistance (R4) has input, output end；
In the voltage feedback module of photocatalytic water module：9th resistance (R9) has input, output end；9th resistance (R9) it is defeated
Enter end to be connected with the input of the 9th resistance (R9)；
In the voltage feedback module of photocatalytic water module：3rd electric capacity (C3) is in parallel with the 9th resistance (R9)；
The input of the 4th resistance (R4) of voltage feedback module and the output end phase of first inductance (L1) of VRM Voltage Regulator Module
Even；
The output end of the 9th resistance (R9) of voltage feedback module is connected with place (GND)；9th resistance of voltage feedback module
(R9) input is connected with an IO pin of the single-chip microcomputer of control unit；
In photocatalytic water module：First electrode (DJ1) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：Second electrode (DJ2) applies to the electrode of photolysis water hydrogen；
In photocatalytic water module：First electrode (DJ1) includes that isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid lead to
Road (S10)；
In the first electrode of photocatalytic water module：Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof access path it
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) runs through isolation layer
Ventilative liquid-proof through with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；Conversion zone (S2) can participate in or accelerate liquid be changed into gas physics it is anti-
Should or chemically react；Physical reactions or chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Produce
Thing gas is having ventilative liquid-proof to appear under buoyancy via passage, to anti-when reducing bubble S99 by reaction layer surface
The adverse effect that layer surface and liquid contact are produced is answered, the efficiency of photodissociation liquid air-generating reaction can be increased, decrease bubble
Merge the scale and quantity of explosion, reduce bubble and merge impact of the explosion to electrode, increased the service life of electrolysis electrode；
Isolation layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2) liquid-proof (S3) of, breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is successively ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1)；
The second electrode (DJ2) of photocatalytic water module includes that isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3), liquid lead to
Road (S10)；
In the second electrode of photocatalytic water module：Conversion zone (S2) be located at isolation layer (S1) and ventilative liquid-proof access path it
Between；Conversion zone (S2) is located between isolation layer (S1) and the space path of ventilative liquid-proof；Fluid passage (S10) runs through isolation layer
Ventilative liquid-proof through with conversion zone；The end of fluid passage (S10) is closed by ventilative liquid-proof (S3), fluid passage
(S10) arrival end is opened on the outside of isolation layer；Conversion zone (S2) can participate in or accelerate liquid be changed into gas physics it is anti-
Should or chemically react；Physical reactions or chemical reaction that isolation layer (S1) is not involved in or accelerates liquid to be changed into gas；Fluid passage
(S10) peak (S129) of the peak (S119) of arrival end (S11) less than the end (S12) of fluid passage (S10)；Every
Exhausted layer (S1) is transparent；Conversion zone (S2) is the electrode material suitable for photolysis water hydrogen；Isolation layer (S1), conversion zone
(S2) liquid-proof (S3) of, breathing freely is cylindrical shape, and isolation layer (S1), conversion zone (S2), ventilative liquid-proof (S3) are in multilayer tubbiness
Structure, distribution sequence from inside to outside is successively ventilative liquid-proof (S3), conversion zone (S2), isolation layer (S1)；
In photocatalytic water module：The output of the conversion zone (S2) of first electrode (DJ1) and first inductance (L1) of VRM Voltage Regulator Module
End is in be electrically connected；
In photocatalytic water module：The conversion zone (S2) of second electrode (DJ2) is in electricity with the place (GND) of the power supply of VRM Voltage Regulator Module
Learn connection；
Solenoid valve driving module includes the 4th diode (D4), coil interface (P5), the 9th triode (Q9), the 17th resistance
(R17)；
In solenoid valve driving module：4th diode (D4) has input, output end, control end, the 4th diode (D4)
Input is connected with the positive pole of the 4th diode (D4)；
In solenoid valve driving module：Coil interface (P5) has the first pin, crus secunda；First pin and the 4th of coil interface (P5)
The negative pole of diode (D4) is connected；The crus secunda of coil interface (P5) is connected with the positive pole of the 4th diode (D4)；
The control end of the 4th diode (D4) of solenoid valve driving module via solenoid valve driving module the 17th resistance (R17)
It is connected to an IO pin of the single-chip microcomputer of the control unit of photocatalytic water module；
The negative pole of the 4th diode (D4) of solenoid valve driving module is connected with the control power supply (VCC) of photocatalytic water module；
The output end of the 4th diode (D4) of solenoid valve driving module is connected with the place (GND) of photocatalytic water module.
2. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：In photocatalytic water module：First electrode
(DJ1) thickness of conversion zone is less than 1 micron.
3. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：Solenoid valve driving module has LED
Pearl, the break-make situation for reacting magnetic valve.
4. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
(DJ2) thickness of conversion zone is less than 1 micron.
5. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：Solenoid valve driving module has PCB electricity
Road plate.
6. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：In photocatalytic water module：First electrode
(DJ1) making material of conversion zone includes titanium dioxide.
7. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：Solenoid valve driving module has insulation
Plastic casing.
8. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：In photocatalytic water module：Second electrode
(DJ2) making material of conversion zone is platinum.
9. photocatalyst catalyzing manufacturing of hydrogen equipment as claimed in claim 1, it is characterised in that：The interface of solenoid valve driving module has
Foolproof function.
10. photocatalytic water treatment device, it is characterised in that：With the technical scheme described in claim 1.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08296077A (en) * | 1995-04-28 | 1996-11-12 | Hitachi Ltd | Gaseous carbon dioxide converting device |
| EP1125636A1 (en) * | 1998-08-21 | 2001-08-22 | Ecodevice Laboratory Co., Ltd | Visible radiation type photocatalyst and production method thereof |
| CN1769532A (en) * | 2005-09-28 | 2006-05-10 | 中国船舶重工集团公司第七一八研究所 | Uses of magnetic valve in hydrogen production plant |
| KR100806168B1 (en) * | 2007-02-12 | 2008-02-21 | 재단법인서울대학교산학협력재단 | Preparation method of hydrogen energy by photocatalytic water splitting using electric field of solar cells |
| CN102713010A (en) * | 2010-01-22 | 2012-10-03 | 松下电器产业株式会社 | Hydrogen generation device |
| CN102933487A (en) * | 2010-09-07 | 2013-02-13 | 松下电器产业株式会社 | Hydrogen production device |
-
2016
- 2016-12-28 CN CN201611237006.6A patent/CN106702418B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08296077A (en) * | 1995-04-28 | 1996-11-12 | Hitachi Ltd | Gaseous carbon dioxide converting device |
| EP1125636A1 (en) * | 1998-08-21 | 2001-08-22 | Ecodevice Laboratory Co., Ltd | Visible radiation type photocatalyst and production method thereof |
| CN1769532A (en) * | 2005-09-28 | 2006-05-10 | 中国船舶重工集团公司第七一八研究所 | Uses of magnetic valve in hydrogen production plant |
| KR100806168B1 (en) * | 2007-02-12 | 2008-02-21 | 재단법인서울대학교산학협력재단 | Preparation method of hydrogen energy by photocatalytic water splitting using electric field of solar cells |
| CN102713010A (en) * | 2010-01-22 | 2012-10-03 | 松下电器产业株式会社 | Hydrogen generation device |
| CN102933487A (en) * | 2010-09-07 | 2013-02-13 | 松下电器产业株式会社 | Hydrogen production device |
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Inventor after: Zhao Xinsheng Inventor after: Nie Xinming Inventor after: Tian Yaping Inventor after: Wan Qiaoyun Inventor after: Li Jianwei Inventor before: Li Jianwei Inventor before: Nie Xinming Inventor before: Tian Yaping Inventor before: Wan Qiaoyun Inventor before: Zhao Xinsheng |
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Effective date of registration: 20190815 Address after: 221000 No. 88 Liaohe West Road, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee after: SU Normal University Semiconductor Materials and Equipment Research Institute (Pizhou) Co., Ltd. Address before: 221116 Shanghai Road, Copper Mt. District, Jiangsu, No. 101, No. Patentee before: Jiangsu Normal University |
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Effective date of registration: 20220516 Address after: 221300 506, block B, electronic industrial park, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee after: Xuzhou Bochuang Construction Development Group Co.,Ltd. Address before: 221000 No.88, Liaohe West Road, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee before: SU Normal University Semiconductor Materials and Equipment Research Institute (Pizhou) Co.,Ltd. |