CN106700693A - Thermal sublimation printed metal photo - Google Patents
Thermal sublimation printed metal photo Download PDFInfo
- Publication number
- CN106700693A CN106700693A CN201611158930.5A CN201611158930A CN106700693A CN 106700693 A CN106700693 A CN 106700693A CN 201611158930 A CN201611158930 A CN 201611158930A CN 106700693 A CN106700693 A CN 106700693A
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- Prior art keywords
- parts
- acid
- thermal sublimation
- photo
- printed metal
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a thermal sublimation printed metal photo. The thermal sublimation printed metal photo is composed of a metal plate and a coating arranged on the metal plate, wherein the coating is prepared from the following components in parts by weight: 5 to 10 parts of cellulose acetate, 15 to 3.6 parts of zinc oxide, 10 to 11.5 parts of hyaluronic acid, 5.5 to 6.5 parts of bentonite powder, 4.5 to 6.6 parts of linolenic acid oil, 5.5 to 8.8 parts of a dispersant, 3.4 to 5.5 parts of water-based silicic acid, 0.5 to 2.2 parts of a thickener, 3.5 to 5.5 parts of hydroxypropyl, 5 to 10 parts of isobutylene, 9 to 12 parts of carboxylic acid, 1.2 to 3.5 parts of a film forming agent, 5.5 to 10 parts of sodium dodecyl sulfate, 3 to 8 parts of diacetone alcohol and 20 to 45 parts of distilled water. By adopting the thermal sublimation printed metal photo, the disadvantages that a traditional paper photo is easily affected with damp, easily becomes yellow and is easy to fade are completely overcome; the thermal sublimation printed metal photo has the advantages of washing resistance, corrosion resistance and strong light exposure resistance and is not faded all the time. Theoretically, the thermal sublimation printed metal photo can be stored for longer time.
Description
Technical field
The present invention relates to Thermal-printing Technology field, and in particular to a kind of heat sublimation stamp metal picture.
Background technology
Stamp metal photograph has mainly used heat sublimation trans-printing technology.To be risen containing heat by ink-jet printer first
Then the ink printed of magnificent molecule is located transfer paper and metallic plate containing specific coatings at high temperature and pressure on transfer paper
Reason, by the dye sublimation on transfer paper to metal plate coating, shows photo effect.The metal made by Thermal-printing Technology
Photo color is gorgeous, becomes clear, and high-resolution, resolution ratio can make difference up to 300dpi, and according to different metal plate coatings
Special-effect, such as wire drawing, pearly-lustre and reticulate pattern etc., color has golden, silver color and pearly-lustre white etc..
The content of the invention
Goal of the invention:A kind of deficiency the invention aims to make up existing investigative technique, there is provided heat sublimation print
Flower metal picture.
Technical scheme:A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, described painting
Layer is grouped into by each group of following parts by weight:Cellulose acetate 5-10 parts, zinc oxide 1.5-3.6 parts, hyaluronic acid 10-11.5
Part, 5.5-6.5 parts of bentonite powder, linolenic oil 4.5-6.6 parts, dispersant 5.5-8.8 parts, waterborne organic silicon acid 3.4-5.5
Part, thickener 0.5-2.2 parts, hydroxypropyl 3.5-5.5 parts, isobutene 5-10 parts, carboxylic acid 9-12 parts, film forming agent 1.2-3.5 parts, ten
Sodium dialkyl sulfate 5.5-10 parts, diacetone alcohol 3-8 parts, distilled water 20-45 parts.
The invention also discloses a kind of preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl
Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm
After filter and package.
Preferably, step 5) in, temperature is 60-70 DEG C.
Beneficial effect:Preparation method of the invention, safety and environmental protection is pollution-free, made heat sublimation stamp metal picture,
The drawbacks of thoroughly overcoming traditionally on paper photo moisture-sensitive, easily flavescence, fugitive color, water-fastness, corrosion-resistant, resistance to high light is exposed to the sun and reaches
To will never fade.In theory, the long period can be preserved.
Specific embodiment:
Embodiment 1:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, by following parts by weight
Each group is grouped into:5 parts of cellulose acetate, 1.5 parts of zinc oxide, 10 parts of hyaluronic acid, 5.5 parts of bentonite powder, linolenic oil 4.5
Part, 5.5 parts of dispersant, waterborne organic silicon acid 3.4 parts, 0.5 part of thickener, 3.5 parts of hydroxypropyl, 5 parts of isobutene, 9 parts of carboxylic acid, into
1.2 parts of film, 5.5 parts of lauryl sodium sulfate, 3 parts of diacetone alcohol, 20 parts of distilled water.
A kind of preparation method of heat sublimation stamp metal picture, comprises the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl
Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm
After filter and package.
Step 5) in, temperature is 60-70 DEG C.
Embodiment 2:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, and coating is by following weight portion
Several each groups are grouped into:8 parts of cellulose acetate, 3.6 parts of zinc oxide, 11.5 parts of hyaluronic acid, 6.5 parts of bentonite powder, flax
Sour 6.6 parts of oil, 8.8 parts of dispersant, 3.4-5.5 parts of waterborne organic silicon acid, 2.2 parts of thickener, 5.5 parts of hydroxypropyl, isobutene 10
Part, 12 parts of carboxylic acid, 3.5 parts of film forming agent, 10 parts of lauryl sodium sulfate, 8 parts of diacetone alcohol, 45 parts of distilled water.
The invention also discloses the preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl
Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm
After filter and package.
Step 5) in, temperature is 60-70 DEG C.
Embodiment 3:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, by following parts by weight
Each group is grouped into:15 parts of cellulose acetate, 3 parts of zinc oxide, 11 parts of hyaluronic acid, 6 parts of bentonite powder, linolenic oil 6 part, point
8 parts of powder, 5 parts of waterborne organic silicon acid, 2 parts of thickener, 4 parts of hydroxypropyl, 6 parts of isobutene, 11 parts of carboxylic acid, 3 parts of film forming agent, 12
8 parts of sodium alkyl sulfate, 6 parts, distilled water 20-45 parts of diacetone alcohol.
The invention also discloses the preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl
Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm
After filter and package.
Step 5) in, temperature is 60-70 DEG C.
Claims (3)
1. a kind of heat sublimation stamp metal picture, it is characterised in that:The coating for setting by metallic plate and thereon is constituted, described painting
Layer is grouped into by each group of following parts by weight:Cellulose acetate 5-10 parts, zinc oxide 1.5-3.6 parts, hyaluronic acid 10-11.5
Part, 5.5-6.5 parts of bentonite powder, linolenic oil 4.5-6.6 parts, dispersant 5.5-8.8 parts, waterborne organic silicon acid 3.4-5.5
Part, thickener 0.5-2.2 parts, hydroxypropyl 3.5-5.5 parts, isobutene 5-10 parts, carboxylic acid 9-12 parts, film forming agent 1.2-3.5 parts, ten
Sodium dialkyl sulfate 5.5-10 parts, diacetone alcohol 3-8 parts, distilled water 20-45 parts.
2. a kind of preparation method of heat sublimation stamp metal picture as claimed in claim 1, it is characterised in that:Including following step
Suddenly:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxypropyl,
Isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is filtered less than after 60mm
Packaging.
3. the preparation method of heat sublimation stamp metal picture as claimed in claim 2, it is characterised in that:Step 5) in, temperature
It is 60-70 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611158930.5A CN106700693A (en) | 2016-12-15 | 2016-12-15 | Thermal sublimation printed metal photo |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611158930.5A CN106700693A (en) | 2016-12-15 | 2016-12-15 | Thermal sublimation printed metal photo |
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CN106700693A true CN106700693A (en) | 2017-05-24 |
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ID=58937785
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CN201611158930.5A Pending CN106700693A (en) | 2016-12-15 | 2016-12-15 | Thermal sublimation printed metal photo |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1990119A (en) * | 2005-12-29 | 2007-07-04 | 海宁市红狮电梯装饰有限公司 | Stainless steel plate surface treatment, pattern heat transfer process and plate made thereby |
CN102009539A (en) * | 2009-09-07 | 2011-04-13 | 陈为江 | Production process and special equipment for novel metal photograph |
CN102089155A (en) * | 2009-04-24 | 2011-06-08 | 韩国科林株式会社 | Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor |
CN102310673A (en) * | 2011-07-01 | 2012-01-11 | 淮安市映像数码科技有限公司 | Method for transferring large-breadth full-color pattern image on metal plate |
CN103809400A (en) * | 2012-11-09 | 2014-05-21 | 富士施乐株式会社 | Image transfer sheet |
-
2016
- 2016-12-15 CN CN201611158930.5A patent/CN106700693A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1990119A (en) * | 2005-12-29 | 2007-07-04 | 海宁市红狮电梯装饰有限公司 | Stainless steel plate surface treatment, pattern heat transfer process and plate made thereby |
CN102089155A (en) * | 2009-04-24 | 2011-06-08 | 韩国科林株式会社 | Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor |
CN102009539A (en) * | 2009-09-07 | 2011-04-13 | 陈为江 | Production process and special equipment for novel metal photograph |
CN102310673A (en) * | 2011-07-01 | 2012-01-11 | 淮安市映像数码科技有限公司 | Method for transferring large-breadth full-color pattern image on metal plate |
CN103809400A (en) * | 2012-11-09 | 2014-05-21 | 富士施乐株式会社 | Image transfer sheet |
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Application publication date: 20170524 |