CN106700693A - Thermal sublimation printed metal photo - Google Patents

Thermal sublimation printed metal photo Download PDF

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Publication number
CN106700693A
CN106700693A CN201611158930.5A CN201611158930A CN106700693A CN 106700693 A CN106700693 A CN 106700693A CN 201611158930 A CN201611158930 A CN 201611158930A CN 106700693 A CN106700693 A CN 106700693A
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CN
China
Prior art keywords
parts
acid
thermal sublimation
photo
printed metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611158930.5A
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Chinese (zh)
Inventor
戚裕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Jigu New Material Co Ltd
Original Assignee
Suzhou Jigu New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Jigu New Material Co Ltd filed Critical Suzhou Jigu New Material Co Ltd
Priority to CN201611158930.5A priority Critical patent/CN106700693A/en
Publication of CN106700693A publication Critical patent/CN106700693A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Abstract

The invention discloses a thermal sublimation printed metal photo. The thermal sublimation printed metal photo is composed of a metal plate and a coating arranged on the metal plate, wherein the coating is prepared from the following components in parts by weight: 5 to 10 parts of cellulose acetate, 15 to 3.6 parts of zinc oxide, 10 to 11.5 parts of hyaluronic acid, 5.5 to 6.5 parts of bentonite powder, 4.5 to 6.6 parts of linolenic acid oil, 5.5 to 8.8 parts of a dispersant, 3.4 to 5.5 parts of water-based silicic acid, 0.5 to 2.2 parts of a thickener, 3.5 to 5.5 parts of hydroxypropyl, 5 to 10 parts of isobutylene, 9 to 12 parts of carboxylic acid, 1.2 to 3.5 parts of a film forming agent, 5.5 to 10 parts of sodium dodecyl sulfate, 3 to 8 parts of diacetone alcohol and 20 to 45 parts of distilled water. By adopting the thermal sublimation printed metal photo, the disadvantages that a traditional paper photo is easily affected with damp, easily becomes yellow and is easy to fade are completely overcome; the thermal sublimation printed metal photo has the advantages of washing resistance, corrosion resistance and strong light exposure resistance and is not faded all the time. Theoretically, the thermal sublimation printed metal photo can be stored for longer time.

Description

Heat sublimation stamp metal picture
Technical field
The present invention relates to Thermal-printing Technology field, and in particular to a kind of heat sublimation stamp metal picture.
Background technology
Stamp metal photograph has mainly used heat sublimation trans-printing technology.To be risen containing heat by ink-jet printer first Then the ink printed of magnificent molecule is located transfer paper and metallic plate containing specific coatings at high temperature and pressure on transfer paper Reason, by the dye sublimation on transfer paper to metal plate coating, shows photo effect.The metal made by Thermal-printing Technology Photo color is gorgeous, becomes clear, and high-resolution, resolution ratio can make difference up to 300dpi, and according to different metal plate coatings Special-effect, such as wire drawing, pearly-lustre and reticulate pattern etc., color has golden, silver color and pearly-lustre white etc..
The content of the invention
Goal of the invention:A kind of deficiency the invention aims to make up existing investigative technique, there is provided heat sublimation print Flower metal picture.
Technical scheme:A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, described painting Layer is grouped into by each group of following parts by weight:Cellulose acetate 5-10 parts, zinc oxide 1.5-3.6 parts, hyaluronic acid 10-11.5 Part, 5.5-6.5 parts of bentonite powder, linolenic oil 4.5-6.6 parts, dispersant 5.5-8.8 parts, waterborne organic silicon acid 3.4-5.5 Part, thickener 0.5-2.2 parts, hydroxypropyl 3.5-5.5 parts, isobutene 5-10 parts, carboxylic acid 9-12 parts, film forming agent 1.2-3.5 parts, ten Sodium dialkyl sulfate 5.5-10 parts, diacetone alcohol 3-8 parts, distilled water 20-45 parts.
The invention also discloses a kind of preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm After filter and package.
Preferably, step 5) in, temperature is 60-70 DEG C.
Beneficial effect:Preparation method of the invention, safety and environmental protection is pollution-free, made heat sublimation stamp metal picture, The drawbacks of thoroughly overcoming traditionally on paper photo moisture-sensitive, easily flavescence, fugitive color, water-fastness, corrosion-resistant, resistance to high light is exposed to the sun and reaches To will never fade.In theory, the long period can be preserved.
Specific embodiment:
Embodiment 1:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, by following parts by weight Each group is grouped into:5 parts of cellulose acetate, 1.5 parts of zinc oxide, 10 parts of hyaluronic acid, 5.5 parts of bentonite powder, linolenic oil 4.5 Part, 5.5 parts of dispersant, waterborne organic silicon acid 3.4 parts, 0.5 part of thickener, 3.5 parts of hydroxypropyl, 5 parts of isobutene, 9 parts of carboxylic acid, into 1.2 parts of film, 5.5 parts of lauryl sodium sulfate, 3 parts of diacetone alcohol, 20 parts of distilled water.
A kind of preparation method of heat sublimation stamp metal picture, comprises the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm After filter and package.
Step 5) in, temperature is 60-70 DEG C.
Embodiment 2:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, and coating is by following weight portion Several each groups are grouped into:8 parts of cellulose acetate, 3.6 parts of zinc oxide, 11.5 parts of hyaluronic acid, 6.5 parts of bentonite powder, flax Sour 6.6 parts of oil, 8.8 parts of dispersant, 3.4-5.5 parts of waterborne organic silicon acid, 2.2 parts of thickener, 5.5 parts of hydroxypropyl, isobutene 10 Part, 12 parts of carboxylic acid, 3.5 parts of film forming agent, 10 parts of lauryl sodium sulfate, 8 parts of diacetone alcohol, 45 parts of distilled water.
The invention also discloses the preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm After filter and package.
Step 5) in, temperature is 60-70 DEG C.
Embodiment 3:
A kind of heat sublimation stamp metal picture, the coating for setting by metallic plate and thereon is constituted, by following parts by weight Each group is grouped into:15 parts of cellulose acetate, 3 parts of zinc oxide, 11 parts of hyaluronic acid, 6 parts of bentonite powder, linolenic oil 6 part, point 8 parts of powder, 5 parts of waterborne organic silicon acid, 2 parts of thickener, 4 parts of hydroxypropyl, 6 parts of isobutene, 11 parts of carboxylic acid, 3 parts of film forming agent, 12 8 parts of sodium alkyl sulfate, 6 parts, distilled water 20-45 parts of diacetone alcohol.
The invention also discloses the preparation method of heat sublimation stamp metal picture, comprise the following steps:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxyl Propyl group, isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is less than 60mm After filter and package.
Step 5) in, temperature is 60-70 DEG C.

Claims (3)

1. a kind of heat sublimation stamp metal picture, it is characterised in that:The coating for setting by metallic plate and thereon is constituted, described painting Layer is grouped into by each group of following parts by weight:Cellulose acetate 5-10 parts, zinc oxide 1.5-3.6 parts, hyaluronic acid 10-11.5 Part, 5.5-6.5 parts of bentonite powder, linolenic oil 4.5-6.6 parts, dispersant 5.5-8.8 parts, waterborne organic silicon acid 3.4-5.5 Part, thickener 0.5-2.2 parts, hydroxypropyl 3.5-5.5 parts, isobutene 5-10 parts, carboxylic acid 9-12 parts, film forming agent 1.2-3.5 parts, ten Sodium dialkyl sulfate 5.5-10 parts, diacetone alcohol 3-8 parts, distilled water 20-45 parts.
2. a kind of preparation method of heat sublimation stamp metal picture as claimed in claim 1, it is characterised in that:Including following step Suddenly:
1) waterborne organic silicon acid, lauryl sodium sulfate are prepared with distilled water in advance;
2) by waterborne organic silicon acid, lauryl sodium sulfate, dispersant, cellulose acetate addition scuffing of cylinder bore, it is uniformly dispersed;
3) under stirring, zinc oxide, hyaluronic acid, bentonite powder are sequentially added, at a high speed dispersion 15-20min;
4) twice are ground with sand mill, fineness is less than stand-by during 60mm;
5) by step 4) in during the material that obtains adds material-compound tank, under stirring, by linolenic oil, thickener, hydroxypropyl, Isobutene, carboxylic acid, film forming agent, diacetone alcohol are added, and twice are ground with sand mill after stirring, and fineness is filtered less than after 60mm Packaging.
3. the preparation method of heat sublimation stamp metal picture as claimed in claim 2, it is characterised in that:Step 5) in, temperature It is 60-70 DEG C.
CN201611158930.5A 2016-12-15 2016-12-15 Thermal sublimation printed metal photo Pending CN106700693A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611158930.5A CN106700693A (en) 2016-12-15 2016-12-15 Thermal sublimation printed metal photo

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611158930.5A CN106700693A (en) 2016-12-15 2016-12-15 Thermal sublimation printed metal photo

Publications (1)

Publication Number Publication Date
CN106700693A true CN106700693A (en) 2017-05-24

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CN201611158930.5A Pending CN106700693A (en) 2016-12-15 2016-12-15 Thermal sublimation printed metal photo

Country Status (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1990119A (en) * 2005-12-29 2007-07-04 海宁市红狮电梯装饰有限公司 Stainless steel plate surface treatment, pattern heat transfer process and plate made thereby
CN102009539A (en) * 2009-09-07 2011-04-13 陈为江 Production process and special equipment for novel metal photograph
CN102089155A (en) * 2009-04-24 2011-06-08 韩国科林株式会社 Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor
CN102310673A (en) * 2011-07-01 2012-01-11 淮安市映像数码科技有限公司 Method for transferring large-breadth full-color pattern image on metal plate
CN103809400A (en) * 2012-11-09 2014-05-21 富士施乐株式会社 Image transfer sheet

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1990119A (en) * 2005-12-29 2007-07-04 海宁市红狮电梯装饰有限公司 Stainless steel plate surface treatment, pattern heat transfer process and plate made thereby
CN102089155A (en) * 2009-04-24 2011-06-08 韩国科林株式会社 Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor
CN102009539A (en) * 2009-09-07 2011-04-13 陈为江 Production process and special equipment for novel metal photograph
CN102310673A (en) * 2011-07-01 2012-01-11 淮安市映像数码科技有限公司 Method for transferring large-breadth full-color pattern image on metal plate
CN103809400A (en) * 2012-11-09 2014-05-21 富士施乐株式会社 Image transfer sheet

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Application publication date: 20170524