CN104449042A - Weak solvent ink-jet ink - Google Patents
Weak solvent ink-jet ink Download PDFInfo
- Publication number
- CN104449042A CN104449042A CN201410672736.3A CN201410672736A CN104449042A CN 104449042 A CN104449042 A CN 104449042A CN 201410672736 A CN201410672736 A CN 201410672736A CN 104449042 A CN104449042 A CN 104449042A
- Authority
- CN
- China
- Prior art keywords
- ink
- ether
- resin emulsion
- polyurethane resin
- jet print
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002904 solvent Substances 0.000 title claims abstract description 39
- 239000000839 emulsion Substances 0.000 claims abstract description 59
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 34
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003960 organic solvent Substances 0.000 claims abstract description 14
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 13
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 8
- 230000007613 environmental effect Effects 0.000 claims abstract description 7
- 230000003750 conditioning effect Effects 0.000 claims abstract description 6
- 238000002372 labelling Methods 0.000 claims abstract description 4
- 239000003755 preservative agent Substances 0.000 claims abstract description 3
- 230000002335 preservative effect Effects 0.000 claims abstract description 3
- -1 ether acetates Chemical class 0.000 claims description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 239000000975 dye Substances 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000006096 absorbing agent Substances 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 238000003384 imaging method Methods 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical group COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 4
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical class CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical class C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000000992 solvent dye Substances 0.000 claims description 4
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 2
- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 claims description 2
- MWGRRMQNSQNFID-UHFFFAOYSA-N 1-(2-methylpropoxy)propan-2-ol Chemical compound CC(C)COCC(C)O MWGRRMQNSQNFID-UHFFFAOYSA-N 0.000 claims description 2
- KTSVVTQTKRGWGU-UHFFFAOYSA-N 1-[2-[2-(2-butoxyethoxy)ethoxy]ethoxy]butane Chemical compound CCCCOCCOCCOCCOCCCC KTSVVTQTKRGWGU-UHFFFAOYSA-N 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 2
- KIAMPLQEZAMORJ-UHFFFAOYSA-N 1-ethoxy-2-[2-(2-ethoxyethoxy)ethoxy]ethane Chemical compound CCOCCOCCOCCOCC KIAMPLQEZAMORJ-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 claims description 2
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- 241000723346 Cinnamomum camphora Species 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical class CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- 150000008360 acrylonitriles Chemical class 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 230000001680 brushing effect Effects 0.000 claims description 2
- 229940043232 butyl acetate Drugs 0.000 claims description 2
- 229960000846 camphor Drugs 0.000 claims description 2
- 229930008380 camphor Natural products 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 230000000855 fungicidal effect Effects 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 2
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 2
- 230000035800 maturation Effects 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 2
- 239000001327 prunus amygdalus amara l. extract Substances 0.000 claims description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical class O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 2
- 150000003873 salicylate salts Chemical class 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 2
- 150000003918 triazines Chemical class 0.000 claims description 2
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 claims description 2
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000007641 inkjet printing Methods 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 67
- 239000004744 fabric Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007592 spray painting technique Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- QPQKUYVSJWQSDY-UHFFFAOYSA-N 4-phenyldiazenylaniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=CC=C1 QPQKUYVSJWQSDY-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000004696 coordination complex Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- WSPPHHAIMCTKNN-UHFFFAOYSA-N 1-amino-4-hydroxy-2-methoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(O)=C3C(=O)C2=C1 WSPPHHAIMCTKNN-UHFFFAOYSA-N 0.000 description 1
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 description 1
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- ROPYWXVRNREIQD-UHFFFAOYSA-N 2-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCC#N)CCOC(=O)C)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl ROPYWXVRNREIQD-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- SOFRHZUTPGJWAM-UHFFFAOYSA-N 3-hydroxy-4-[(2-methoxy-5-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound COc1ccc(cc1N=Nc1c(O)c(cc2ccccc12)C(=O)Nc1cccc(c1)[N+]([O-])=O)[N+]([O-])=O SOFRHZUTPGJWAM-UHFFFAOYSA-N 0.000 description 1
- FWTBRYBHCBCJEQ-UHFFFAOYSA-N 4-[(4-phenyldiazenylnaphthalen-1-yl)diazenyl]phenol Chemical compound C1=CC(O)=CC=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 FWTBRYBHCBCJEQ-UHFFFAOYSA-N 0.000 description 1
- TUDSTYFYBDBDRC-UHFFFAOYSA-N C=1C=CC=CC=1P(=O)C(=O)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(=O)C(=O)C1=CC=CC=C1 TUDSTYFYBDBDRC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- ORFCMOKLZKHQKR-UHFFFAOYSA-N S(=O)(=O)(O)C1=C(C=2C(C3=CC=CC=C3SC=2C=C1)=O)OCCC Chemical compound S(=O)(=O)(O)C1=C(C=2C(C3=CC=CC=C3SC=2C=C1)=O)OCCC ORFCMOKLZKHQKR-UHFFFAOYSA-N 0.000 description 1
- 239000004283 Sodium sorbate Substances 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
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- YCUVUDODLRLVIC-UHFFFAOYSA-N Sudan black B Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 YCUVUDODLRLVIC-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical class C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HADJHXHBAFQEAO-UHFFFAOYSA-L disodium 4-[(1-amino-8-oxido-7-phenyldiazenyl-3,6-disulfonaphthalen-2-yl)diazenyl]-N-[4-[(2,4-diaminophenyl)diazenyl]phenyl]benzenecarboximidate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(NC(=O)c3ccc(cc3)N=Nc3c(N)c4c(O)c(N=Nc5ccccc5)c(cc4cc3S([O-])(=O)=O)S([O-])(=O)=O)cc2)c(N)c1 HADJHXHBAFQEAO-UHFFFAOYSA-L 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- WTIFIAZWCCBCGE-UUOKFMHZSA-N guanosine 2'-monophosphate Chemical compound C1=2NC(N)=NC(=O)C=2N=CN1[C@@H]1O[C@H](CO)[C@@H](O)[C@H]1OP(O)(O)=O WTIFIAZWCCBCGE-UUOKFMHZSA-N 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention relates to weak solvent ink-jet ink. The weak solvent ink-jet ink at least comprises the following components in percentages by weight: 0.2-12% of a coloring agent, 0-5% of a dispersing agent, 1-10% of modified acrylic resin emulsion and/or modified polyurethane resin emulsion in solid content, 0.1-3% of an ultraviolet light absorber, 0-2% of a surface active agent, 0-2% of a pH conditioning agent, 0.1-0.5% of an antibacterial preservative and the balance of an organic solvent. The ink-jet ink accords with the standard of Technical Requirement for Environmental Labeling Products Ink for Ink Jet Printing (HJ567-2010); the technical problem that images cannot be clearly formed on a smooth printed surface in the prior art is solved, and the drying rate of the ink-jet ink is quickened.
Description
Technical field
The present invention relates to a kind of ink for ink-jet print, be specifically related to a kind of ink for ink-jet print of printer.
Background technology
Ink for ink-jet print is broadly divided into water-base ink, solvent-based inks and Weak solvent ink according to the difference of its Main Components.
The main ingredient of solvent-based inks is organic solvent, the general solvent all adopting ester and ketone, first carry out swelling to medium in the process be combined with medium, then merge, tinting material in ink and ground are combined closely, so solvent-based inks does not require that medium is covered with coating, and its evaporation rate is fast, can meet the requirement of flying print.Because volatilizable organic content is high in ink, the maximum problem of solvent-based inks is exactly not environmentally.
Weak solvent ink is compared with solvent-based inks, and maximum advantage is the friendly to environment, is mainly reflected in the minimizing of volatilizable thing VOC and no longer adopts many toxic organic solvents, no longer needing ventilation plant at the production plant of Weak solvent spray drawing machine; Weak solvent ink is an environmental protection of solvent-based inks " version ".In the production process of ink, Weak solvent ink is except selecting environmentally friendly solvent, compare with solvent-based inks and also proposed two higher requirements: one is must control better to the point of ink is loose to realize high-precision output, another one is exactly that the filtering accuracy of ink production process requires higher.
The principal feature of water-base ink is with low cost, not pollution, bright in luster, but because the evaporation rate of its main ingredient water is slow, not easily dry and by Absorption of Medium (it requires that medium has special coating) by the picture of water-base ink ink-jet, its be mainly used in paper and various fiber-like (cloth) be ground, on cated medium.
Weak solvent ink is compared with water-base ink, and Weak solvent ink, while the advantage that the picture precision maintaining water-base ink making is high, overcomes again the picture of water-base ink to the harshness of ground and making and cannot be applied in the shortcomings such as outdoor.Therefore, Weak solvent ink, between water-based and solvent-based inks, takes into account both advantages.
Weak solvent ink for ink-jet print can be accomplished to exempt from coating and print in some material, or adopts the means such as printer heating can in order to avoid coating prints, but for some smooth surfaces, only helpless with ink, ink can be deposited in together, can not blur-free imaging.
Summary of the invention
Printing smooth surface for prior art can not the defect of blur-free imaging, as: the enamelled paper, spray painting cloth etc. of polished glazed tile, glass, plastics, the cloth having water-proof coating, printed coating, the present invention devises the technical scheme solved the problems of the technologies described above; The technical program meets the standard of the HJ 567-2010 " environmental labelling product technical requirements, ink for ink-jet print " that on June 1st, 2010 implements.
Meanwhile, present invention also offers the preparation method of the technical program.
The bulk solvent of the technical program adopts preferred organic solvent, safety non-toxic, and the volatile dry time is quicker than water-based jet ink.
The water-soluble dye that the technical program adopts, solvent dye can dissolve in organic solvent equably.
Modified polyurethane resin emulsion and modified acrylic resin emulsion, have alcohol dissolubility, fat-soluble, alcohol water two dissolubility, water miscible in prior art, the technical program adopts water miscible; The resin emulsion overcoming alcohol ester dissolubility needs special organic solvent, and not environmentally defect odorous; Meanwhile, water miscible modified polyurethane resin emulsion and modified acrylic resin emulsion, also have solvent type group, can be dissolved in the preferred organic solvent of this programme; As for the content of the deionized water in resin emulsion, its maximum is no more than 20% of ink system gross weight, therefore or not impact very little on the overall performance impact of ink system; Utilize the film-forming properties of resin emulsion, water-fast chemical reagent resistance, cementability, rub resistance, the transparency, solve prior art print smooth surface can not the technical problem of blur-free imaging; Accelerate ink for ink-jet print rate of drying; Some resin emulsions also have resistant to elevated temperatures performance, and ink-jet products can be high temperature resistant.
The insoluble tinting material of solvent of the technical program, can be evenly dispersed in ink system with dispersion agent.
The resistance to optical issue of this programme ink for ink-jet print, is solved by the absorption UV-light of resin emulsion, the photostabilization of tinting material and interpolation UV light absorber.
The physical and chemical index of this programme ink for ink-jet print, is realized by the comprehensive action of tensio-active agent and PH conditioning agent, anticorrosion and bactericidal agent, each component.
Technical scheme of the present invention is: Weak solvent ink for ink-jet print, and weight percent meter has component at least, and resin emulsion is by solid content:
Tinting material 0.2-12%,
Dispersion agent 0-5%,
Modified acrylic resin emulsion and/or modified polyurethane resin resin emulsion 1-10%,
UV light absorber 0.1-3%,
Tensio-active agent 0-2%,
PH conditioning agent 0-2%,
Fungicidal preservative 0.1-0.5%,
Surplus is organic solvent;
As preferably: the conven-tional adjuvants adding its performance of raising of any technology maturation.
Described tinting material is: at least one in water-soluble dye, solvent dye, dispersed dye, mineral dye, pigment dyestuff, metalluster pigment; The particle diameter <100 nanometer of the insoluble tinting material of organic solvent.
As preferably: water-soluble dye is selected from: described fast light 6 grades and above water-soluble dye, including but not limited to light fastness 6 grades used in prior art and above water-soluble dye.The direct Huang 132 of such as C.I., C.I. be Huang 86, C.I. directly Huang 17, C.I. Reactive Red 23, C.I. direct yellow 142 directly; The water-soluble metal complex dyestuff of now commercially available light fastness 6-7 level and alcohol water two solube metallic complex dyestuff.Such as have C.I. solvent yellow 21, C.I. solvent red 8,122, C.I. solvent blue 70, the water-soluble metal complex dyestuff of C.I. solvent black 27,55,34 modification and alcohol water two solube metallic complex dyestuff.Also has C.I. directly Huang 106, C.I. directly red 80, C.I. the direct black N-BN of direct black 166(), the gorgeous blue FF2GL of the direct sun-proof of the direct blue 106(of C.I.), the direct blue 108(direct fast blue FFRL of C.I.), at least one in C.I. Xylene Red 336 grade.
As preferably: solvent dye is selected from: C.I. solvent yellow 14,16,18,19,21,56,93,98,163,185; C.I. solvent orange 45,60,62,63,86; C.I. solvent red 8,60,62,63,86,25,30,49,52,109,111,135,146,149,179,196,197,207,242; C.I. solvent purple 8,13,31; C.I. solvent blue 35,36,38,59,63,78,97,104,122; C.I. solvent green 3,5,20,28; C.I. at least one in solvent black 3 etc.
As preferably: nano metal colour lustre pigments: it is composite that the nano-metal particles such as metallic copper, metallic aluminium, metallic zinc, metallic tin carry out different ratios; Metal particle is preferably preferred in 50-80 nanometer; Mineral dye selective oxidation iron oxide red, iron oxide yellow, group's indigo plant, carbon black, Rutile type Titanium Dioxide etc.; Pigment dyestuff is selected: red C.I. Pigment Red 112,122,188,184,179; Yellow: C.I. pigment yellow 17,83,14 etc.; Blue: C.I. pigment Blue 15: 3,56,60,63 etc.; Orange: C.T. pigment Orange 13; Green: C.I. pigment Green 7; Purple: at least one in C.I. pigment violet 1,23 etc.
As preferably: C.I. EX-SF DISPERSE BLUE EX-SF 300 14,20,56,60,72,73,79,87,93,165,183,284 selected by dispersed dye, one or more the mixing of 301,359 grades; C.I. one or more the mixing such as DISPERSE YELLOW 5,7,23,26,42,50,54,64,79,82,104,114,124,153:1; C.I. Disperse Red 4, one or more the mixing of 9,50,53,54,60,72,73,74,79,82,86,92,153,167,177,278 grades; C.I. DISPERSE ORANGE 30 200 73, one or more the mixing of 30,36 grades; Particle Size of Disperse Dyes <100 nanometer.
Described dispersion agent is: organic high molecular polymer; As preferably: described organic high molecular polymer is at least one in BYK-2163, BYK-2164, BYK-180, BYK-184, BYK-190, BYK-2012, BYK-2020 dispersion agent of Bi Ke chemistry.
As preferably: described modified acrylic resin emulsion is selected from: water miscible, comprising is the Emulsion acrylic resin of at least one modification in epoxy resin, organosilicon, organic fluorine, urethane resin; Particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming; Modified polyurethane resin emulsion tree and modified acroleic acid fat liquor addition amount to preferred at 3-8%.
As preferably: described modified polyurethane resin emulsion is selected from: water miscible, comprise epoxy resin-polyurethane resin emulsion, epoxy resin and acrylic ester-ester-polyurethane resin emulsion, Viscotrol C-acrylate-polyurethane resin emulsion, acrylate-polyurethane resin emulsion, polysiloxane-polyurethane resin emulsion, organic silicon-acrylate-ester-polyurethane resin emulsion, fluosilicic-ester-polyurethane resin emulsion, fluoro-ester-polyurethane resin emulsion, aliphatic polyurethane resin emulsion, polyester-urethane resin emulsion, polyether-polyurethane resin emulsion, at least one in polyurea-polyuretahne resin emulsion etc., particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming, modified polyurethane resin emulsion tree and modified acroleic acid fat liquor addition amount to preferred at 3-8%.
As preferably: described organic solvent is: to be selected from monohydroxy-alcohol, dibasic alcohol, alcohol ether, ester class, ketone, ether acetates at least two or more mixture; Monohydroxy-alcohol is selected from Virahol, ethanol, isopropylcarbinol; Dibasic alcohol is selected from glycol ether, propylene glycol, butyleneglycol, triglycol, Tetraglycol 99, polyoxyethylene glycol, polypropylene glycol, glycerine, 1,2-PD, BDO, 1, ammediol, BDO, 1,3-PD, 1,2-hexylene glycol, the polyvalent alcohols such as 2-methyl-2,4-pentanediol; Alcohol ether is selected from diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propandiol butyl ether, propylene glycol isobutyl ether, diethylene glycol monobutyl ether, diethylene glycol monomethyl ether, the only butyl ether of Diethylene Glycol, triethylene glycol monomethyl ether, Triethylene glycol ethyl ether, TRIGLYME, triethylene glycol diethyl ether, triethylene glycol dibutyl ether, tetraethyleneglycol dimethyl ether, TEG diethyl ether, monoethylene glycol and polyoxyethylene glycol phenyl ether, MPG and polypropylene glycol phenyl ether; Ether acetates is selected from 1-Methoxy-2-propyl acetate, dipropylene glycol methyl ether acetate, Dipropylene glycol mono-n-butyl Ether adipic acid ester; Ketone is selected from 2-Pyrrolidone, METHYLPYRROLIDONE, hexone; Ester class is selected from methyl acetate, ethyl acetate, isobutyl acetate, butylacetate; According to range of application and the appropriate composite organic solvent of environment for use.
As preferably: described UV light absorber is bitter almond oil camphor and derivative (st-yrax, benzoin dimethylether, Benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether), benzil class (diphenylethan, α, alpha, alpha-dimethyl oxygen base-α-phenyl acetophenone), alkylbenzene ketone (α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones), acyl group phosphorous oxides (aroyl phosphine oxide, two benzoylphenyl phosphine oxide), benzophenone (benzophenone, 2, 4-dihydroxy benaophenonel, Michler's keton), thioxanthones (sulfo-propoxy-thioxanthone, isopropyl thioxanthone), dibenzoyl, salicylate class, group-substituted acrylonitrile, triazines, hindered amines etc.
Further preferably: use two or more above-mentioned UV light absorber composite, its performance is better than the light trigger that any one is used alone.
As preferably: above-mentioned tensio-active agent, select the raw material of safety non-toxic; Such as: nonionogenic tenside, anion surfactant, amphoterics; Nonionogenic tenside, is preferably polyoxyethylene aliphatic alcohol ether (AEO), polyoxyethylene fatty acid ester (AE), polyol ester, sucrose ester, alcohol ether carboxylate (AEC-H), alkyl polyglycoside (APG); Anion surfactant, is preferably alcohol ether carboxylate surfactant (AEC), sulphosuccinates, secondary alkyl sulfonate (MES), polyoxyethylene alkyl ether sulfate salt (AES), a-alkenyl sulphonate; Amphoterics, is preferably betaine type amphoteric surfac-tant, imidazoline type amphoterics.
Further preferably: use two or more above-mentioned surfactant compound, its performance is better than the tensio-active agent that any one is used alone.
As preferably: above-mentioned PH conditioning agent, select the raw material of safety non-toxic; PH conditioning agent is selected from citric acid, Tripotassium Citrate, lactic acid, oxysuccinic acid, Trisodium Citrate, hydrochloric acid, Potassium Hydrogen Phthalate, potassium hydroxide, sodium hydroxide, quaternary ammonium hydroxide, such as tetramethyl-ammonium; Carbonate: such as salt of wormwood, sodium carbonate, Quilonum Retard; Phosphoric acid salt; N-methyl-2-pyrrolidone; Ethamine, diethanolamine, trolamine, ammoniacal liquor etc.
As preferably: anticorrosion and bactericidal agent selects the raw material of safety and environmental protection.Such as sodium sorbate, potassium sorbate, isothiazolinone, BIT class etc.
Ink for ink-jet print of the present invention, is characterized in that: preparation method
(1) prepare each component of ink by formula, stir, grinding machinery 500-3000 rev/min of speed lapping 1-3 hour; Detection of particles fineness D90 < 120 nanometer, obtains ink mixture.
(2) ink mixture leaves standstill slaking in-7 days in 12 hours.
(3) the every physical and chemical index of ink mixture is detected by QB/T2730.1-2013.
(4) successively with 1 micron, 0.45 micron, 0.22 micron membrane filter filtration, finished product is obtained.
Ink for ink-jet print of the present invention, is characterized in that: be printed on without in coating and non-print coating media.Such as have: the enamelled paper, spray painting cloth etc. of polished glazed tile, glass, plastics, the cloth having water-proof coating, printed coating.
Ink for ink-jet print of the present invention, is characterized in that: be applied to digital printing, outdoor air brushing, ceramic tile wallpaper, glass plastic, hot transfer ink jet etc.
Ink for ink-jet print of the present invention, both can use the printer of solvent-based inkjet, also can use the printer of water based ink jet ink.
Significant advantage of the present invention and outstanding effect are:
1. the selected various starting material of the present invention, ink for ink-jet print is environmental protection odorlessness when preparing and use, safety non-toxic, meets HJ 567-2010 " environmental labelling product technical requirements, the ink for ink-jet print " standard implemented on June 1st, 2010.
2. the present invention selects Weak solvent system, improves the rate of drying of ink for ink-jet print, prints smooth surface, as: polished glazed tile, glass, plastics, there is the ability of the enamelled paper of the cloth of water-proof coating, printed coating, spray painting cloth etc. to strengthen further.
3. the present invention selects modified acrylic resin emulsion and modified polyurethane resin emulsion as ink for ink-jet print component, utilize the film-forming properties of resin emulsion, cementability, water-fast chemical reagent resistance, rub resistance, the transparency, solve prior art print smooth surface can not the technical problem of blur-free imaging; Some resin emulsions also have resistant to elevated temperatures performance, and ink-jet products can be high temperature resistant.
Embodiment
Embodiment is the detailed explaination to foregoing invention content, but can not be interpreted as that embodiment is the restriction to summary of the invention.
Table 1 water-soluble dye ink for ink-jet print is filled a prescription: modified polyurethane resin emulsion measures with solid content 33.3%
Table 2 solvent-based inkjet ink set: modified polyurethane resin emulsion measures with solid content 33.3%, modified acrylic resin emulsion measures with solid content 50%
Table 3 Disperse dye ink-jet ink formula: modified polyurethane resin emulsion measures with solid content 33.3%, modified acrylic resin emulsion measures with solid content 50%
Table 4 pigment dyestuff ink for ink-jet print is filled a prescription: modified polyurethane resin emulsion measures with solid content 33.3%, and modified acrylic resin emulsion measures with solid content 50%
Embodiment 16-19: ink on a variety of media print performance detects
Detection method: the embodiment ink of preparation and comparative example ink are loaded in improved Epson me1+ ink-cases of printers, is printed on various media as described below, observes and evaluates printing effect, and observes evaluation rate of drying.
Evaluate: with clear A, more clear B, unintelligible C, evaluate printing effect; With fast A, very fast B, slow C, evaluate rate of drying:
Table 5 detected result
As can be seen here, due to the characteristic feature of Weak solvent ink for ink-jet print of the present invention, improve the rate of drying of ink for ink-jet print, effect and the rate of drying of spray ink Printing of the present invention are better than prior art.
Claims (8)
1. Weak solvent ink for ink-jet print, weight percent meter has component at least: tinting material 0.2-12%, dispersion agent 0-5%, modified acrylic resin emulsion and/or modified polyurethane resin resin emulsion are by solid content 1-10%, UV light absorber 0.1-3%, tensio-active agent 0-2%, PH conditioning agent 0-2%, fungicidal preservative 0.1-0.5%, surplus is organic solvent; Ink for ink-jet print meets HJ 567-2010 " environmental labelling product technical requirements, ink for ink-jet print " standard; Solve prior art print smooth surface can not the technical problem of blur-free imaging; Accelerate ink for ink-jet print rate of drying;
Wherein, described tinting material is: at least one in water-soluble dye, solvent dye, dispersed dye, mineral dye, pigment dyestuff, metalluster pigment; The particle diameter <100 nanometer of the insoluble tinting material of organic solvent;
Described dispersion agent is: organic high molecular polymer;
Described modified acrylic resin emulsion is selected from: water miscible, comprises the Emulsion acrylic resin of at least one modification in epoxy resin, organosilicon, organic fluorine, urethane resin; Particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming;
Described modified polyurethane resin emulsion is selected from: water miscible, comprise epoxy resin-polyurethane resin emulsion, epoxy resin and acrylic ester-ester-polyurethane resin emulsion, Viscotrol C-acrylate-polyurethane resin emulsion, acrylate-polyurethane resin emulsion, polysiloxane-polyurethane resin emulsion, organic silicon-acrylate-ester-polyurethane resin emulsion, fluosilicic-ester-polyurethane resin emulsion, fluoro-ester-polyurethane resin emulsion, aliphatic polyurethane resin emulsion, polyester-urethane resin emulsion, polyether-polyurethane resin emulsion, at least one in polyurea-polyuretahne resin emulsion, particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming,
Described organic solvent is: to be selected from monohydroxy-alcohol, dibasic alcohol, alcohol ether, ester class, ketone, ether acetates at least two or more mixture.
2. ink for ink-jet print according to claim 1, is characterized in that: monohydroxy-alcohol is selected from Virahol, ethanol, isopropylcarbinol; Dibasic alcohol is selected from glycol ether, propylene glycol, butyleneglycol, triglycol, Tetraglycol 99, polyoxyethylene glycol, polypropylene glycol, glycerine, 1,2-PD, BDO, 1, ammediol, BDO, 1,3-PD, 1,2-hexylene glycol, the polyvalent alcohols such as 2-methyl-2,4-pentanediol; Alcohol ether is selected from diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propandiol butyl ether, propylene glycol isobutyl ether, diethylene glycol monobutyl ether, diethylene glycol monomethyl ether, the only butyl ether of Diethylene Glycol, triethylene glycol monomethyl ether, Triethylene glycol ethyl ether, TRIGLYME, triethylene glycol diethyl ether, triethylene glycol dibutyl ether, tetraethyleneglycol dimethyl ether, TEG diethyl ether, monoethylene glycol and polyoxyethylene glycol phenyl ether, MPG and polypropylene glycol phenyl ether; Ether acetates is selected from 1-Methoxy-2-propyl acetate, dipropylene glycol methyl ether acetate, Dipropylene glycol mono-n-butyl Ether adipic acid ester; Ketone is selected from 2-Pyrrolidone, METHYLPYRROLIDONE, hexone; Ester class is selected from methyl acetate, ethyl acetate, isobutyl acetate, butylacetate.
3. ink for ink-jet print according to claim 1, is characterized in that: described organic high molecular polymer is at least one in BYK-2163, BYK-2164, BYK-180, BYK-184, BYK-190, BYK-2012, BYK-2020 dispersion agent of Bi Ke chemistry.
4. ink for ink-jet print according to claim 1, is characterized in that: UV light absorber is at least one in bitter almond oil camphor and derivative, benzil class, alkylbenzene ketone, benzophenone, acyl group phosphorous oxides, salicylate class, group-substituted acrylonitrile, triazines, hindered amines, dibenzoyl.
5. ink for ink-jet print according to claim 1, is characterized in that: the conven-tional adjuvants adding its performance of raising of any technology maturation.
6. the ink for ink-jet print described in claim 1-5, is characterized in that: preparation method
(1) prepare each component of ink by formula, stir, grinding machinery 500-3000 rev/min of speed lapping 1-3 hour; Detection of particles fineness D90 < 120 nanometer, obtains ink mixture;
(2) ink mixture leaves standstill slaking in-7 days in 12 hours;
(3) the every physical and chemical index of ink mixture is detected by QB/T2730.1-2013;
(4) successively with 1 micron, 0.45 micron, 0.22 micron membrane filter filtration, finished product is obtained.
7. the ink for ink-jet print described in claim 1,5, is characterized in that: be printed on without in coating and non-print coating media.
8. the ink for ink-jet print described in claim 1,5, is characterized in that: be applied to digital printing, outdoor air brushing, ceramic tile wallpaper, glass plastic, hot transfer ink jet.
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| CN105567015A (en) * | 2016-03-22 | 2016-05-11 | 珠海华彩打印耗材有限公司 | Weak solvent white ink for dark-color leather color printing |
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| CN108909224A (en) * | 2018-06-01 | 2018-11-30 | 上海泰画服饰铺料有限公司 | A kind of boiling hot target manufacture craft of digital ink-jet |
| CN109306208A (en) * | 2017-07-27 | 2019-02-05 | 汪国军 | Connection material and its application |
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| CN105567015A (en) * | 2016-03-22 | 2016-05-11 | 珠海华彩打印耗材有限公司 | Weak solvent white ink for dark-color leather color printing |
| CN105778431B (en) * | 2016-03-31 | 2019-01-08 | 浙江工业大学 | A kind of thermally conductive slurry and its preparation and application |
| CN105778431A (en) * | 2016-03-31 | 2016-07-20 | 浙江工业大学 | Thermally conductive slurry as well as preparation method and application thereof |
| CN109996849A (en) * | 2016-09-26 | 2019-07-09 | 图像电子公司 | The ink-jet of construction material is decorated |
| CN109306208A (en) * | 2017-07-27 | 2019-02-05 | 汪国军 | Connection material and its application |
| CN113031411A (en) * | 2017-08-29 | 2021-06-25 | 邯郸汉光办公自动化耗材有限公司 | Multifunctional color toner, preparation method thereof and thermal transfer printing method |
| CN108909224A (en) * | 2018-06-01 | 2018-11-30 | 上海泰画服饰铺料有限公司 | A kind of boiling hot target manufacture craft of digital ink-jet |
| CN109371719A (en) * | 2018-10-11 | 2019-02-22 | 珠海佳印数码科技有限公司 | A kind of water-fastness digit printing weaving white ink and preparation method thereof |
| CN110183905A (en) * | 2019-06-19 | 2019-08-30 | 张小清 | A kind of scratch resistant water-based ink and preparation method thereof |
| CN110655830A (en) * | 2019-10-30 | 2020-01-07 | 珠海格美达科技有限公司 | Ink-jet printing ink and preparation method thereof |
| CN111662591A (en) * | 2020-07-16 | 2020-09-15 | 浙江龙游道明光学有限公司 | Preparation method of outdoor high-weather-resistance weak-solvent spray-painting ink |
| CN111662591B (en) * | 2020-07-16 | 2023-04-14 | 浙江龙游道明光学有限公司 | Preparation method of outdoor high-weather-resistance weak-solvent inkjet ink |
| CN112280379A (en) * | 2020-11-18 | 2021-01-29 | 梁贻波 | High-temperature-resistant ink composition and preparation method thereof |
| CN114701275A (en) * | 2022-03-16 | 2022-07-05 | 珠海天威新材料股份有限公司 | Digital printable water-coated film, ink, water transfer printing method and water transfer printing product |
| CN114701275B (en) * | 2022-03-16 | 2023-09-05 | 珠海天威新材料股份有限公司 | Digital printing water coating film, ink, water transfer printing method and water transfer printing product |
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Effective date of registration: 20190726 Address after: Two Blocks No. 766 Xianghua Road, Chedun Town, Songjiang District, Shanghai, 20111 Patentee after: Shanghai super color Ink Co., Ltd. Address before: 646000 No. 6, 9th floor, Dongfeng Street, Shidong Town, Longmatan District, Luzhou City, Sichuan Province Patentee before: Lu Jilie |