CN112280379A - High-temperature-resistant ink composition and preparation method thereof - Google Patents
High-temperature-resistant ink composition and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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Abstract
The invention belongs to the technical field of printing ink, and particularly relates to a high-temperature-resistant ink composition and a preparation method thereof, wherein the high-temperature-resistant ink composition comprises the following raw materials in parts by weight: 80-150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10-20 parts of polyaldehyde calcium alginate coated titanium dioxide, 4-8 parts of glass fiber short fibers, 4-6 parts of mica powder and 3-5 parts of sepiolite; the organic fluorine-silicon/acrylate copolymer emulsion is obtained by copolymerizing a silane coupling agent, hexafluorobutyl methacrylate and an acrylic monomer; the polyaldehyde calcium alginate coated titanium dioxide is obtained by coating polyaldehyde calcium alginate on the surface of titanium dioxide; the length-diameter ratio of the glass fiber short fibers is 5: 1-10: 1, glass fiber with the length of 100-500 μm. The glass fiber short fiber is glass fiber short fiber with nano silicon dioxide adsorbed on the surface; the nano silicon dioxide is combined with the surface of the glass fiber short fiber through a silane coupling agent KH-550. The product obtained by the invention has good high temperature resistance and can be firmly combined on the surface of the base material.
Description
Technical Field
The invention belongs to the technical field of printing ink. And more particularly, to a high temperature resistant ink composition and a method of preparing the same.
Background
Ink is an important material for printing packaging materials, which represents patterns and characters on a support by printing, and includes a main component and an auxiliary component, which are uniformly mixed and repeatedly rolled to form a viscous colloidal fluid. The printing ink is a slurry colloid formed by uniformly dispersing and mixing materials such as pigment, connecting material, auxiliary agent, solvent and the like. The vehicle for solvent-based inks is composed of a solid resin and a large amount of volatile organic solvent. After the solid resin is dissolved in the solvent, the pigment is uniformly dispersed in the binder, and after the ink is printed on a printing medium, the solvent is quickly volatilized and a film is dried. For inks, it is generally desirable to use printing characteristics that produce a result on the print medium that simultaneously exhibits a pleasing aesthetic effect and long-lasting retention. Examples of such printing characteristics include print quality such as optical density, chroma, etc., and durability such as water resistance, discoloration resistance, acid and alkali resistance.
However, in the prior art, the printing ink used for printing has poor light resistance and high temperature resistance, poor chemical stability, poor adhesive force, easy shedding of pigment and limited applicable materials. Meanwhile, in order to ensure the printing quality, a large amount of solvents with strong toxicity, such as benzenes, ketones and the like, are used in the preparation process, for example, hydrocarbon solvents, such as organic solvents, aromatic solvents, such as xylene, ethylbenzene and the like, ester solvents, such as ethyl acetate and the like, in the production process of the ink, when the solvents are not properly treated, the solvents are easy to damage the bodies of production workers, when the ink is printed, the volatilization of the toxic solvents in the ink can also have adverse effects on the bodies of the printing workers, and harmful substances often remain in the dried ink, so that the requirements of environmental protection are difficult to obtain, and the body health of users of the printed products and the polluted environments of different degrees are certainly influenced.
Therefore, it is one of the technical problems to be solved by those skilled in the art that how to develop an ink that can not only prevent pollution and ensure environmental sanitation, but also exhibit good high temperature resistance, while ensuring the quality of the ink.
Disclosure of Invention
The invention aims to solve the technical problem of overcoming the defect and the defect of insufficient high-temperature resistance of the existing printing ink and provides a high-temperature-resistant printing ink composition and a preparation method thereof.
The invention aims to provide a high-temperature-resistant ink composition.
The invention also aims to provide a preparation method of the high-temperature-resistant ink composition.
The above purpose of the invention is realized by the following technical scheme:
a high-temperature-resistant ink composition comprises the following raw materials in parts by weight:
80-150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10-20 parts of polyaldehyde calcium alginate coated titanium dioxide, 4-8 parts of glass fiber short fibers, 4-6 parts of mica powder and 3-5 parts of sepiolite;
the organic fluorine-silicon/acrylate copolymer emulsion is obtained by copolymerizing a silane coupling agent, hexafluorobutyl methacrylate and an acrylic monomer;
the polyaldehyde calcium alginate coated titanium dioxide is obtained by coating polyaldehyde calcium alginate on the surface of titanium dioxide;
the length-diameter ratio of the glass fiber short fibers is 5: 1-10: 1, glass fiber with the length of 100-500 μm.
According to the technical scheme, the organic fluorine-silicon/acrylate copolymer is used as matrix resin, the stability of a formed film can be effectively improved due to the introduction of Si-O bonds and C-F bonds, and the organic silicon molecular chain has good flexibility and can creep to a certain degree under a high-temperature condition to convert heat energy into kinetic energy of internal high-molecular motion and reduce the influence of temperature on a product to a certain degree;
in addition, due to the assistance of the glass fiber short fibers, when the flexible organic silicon molecular chain wriggles under the high-temperature condition, the glass fiber short fibers dispersed inside can be dragged to move, so that the heat energy is further converted into kinetic energy, and in addition, along with the further increase of the temperature, the breaking strength of the glass fiber short fibers is required to be overcome, so that the printing ink can be failed and cracked, and the high-temperature resistance of the product is effectively improved;
in addition, under the action of polyaldehyde calcium alginate, calcium ions can form a chelate structure with polyaldehyde alginic acid, the binding force among alginate chains is increased, the stability of a molecular structure is greatly improved, the mechanical property of a product is improved, and meanwhile, in the heating process, more energy needs to be consumed to destroy the structure, so that the original breaking mode of the fiber is changed, in addition, in the heating process, the calcium ions can catalyze the dehydration reaction of an active center of a system, so that the organic fluorine silicon/acrylate copolymer and polyaldehyde calcium alginate and other substances are pyrolyzed and dehydrated, a substance with higher stability is formed, and the high temperature resistance of the product is further improved.
Further, the glass fiber short fiber is a glass fiber short fiber with nano silicon dioxide adsorbed on the surface; the nano silicon dioxide is combined with the surface of the glass fiber short fiber through a silane coupling agent KH-550.
According to the technical scheme, the nano silicon dioxide is introduced to the surface of the glass fiber, so that the surface roughness of the glass fiber is effectively improved, and therefore, in the heating process, the flexible organic silicon molecular chain can more easily pull the glass fiber to move through the protrusions on the surface of the glass fiber, and heat energy is quickly converted into the internal kinetic energy of the molecular structure.
Further, the acrylic monomer includes: methyl methacrylate, butyl acrylate and acrylic acid.
A preparation method of a high-temperature-resistant ink composition comprises the following specific preparation steps:
preparing organic fluorine-silicon/acrylate copolymer emulsion:
uniformly dispersing an emulsifier, a silane coupling agent, hexafluorobutyl methacrylate, butyl acrylate and methyl methacrylate in water to obtain emulsion A;
uniformly mixing an emulsifier, methyl methacrylate, butyl acrylate, acrylic acid, water and a sodium bicarbonate solution, then dropwise adding an initiator, heating and stirring for reaction, then adding the emulsion A and the initiator, continuing heating and stirring for reaction, cooling, and discharging to obtain the organic fluorine-silicon/acrylate copolymer emulsion;
preparing the polyaldehyde calcium alginate coated titanium dioxide:
mixing sodium alginate and water for swelling, adding sodium periodate, heating, stirring for reaction, adding a calcium chloride solution, continuing heating, stirring for reaction, adding titanium dioxide, stirring uniformly, and spray-drying to obtain multi-aldehyde calcium alginate coated titanium dioxide;
preparation of a product:
according to the weight parts, 80-150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10-20 parts of polyaldehyde calcium alginate coated titanium dioxide, 4-8 parts of glass fiber short fibers, 4-6 parts of mica powder and 3-5 parts of sepiolite are taken in sequence, and after being uniformly dispersed, the high-temperature resistant ink composition is obtained after discharging and packaging.
Further, the specific preparation steps further comprise:
adsorbing nano silicon dioxide on the surface of the glass fiber short fiber:
dispersing the glass fiber short fiber in absolute ethyl alcohol, adding a silane coupling agent KH-550 and nano silicon dioxide, heating, stirring, reacting, filtering, washing and drying to obtain the glass fiber short fiber with the nano silicon dioxide adsorbed on the surface.
Further, the emulsifier is any one of emulsifiers OP-10, Tween-60 and span-80.
Further, the initiator is ammonium persulfate or potassium persulfate solution.
Detailed Description
The present invention is further illustrated by the following specific examples, which are not intended to limit the invention in any way. Reagents, methods and apparatus used in the present invention are conventional in the art unless otherwise indicated.
Unless otherwise indicated, reagents and materials used in the following examples are commercially available.
Example 1
Preparing organic fluorine-silicon/acrylate copolymer emulsion:
mixing 3 parts of emulsifier, 20 parts of silane coupling agent KH-560, 10 parts of hexafluorobutyl methacrylate, 8 parts of butyl acrylate, 6 parts of methyl methacrylate and 120 parts of water, pouring into a mixer, and ultrasonically dispersing for 1h under the condition that the ultrasonic frequency is 60kHz to obtain emulsion A;
mixing and pouring 1 part of emulsifier, 10 parts of methyl methacrylate, 10 parts of butyl acrylate, 8 parts of acrylic acid, 80 parts of water and 8 parts of 5 mass percent sodium bicarbonate solution into a reactor, dropwise adding an initiator which is 0.1 time of the mass of the methyl methacrylate under the conditions that the temperature is 65 ℃ and the stirring speed is 300r/min to obtain an emulsion B after the dropwise adding of the initiator is finished, then adding an emulsion A which is 0.6 time of the mass of the emulsion B and an initiator which is 1% of the mass of the emulsion B, continuously heating and stirring for reacting for 6 hours under the conditions that the temperature is 75 ℃ and the rotating speed is 400r/min, cooling and discharging to obtain the organic fluorine-silicon/acrylate copolymer emulsion;
preparing the polyaldehyde calcium alginate coated titanium dioxide:
sodium alginate and water are mixed according to the mass ratio of 1: 5, stirring and swelling for 6 hours at the temperature of 75 ℃, adding sodium periodate with the mass of 5% of sodium alginate, heating and stirring for reaction for 3 hours at the temperature of 85 ℃ and the rotating speed of 300r/min, adding a calcium chloride solution with the mass fraction of 5% of 10% of sodium alginate, continuously heating and stirring for reaction, adding titanium dioxide with the mass of 2 times of the sodium alginate, stirring and mixing uniformly, and performing spray drying to obtain the multi-aldehyde calcium alginate coated titanium dioxide;
adsorbing nano silicon dioxide on the surface of the glass fiber short fiber:
mixing glass fiber short fibers and absolute ethyl alcohol according to a mass ratio of 1: 5, mixing and dispersing, then adding a silane coupling agent KH-550 accounting for 5 percent of the mass of the glass fiber short fibers and nano-silica accounting for 5 percent of the mass of the glass fiber short fibers, heating and stirring for reaction for 1 hour at the temperature of 75 ℃ and the rotating speed of 400r/min, filtering, washing and drying to obtain the glass fiber short fibers with the nano-silica adsorbed on the surfaces;
preparation of a product:
according to the weight parts, sequentially taking 80 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10 parts of polyaldehyde calcium alginate coated titanium dioxide, 4 parts of glass fiber short fibers, 4 parts of mica powder and 3 parts of sepiolite, dispersing for 10min under the condition that the ultrasonic frequency is 55kHz, discharging and packaging to obtain the high-temperature-resistant ink composition;
the emulsifier is emulsifier OP-10;
the initiator is ammonium persulfate.
Example 2
Preparing organic fluorine-silicon/acrylate copolymer emulsion:
mixing 4 parts of emulsifier, 25 parts of silane coupling agent KH-570, 12 parts of hexafluorobutyl methacrylate, 9 parts of butyl acrylate, 7 parts of methyl methacrylate and 130 parts of water, pouring into a mixer, and performing ultrasonic dispersion for 2 hours under the condition that the ultrasonic frequency is 80kHz to obtain emulsion A;
mixing 2 parts of emulsifier, 12 parts of methyl methacrylate, 15 parts of butyl acrylate, 10 parts of acrylic acid, 90 parts of water and 9 parts of sodium bicarbonate solution with the mass fraction of 6%, pouring the mixture into a reactor, dropwise adding an initiator with the mass of 0.15 time that of the methyl methacrylate under the conditions that the temperature is 70 ℃ and the stirring speed is 400r/min, obtaining an emulsion B after the dropwise adding of the initiator is finished, then adding an emulsion A with the mass of 1.2 times that of the emulsion B and an initiator with the mass of 4% of the emulsion B, continuously heating, stirring and reacting for 7 hours under the conditions that the temperature is 78 ℃ and the rotating speed is 500r/min, cooling and discharging to obtain the organic fluorine-silicon/acrylate copolymer emulsion;
preparing the polyaldehyde calcium alginate coated titanium dioxide:
sodium alginate and water are mixed according to the mass ratio of 1: 8, stirring and swelling for 7 hours at the temperature of 78 ℃, adding sodium periodate with the mass of 8% of sodium alginate, heating and stirring for reaction for 4 hours at the temperature of 88 ℃ and the rotating speed of 400r/min, adding calcium chloride solution with the mass fraction of 8% of 15% of sodium alginate, continuing heating and stirring for reaction, adding titanium dioxide with the mass of 3 times of the sodium alginate, stirring and mixing uniformly, and performing spray drying to obtain the multi-aldehyde calcium alginate coated titanium dioxide;
adsorbing nano silicon dioxide on the surface of the glass fiber short fiber:
mixing glass fiber short fibers and absolute ethyl alcohol according to a mass ratio of 1: 8, mixing and dispersing, then adding a silane coupling agent KH-550 accounting for 8 percent of the mass of the glass fiber short fibers and nano-silica accounting for 8 percent of the mass of the glass fiber short fibers, heating and stirring for reaction for 2 hours at the temperature of 78 ℃ and the rotating speed of 600r/min, filtering, washing and drying to obtain the glass fiber short fibers with the nano-silica adsorbed on the surfaces;
preparation of a product:
according to the weight parts, sequentially taking 120 parts of organic fluorine-silicon/acrylate copolymer emulsion, 15 parts of polyaldehyde calcium alginate coated titanium dioxide, 5 parts of glass fiber short fibers, 5 parts of mica powder and 4 parts of sepiolite, dispersing for 15min under the condition that the ultrasonic frequency is 58kHz, discharging and packaging to obtain the high-temperature-resistant ink composition;
the emulsifier is tween-60;
the initiator is ammonium persulfate.
Example 3
Preparing organic fluorine-silicon/acrylate copolymer emulsion:
mixing 5 parts of emulsifier, 30 parts of silane coupling agent KH-550, 15 parts of hexafluorobutyl methacrylate, 10 parts of butyl acrylate, 8 parts of methyl methacrylate and 150 parts of water, pouring into a mixer, and performing ultrasonic dispersion for 3 hours under the condition that the ultrasonic frequency is 90kHz to obtain emulsion A;
mixing 3 parts of emulsifier, 15 parts of methyl methacrylate, 20 parts of butyl acrylate, 12 parts of acrylic acid, 120 parts of water and 10 parts of sodium bicarbonate solution with the mass fraction of 10%, pouring the mixture into a reactor, dropwise adding an initiator with the mass of 0.2 time that of the methyl methacrylate under the conditions that the temperature is 80 ℃ and the stirring speed is 500r/min to obtain an emulsion B after the dropwise adding of the initiator is finished, then adding an emulsion A with the mass of 1.5 times that of the emulsion B and an initiator with the mass of 5% that of the emulsion B, continuously heating, stirring and reacting for 8 hours under the conditions that the temperature is 80 ℃ and the rotating speed is 600r/min, cooling and discharging to obtain the organic fluorine-silicon/acrylate copolymer emulsion;
preparing the polyaldehyde calcium alginate coated titanium dioxide:
sodium alginate and water are mixed according to the mass ratio of 1: 10, stirring and swelling for 8 hours at the temperature of 80 ℃, adding sodium periodate with the mass of 10% of the sodium alginate, heating and stirring for reaction for 5 hours at the temperature of 90 ℃ and the rotation speed of 500r/min, adding a calcium chloride solution with the mass fraction of 10% of the sodium alginate with the mass of 30%, continuing heating and stirring for reaction, adding titanium dioxide with the mass of 4 times of the sodium alginate, stirring and mixing uniformly, and performing spray drying to obtain the multi-aldehyde calcium alginate coated titanium dioxide;
adsorbing nano silicon dioxide on the surface of the glass fiber short fiber:
mixing glass fiber short fibers and absolute ethyl alcohol according to a mass ratio of 1: 10, mixing and dispersing, then adding a silane coupling agent KH-550 accounting for 10 percent of the mass of the glass fiber short fibers and nano-silica accounting for 10 percent of the mass of the glass fiber short fibers, heating and stirring for reaction for 3 hours at the temperature of 80 ℃ and the rotating speed of 900r/min, filtering, washing and drying to obtain the glass fiber short fibers with the nano-silica adsorbed on the surfaces;
preparation of a product:
taking 150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 20 parts of polyaldehyde calcium alginate coated titanium dioxide, 8 parts of glass fiber short fiber, 6 parts of mica powder and 5 parts of sepiolite in sequence according to parts by weight, dispersing for 30min under the condition that the ultrasonic frequency is 65kHz, discharging and packaging to obtain the high-temperature-resistant ink composition;
the emulsifier is span-80;
the initiator is potassium persulfate solution.
Comparative example 1
This comparative example differs from example 1 in that: the polymethyl silicone resin with equal mass is adopted to replace the organic fluorine-silicon/acrylic ester copolymer emulsion, and the rest conditions are kept unchanged.
Comparative example 2
This comparative example differs from example 1 in that: the substituted multi-aldehyde calcium alginate coated titanium dioxide with the same mass as the common titanium dioxide is adopted.
Comparative example 3
This comparative example differs from example 1 in that: the nano-silica is not added, and the rest conditions are kept unchanged.
The products obtained in examples 1 to 3 and comparative examples 1 to 3 were subjected to performance tests, and the specific test methods and test results were as follows:
deoiling, cleaning and drying the microcrystalline glass sheet for later use; printing the surfaces of the prepared microcrystalline glass sheets by using a 200-mesh screen printing plate, placing the microcrystalline glass sheets into a constant-temperature drying box, and curing for 2 hours at the temperature of 200 ℃;
respectively putting the cured glass sheets into a resistance furnace with the temperature of 500 ℃, preserving heat for 1h, taking out the glass sheets, cooling to room temperature, observing the surface coating condition by using a magnifying lens, and if the phenomena of cracking, dropping, color change and edge cracking do not exist, indicating that the heat resistance of the coating is good; specific test results are shown in table 1;
table 1: product performance test results
| Surface condition of the surface | |
| Example 1 | Good surface |
| Example 2 | Good surface |
| Example 3 | Good surface |
| Comparative example 1 | Complete disintegration and falling off |
| Comparative example 2 | Chipping or falling off of the edge |
| Comparative example 3 | Has fine cracks |
As can be seen from the test results in Table 1, the product obtained by the invention has excellent high temperature resistance.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (7)
1. The high-temperature-resistant ink composition is characterized by comprising the following raw materials in parts by weight:
80-150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10-20 parts of polyaldehyde calcium alginate coated titanium dioxide, 4-8 parts of glass fiber short fibers, 4-6 parts of mica powder and 3-5 parts of sepiolite;
the organic fluorine-silicon/acrylate copolymer emulsion is mainly obtained by copolymerizing a silane coupling agent, hexafluorobutyl methacrylate and an acrylic monomer;
the polyaldehyde calcium alginate coated titanium dioxide is obtained by coating polyaldehyde calcium alginate on the surface of titanium dioxide;
the length-diameter ratio of the glass fiber short fibers is 5: 1-10: 1, glass fiber with the length of 100-500 μm.
2. The high-temperature-resistant ink composition as claimed in claim 1, wherein the glass fiber short fiber is a glass fiber short fiber with nano silica adsorbed on the surface; the nano silicon dioxide is combined with the surface of the glass fiber short fiber through a silane coupling agent KH-550.
3. A high temperature resistant ink composition as recited in claim 1, wherein said acrylic monomer comprises: methyl methacrylate, butyl acrylate and acrylic acid.
4. The preparation method of the high-temperature-resistant ink composition is characterized by comprising the following specific preparation steps:
preparing organic fluorine-silicon/acrylate copolymer emulsion:
uniformly dispersing an emulsifier, a silane coupling agent, hexafluorobutyl methacrylate, butyl acrylate and methyl methacrylate in water to obtain emulsion A;
uniformly mixing an emulsifier, methyl methacrylate, butyl acrylate, acrylic acid, water and a sodium bicarbonate solution, then dropwise adding an initiator, heating and stirring for reaction, then adding the emulsion A and the initiator, continuing heating and stirring for reaction, cooling, and discharging to obtain the organic fluorine-silicon/acrylate copolymer emulsion;
preparing the polyaldehyde calcium alginate coated titanium dioxide:
mixing sodium alginate and water for swelling, adding sodium periodate, heating, stirring for reaction, adding a calcium chloride solution, continuing heating, stirring for reaction, adding titanium dioxide, stirring uniformly, and spray-drying to obtain multi-aldehyde calcium alginate coated titanium dioxide;
preparation of a product:
according to the weight parts, 80-150 parts of organic fluorine-silicon/acrylate copolymer emulsion, 10-20 parts of polyaldehyde calcium alginate coated titanium dioxide, 4-8 parts of glass fiber short fibers, 4-6 parts of mica powder and 3-5 parts of sepiolite are taken in sequence, and after being uniformly dispersed, the high-temperature resistant ink composition is obtained after discharging and packaging.
5. The method for preparing the high temperature resistant ink composition according to claim 4, wherein the specific preparation steps further comprise:
adsorbing nano silicon dioxide on the surface of the glass fiber short fiber:
dispersing the glass fiber short fiber in absolute ethyl alcohol, adding a silane coupling agent KH-550 and nano silicon dioxide, heating, stirring, reacting, filtering, washing and drying to obtain the glass fiber short fiber with the nano silicon dioxide adsorbed on the surface.
6. The method for preparing a high temperature resistant ink composition according to claim 4, wherein the emulsifier is any one of emulsifiers OP-10, Tween-60 and span-80.
7. The method of claim 4, wherein the initiator is ammonium persulfate or potassium persulfate solution.
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|---|---|---|---|---|
| CN116875149A (en) * | 2023-07-24 | 2023-10-13 | 中国人民解放军海军潜艇学院 | Marine ship corrosion-resistant coating and preparation method thereof |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1024660A (en) * | 1996-07-10 | 1998-01-27 | Fujicopian Co Ltd | Thermal transfer recording material |
| CN101040014A (en) * | 2004-09-17 | 2007-09-19 | 株式会社理光 | Recording ink, and ink cartridge, ink-recorded article, inkjet recording device and inkjet recording method |
| CN101570587A (en) * | 2009-05-08 | 2009-11-04 | 厦门大学 | Fluorine-silicon modified acrylic copolymer resin and preparation method thereof |
| CN101579643A (en) * | 2009-06-11 | 2009-11-18 | 湖州师范学院 | Sol-gel in situ preparation method of titanium dioxide nano powder coated with alginate |
| CN102086245A (en) * | 2010-11-15 | 2011-06-08 | 湖南汇博化工科技有限公司 | Method for preparing organosilicon-acrylic acid copolymer emulsion |
| CN102516448A (en) * | 2011-12-22 | 2012-06-27 | 苏州大学 | Fluorine-containing silicon acrylate copolymer emulsion prepared by using reactive emulsifier and method |
| CN102585073A (en) * | 2012-01-16 | 2012-07-18 | 中山大学 | Fluorine silicon-modified acrylic ester emulsion and preparation method thereof |
| CN104449042A (en) * | 2014-11-23 | 2015-03-25 | 鲁继烈 | Weak solvent ink-jet ink |
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN105884961A (en) * | 2014-12-15 | 2016-08-24 | 江南大学 | Preparation method of high-weather-resistance high-elasticity fluorine-silicon-modified acrylic emulsion for building thermal-insulation paints |
| KR20170034636A (en) * | 2015-09-21 | 2017-03-29 | 애경화학 주식회사 | Fluorine-containing acrylic pressure sensitive adhesive composition having excellent fouling resistant and the method of manufacturing the same |
| CN108299771A (en) * | 2018-02-10 | 2018-07-20 | 雷春生 | A kind of fire-retardant caulking gum material of civil aircraft |
| CN110607091A (en) * | 2019-10-17 | 2019-12-24 | 石柳青 | Acid and alkali resistant automobile glass printing ink and preparation method thereof |
| CN110769527A (en) * | 2019-09-12 | 2020-02-07 | 宁波科诺佳新材料有限公司 | Organic high-temperature electric heating composite film and preparation method thereof |
| CN110791004A (en) * | 2019-11-18 | 2020-02-14 | 界首市天路包装材料有限公司 | Environment-friendly degradable heat-insulation food packaging bag |
| CN110981223A (en) * | 2019-12-18 | 2020-04-10 | 安徽省宁国昊成高温材料有限公司 | High-temperature-resistant glass fiber and preparation method thereof |
-
2020
- 2020-11-18 CN CN202011297118.7A patent/CN112280379A/en active Pending
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1024660A (en) * | 1996-07-10 | 1998-01-27 | Fujicopian Co Ltd | Thermal transfer recording material |
| CN101040014A (en) * | 2004-09-17 | 2007-09-19 | 株式会社理光 | Recording ink, and ink cartridge, ink-recorded article, inkjet recording device and inkjet recording method |
| CN101570587A (en) * | 2009-05-08 | 2009-11-04 | 厦门大学 | Fluorine-silicon modified acrylic copolymer resin and preparation method thereof |
| CN101579643A (en) * | 2009-06-11 | 2009-11-18 | 湖州师范学院 | Sol-gel in situ preparation method of titanium dioxide nano powder coated with alginate |
| CN102086245A (en) * | 2010-11-15 | 2011-06-08 | 湖南汇博化工科技有限公司 | Method for preparing organosilicon-acrylic acid copolymer emulsion |
| CN102516448A (en) * | 2011-12-22 | 2012-06-27 | 苏州大学 | Fluorine-containing silicon acrylate copolymer emulsion prepared by using reactive emulsifier and method |
| CN102585073A (en) * | 2012-01-16 | 2012-07-18 | 中山大学 | Fluorine silicon-modified acrylic ester emulsion and preparation method thereof |
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