CN105567015A - Weak solvent white ink for dark-color leather color printing - Google Patents
Weak solvent white ink for dark-color leather color printing Download PDFInfo
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- CN105567015A CN105567015A CN201610165478.9A CN201610165478A CN105567015A CN 105567015 A CN105567015 A CN 105567015A CN 201610165478 A CN201610165478 A CN 201610165478A CN 105567015 A CN105567015 A CN 105567015A
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- Prior art keywords
- white ink
- weak solvent
- solvent white
- parts
- ether
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/40—Ink-sets specially adapted for multi-colour inkjet printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a weak solvent white ink for dark-color leather color printing, belonging to the technical field of inkjet printing. The weak solvent white ink is prepared from the following components in parts by weight: 30-50 parts of white pigment, 20-30 parts of slow-drying solvent, 5-10 parts of quick-drying solvent, 1-5 parts of high-molecular polymer resin, 1-5 parts of high-molecular dispersing agent, 0.1-3 parts of surfactant and 0.1-3 parts of defoaming agent. The preparation method comprises the following steps: proportionally adding all the components expect the titanium white into a dispersion cylinder, and stirring uniformly; and slowly adding the titanium white in the stirring state, stirring at high speed, grinding, and filtering to obtain the weak solvent white ink. The weak solvent white ink can be stably and smoothly printed on inkjet equipment, and the finished product has excellent covering power, so that the weak solvent white ink has excellent color expression force. The weak solvent white ink has the advantages of excellent adhesive force, favorable flexibility, water resistance, wear resistance and the like, and can be widely applied to the field of dark-color leather color printing.
Description
Technical field
The present invention relates to inkjet technology field, be specifically related to a kind of Weak solvent white ink for dark leather color printing.
Background technology
Ink-jet printed is the fabrics printing and dyeing New Machining Technology integrating the multidisciplinary fields such as computer, information, novel material and fine chemistry industry, have that stamp fineness is high, batch flexibly, without advantages such as dyestuff and auxiliary agent wastes.Along with reaching its maturity of printing device and technology, ink-jet printed industry is in full flourish, and increasing people adopts number in conjunction with the mode of printer to realize different field, differing materials, the different stamp required.In leather color printing field, the convention resolution method that the color printing realizing dark leather at present adopts is silk-screen, and this method plate-making is complicated, expensive, inefficiency, and the coating that obtained product has one deck thick and heavy, cause feel poor, the requirement of high-end user can not be met.In addition, the UV ink in ink jet applications also can realize the color printing of dark leather, but UV ink price is high, and after solidification, snappiness is poor, and the time has been grown and also can cause leather serious cracking, thus makes it lose value of the product.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of Weak solvent white ink for dark leather color printing, this Weak solvent white ink can stablize smooth printing on ink-jet apparatus, and finished product has outstanding opacifying power, thus make color representation power splendid, and sticking power is excellent, snappiness is good, and has the advantages such as waterproof antiwear concurrently.
For solving the problem, the technical solution adopted in the present invention is as follows:
For a Weak solvent white ink for dark leather color printing, described Weak solvent white ink is made up of following component according to the mass fraction:
As the preferred a kind of embodiment of the present invention, described Weak solvent white ink is made up of following component according to the mass fraction:
As further preferred embodiment of the present invention, described Weak solvent white ink is made up of following component according to the mass fraction:
Preferably, described white pigment is the one in Rutile type Titanium Dioxide or anatase thpe white powder.Particularly, white pigment is preferably R706, R900, R960, R104, R105 type titanium dioxide that du pont company produces; Or U.S.'s Hensel steps TR28, TR92 type titanium dioxide of group's production; Or A100, R930, R980 type titanium dioxide that Japanese Ishihara Sangyo Kaisha, Ltd. produces; Or RD-3, RDI-S type titanium dioxide that Finland Sha Haliben produces.
Preferably, described slow drying solvent is a kind of or two or more arbitrarily mixing in butyl, propandiol butyl ether, propylene glycol monopropyl ether, 2-Butoxyethyl acetate, dipropylene glycol methyl ether, dipropylene, glycol diacetate, diethylene glycol dimethyl ether, Diethylene Glycol propyl ether, diethylene glycol ether acetic ester, diethylene glycol dimethyl ether acetic ester, diethylene glycol diethyl ether, diethylene glycol ethylmethyl ether, butyl acetic ester.
Preferably, described quick-drying solvent is a kind of or two or more arbitrarily mixing in ethanol, n-propyl alcohol, Virahol.
Preferably, described macromolecule copolymer resin is a kind of or two or more arbitrarily mixing in binary vinyl chloride-vinyl acetate resin, ternary chlorine vinegar resin, acrylic resin, aldehyde ketone resin, vibrin, urethane resin.
Preferably, described macromolecule dispersing agent is polyurethane polymer or the segmented copolymer containing pigment affinity groups.Wherein, polyurethane polymer is preferably one or more in AFCONA4000, AFCONA4001, AFCONA4071, AFCONA4200, AFCONA4201, AFCONA4474; Segmented copolymer containing pigment affinity groups is preferably one or more in BYK160, BYK161, BYK162, BYK163, DISPERBYK2150, DISPERBYK2155, DISPERBYK2163.
Preferably, described tensio-active agent is polyether-modified polydimethylsiloxane or the polydimethylsiloxane of polyester modification.Particularly, tensio-active agent is preferably one or more in BYK371, BYK373, BYK375, BYK377, BYK378, BYK3700, BYK3710, AFCONA3030, AFCONA3031, AFCONA3034, AFCONA3037, AFCONA3230, AFCONA3250.
Preferably, described defoamer is not containing organosilyl broken bubble polymers soln.Particularly, defoamer is preferably one or more in BYK051, BYK052, BYK053, BYK054, BYK055, BYK057, AFCONA2018, AFCONA2024, AFCONA2290, AFCONA2754.
In formula of the present invention:
White pigment is a kind of mineral dye, and be divided into rutile-type and anatase titanium dioxide two kinds of crystal formations, they all have excellent dispersiveness and stability, and opacifying power is excellent, and whiteness is high, safety non-toxic.
Slow drying solvent is the water-miscible organic solvent of environmental protection, it is the important component part of ink, be the carrier of colo(u)rant dispersion, play a part to regulate ink evaporation rate simultaneously, and slow drying solvent used in the present invention all has features such as boiling point is high, smell extremely low, safe pole hypotoxicity.In use, also well can adjust ink because of the standby dry head problem that may cause, reduce equipment failure.In addition, it is dissolve high molecular polymer that slow drying solvent also serves a vital role, the high molecular polymer as binder can be dissolved in ink fully, and keep the stability of standing storage.
Quick-drying solvent is a class environmental protection, lower boiling water-miscible organic solvent.Because formula of the present invention employs a large amount of slow drying solvent, ink evaporation rate may be caused too slow and affect printing quality, so need to add appropriate quick-drying solvent to regulate the evaporation rate of ink system, make product of the present invention not only meet excellent fluency and print stability, improve sharpness and the vividness of production efficiency and product color simultaneously.
High molecular polymer is a kind of resin possessing certain molecular weight, and it not only plays the effect connecting pigment and print substrate, also regulates the viscosity of ink simultaneously, makes ink jet smoothness stable.In addition vital effect is all played to performances such as the attachment of pigment, water-fastness, dry wet rubbing fastness.
The dispersion of macromolecule dispersing agent major effect white pigment and stable, because adding of it, makes the particle diameter of granules of pigments can be distributed to 200 nanometers, and can stablize preservation and be greater than 1 year.
Tensio-active agent improves the mobility of ink system and base material soaks levelling property, makes to print more smooth stable.
Defoamer can greatly reduce the generation of bubble in ink production and use procedure, thus improves printing fluency and stability.
Compared to existing technology, beneficial effect of the present invention is:
Weak solvent white ink of the present invention has and well prints stability, smooth excellent performance, the spray orifice of printer can not be blocked, and finished product has outstanding opacifying power, thus make color representation power splendid, and sticking power is excellent, snappiness is good, and have waterproof, the advantage such as wear-resisting concurrently, while realizing digital color printing, solve again shortcomings such as using UV ink printed snappiness is poor, leather cracking, can be widely used in dark leather color printing field.
Embodiment
Embodiment is described in further detail the present invention below.
Embodiment 1:
For a Weak solvent white ink for dark leather color printing, it is made up of following component according to the mass fraction:
The preparation method of above-mentioned Weak solvent white ink is as follows:
All components above except titanium dioxide is proportionally dropped in dispersion cylinder, opens dispersion machine moderate-speed mixer dispersion 10-30min until dissolution homogeneity; Then under whipped state, slowly titanium dioxide is added, high-speed stirring dispersion 30-60min; Grind until its particle diameter D with horizontal sand mill afterwards
50be less than 200nm, finally obtain described Weak solvent white ink with the filter paper filtering of 0.5 μm.
Embodiment 2:
For a Weak solvent white ink for dark leather color printing, it is made up of following component according to the mass fraction:
The preparation method of above-mentioned Weak solvent white ink is with embodiment 1.
Embodiment 3:
For a Weak solvent white ink for dark leather color printing, it is made up of following component according to the mass fraction:
The preparation method of above-mentioned Weak solvent white ink is with embodiment 1.
Embodiment 4:
For a Weak solvent white ink for dark leather color printing, it is made up of following component according to the mass fraction:
The preparation method of above-mentioned Weak solvent white ink is with embodiment 1.
Physical and chemical parameter is tested:
Relevant physical and chemical parameter test is carried out to the Weak solvent white ink obtained by above embodiment 1-4, and adopts model to be that the printing device of MimakiJV33 carries out printing test, obtain following data:
The physical and chemical parameter of the Weak solvent white ink obtained by table 1 embodiment 1-4
As shown in Table 1, Weak solvent white ink of the present invention has and well prints stability, smooth excellent performance, can not block the spray orifice of printer.
Dark leather performance test:
The test such as sense organ is carried out to the dark leather color printing finished product of the embodiment 1-4 obtained in the test of above-mentioned physical and chemical parameter, snappiness, tension are split, the same dark leather product obtained to adopt existing UV ink printed as a comparison case 1, with the same dark leather product adopting traditional silk screen printing process to obtain as a comparison case 2, after tested, following data are obtained:
The performance test of table 2 dark leather contrasts
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 |
| Whiteness | Good | Good | Good | Good | Better | Very well |
| Feel | Fine and smooth | Fine and smooth | Fine and smooth | Fine and smooth | Stiff | Stiff |
| Snappiness | Very well | Very well | Very well | Very well | Very poor | Difference |
| Tension is split | Very well | Very well | Very well | Very well | Very poor | Difference |
As shown in Table 2, the dark leather color printing finished product adopting Weak solvent white ink of the present invention to obtain has outstanding opacifying power, color representation power is splendid, and sticking power is excellent, snappiness is good, feel is fine and smooth and have waterproof antiwear concurrently, the advantage such as tension is split, Weak solvent white ink of the present invention be can be widely used in dark leather color printing.
Above-mentioned embodiment is only the preferred embodiment of the present invention; can not limit the scope of protection of the invention with this, change and the replacement of any unsubstantiality that those skilled in the art does on basis of the present invention all belong to the present invention's scope required for protection.
Claims (10)
1. for a Weak solvent white ink for dark leather color printing, it is characterized in that: described Weak solvent white ink is made up of following component according to the mass fraction:
2. Weak solvent white ink according to claim 1, is characterized in that: described Weak solvent white ink is made up of following component according to the mass fraction:
3. Weak solvent white ink according to claim 1, is characterized in that: described Weak solvent white ink is made up of following component according to the mass fraction:
4. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described white pigment is the one in Rutile type Titanium Dioxide or anatase thpe white powder.
5. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described slow drying solvent is a kind of or two or more arbitrarily mixing in butyl, propandiol butyl ether, propylene glycol monopropyl ether, 2-Butoxyethyl acetate, dipropylene glycol methyl ether, dipropylene, glycol diacetate, diethylene glycol dimethyl ether, Diethylene Glycol propyl ether, diethylene glycol ether acetic ester, diethylene glycol dimethyl ether acetic ester, diethylene glycol diethyl ether, diethylene glycol ethylmethyl ether, butyl acetic ester.
6. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described quick-drying solvent is a kind of or two or more arbitrarily mixing in ethanol, n-propyl alcohol, Virahol.
7. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described macromolecule copolymer resin is a kind of or two or more arbitrarily mixing in binary vinyl chloride-vinyl acetate resin, ternary chlorine vinegar resin, acrylic resin, aldehyde ketone resin, vibrin, urethane resin.
8. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described macromolecule dispersing agent is the segmented copolymer or the polyurethane polymer that contain pigment affinity groups.
9. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described tensio-active agent is polyether-modified polydimethylsiloxane or the polydimethylsiloxane of polyester modification.
10. the Weak solvent white ink according to any one of claim 1-3, is characterized in that: described defoamer is not for containing organosilyl broken bubble polymers soln.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610165478.9A CN105567015A (en) | 2016-03-22 | 2016-03-22 | Weak solvent white ink for dark-color leather color printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610165478.9A CN105567015A (en) | 2016-03-22 | 2016-03-22 | Weak solvent white ink for dark-color leather color printing |
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| Publication Number | Publication Date |
|---|---|
| CN105567015A true CN105567015A (en) | 2016-05-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610165478.9A Pending CN105567015A (en) | 2016-03-22 | 2016-03-22 | Weak solvent white ink for dark-color leather color printing |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113354970A (en) * | 2021-07-01 | 2021-09-07 | 海南必凯水性新材料有限公司 | Aqueous coating liquid suitable for weak solvent ink and preparation method thereof |
| CN116925597A (en) * | 2022-03-31 | 2023-10-24 | 高宝新材料(珠海)有限公司 | Scrubbing solvent type silvery white ink for battery film and preparation method and application thereof |
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|---|---|---|---|---|
| US5395431A (en) * | 1993-06-22 | 1995-03-07 | Videojet Systems International, Inc. | Aqueous based jet ink |
| JPH0834941A (en) * | 1994-07-22 | 1996-02-06 | Seiko Epson Corp | Water-based ink for ink jet recording |
| TW200609307A (en) * | 2004-09-02 | 2006-03-16 | Ming-An Xue | Non-yellowing water transfer eco-printing-ink |
| CN101020795A (en) * | 2006-11-21 | 2007-08-22 | 陕西科技大学 | Prepn process of ink for ink jet printing of leather |
| CN102597134A (en) * | 2009-07-20 | 2012-07-18 | 马克姆-伊玛杰公司 | Solvent-based inkjet ink formulations |
| CN103468058A (en) * | 2013-09-25 | 2013-12-25 | 山东德创喷墨科技有限公司 | Weak-solvent ink-jet ink for industrial piezoelectric jetting head and preparation method thereof |
| CN104449042A (en) * | 2014-11-23 | 2015-03-25 | 鲁继烈 | Weak solvent ink-jet ink |
-
2016
- 2016-03-22 CN CN201610165478.9A patent/CN105567015A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5395431A (en) * | 1993-06-22 | 1995-03-07 | Videojet Systems International, Inc. | Aqueous based jet ink |
| JPH0834941A (en) * | 1994-07-22 | 1996-02-06 | Seiko Epson Corp | Water-based ink for ink jet recording |
| TW200609307A (en) * | 2004-09-02 | 2006-03-16 | Ming-An Xue | Non-yellowing water transfer eco-printing-ink |
| CN101020795A (en) * | 2006-11-21 | 2007-08-22 | 陕西科技大学 | Prepn process of ink for ink jet printing of leather |
| CN102597134A (en) * | 2009-07-20 | 2012-07-18 | 马克姆-伊玛杰公司 | Solvent-based inkjet ink formulations |
| CN103468058A (en) * | 2013-09-25 | 2013-12-25 | 山东德创喷墨科技有限公司 | Weak-solvent ink-jet ink for industrial piezoelectric jetting head and preparation method thereof |
| CN104449042A (en) * | 2014-11-23 | 2015-03-25 | 鲁继烈 | Weak solvent ink-jet ink |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113354970A (en) * | 2021-07-01 | 2021-09-07 | 海南必凯水性新材料有限公司 | Aqueous coating liquid suitable for weak solvent ink and preparation method thereof |
| CN116925597A (en) * | 2022-03-31 | 2023-10-24 | 高宝新材料(珠海)有限公司 | Scrubbing solvent type silvery white ink for battery film and preparation method and application thereof |
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Application publication date: 20160511 |