CN106700151A - Cable material with high mechanical property for computer - Google Patents

Cable material with high mechanical property for computer Download PDF

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Publication number
CN106700151A
CN106700151A CN201611184076.XA CN201611184076A CN106700151A CN 106700151 A CN106700151 A CN 106700151A CN 201611184076 A CN201611184076 A CN 201611184076A CN 106700151 A CN106700151 A CN 106700151A
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CN
China
Prior art keywords
parts
rubber
antioxidant
mechanical property
cable material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611184076.XA
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Chinese (zh)
Inventor
沈学忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Hua Tian Cable Co Ltd
Original Assignee
Anhui Hua Tian Cable Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Hua Tian Cable Co Ltd filed Critical Anhui Hua Tian Cable Co Ltd
Priority to CN201611184076.XA priority Critical patent/CN106700151A/en
Publication of CN106700151A publication Critical patent/CN106700151A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a cable material with a high mechanical property for a computer. The cable material comprises the following raw materials in parts by weight: 25-35 parts of nitrile rubber, 5-15 parts of fluorine rubber, 15-22 parts of butadiene rubber, 10-30 parts of isoprene rubber, 10-18 parts of silicone rubber, 2-4 parts of palm wax, 1-3 parts of microcrystalline wax, 1-2 parts of sulfur, 0.5-1.5 parts of a vulcanizing agent HTDM, 1-2 parts of a vulcanization accelerator CZ, 1.2-2.2 parts of a vulcanization accelerator TMTD, 20-40 parts of zeolite powder, 15-25 parts of calcium silicate hydrate, 1-2 parts of zinc oxide, 10-20 parts of calcium carbonate, 1-3 parts of a silane coupling agent, 2-4 parts of silicon nitride, 0.5-1.5 parts of molybdenum disulfide, 1.4-1.8 parts of an antioxidant CA, 1.2-1.6 parts of an anti-aging agent and 1-3 parts of an antioxidant 164.

Description

A kind of good computer cable material of mechanical property
Technical field
The present invention relates to field of cable technology, more particularly to a kind of good computer cable material of mechanical property.
Background technology
The good computer cable material of mechanical property applies to rated voltage 300/500V and following to anti-electromagnetic interference Property require the cable of the connections such as cybernation higher, instrument detection, be widely used in automation equipment Deng field, the automatic control circuit in some emphasis fire-fighting regions needs the substantial amounts of good computer electricity consumption of fire resistant flame retardant mechanical property Cable material, but the fire resisting of the good computer cable material of existing mechanical property, mechanical property can not meet growing demand, Larger hidden danger is constituted to line facility and personal security.
The content of the invention
The present invention proposes a kind of good computer cable material of mechanical property, fire resisting, excellent in mechanical performance,
A kind of good computer cable material of mechanical property proposed by the present invention, its raw material includes by weight：Butyronitrile rubber Glue 25-35 parts, fluorubber 5-15 parts, butadiene rubber 15-22 parts, isoprene rubber 10-30 parts, silicon rubber 10-18 parts, palm wax 2- 4 parts, microcrystalline wax 1-3 parts, sulphur 1-2 parts, vulcanizing agent HTDM0.5-1.5 parts, accelerator CZ 1-2 parts, vulcanization accelerator TMTD 1.2-2.2 parts, zeolite powder 20-40 parts, afwillite 15-25 parts, zinc oxide 1-2 parts, calcium carbonate 10-20 parts, silane Coupling agent 1-3 parts, silicon nitride 2-4 parts, molybdenum bisuphide 0.5-1.5 parts, antioxidant CA 1.4-1.8 parts, antioxidant D 1.2-1.6 Part, 1-3 parts of antioxidant 164.
Preferably, nitrile rubber, isoprene rubber, butadiene rubber, isoprene rubber, the weight ratio of silicon rubber are 28-30：10- 12：20-21.5：20-24：12-14.
Preferably, palm wax, the weight ratio of microcrystalline wax are 3-3.6：1.2-2.
Preferably, sulphur, vulcanizing agent HTDM, accelerator CZ, the weight ratio of vulcanization accelerator TMTD are 1.4-1.8： 1-1.4：1.4-1.6：1.4-1.6.
Preferably, zeolite powder, afwillite, zinc oxide, calcium carbonate, silane coupler, the weight ratio of silicon nitride are 30- 34：20-23：1.4-1.8：12-14：2-2.4：2.5-3.
Preferably, antioxidant CA, antioxidant D, the weight ratio of antioxidant 164 are 1.5-1.6：1.3-1.5：2-2.6.
Preferably, the good computer cable material of described mechanical property, its raw material includes by weight：Nitrile rubber 28-30 parts, fluorubber 10-12 parts, butadiene rubber 20-21.5 parts, isoprene rubber 20-24 parts, silicon rubber 12-14 parts, palm wax 3-3.6 parts, microcrystalline wax 1.2-2 parts, sulphur 1.4-1.8 parts, 1-1.4 parts of vulcanizing agent HTDM, accelerator CZ 1.4-1.6 Part, vulcanization accelerator TMTD 1.4-1.6 parts, zeolite powder 30-34 parts, afwillite 20-23 parts, zinc oxide 1.4-1.8 parts, Calcium carbonate 12-14 parts, silane coupler 2-2.4 parts, silicon nitride 2.5-3 parts, molybdenum bisuphide 1-1.2 parts, antioxidant CA 1.5- 1.6 parts, antioxidant D 1.3-1.5 parts, 2-2.6 parts of antioxidant 164.
In the present invention, with nitrile rubber, fluorubber, butadiene rubber, isoprene rubber and silicon rubber as base material, palm wax and Microcrystalline wax mating reaction, good processability, thermal stability is excellent, and fire resistance is fabulous, and sulphur, vulcanizing agent HTDM are used as sulphur Agent, coordinates addition accelerator CZ and vulcanization accelerator TMTD to help vulcanization, and product rubber has good fire resisting and mechanical property Energy；Add zeolite powder, afwillite, zinc oxide and calcium carbonate synergy, it is not only cheap, and product can be applicable to it is right The more harsh occasion of fire resistant requirements, and halogen-free environmental, coordinate silane coupler effect, knot with inorganic material organic with other Fabulous with joint efforts, the fire resisting of product and mechanical property are further enhanced.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of good computer cable material of mechanical property, its raw material includes by weight：25 parts of nitrile rubber, fluorubber 15 parts, 15 parts of butadiene rubber, 30 parts of isoprene rubber, 10 parts of silicon rubber, 4 parts of palm wax, 1 part of microcrystalline wax, 2 parts of sulphur, vulcanization 0.5 part of agent HTDM, 2 parts of accelerator CZ, 1.2 parts of vulcanization accelerator TMTD, 40 parts of zeolite powder, 15 parts of afwillite, 2 parts of zinc oxide, 10 parts of calcium carbonate, 3 parts of silane coupler, 2 parts of silicon nitride, 1.5 parts of molybdenum bisuphide, 1.4 parts of antioxidant CA is prevented 1.6 parts of old agent D, 164 1 parts of antioxidant.
Embodiment 2
A kind of good computer cable material of mechanical property, its raw material includes by weight：35 parts of nitrile rubber, fluorubber 5 parts, 22 parts of butadiene rubber, 10 parts of isoprene rubber, 18 parts of silicon rubber, 2 parts of palm wax, 3 parts of microcrystalline wax, 1 part of sulphur, vulcanizing agent 1.5 parts of HTDM, 1 part of accelerator CZ, 2.2 parts of vulcanization accelerator TMTD, 20 parts of zeolite powder, 25 parts of afwillite, oxygen Change 1 part of zinc, 20 parts of calcium carbonate, 1 part of silane coupler, 4 parts of silicon nitride, 0.5 part of molybdenum bisuphide, 1.8 parts of antioxidant CA prevents old 1.2 parts of agent D, 164 3 parts of antioxidant.
Embodiment 3
A kind of good computer cable material of mechanical property, its raw material includes by weight：28 parts of nitrile rubber, fluorubber 12 parts, 20 parts of butadiene rubber, 24 parts of isoprene rubber, 12 parts of silicon rubber, 3.6 parts of palm wax, 1.2 parts of microcrystalline wax, sulphur 1.8 Part, 1 part of vulcanizing agent HTDM, 1.6 parts of accelerator CZ, 1.4 parts of vulcanization accelerator TMTD, 34 parts of zeolite powder, silicate hydrate 20 parts of calcium, 1.8 parts of zinc oxide, 12 parts of calcium carbonate, 2.4 parts of silane coupler, 2.5 parts of silicon nitride, 1.2 parts of molybdenum bisuphide, antioxygen 1.5 parts of agent CA, 1.5 parts of antioxidant D, 164 2 parts of antioxidant.
Embodiment 4
A kind of good computer cable material of mechanical property, its raw material includes by weight：30 parts of nitrile rubber, fluorubber 10 parts, 21.5 parts of butadiene rubber, 20 parts of isoprene rubber, 14 parts of silicon rubber, 3 parts of palm wax, 2 parts of microcrystalline wax, 1.4 parts of sulphur, 1.4 parts of vulcanizing agent HTDM, 1.4 parts of accelerator CZ, 1.6 parts of vulcanization accelerator TMTD, 30 parts of zeolite powder, silicate hydrate 23 parts of calcium, 1.4 parts of zinc oxide, 14 parts of calcium carbonate, 2 parts of silane coupler, 3 parts of silicon nitride, 1 part of molybdenum bisuphide, antioxidant CA 1.6 parts, 1.3 parts of antioxidant D, 164 2.6 parts of antioxidant.
Embodiment 5
A kind of good computer cable material of mechanical property, its raw material includes by weight：29 parts of nitrile rubber, fluorubber 11 parts, 21.2 parts of butadiene rubber, 22 parts of isoprene rubber, 13 parts of silicon rubber, 3.3 parts of palm wax, 1.26 parts of microcrystalline wax, sulphur 1.6 parts, 1.2 parts of vulcanizing agent HTDM, 1.5 parts of accelerator CZ, 1.5 parts of vulcanization accelerator TMTD, 32 parts of zeolite powder, water Close 21 parts of calcium silicates, 1.6 parts of zinc oxide, 13 parts of calcium carbonate, 2.2 parts of silane coupler, 2.8 parts of silicon nitride, molybdenum bisuphide 1.12 Part, 1.55 parts of antioxidant CA, 1.4 parts of antioxidant D, 164 2.3 parts of antioxidant.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (7)

1. the good computer cable material of a kind of mechanical property, it is characterised in that its raw material includes by weight：Nitrile rubber 25-35 parts, fluorubber 5-15 parts, butadiene rubber 15-22 parts, isoprene rubber 10-30 parts, silicon rubber 10-18 parts, palm wax 2-4 Part, microcrystalline wax 1-3 parts, sulphur 1-2 parts, 0.5-1.5 parts of vulcanizing agent HTDM, accelerator CZ 1-2 parts, vulcanization accelerator TMTD 1.2-2.2 parts, zeolite powder 20-40 parts, afwillite 15-25 parts, zinc oxide 1-2 parts, calcium carbonate 10-20 parts, silane Coupling agent 1-3 parts, silicon nitride 2-4 parts, molybdenum bisuphide 0.5-1.5 parts, antioxidant CA 1.4-1.8 parts, antioxidant D 1.2-1.6 Part, 1-3 parts of antioxidant 164.
2. the good computer cable material of mechanical property according to claim 1, it is characterised in that nitrile rubber, fluorine rubber Glue, butadiene rubber, isoprene rubber, the weight ratio of silicon rubber are 28-30：10-12：20-21.5：20-24：12-14.
3. the good computer cable material of mechanical property according to claim 1, it is characterised in that palm wax, microlite The weight ratio of wax is 3-3.6：1.2-2.
4. the good computer cable material of mechanical property according to claim 1, it is characterised in that sulphur, vulcanizing agent HTDM, accelerator CZ, the weight ratio of vulcanization accelerator TMTD are 1.4-1.8：1-1.4：1.4-1.6：1.4-1.6.
5. the good computer cable material of mechanical property according to claim 1, it is characterised in that zeolite powder, hydration silicon Sour calcium, zinc oxide, calcium carbonate, silane coupler, the weight ratio of silicon nitride are 30-34：20-23：1.4-1.8：12-14：2- 2.4：2.5-3.
6. the good computer cable material of mechanical property according to claim 1, it is characterised in that antioxidant CA, anti-old Agent D, the weight ratio of antioxidant 164 are 1.5-1.6：1.3-1.5：2-2.6.
7. the good computer cable material of mechanical property according to claim 1, it is characterised in that its raw material is by weight Including：Nitrile rubber 28-30 parts, fluorubber 10-12 parts, butadiene rubber 20-21.5 parts, isoprene rubber 20-24 parts, silicon rubber 12-14 parts, palm wax 3-3.6 parts, microcrystalline wax 1.2-2 parts, sulphur 1.4-1.8 parts, 1-1.4 parts of vulcanizing agent HTDM, vulcanization promotees Enter 1.4-1.6 parts of agent CZ, vulcanization accelerator TMTD 1.4-1.6 parts, zeolite powder 30-34 parts, afwillite 20-23 parts, oxygen 1.4-1.8 parts of zinc of change, calcium carbonate 12-14 parts, silane coupler 2-2.4 parts, silicon nitride 2.5-3 parts, molybdenum bisuphide 1-1.2 parts, Antioxidant CA 1.5-1.6 parts, antioxidant D 1.3-1.5 parts, 2-2.6 parts of antioxidant 164.
CN201611184076.XA 2016-12-20 2016-12-20 Cable material with high mechanical property for computer Pending CN106700151A (en)

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Application Number Priority Date Filing Date Title
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06263926A (en) * 1993-03-11 1994-09-20 Asahi Chem Ind Co Ltd Filler for rubber
CN103554570A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 High-strength wear-resisting nitrile butadiene rubber cable material
CN105244098A (en) * 2015-11-19 2016-01-13 国家电网公司 Cold-resistant anti-oxidation flame-retardant cable
CN105575469A (en) * 2016-02-03 2016-05-11 安徽华海特种电缆集团有限公司 High temperature resistant cable
CN105802090A (en) * 2016-04-29 2016-07-27 安徽华宇电缆集团有限公司 Preparation method of high-performance fluoride rubber/silicone rubber cable sheath material
CN105906861A (en) * 2016-05-31 2016-08-31 徐挺 High wear resistant rubber cable material and preparation method thereof
CN105924695A (en) * 2016-05-23 2016-09-07 国网山东省电力公司蓬莱市供电公司 Wear-resistant power cable protection layer material

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06263926A (en) * 1993-03-11 1994-09-20 Asahi Chem Ind Co Ltd Filler for rubber
CN103554570A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 High-strength wear-resisting nitrile butadiene rubber cable material
CN105244098A (en) * 2015-11-19 2016-01-13 国家电网公司 Cold-resistant anti-oxidation flame-retardant cable
CN105575469A (en) * 2016-02-03 2016-05-11 安徽华海特种电缆集团有限公司 High temperature resistant cable
CN105802090A (en) * 2016-04-29 2016-07-27 安徽华宇电缆集团有限公司 Preparation method of high-performance fluoride rubber/silicone rubber cable sheath material
CN105924695A (en) * 2016-05-23 2016-09-07 国网山东省电力公司蓬莱市供电公司 Wear-resistant power cable protection layer material
CN105906861A (en) * 2016-05-31 2016-08-31 徐挺 High wear resistant rubber cable material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭红霞 主编: "《电线电缆材料-结构.性能.应用》", 31 July 2012, 机械工业出版社 *

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