CN106699414A - Fertilizer additive and preparation method and use thereof - Google Patents

Fertilizer additive and preparation method and use thereof Download PDF

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Publication number
CN106699414A
CN106699414A CN201710086580.4A CN201710086580A CN106699414A CN 106699414 A CN106699414 A CN 106699414A CN 201710086580 A CN201710086580 A CN 201710086580A CN 106699414 A CN106699414 A CN 106699414A
Authority
CN
China
Prior art keywords
fertilizer
fertilizer additive
additive
sodium polyacrylate
active ingredient
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710086580.4A
Other languages
Chinese (zh)
Inventor
朱晓辉
任丽新
朱思博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hengshui Donghui Biology Tech Co Ltd
Hengshui Donghui Biology Technology Co Ltd
Original Assignee
Hengshui Donghui Biology Tech Co Ltd
Hengshui Donghui Biology Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hengshui Donghui Biology Tech Co Ltd, Hengshui Donghui Biology Technology Co Ltd filed Critical Hengshui Donghui Biology Tech Co Ltd
Priority to CN201710086580.4A priority Critical patent/CN106699414A/en
Publication of CN106699414A publication Critical patent/CN106699414A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/20Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings

Abstract

The invention relates to a fertilizer additive and a preparation method and use thereof. The fertilizer additive comprises active ingredients and water. The active ingredients comprise sodium polyacrylate and xanthan gum in a match ratio of (30-40): (5-10) in parts by weight. The fertilizer additive provided by the invention is a liquid anti-blocking color-fixing brightener. The fertilizer additive which is applied to a powdery chemical fertilizer product can improve the brightness of the chemical fertilizer, reduce the moisture rate of the chemical fertilizer and prevent agglomeration of the chemical fertilizer. The fertilizer additive also can improve the slow release property of the chemical fertilizer and improve the fertilizer efficiency of the chemical fertilizer.

Description

A kind of fertilizer additive and its production and use
Technical field
The present invention relates to a kind of fertilizer additive, preparation method and its usage.
Background technology
The primary raw material of current compound fertilizer production is:Urea, ammonium chloride, ammonium nitrate, ammonium sulfate, MAP, phosphoric acid Two ammoniums, calcium superphosphate, coarse whiting, potassium chloride, potassium sulfate etc..These fertilizer all have larger solubility and relatively low moisture absorption point, and The composite fertilizer's moisture absorption point being made up of them is lower.Therefore in production and storage and transport process, exist moisture-sensitive efflorescence, easily it is hardened, easy Fade, pilling up time is short, the low technical problem of fertilizer efficiency.These problems need multiple product use could be solved respectively in market, Both wasting manpower and material resources, and cost of idleness.The B of Chinese patent CN 103664334 disclose a kind of fertilizer anti-caking agents, and it is by day Right mineral dust, modifying agent and modified plastics composition.The agglomeration agent belongs to the anticaking agent of solid state, does not allow when there is processing The problem of easy and chemical fertilizer products mixing.
The content of the invention
The present invention provides a kind of fertilizer additive, and it can overcome the defect of above-mentioned prior art, can be in production chemical fertilizer When be easier addition, with fixation, blast, the effect of anti-caking.
In addition, the present invention also provides the preparation method and its usage of above-mentioned fertilizer additive.
Problem of the present invention is solved by the following technical programs:
A kind of fertilizer additive, including active ingredient and water, contain Sodium Polyacrylate and xanthans in the active ingredient, Wherein Sodium Polyacrylate:The match ratio of xanthans is (30-40):(5-10) weight portion.
Above-mentioned fertilizer additive, contains Sodium Polyacrylate, xanthans, citrate, acetate in the active ingredient, its Middle Sodium Polyacrylate:Xanthans:Citrate:Acetate match ratio is (30-40):(5-10):(12-20):(8-10) Weight portion.
Above-mentioned fertilizer additive, contains Sodium Polyacrylate, xanthans, sodium citrate, ironic citrate in the active ingredient Ammonium, sodium acetate, wherein Sodium Polyacrylate:Xanthans:Sodium citrate:Ferric citrate:Sodium acetate match ratio is (30-40): (5-10):(10-15):(2-5):(8-10) weight portion.
Above-mentioned fertilizer additive, the content of the water is identical with the parts by weight of active ingredient.
The present invention utilizes Sodium Polyacrylate, xanthans, sodium citrate, ferric citrate, five kinds of raw materials of sodium acetate in proportion It is made the liquiform product of additive, wherein, each component act as:
Sodium Polyacrylate:It is a kind of water-soluble high-molecular compound, molecular weight can reach several ten million, thick gel, nothing Corrosivity, nontoxic, tasteless, water imbibition are extremely strong, can quickly blot the moisture content on granular chemical fertilizer surface.
Xanthans, also known as Xanthan Gum:It is soluble in water, solution neutral, due to its macromolecular special construction and colloid Characteristic, so as to strengthen the cohesive force of fertilizer, makes to be combined with each other inside particle, is distributed in the network structure of particle, forms stabilization Cluster of grains colloid, prevent from pellet moisture from oozing out to form crystal brige and make fertilizer agglomeration.
The compositions such as citrate, acetate, can adjust the PH levels of fertilizer additive, make fertilizer fixation, highlight.
The present invention furthermore provides the preparation method of fertilizer additive, the chemical fertilizer mainly include composite fertilizer, Chemical Mixed Fertilizer, Compoiste fertilizer, inorganic composite fertilizer or Water soluble fertilizer etc.;These chemical fertilizer are conventional powder or granular N, P or K fertilizer, Yi Jizhong The fertilizer of amount or trace element.It is preferred that powdered or granular urea, ammonium chloride, ammonium nitrate, ammonium sulfate, MAP, phosphorus The fertilizer such as sour two ammoniums, calcium superphosphate, coarse whiting, potassium chloride, potassium sulfate.
Its preparation method is:
A kind of method for preparing above-mentioned fertilizer additive, under 50 DEG C of constant temperatures, using above-mentioned each composition and match ratio, With Sodium Polyacrylate as primary raw material, mix to other active ingredients of certainty ratio, add water, stir, that is, liquid is obtained The fertilizer additive of shape.
Fertilizer additive of the invention is with the mixed ratio of chemical fertilizer, fertilizer additive:Fertilizer is 0.05-5:1000 weight Part, preferably 0.1-2:1000 weight portions.
The processing step that uses of the present invention for:Fertilizer additive is sprayed directly on granular chemical fertilizer surface, is well mixed, made It quickly forms a kind of diaphragm.Sprinkling is sprayed preferably before finished product fills bag, in coating cylinder in the form of spraying.
The present invention can increase the brightness of chemical fertilizer appearance when above-mentioned fertilizer additive is sprayed on chemical fertilizer products, increase Plus the intensity of particle, chemical fertilizer hydroscopicity is reduced, solid chemical fertilizer particle from caking is prevented, increase the ratio of discrete particles, improve chemical fertilizer The slow release of active ingredient, the final drug effect for improving chemical fertilizer.
Using fertilizer prepared by fertilizer additive of the invention, bright in appearance can increase more than the newton of granule strength 5;Inhale Wet rate reduction 30-60%, discrete particles up to more than 95%, reach as high as more than 98%;Increase the storage time of fertilizer, making The active ingredient of fertilizer can slowly discharge, and fertilizer efficiency can improve 5%-20%.
Production process of the invention is produced without " three wastes ", safety and environmental protection.
Specific embodiment
Embodiment 1
Formula:
3 kilograms of Sodium Polyacrylate, 0.5 kilogram of xanthans, 1 kilogram of sodium citrate, 0.2 kilogram of ferric citrate, sodium acetate 0.8 kilogram.
Operating procedure:
In proportion by 2.2 kg of water addition mixture tank, 50 DEG C are heated up to, add 3 kilograms of Sodium Polyacrylate and xanthans 0.5 kilogram is stirred 10-15 minutes, and water and 1 kilogram of sodium citrate, the ferric citrate 0.2 for being subsequently adding 3.3 kilograms are public Jin, 0.8 kilogram of sodium acetate keeps the temperature at 50 DEG C, carries out sufficiently stirring and can obtain liquid finished product.
Embodiment 2
Formula:
3.5 kilograms of Sodium Polyacrylate, 0.8 kilogram of xanthans, 1.2 kilograms of sodium citrate, 0.3 kilogram of ferric citrate, second 0.9 kilogram of sour sodium.
Operating procedure:
In proportion by 2.68 kilograms of water addition mixture tank, 50 DEG C are heated up to, add 3.5 kilograms of Sodium Polyacrylate and Huang 0.8 kilogram of virgin rubber is stirred 10-15 minutes, is subsequently adding 4.02 kilograms of water and 1.2 kilograms of sodium citrate, ferric citrate 0.3 kilogram, sodium acetate kilogram 0.9%, keep the temperature at 50 DEG C, carry out sufficiently stirring and can obtain liquid finished product.
Embodiment 3
Formula:
40 kilograms of Sodium Polyacrylate, 10 kilograms of xanthans, 15 kilograms of sodium citrate, 5 kilograms of ferric citrate, sodium acetate 10 Kilogram.
Operating procedure:
In proportion by 32 kg of water addition mixture tank, 50 DEG C are heated up to, add 40 kilograms of Sodium Polyacrylate and xanthans 10 kilograms are stirred 10-15 minutes, are subsequently adding 48 kilograms of water and 15 kilograms of sodium citrate, 5 kilograms of ferric citrate, second 10 kilograms of sour sodium, keeps the temperature at 50 DEG C, carries out sufficiently stirring and can obtain liquid finished product.
Embodiment 4
In 0.5 kilogram of ratio of fertilizer additive of the present invention of fertilizer per ton, to the chemical fertilizer being made, bag is filled in finished product Before, in coating cylinder, in the form of spraying, the particle that above-mentioned fertilizer additive is sprayed on chemical fertilizer in the form of spraying is shown, and It is mixed uniform.
Beneficial effect
The present invention is fertilizer additive, is the anti-caking fixation brightener of liquid.In production process without dust, can degrade, Produced without " three wastes ", instead of the powdery anti-caking agent and oily anti-skinning agent in existing market, both anti-caking agent, the former dust Greatly, it is non-degradable;The latter is more with waste oil as primary raw material, has stink, is equally not easy to degraded.The present invention is easy to use, directly sprays Granular chemical fertilizer surface is sprinkled upon, it is quickly formed a kind of diaphragm, prevent it from luming, granulated fertilizer period of storage can be made to reach 12 More than individual month.
Compound fertilizer in existing market is generally color grains shape, and moisture-sensitive efflorescence, colour fading, fertilizer efficiency reduction influence benefit. The present invention can increase the hardness of chemical fertilizer granule, prevent its efflorescence, fade, play slow releasing function, increase fertilizer efficiency more than 20%.
The present invention granular chemical fertilizer is not only played anti-caking, fixation, sustained release etc. effect, while also act as increase particle brightness, Hardness, granular chemical fertilizer is kept loose, to be truly realized that only can play increase particle to granular chemical fertilizer simultaneously with a kind of product hard Spend, do not fade, not efflorescence, anti-compaction, sustained release increase fertilizer efficiency, extension pilling up time, increase the effect such as particle brightness, use cost Reduce by more than 20%.

Claims (9)

1. a kind of fertilizer additive, including active ingredient and water, it is characterised in that contain Sodium Polyacrylate in the active ingredient And xanthans, wherein Sodium Polyacrylate:The match ratio of xanthans is (30-40):(5-10) weight portion.
2. fertilizer additive according to claim 1, it is characterised in that contain Sodium Polyacrylate, Huang in the active ingredient Virgin rubber, citrate, acetate, wherein Sodium Polyacrylate:Xanthans:Citrate:Acetate match ratio is (30-40): (5-10):(12-20):(8-10) weight portion.
3. fertilizer additive according to claim 2, it is characterised in that contain Sodium Polyacrylate, Huang in the active ingredient Virgin rubber, sodium citrate, ferric citrate, sodium acetate, wherein Sodium Polyacrylate:Xanthans:Sodium citrate:Ferric citrate:Second Sour sodium match ratio is (30-40):(5-10):(10-15):(2-5):(8-10) weight portion.
4. fertilizer additive according to claim 3, it is characterised in that the content of the water and the parts by weight of active ingredient It is identical.
5. a kind of method for preparing the fertilizer additive as described in claim any one of 1-4, it is characterised in that in 50 DEG C of constant temperature bars Under part, using above-mentioned active ingredient and match ratio, with Sodium Polyacrylate as primary raw material, mix to certainty ratio other effectively into Point, water is added, stir, that is, the fertilizer additive of liquid is obtained.
6. according to claim 1-4 any one rights fertilizer additive purposes, it is characterised in that above-mentioned fertilizer is added Plus agent is sprayed on chemical fertilizer products.
7. the purposes of fertilizer additive according to claim 6, it is characterised in that the chemical fertilizer products are composite fertilizer, compound Fertilizer, compoiste fertilizer, inorganic composite fertilizer or Water soluble fertilizer.
8. the purposes of fertilizer additive according to claim 7, it is characterised in that the fertilizer additive is mixed with chemical fertilizer Ratio is, fertilizer additive:Fertilizer is (0.05-5):1000 weight portions.
9. the purposes of fertilizer additive according to claim 8, it is characterised in that be sprayed directly on the fertilizer additive Granular chemical fertilizer surface, is well mixed, and it is quickly formed a kind of diaphragm.
CN201710086580.4A 2017-02-17 2017-02-17 Fertilizer additive and preparation method and use thereof Pending CN106699414A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710086580.4A CN106699414A (en) 2017-02-17 2017-02-17 Fertilizer additive and preparation method and use thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710086580.4A CN106699414A (en) 2017-02-17 2017-02-17 Fertilizer additive and preparation method and use thereof

Publications (1)

Publication Number Publication Date
CN106699414A true CN106699414A (en) 2017-05-24

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Country Status (1)

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CN (1) CN106699414A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619667A (en) * 2017-08-31 2018-01-23 寿光园林建设集团有限公司 A kind of greenery patches restoration of the ecosystem composition and its production method
CN107857667A (en) * 2017-09-30 2018-03-30 无为县良峰苗木花卉种植专业合作社 A kind of fertilizer additive

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1785937A (en) * 2004-12-06 2006-06-14 邵建华 Multifunction chemical fertilizer coating agent and its preparation method
CN101654387A (en) * 2008-08-21 2010-02-24 北京科普基业精细化工科技有限公司 Liquid anti-caking agent for compound fertilizer
CN102153408A (en) * 2011-03-15 2011-08-17 山东省农业科学院农业资源与环境研究所 Antiblocking agent for macroelement water-dissolvable fertilizer, as well as preparation and application of the antiblocking agent
CN102992896A (en) * 2012-11-27 2013-03-27 深圳市芭田生态工程股份有限公司 Powdery multi-element fertilizer anti-hardening additive and application thereof
CN104151442A (en) * 2014-08-01 2014-11-19 中国海洋石油总公司 Surface hydrophobic modified xanthan gum and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1785937A (en) * 2004-12-06 2006-06-14 邵建华 Multifunction chemical fertilizer coating agent and its preparation method
CN101654387A (en) * 2008-08-21 2010-02-24 北京科普基业精细化工科技有限公司 Liquid anti-caking agent for compound fertilizer
CN102153408A (en) * 2011-03-15 2011-08-17 山东省农业科学院农业资源与环境研究所 Antiblocking agent for macroelement water-dissolvable fertilizer, as well as preparation and application of the antiblocking agent
CN102992896A (en) * 2012-11-27 2013-03-27 深圳市芭田生态工程股份有限公司 Powdery multi-element fertilizer anti-hardening additive and application thereof
CN104151442A (en) * 2014-08-01 2014-11-19 中国海洋石油总公司 Surface hydrophobic modified xanthan gum and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619667A (en) * 2017-08-31 2018-01-23 寿光园林建设集团有限公司 A kind of greenery patches restoration of the ecosystem composition and its production method
CN107857667A (en) * 2017-09-30 2018-03-30 无为县良峰苗木花卉种植专业合作社 A kind of fertilizer additive

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