CN106691877A - Transparent spraying type ultraviolet blocking composition containing organic ultraviolet blocker - Google Patents
Transparent spraying type ultraviolet blocking composition containing organic ultraviolet blocker Download PDFInfo
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- CN106691877A CN106691877A CN201510492624.4A CN201510492624A CN106691877A CN 106691877 A CN106691877 A CN 106691877A CN 201510492624 A CN201510492624 A CN 201510492624A CN 106691877 A CN106691877 A CN 106691877A
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Abstract
The invention relates to a transparent spraying type ultraviolet blocking composition containing an organic ultraviolet blocker, ethanol, oil and purified water. The ultraviolet B blocking coefficient of the transparent spraying type ultraviolet blocking composition containing the organic ultraviolet blocker, ethanol, oil and purified water is SPF50 or above, the ultraviolet A blocking grade keeps PA+++, and the composition has cooling and makeup finishing functions, has no white turbidity phenomenon, and can be used for dry skins and wet skins.
Description
Technical field
The present invention relates to the transparent ejection-type ultraviolet blocking combination containing organic uv blocking agent
Thing, more specifically, is related to contain the transparent of organic uv blocking agent, ethanol, oil and purified water
Ejection-type ultraviolet blocking composition.
Background technology
Recently, with the destruction of the ozone layer caused by environmental pollution, ultraviolet is caused to reach ground surface
Amount increase, therefore, the influence caused to human body for ultraviolet carries out numerous studies, wherein, most
Representative research is related to the problem of the skin aging produced due to being constantly exposed to ultraviolet.
As the method for delaying skin ageing phenomenon described above, primary method be by using
UV blockers reduce method of the ultraviolet to Cutaneous permeation, in connection with this, currently just carry out
The ultraviolet resistance for the protection skin from ultraviolet (especially, ultraviolet light,long wave, B (UV-A, B))
Many research of disconnected composition.
Currently, the UV blockers for being used in cosmetic industry are broadly divided into inorganic UV blocking
Agent and organic uv blocking agent.Inorganic UV blocking agent is only acted on as that will not be absorbed by the skin
In the material on surface, with reflecting and disperse the physical property of ultraviolet.Due to inorganic UV blocking
The refractive index of agent is high, thus while having very big effect to scatters ultraviolet, but works as inorganic UV
When line blocking agent is coated on skin, with sticky use feeling, feel and clouding, so as to cause not
Suitable sense, if also, do not smear out carefully, occur as soon as gonorrhoea phenomenon so that skin seems Tai Bai or gloomy
Or make skin heavy wool.Organic uv blocking agent refers to lock in intramolecular by by solar energy, so as to inhale
Ultraviolet is received, so as to show the material of ultraviolet barrier effect.Different from inorganic UV blocking agent,
It is not in gonorrhoea phenomenon that organic uv blocking agent has, and smear is good, and the few spy of fat constituent
Point.
The product major part of ultraviolet barrier effect is typically exhibited out containing inorganic UV blocking agent or is had
Machine UV blockers, be made by way of it is uniformly disperseed or is emulsified emulsion or
The product of creme is more.Also, with containing gas by making content, so as to by gas come with
The product of spray regime injection.But this formulation is not appropriate for for the skin with sweat or moisture.
For example, in South Korea logs in special permission 10-1002866, although with containing organic uv blocking agent and
The ultraviolet high blocking coefficient of the water in oil latex form of inorganic UV blocking agent, but gonorrhoea phenomenon
Seriously, and if be applied to moist skin, there is product and be difficult to be coated on skin, occur objectionable intermingling or
The phenomenon of accumulation.Also, South Korea logs in special permission 10-0678790 as oil type emulsification composition in water,
Though having ultraviolet block function, occur emulsion during moist skin due to being coated on, thus cannot
For moist skin.
Because the content of ejection-type ultraviolet blocking product is sprayed with mist form, thus can be easy
Be coated on the skin of large area, so as to be mainly used in body.But due to inorganic UV blocking agent
Powder condenses the blocking of the valve for causing, thus is gone wrong in terms of jet power, inorganic UV blocking agent
Use be restricted, and be difficult to expect ultraviolet barrier effect high.Thus utilize butyl octanol water
The powder such as poplar acid esters (Butyloctyl Salicylate) or film forming agent, silica hinders as ultraviolet
Disconnected reinforcing agent, makes every effort to improve ultraviolet blocking index, but ultraviolet blocking coefficient is not above using nothing
Coefficient during machine UV blockers, even and if using inorganic UV blocking agent, also because valve is blocked
And substantial amounts of inorganic UV blocking agent cannot be used, therefore, it is difficult to be expected by ejection-type as common
Creme or emulsion-type ultraviolet blocking index for SPF50, ultraviolet light,long wave blocking grade be PA+++ with
On effect.
Also, Korean Patent Laid-Open 10-2013-0048886 has in applicable inorganic UV blocking agent
In the case of to be sprayed to the ejection-type formulation with ultraviolet blocking index high or moist skin, condense or
Gonorrhoea phenomenon is serious, and in the case where clothes is bonded at, has the shortcomings that to produce white spot.It is difficult to
Expect that convenience is outstanding, no matter can be used in any case in moist skin or dry skin etc., and do not have
There is the ejection-type formulation with SPF50+, PA+++ of gonorrhoea phenomenon.
In this regard, the present inventor has carried out continuous effort and has ground to solve above-mentioned problem of the prior art
Study carefully, as a result, confirm that the ejection-type containing organic uv blocking agent, ethanol, oil and purified water is purple
The UV-B blocking coefficient of the ejection-type UV blockers of outside line blocking composition be SPF50 with
On, ultraviolet light,long wave blocking grade keeps PA+++, with cooling down and function of fixing, and go be not in
Gonorrhoea phenomenon, can be used for dry skin and moist skin, so as to complete the present invention.
Patent document 1：Korean Patent Laid-Open KR10-2013-0048886A
Patent document 2：South Korea logs in special permission KR10-1002866B
Patent document 3：South Korea logs in special permission KR10-0678790B
The content of the invention
Therefore, it is a primary object of the present invention to, there is provided using with cooling down and function of fixing, without white
Turbid phenomenon, and can be used for the transparent ejection-type ultraviolet blocking of the organic uv blocking agent of moist skin
Use composition.
According to an embodiment of the present invention, the present invention provide containing organic uv blocking agent, ethanol,
The transparent ejection-type ultraviolet blocking composition of oil and purified water.
It is a feature of the present invention that the ultraviolet blocking coefficient of above-mentioned composition is more than SPF50, it is purple
Outside line A blocking grades are PA+++.
Embodiments in accordance with the present invention, to the ejection-type ultraviolet blocking combination containing above-mentioned composition
The ultraviolet of thing (embodiment 1 to embodiment 4) blocks coefficient (SPF) and ultraviolet light,long wave blocking grade
(PA) result being measured, all of ultraviolet blocking coefficient is more than SPF50, ultraviolet light,long wave
Blocking grade is PA+++.By this result, transparent ejection-type ultraviolet blocking of the invention
Ultraviolet is blocked with composition highly effective.
It is a feature of the present invention that organic uv of the above-mentioned composition comprising 5 to 50 percentage by weights
Blocking agent, the ethanol of 1 to 60 percentage by weight, the oil and 1 to 30 weight of 1 to 30 percentage by weight
Measure the purified water of percentage.
In the present compositions, the organic uv blocking agent containing 5 to 50 percentage by weights,
When containing organic uv blocking agent less than 5 percentage by weights, it is impossible to expect ultraviolet blocking high
Agent, in the case of containing the organic uv blocking agent more than 50 percentage by weights, reduces use feeling
And cutaneous safety.
In the compositions of the present invention, ethanol can improve use feeling, improve the solubility of cooling sense and raw material,
Especially, the solubility of UV blockers is improved, such that it is able to be made transparent formulation.In order to embody
The effect above, the ethanol containing 1 to 60 percentage by weight, when containing the second less than 1 percentage by weight
During alcohol, it is impossible to expect cooling sense and the improvement of solubility, containing the ethanol more than 50 percentage by weights
In the case of, reduce cutaneous safety and smell.
According to the present invention, the present invention increases to 50 percentage by weights, makes ethanol generation by by the amount of ethanol
Improve the gonorrhoea phenomenon of the shortcoming occurred during as containing surfactant for Action of Surfactant,
Can be used for moist skin, and increase cooling effect.
In the present compositions, oil component can improve the solubility and use feeling of UV blockers,
Especially having improves the effect of viscosity.In order to embody the effect above, contain 1 to 30 percentage by weight
Oil component, when containing less than 1 percentage by weight it is oily when, it is impossible to expect improve solubility and use feeling,
In the case of containing the oil more than 30 percentage by weights, use feeling is reduced.
In the present compositions, used pure to dissolving UV blockers and assign moisture sense
Change water, the purified water containing 1 to 30 percentage by weight, when containing the purifying less than 1 percentage by weight
During water, it is impossible to solubility and moisture sense are expected, in the feelings containing the purified water more than 30 percentage by weights
Under condition, the stability of formulation is reduced.
It is a feature of the present invention that above-mentioned organic uv blocking agent is selected from by Homosalate
(Homosalate), salicylic acid isooctyl ester (Ethylhexyl salicylate), phenylbenzimidazol
Sulfonic acid (Phenylbenzimidazole Sulfonic Acid), Octocrilene (Octocrylene),
Ethylhexyl methoxy cinnamate (Ethylhexyl Methoxycinnamate), palm acid ethyl oneself
Ester (Ethylhexyl Palmitate), butylmethoxydibenzoylmethane (Butyl
Methoxydibenzoy lmethane) and BEMT
(Bis-ethylhexyloxyphenolmethoxyphenyltriazine) one kind in the group of composition
More than.
It is a feature of the present invention that above-mentioned grease separation freely includes saualane (Squalane) or mineral matter
Oil hydrocarbon-type oil, comprising isopropyl palmitate (Isopropyl Palmitate), 2- octyldodecyls
Base myristinate (2-Octyldodecyl Myristate), isopropyl myristate (Isopropyl
Myristate), C12-15 alcohol benzoic ethers (C12-15 Alkyl Benzoate), carbonic acid dioctyl ester
The Esters oil of (Dicaprylyl Carbonate) or butyl octanol salicylate, comprising castor oil,
The vegetable oil of olive oil or SIMMONDSIA CHINENSIS SEED OIL and comprising cyclomethicone (Cyclomethicone) or diformazan silicon
One or more of the group of silicone oil composition of oily (Dimethicone).
Also, composition known to the technical field of the invention can also be included in composition of the invention,
For example, ethylenediamine tetra-acetic acid (EDTA), NMF, fatty material, moistening material, silicon, oil, perfume (or spice)
Material, preservative, clarifier (sugar, alcohol), vitamin, protein, pigment etc. are commonly used for preparing
The composition of UV blockers is used as the common any condition for keeping basic physical properties and quality.
Also, in addition to mentioned component, composition of the invention can also include antioxidant, skin
Skin conditioning ingredients, pH modifying ingredients, skin sparing composition etc..
In the present invention, the liquefied gas that may be selected to be generally used for aerosol container sprays as above-mentioned aerosol
Agent is used, it is preferable that can mix selected from by liquefied petroleum gas (LPG), propane (Propane),
Normal butane (n-butane), iso-butane (Isobutane), dimethyl ether (Dimethyl ether),
One or more of group of nitrogen and tetrafluoropropene (Tetrafluoropropene) composition is used.
In the present compositions, relative to composition total weight, 10 to 90 weight can be included
The above-mentioned propellant of percentage, it is preferable that the above-mentioned propellant of 40 to 60 percentage by weights can be included.
When using the above-mentioned propellant for being less than 10 percentage by weights, it is impossible to obtain expected effect, make
In the case of with the above-mentioned propellant more than 90 percentage by weights, there is frostbite because injection pressure is too strong
Hidden danger, and cause the usability to reduce because content disperses.
It is a feature of the present invention that above-mentioned composition does not include surfactant.
Embodiments in accordance with the present invention, in the organic uv blocking agent comprising surfactant or applicable
The ejection-type UV blockers (comparative example 4 and comparative example 5) of organic/inorganic UV blockers
In the case of, there is gonorrhoea phenomenon, and be difficult with moist skin (Fig. 2 and Fig. 3), but be applicable and do not wrap
In the case of organic uv blocking agent (embodiment 1 to embodiment 4) containing surfactant, not only
Gonorrhoea phenomenon is occurred without, and moist skin (Fig. 1) can be used in.By this result,
In the case of not comprising surfactant, gonorrhoea phenomenon is occurred without, even and if by the spray without gonorrhoea phenomenon
Emitting UV blockers are used for face, are also not bound to hair or clothes, thus easy to use.
It is a feature of the present invention that above-mentioned composition has refrigerating function and function of fixing.
Embodiments in accordance with the present invention, it is thus identified that in the case where the UV blockers of ethanol are not used,
Almost without cooling effect, but in the case of using ejection-type UV blockers of the invention, have
Cooling effect.Also, in the case of comparative example 1 to comparative example 3, due to occur gonorrhoea phenomenon and
Immiscible phenomenon and be difficult to measure and fix function, in the case of comparative example 4 and comparative example 5, although
Somewhat fix effect, but when by (12 hours) for a long time, fail maintenance and fix effect, and
Due to gonorrhoea phenomenon, occur the phenomenon for being bonded at hair and clothes when causing to be coated on face, thus use
Get up and inconvenient.On the contrary, ejection-type UV blockers of the invention are coated on after making up
When facial, due to being sprayed with transparent proterties, so that there is not gonorrhoea phenomenon and immiscible phenomenon, and
Even across for a long time (12 hours), effect of fixing also is kept.By this result, the present invention
Ejection-type UV blockers composition (embodiment 1 to embodiment 4) due to occurring without gonorrhoea phenomenon,
Be not in the phenomenon for being bonded at hair and clothes thus when face, so as to have easy to use
Advantage, and with significant cooling effect (experimental example 2) and for keep make up effect of fixing
(experimental example 3), therefore, it is suitable as transparent ejection-type UV blockers composition.
It is a feature of the present invention that above-mentioned composition is not in gonorrhoea phenomenon.
Embodiments in accordance with the present invention, in the ejection-type UV blockers (ratio comprising surfactant
Compared with example 4 and comparative example 5) in the case of, there is gonorrhoea phenomenon, and be difficult with moist skin (Fig. 2
And Fig. 3), but the ejection-type UV blockers (embodiment 1 to implementation of surfactant is not being included
Example 4) in the case of, gonorrhoea phenomenon is not only occurred without, and moist skin (Fig. 1) can be used in.
By this result, ejection-type UV blockers composition of the invention is due to occurring without gonorrhoea
Phenomenon, thus the phenomenon for being bonded at hair and clothes is occurred without, such that it is able to be used in face, therefore,
It is suitable as transparent ejection-type UV blockers composition.
It is a feature of the present invention that above-mentioned composition can be used in dry skin and moist skin.
As described above, containing transparent ejection-type ultraviolet blocking group using provided by the present invention
In the case of the ejection-type UV blockers of compound, UV-B blocking coefficient is more than SPF50,
Ultraviolet light,long wave blocking grade keeps PA+++, and occurs without gonorrhoea phenomenon, thus can effectively be used in
Dry skin and moist skin, there is provided outstanding jet power, and with cooling effect and function of fixing, so that
Leisure use or the day for being adapted to open air are conventional.
Brief description of the drawings
Fig. 1 is that the photograph after ultraviolet blocking composition of the invention is sprayed to dry skin and moist skin
Piece.
Fig. 2 is the injection formulation (comparative example that organic/inorganic UV blockers are applicable to moist skin injection
4) photo after.
Fig. 3 is the injection formulation (comparative example 5) that organic uv blocking agent is only applicable to moist skin injection
Photo afterwards.
Fig. 4 is the photo of the cooling effect for showing ultraviolet blocking composition of the invention.
Fig. 5 is the photo of the effect of fixing for showing ultraviolet blocking composition of the invention.
Specific embodiment
Hereinafter, the present invention is described in more details by embodiment.But these embodiments are only used
In the present invention is illustrated, the scope of the present invention should not be construed as and be to be restricted to such embodiments.
Embodiment 1 is to embodiment 4：The transparent organic purple of ejection-type of the constituent based on oil and ethanol
The preparation of outside line blocking agent
Embodiment 1 to embodiment 4 is to change oil phase to prepare ejection-type ultraviolet blocking cosmetics
Optimize the formula of viscosity, cooling sense and jet power with the constituent of ethanol etc..
According to the composition ratio of table 1 below, by organic uv blocking agent (methoxy cinnamic acid ethyl
Own ester, Homosalate, ethylhexyl salicylate, butylmethoxydibenzoylmethane, Losec stand
Woods, BEMT) and oil-phase component (dimeticone, the poly- silicon of pungent methyl
Oxygen alkane, cetyl dimethicone (Cetyl Dimethicone), ethylhexyl palmitate,
Cyclopentasiloxane (Cyclopentasiloxane), acrylate/dimethicone copolymer) it is heated to
80 DEG C, and after being made identical phase, ethanol and spices is mixed and is dissolved by dissolving.Water is coordinated
The organic uv blocking agent (Phenylbenzimidazolesulfonic acid) and water for dividing mutually individually dissolving, and add successively
Calais is made after solvable state, with aerosol stoste:(ratio of components is propane to liquefied petroleum gas:Butane
=30wt%:70wt%)=50wt%:The ratio of 50wt% is by aerosol stoste is mounted in aluminium pot and covers (Capping)
Valve, afterwards filling gas and rocked prepare ultraviolet blocking composition.
Table 1
Comparative example 1 is to comparative example 2：The preparation of white shape UV blockers
Comparative example 1 is prepared for oil type frost shape ultraviolet blocking cosmetics in water.
According to the composition ratio of table 1, using water phase, (purified water, aminomethyl propanol are mutually organic with as water
The Phenylbenzimidazolesulfonic acid of UV blockers) 80 DEG C are heated to, and be made by dissolving identical
Phase, and by organic uv blocking agent (ethylhexyl methoxy cinnamate, Homosalate, salicylic acid
Octyl Nitrite, butylmethoxydibenzoylmethane, Octocrilene, double-ethyl hexyl oxy phenol methoxy
Phenyl triazine), oil-phase component (dimeticone, pungent methyl polysiloxane, cetyl polydimethylsiloxanes
Alkane, ethylhexyl palmitate, cyclopentasiloxane, acrylate/dimethicone copolymer) and surface work
Property agent (three (ceteareth -4) phosphates (Triceteareth-4phosphate)/hard
Resin acid glycol ester (Glycol Stearate)/PEG-2 stearates (PEG-2stearate)~
Polysorbate 60 (Polysorbate60)) composition is heated to 80 DEG C, and be made by dissolving identical
Xiang Hou, is mutually stirred with homogeneous mixer to water, and adds oil phase successively, is stirred 5 minutes afterwards
Left and right.Here, addition is scattered in the acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymerics of suitable quantity of water
Thing (Acrylates/C10-30Alkyl Acrylate Crosspolymer), and use homogeneous mixer
Stirring 5 minutes.After addition triethanolamine (Triethanolamine), stirred with homogeneous mixer
5 minutes or so, it is being cooled to 45 DEG C afterwards, is adding appropriate spices, then 2 are stirred with homogeneous mixer
Minute or so, and it is cooled to 30 DEG C, oil type ultraviolet sun screen in water is prepared for this.
Comparative example 2 is prepared for water in oil frost shape ultraviolet blocking cosmetics.
According to the composition ratio of table 1, using water phase (purified water, aminomethyl propanol and mutually organic as water
The Phenylbenzimidazolesulfonic acid of UV blockers) it is completely dissolved and is made identical phase, by organic ultraviolet
Line blocking agent (ethylhexyl methoxy cinnamate, Homosalate, ethylhexyl salicylate, butyl first
Epoxide dibenzoyl methane, Octocrilene, BEMT), oil phase
Composition (dimeticone, pungent methyl polysiloxane, cetyl dimethicone, palm acid ethyl
Own ester, cyclopentasiloxane, acrylate/dimethicone copolymer) and surfactant (PEG-10 bis-
First silicone oil and palmityl PEG/PPG-10/1 dimeticones) 80 DEG C are heated to, and be made by dissolving
After identical phase, 30 DEG C are cooled to, and add appropriate spices.Oil phase is stirred with homogeneous mixer, and
Water phase is slowly added, after stirring 20 minutes or so, water in oil ultraviolet sun screen is made.
Comparative example 3：The preparation of ejection-type inorganic UV blocking agent
Comparative example 3 is prepared for only being applicable the ejection-type blocking cosmetics of inorganic UV blocking agent.According to
The composition ratio of table 1, is dissolved after water phase (purified water and aminomethyl propanol) is heated into 80 DEG C
It is made identical phase, and by oil-phase component (dimeticone, pungent methyl polysiloxane, the poly- diformazan of cetyl
Radical siloxane, ethylhexyl palmitate, cyclopentasiloxane, acrylate/dimethicone copolymer) and
Inorganic UV blocking agent (titanium dioxide/aluminium hydroxide stearic acid) and surfactant (lauroyl sodium
Smooth stearate/the trideceth -12 of/sorb and the phosphate of PPG-5- ceteths -10) composition
Be heated to it is after 80s after dissolving is made identical phase, oil phase is stirred with homogeneous mixer, and by
Gradually stirred 20 minutes or so after addition water phase, 45 DEG C are cooled to afterwards.Addition appropriate spices and ethanol
And it is cooled to 30 DEG C after being stirred 2 minutes or so with homogeneous mixer.With aerosol stoste：LPG (ratio of components
It is propane：Butane=30：70wt%)=50：The aerosol stoste that the ratio of 50wt% will be prepared is loaded on aluminium
Tank simultaneously covers (Capping) valve, afterwards filling gas and rocked prepare ejection-type ultraviolet resistance
Disconnected agent.
Comparative example 4：The preparation of ejection-type organic/inorganic UV blockers
Comparative example 4 is prepared for being applicable the ejection-type blocking cosmetics of organic/inorganic UV blockers.Root
According to the composition ratio of table 1, water phase (purified water~aminomethyl propanol) is heated to 80 DEG C, and pass through
Dissolve to be made identical phase, by organic uv blocking agent (ethylhexyl methoxy cinnamate, Hu Mo
Willow ester, ethylhexyl salicylate, butylmethoxydibenzoylmethane, Octocrilene, double-ethyl
Own oxy phenol anisyl triazine), inorganic UV blocking agent (titanium dioxide (Titanium Dioxide)
/ aluminium hydroxide stearic acid (Aluminum hydroxide stearic acid)) and oil-phase component and table
Face activating agent (three (ceteareth -4) phosphate/glycol stearate/PEG-2 stearic acid
Ester and polysorbate 60) composition is heated to 80 DEG C, and after being made identical phase, use homogeneous by dissolving
Mixer is mutually stirred to water, and be slowly added oil phase and stir 10 minutes or so after, be cooled to
45℃.The appropriate spices and ethanol of addition, and after being stirred 2 minutes or so with homogeneous mixer, cooling
To 30 DEG C.With aerosol stoste:(ratio of components is propane to LPG:Butane=30wt%:70wt%)=50wt%:50wt%
The aerosol stoste that will prepare of ratio filling gas and rocked mounted in aluminium pot and valve in head, afterwards
Prepare ejection-type UV blockers.
Comparative example 5：The preparation of the ejection-type organic uv blocking agent containing surfactant
Comparative example 5 is prepared for the ejection-type blockingization containing organic uv blocking agent and surfactant
Cosmetic.According to the composition ratio of table 1, water phase (purified water~aminomethyl propanol) is heated to 80 DEG C,
And be made identical phase by dissolving, by organic uv blocking agent (ethylhexyl methoxy cinnamate,
Homosalate, ethylhexyl salicylate, butylmethoxydibenzoylmethane, Octocrilene, it is double-
Ethyl hexyl oxy phenol anisyl triazine) and oil-phase component and surfactant (three (cetostearyl alcohols
Polyethers -4) phosphate/glycol stearate/PEG-2 stearates and polysorbate 60) composition adds
Heat after being made identical phase, is mutually stirred with homogeneous mixer by dissolving to 80 DEG C to water,
And oil phase is slowly added, after stirring 10 minutes or so, it is cooled to 45 DEG C.The appropriate spices of addition and
Ethanol, and with homogeneous mixer stir 2 minutes or so after, be cooled to 30 DEG C.With aerosol stoste:LPG
(ratio of components is propane:Butane=30wt%:70wt%)=50wt%:The aerosol that the ratio of 50wt% will be prepared is former
Liquid filling gas and is rocked and is prepared the blocking of ejection-type ultraviolet mounted in aluminium pot and valve in head, afterwards
Agent.
Experimental example 1：The usability of use feeling and moist skin
Ultraviolet blocking to being prepared according to embodiment 1 to embodiment 4 and comparative example 1 to comparative example 5
The use feeling of agent and the use feeling of moist skin are tested.
As a result, as shown in figure 1, being only applicable organic uv and blocking by not containing surfactant
Agent can obtain the soft and salubrious group of no gonorrhoea phenomenon come embodiment 1 to the embodiment 4 for preparing
Compound.Especially, it is known that the composition of embodiment 1 and embodiment 2 containing substantial amounts of silicon class and ethanol
Feel with salubrious use feeling and cooling and be applicable to moist skin.
Conversely, by comparative example 1 be applied to moist skin when, due to occur emulsion, thus be difficult to by
UV blockers are coated on skin, so as to ultraviolet barrier effect cannot be expected.By comparative example 2 to
When comparative example 3 is applied to moist skin, there is gonorrhoea phenomenon, and because tight use feeling is without logical
The normal use feeling expected in cosmetics, because cannot it is soft, be uniformly applied to face be difficult to the phase
Treat ultraviolet barrier effect.Also, as shown in Fig. 2 in the ejection-type organic ultraviolet containing activating agent
In the case of line blocking agent (comparative example 5), occur gonorrhoea phenomenon, and be difficult with because of emulsification in
Moist skin, and in ejection-type organic/inorganic UV blockers (comparative example 4) containing surfactant
In the case of, there is gonorrhoea phenomenon.
Experimental example 2：The measure of ultraviolet blocking coefficient (SPF), ultraviolet light,long wave blocks grade (PA)
Measure
The ultraviolet barrier effect of the UV blockers composition to being prepared according to embodiment 1 is carried out
Test." standards and method of testing of functional cosmetics " of Room bulletin are managed according to food and medicine
In " ultraviolet block function method of testing ", to ultraviolet block coefficient and ultraviolet light,long wave blocking grade
PA has carried out following test, by transparent plastic adhesive tape (Transpore Tape：3M, USA) attachment
In after ready model (cast), using sample 2mg/cm2Carry out coating composition, purple is used afterwards
Outside line (UV) measuring instrument (analyzers of SPF 290 (Analyzer)) come determine ultraviolet blocking effect
Really, the measure of ultraviolet light,long wave blocking grade PA has been used and has been provided with 300W xenon arc lamps (xenonarc lamp)
As solar simulator (the Multi-port Solar of the artificial ultra violet radiation instrument-multiport of light source
Simulator) 601-300W (Solar lamp (Solar Light) company, the U.S.), and utilize three
Ultraviolet photometer (3D UV meter) (Solar lamp company, the U.S.) is tieed up to determine light intensity, so that
Determine embodiment 1 and blocked to the ultraviolet of the composition of comparative example 5 to embodiment 4 and comparative example 1 and be
Number SPF and ultraviolet light,long wave blocking grade PA.Measurement result is as follows.Ultraviolet is blocked into coefficient with 3 times
The average value of experiment value is arranged, and its result is presented in table 2 below.
Table 2
By the value shown in above-mentioned table 2, the comparative example 3 of organic uv blocking agent is being not used
In the case of, ultraviolet blocking coefficient cannot meet SPF50 and PA+++.
Experimental example 3：Cooling effect
The cooling effect of the UV blockers composition to being prepared according to embodiment and comparative example is carried out
Test.Cooling effect is implemented in the following way：Preceding, infrared radiation 10 minutes is used in product
Afterwards, random (randomization) mode is passed through using the time point after product 1 minute, by face
After left and right is divided into test product using position (test group) and does not use position (control group), from
Test coating part 15cm distances spray 2~3 times/second to test position.Using infrared camera
ThermacamTM PM360 shoot to whole face, and above-mentioned infrared camera is by each position temperature
Degree shows in numerical data mode, and according to temperature in different colors come the camera for representing, and it is sharp
With captured thermal imaging picture come analyzing skin temperature change, and with this to cooling (reduction temperature)
Effect is evaluated.In order to improve the skin temperature of facial, using infrared ray (Infrared
ray；IR after) lamp (infralux-300,220v/60hz) keeps 40cm distances, to entire surface
Portion is irradiated 10 minutes.Result is as follows.Cooling effect is arranged with 3 average values of experiment value, and will
Its result is presented in Table 3 below.
Table 3
By the value shown in above-mentioned table 3, the comparative example 1 of ethanol to comparative example 2 is being not used
In the case of, almost without cooling effect.
Embodiment 4：Fix effect
The effect of fixing of the UV blockers composition to being prepared according to embodiment and comparative example is carried out
Test.Cosmetic endurance after 200 μ l vanishing cream to be coated on whole face, from facial 30cm
Distance sprayed in the way of 3~4 times/second.Using before product, use 20 points of product
Clock, utilized using product 4 hours, using product 8 hours and using the time point after product 12 hours
As the Facial of face shots deviceDM-3 (jasmine Li Te (Moritex), Japan) comes
Whole face is shot, and utilizes the captured ultraviolet picture analyzing positive intensity of cheek
(Intensity) average value of (brightness).The position of uncoated product seems on ultraviolet picture
It is bright, thus intensity level (Intensity value) is high, and the position for applying product seems dark,
Thus intensity level is low.Result is as follows.Effect of fixing is arranged with the average value of 3 this measured value, and will
Its result is presented in table 4 below and Fig. 3.
Table 4
As shown in Table 4 above, in the case of comparative example 1, due to there is immiscible phenomenon, thus
Have the shortcomings that to be difficult to embody function of fixing, in the case of comparative example 2, because gonorrhoea sense is serious,
Thus have the shortcomings that usability is poor, in the case of comparative example 3, when face is used in, due to
Use feeling or gonorrhoea phenomenon are serious, thus have the shortcomings that formulation cannot be embodied.Because this gonorrhoea is existing
As and formulation embodiment in terms of problem, thus be difficult to measure and fix effect.In comparative example 4 and comparative example 5
In the case of, when ejection-type UV blockers are coated on into face after cosmetic, although there are some to determine
Adornment effect, but when by (12 hours) for a long time, it is impossible to effect of fixing is kept, and it is white because occurring
Turbid phenomenon and occur the phenomenon for being bonded at hair and clothes when face is coated on, so as to be not convenient to use.
On the contrary, when ejection-type UV blockers of the invention are coated on into face after cosmetic, this
The composition of invention is sprayed with transparent proterties, so that there is not gonorrhoea phenomenon and immiscible phenomenon, and
Even across for a long time (12 hours), effect of fixing also is kept.Also, the cooling effect of skin is also very
It is outstanding, and there is not gonorrhoea phenomenon yet in usability aspect, thus it is suitable for face.
Claims (10)
1. a kind of transparent ejection-type ultraviolet blocking composition containing organic uv blocking agent, it is special
Levy and be, contain organic uv blocking agent, ethanol, oil and purified water.
2. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
The ultraviolet blocking coefficient of above-mentioned composition is more than SPF50, and ultraviolet light,long wave blocking grade is PA+++.
3. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
Organic uv blocking agent, 1 to 60 percentage by weight of the above-mentioned composition comprising 5 to 50 percentage by weights
Ethanol, 1 to 30 percentage by weight oil and 1 to 30 percentage by weight purified water.
4. transparent ejection-type ultraviolet blocking composition according to claim 3, it is characterised in that
Above-mentioned organic uv blocking agent be selected from by Homosalate, salicylic acid isooctyl ester, Phenylbenzimidazolesulfonic acid,
Octocrilene, ethylhexyl methoxy cinnamate, ethylhexyl palmitate, butyl methoxy dibenzoyl base
One or more of group of methane and BEMT composition.
5. transparent ejection-type ultraviolet blocking composition according to claim 3, it is characterised in that
Above-mentioned grease separation freely includes the hydrocarbon-type oil of saualane or mineral oil；Comprising isopropyl palmitate, 2- octyl groups ten
Dialkyl group myristinate, isopropyl myristate, C12-15 alcohol benzoic ethers, carbonic acid dioctyl ester or butyl are pungent
The Esters oil of alcohol salicylate；Vegetable oil comprising castor oil, olive oil or SIMMONDSIA CHINENSIS SEED OIL；And comprising ring
One or more of group of silicone oil composition of first silicone oil or dimeticone.
6. transparent ejection-type ultraviolet blocking composition according to claim 3, it is characterised in that
Injection propellant is selected from by liquefied petroleum gas, propane, normal butane, iso-butane, dimethyl ether, nitrogen and four
One or more of group of fluoropropene composition.
7. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
Above-mentioned composition does not include surfactant.
8. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
Above-mentioned composition has refrigerating function and function of fixing.
9. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
Above-mentioned composition is not in gonorrhoea phenomenon.
10. transparent ejection-type ultraviolet blocking composition according to claim 1, it is characterised in that
Above-mentioned composition can be used in dry skin and moist skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510492624.4A CN106691877A (en) | 2015-08-12 | 2015-08-12 | Transparent spraying type ultraviolet blocking composition containing organic ultraviolet blocker |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510492624.4A CN106691877A (en) | 2015-08-12 | 2015-08-12 | Transparent spraying type ultraviolet blocking composition containing organic ultraviolet blocker |
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| Publication Number | Publication Date |
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| CN106691877A true CN106691877A (en) | 2017-05-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510492624.4A Pending CN106691877A (en) | 2015-08-12 | 2015-08-12 | Transparent spraying type ultraviolet blocking composition containing organic ultraviolet blocker |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110339092A (en) * | 2019-08-22 | 2019-10-18 | 广州亦妆生物科技有限公司 | It is a kind of with sun-proof and moisture-keeping functions homogeneous care composition |
| CN110368329A (en) * | 2019-08-22 | 2019-10-25 | 广州亦妆生物科技有限公司 | A kind of homogeneous care composition of not silicate-containing oil |
| CN110664661A (en) * | 2019-11-01 | 2020-01-10 | 陕西崇文生物科技有限公司 | Mild repairing skin-brightening sunscreen lotion and preparation method thereof |
| CN111481467A (en) * | 2019-01-25 | 2020-08-04 | 科丝美诗株式会社 | Cosmetic composition for blocking ultraviolet rays, which imparts cooling effect |
| CN115813813A (en) * | 2023-01-06 | 2023-03-21 | 湖北美凯化工有限公司 | Optical protection material and preparation method and application thereof |
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| KR20140021963A (en) * | 2013-07-11 | 2014-02-21 | 코스맥스 주식회사 | Spray type sun screening cosmetic composition by inorganic uv filter |
| KR20150089517A (en) * | 2014-01-28 | 2015-08-05 | 코스맥스 주식회사 | Transparency spray type Sun Screening Cosmetic composition by Inorganic UV Filter |
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| KR20140021963A (en) * | 2013-07-11 | 2014-02-21 | 코스맥스 주식회사 | Spray type sun screening cosmetic composition by inorganic uv filter |
| KR20150089517A (en) * | 2014-01-28 | 2015-08-05 | 코스맥스 주식회사 | Transparency spray type Sun Screening Cosmetic composition by Inorganic UV Filter |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111481467A (en) * | 2019-01-25 | 2020-08-04 | 科丝美诗株式会社 | Cosmetic composition for blocking ultraviolet rays, which imparts cooling effect |
| CN110339092A (en) * | 2019-08-22 | 2019-10-18 | 广州亦妆生物科技有限公司 | It is a kind of with sun-proof and moisture-keeping functions homogeneous care composition |
| CN110368329A (en) * | 2019-08-22 | 2019-10-25 | 广州亦妆生物科技有限公司 | A kind of homogeneous care composition of not silicate-containing oil |
| CN110368329B (en) * | 2019-08-22 | 2022-08-30 | 广州亦妆生物科技有限公司 | Silicone oil-free homogeneous phase nursing composition |
| CN110664661A (en) * | 2019-11-01 | 2020-01-10 | 陕西崇文生物科技有限公司 | Mild repairing skin-brightening sunscreen lotion and preparation method thereof |
| CN115813813A (en) * | 2023-01-06 | 2023-03-21 | 湖北美凯化工有限公司 | Optical protection material and preparation method and application thereof |
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Application publication date: 20170524 |