CN104640536A - Mousse-type UV blocking cosmetic composition - Google Patents
Mousse-type UV blocking cosmetic composition Download PDFInfo
- Publication number
- CN104640536A CN104640536A CN201380048556.1A CN201380048556A CN104640536A CN 104640536 A CN104640536 A CN 104640536A CN 201380048556 A CN201380048556 A CN 201380048556A CN 104640536 A CN104640536 A CN 104640536A
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- CN
- China
- Prior art keywords
- cosmetic composition
- weight
- compositions
- isolating
- isolating ultraviolet
- Prior art date
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- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 127
- 239000002537 cosmetic Substances 0.000 title claims abstract description 40
- 230000000903 blocking effect Effects 0.000 title abstract 2
- 230000037072 sun protection Effects 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000002562 thickening agent Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 238000002955 isolation Methods 0.000 claims description 14
- 239000003921 oil Substances 0.000 claims description 14
- 150000005846 sugar alcohols Polymers 0.000 claims description 11
- -1 aliphatic alcohols Chemical class 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 235000013772 propylene glycol Nutrition 0.000 claims description 4
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 claims description 2
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 claims description 2
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 claims description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 2
- 229960001631 carbomer Drugs 0.000 claims description 2
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 2
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 229960000735 docosanol Drugs 0.000 claims description 2
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 claims description 2
- 229960000655 ensulizole Drugs 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229940068171 ethyl hexyl salicylate Drugs 0.000 claims description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 2
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229960001679 octinoxate Drugs 0.000 claims description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 2
- 229960000601 octocrylene Drugs 0.000 claims description 2
- 239000010773 plant oil Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000011863 silicon-based powder Substances 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 239000004519 grease Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 241000195940 Bryophyta Species 0.000 abstract 1
- 235000011929 mousse Nutrition 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 23
- 239000006260 foam Substances 0.000 description 15
- 239000002552 dosage form Substances 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 230000035807 sensation Effects 0.000 description 5
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 239000003213 antiperspirant Substances 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000001835 salubrious effect Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 description 1
- WYUAMLXGVWEBIQ-SSZFMOIBSA-N 2-octyldodecyl (Z)-tetradec-9-enoate Chemical compound C(CCCCCCC\C=C/CCCC)(=O)OCC(CCCCCCCCCC)CCCCCCCC WYUAMLXGVWEBIQ-SSZFMOIBSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 241000289669 Erinaceus europaeus Species 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 229960005193 avobenzone Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- GBUIEYIEDRACFN-UHFFFAOYSA-N propane-1,1-diol;propane-1,2-diol Chemical compound CCC(O)O.CC(O)CO GBUIEYIEDRACFN-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 229940083037 simethicone Drugs 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a mousse-type UV block composition, and more specifically, to a UV blocking cosmetic composition which has a high sun protection factor and a light feeling of use, promotes repeated usage and is simple to apply to a wide area by being formulated in mousse form, and can be used for leisure sports and in daily life by being waterproof.
Description
Technical field
The present invention relates to one to rub this type UV-screens compositions, more specifically, relate to a kind of SPF (sun protection factor) high and use and feel frivolous, rub this form by being mixed with and being easy to reuse and be convenient to large area and smearing, resistance to water strengthened for isolating ultraviolet cosmetic composition.
Background technology
The cosmetic composition of this type that rubs, its content sprays with foam form, thus not only can be applied in face, can also easily launch and large area is applied on skin, feel frivolous owing to using, therefore, when being applicable to isolation ultraviolet product, having and easily smearing, facilitating reusable feature.But from the characteristic of rubbing this dosage form, surfactant must be contained in its component, thus make the ability of its water resistant or anti-antiperspirant more weak, cause persistence poor, therefore, namely use sense is made it have frivolous, reusable and can easily to launch and large area is applied in the advantage on skin, but owing to not possessing resistance to water, be therefore merely able to use in daily life, can not use when lying fallow or when moving, thus limited in use.
Owing to there are the problems referred to above, compared with the UV-screens of the UV-screens of this type that rubs and normally used facial cream or emulsion-type, inactive in product development.
Prior art document
No. 2010-0031097th, patent documentation 1 KR published patent
Summary of the invention
The technical problem to be solved in the present invention
Given this, the present inventor does not use surfactant, by suitably regulating wax
composition and thickener ingredients, thus the cosmetics providing a kind of this type that rubs, rub in this dosage form by making organic uv interleaving agent and inorganic UV interleaving agent be stable at, thus obtain the UV-screens compositions of high this type that rubs of a kind of SPF (sun protection factor).
Therefore, the object of the present invention is to provide a kind of SPF (sun protection factor) high and have this type that rubs of resistance to water for isolating ultraviolet cosmetic composition.
The technological means of technical solution problem
To achieve these goals, the invention provides a kind of for isolating ultraviolet cosmetic composition, it contains wax and thickening agent; Described wax is selected from aliphatic alcohols wax
and fatty acid wax
in at least one.
The effect of invention
This type that rubs provided by the invention maintaining the SPF (sun protection factor) of more than SPF50 for isolating ultraviolet cosmetic composition, and while isolation ultraviolet light,long wave grade is PA+++, easily can also reuse with frivolous use sensation, and owing to being this type that rubs, thus can smear on a large scale securely.In addition, owing to having resistance to water, the ability of opposing antiperspirant and water is strong, thus can not only use in daily life, also can use in Leisure Sports motion.
Preferred implementation
The present invention relates to a kind of for isolating ultraviolet cosmetic composition, by using wax and the thickening agent of particular combination, thus providing a kind of this type that rubs not containing surfactant for isolating ultraviolet cosmetic composition.
Compositions of the present invention contains organic uv interleaving agent, inorganic UV interleaving agent, oil
alcohol
polyhydric alcohol
powder body
wax and thickener ingredients, especially simultaneously containing organic uv interleaving agent and inorganic UV interleaving agent, thus have high SPF (sun protection factor).Preferably, SPF (sun protection factor) is more than SPF50, and isolation ultraviolet light,long wave grade is PA+++, but, owing to making this dosage form of rubbing, thus there is use feel frivolous, easily reuse, be easy to the feature of carrying out on a large scale smearing.
In compositions of the present invention, preferably use ethylhexyl methoxy cinnamate
at least one in iso-amyl p-methoxycinnamate, PAROSOL 1789 (butyl methoxydibenzoylmethane), ethylhexyl salicylate, octocrylene, heliophan, BEMT, Uvinul T 150, Phenylbenzimidazolesulfonic acid and Uvinul A Plus is as organic uv interleaving agent.In compositions of the present invention, with the total weight of compositions, the organic uv interleaving agent of more than 1 % by weight can be used, preferably can use more than 10 % by weight, be more preferably more than 20 % by weight, more preferably the organic uv interleaving agent of more than 25 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the organic uv interleaving agent of less than 40 % by weight can be used, preferably can use less than 35 % by weight, be more preferably the organic uv interleaving agent of less than 33 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the organic uv interleaving agent of 1-40 % by weight can be used, preferably can use 10-35 % by weight, be more preferably 25-33 % by weight, more preferably the organic uv interleaving agent of about 30 % by weight.If containing quantity not sufficient 1 % by weight, then can not obtain desired ultraviolet isolation effect, if more than 40 % by weight, then stable dosage forms degree aspect can have problems, so be not preferred.
In compositions of the present invention, preferably use at least one in titanium dioxide, zinc oxide and ferrum oxide as inorganic UV interleaving agent.In compositions of the present invention, with the total weight of compositions, the inorganic UV interleaving agent of more than 1 % by weight can be used, preferably can use more than 5 % by weight, be more preferably more than 10 % by weight, more preferably the inorganic UV interleaving agent of more than 15 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the inorganic UV interleaving agent of less than 30 % by weight can be used, preferably can use less than 25 % by weight, be more preferably the inorganic UV interleaving agent of less than 20 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the inorganic UV interleaving agent of 1-30 % by weight can be used, preferably can use 5-25 % by weight, be more preferably the inorganic UV interleaving agent of 10-20 % by weight.If containing quantity not sufficient 1 % by weight, then desired ultraviolet isolation effect can not be obtained, if more than 30 % by weight, then use sensation can reduce, so be not preferred.
In compositions of the present invention, preferably use the hydrocarbon-type oil comprising squalane or mineral oil; Comprise the Esters oil of isopropyl palmitate, 2-octyl dodecanol myristinate, isopropyl myristate or butyl capryl alcohol salicylate; Comprise the plant oil of Oleum Ricini, olive oil or Jojoba oil; And at least one comprised in the silicone oil of cyclomethicone or simethicone is as oil.In addition, in compositions of the present invention, with the total weight of compositions, the oil of more than 1 % by weight can be used, preferably can use more than 5 % by weight, be more preferably more than 10 % by weight, more preferably the oil of more than 15 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the oil of less than 30 % by weight can be used, preferably can use less than 25 % by weight, be more preferably the oil of less than 20 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the oil of 1-30 % by weight can be used, preferably can use 5-25 % by weight, be more preferably the oil of 10-20 % by weight.If containing quantity not sufficient 1 % by weight, then smear can reduce, if more than 30 % by weight, then stable dosage forms degree aspect can have problems, so be not preferred.
In compositions of the present invention, in order to give nice and cool sensation, can alcohol be used, at least one in isopropyl alcohol or ethanol preferably can be used as alcohol.In compositions of the present invention, with the total weight of compositions, the alcohol of more than 1 % by weight can be used, preferably can use more than 2 % by weight, be more preferably the alcohol of more than 4 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the alcohol of less than 10 % by weight can be used, preferably can use less than 8 % by weight, be more preferably the alcohol of less than 6 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the alcohol of 1-10 % by weight can be used, preferably can use 2-8 % by weight, be more preferably the alcohol of 4-6 % by weight.If containing quantity not sufficient 1 % by weight, then can not feel salubrious sensation.If more than 10 % by weight, then stable dosage forms degree aspect can have problems, so be not preferred.
In compositions of the present invention, at least one in butanediol, glycerol, propyleneglycoles (propylene glycol), dipropylene glycol and propylene glycol (propane diol) preferably can be used as polyhydric alcohol.In compositions of the present invention, with the total weight of compositions, the polyhydric alcohol of more than 1 % by weight can be used, preferably can use more than 2 % by weight, be more preferably the polyhydric alcohol of more than 4 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the polyhydric alcohol of less than 10 % by weight can be used, preferably can use less than 8 % by weight, be more preferably the polyhydric alcohol of less than 6 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the polyhydric alcohol of 1-10 % by weight can be used, preferably can use 2-8 % by weight, be more preferably the polyhydric alcohol of 4-6 % by weight.If containing quantity not sufficient 1 % by weight, then can have problems in anticorrosion, if more than 10 % by weight, then can not form foam up to specification.
In compositions of the present invention, using powder body to improve sticky sense, at least one in polystyrene powder body, polymethyl methacrylate powder body, polyethylene powder body, nylon powder body, polymethylsilsesquioxane powder body and silicon powder preferably can be used as powder body.In compositions of the present invention, with the total weight of compositions, the powder body of more than 1 % by weight can be used, preferably can use more than 2 % by weight, be more preferably the powder body of more than 4 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the powder body of less than 10 % by weight can be used, preferably can use less than 8 % by weight, be more preferably the powder body of less than 6 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the powder body of 1-10 % by weight can be used, preferably can use 2-8 % by weight, be more preferably the powder body of 4-6 % by weight.If containing quantity not sufficient 1 % by weight, then sticky sense is serious, if more than 10 % by weight, then the jetting stability degree of product can reduce.
In compositions of the present invention, in order to strengthen resistance to water, and make organic uv interleaving agent and inorganic UV interleaving agent stabilisation in compositions, thus higher ultraviolet isolation effect is provided and employs wax.Preferably can be used as the docosanol of aliphatic alcohols wax, octadecanol, spermol and cetearyl alcohol; With as at least one in the stearic acid of fatty acid wax and Palmic acid.In compositions of the present invention, with the total weight of compositions, the wax of more than 0.1 % by weight can be used, preferably can use more than 0.3 % by weight, be more preferably more than 0.5 % by weight, more preferably the wax of more than 1 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the wax of less than 5 % by weight can be used, preferably can use less than 4.5 % by weight, be more preferably less than 4 % by weight, more preferably the wax of less than 3 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the wax of 0.1-5 less than % by weight can be used, be preferably 0.3-4 less than % by weight, be more preferably the wax of 0.5-3 less than % by weight.If containing quantity not sufficient 0.1 % by weight, then foam stabilization degree can be deteriorated, if more than 5 % by weight, then stable dosage forms degree can be deteriorated.
In compositions of the present invention, can use xanthan gum, carbomer, match Bick (
sEP IGEL) and hydroxyethyl-cellulose at least one (preferably two or more) as thickening agent.In compositions of the present invention, with the total weight of compositions, the thickening agent of more than 0.1 % by weight can be used, preferably can use more than 0.3 % by weight, be more preferably the thickening agent of more than 0.5 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the thickening agent of less than 5 % by weight can be used, preferably can use less than 4 % by weight, be more preferably less than 3.5 % by weight, more preferably less than 3 % by weight, be further preferably the thickening agent of less than 2 % by weight.In addition, in compositions of the present invention, with the total weight of compositions, the thickening agent of 0.1-5 less than % by weight can be used, preferably can use 0.3-4 less than % by weight, be more preferably 0.5-3 less than % by weight, more preferably the thickening agent of 0.5-2 less than % by weight.If containing quantity not sufficient 0.1 % by weight, then stable dosage forms degree can be deteriorated, if more than 5 % by weight, then can not form foam up to specification.
Under normal circumstances, surfactant must be contained in this dosage form of rubbing.But compositions of the present invention does not use surfactant, and not containing in pik woods (pickering) dosage form of surfactant, add wax and the thickening agent of content described above with suitable ratio, to obtain this form of rubbing.In addition, due to the use of wax and thickener ingredients, resistance to water is strengthened, even if repeated impregnations twice in water, total immersion stain 20 minutes, also can maintain more than 50% of initial stage SPF index, therefore, compositions of the present invention can obtain the certification of resistance to water aspect.
In addition, except mentioned component, when not reducing composition effect, compositions of the present invention can contain spice, pigment, antiseptic, antibacterial, oxidation stabilizers and brightener further
Detailed description of the invention
Below, be described by preferred embodiment and comparative example.The record of following embodiment and comparative example is just in order to further clear and definite the present invention, and content of the present invention is not limited in following embodiment and comparative example.
The preparation of reference example embodiment and comparative example
This type UV-screens that rubs that SPF (sun protection factor) is adjusted to SPF50+/PA+++ is prepared according to the formula of following table 1.Embodiment 1-5 is altered this type UV-screens compositions of rubbing of the content of wax and thickening agent, comparative example 1 is the compositions eliminating wax in the formula of embodiment, and comparative example 2 is the UV-screens containing surfactant (lauryl PEG/PPG-18/18 gathers methyl polysiloxane (Lauryl PEG/PPG-18/18Methicone)).
Table 1
Preparation method
According to the proportioning shown in above-mentioned table 1, organic uv interleaving agent and oil-phase component are dissolved at 80 DEG C.In the mixture of room temperature being mixed with all water-phase components, add the mixture of above-mentioned organic uv interleaving agent and oil-phase component lentamente, then stir.Afterwards, add remaining additive, after obtained oil-in-water type (O/W) emulsion, with emulsion: the ratio of LPG (ratio of components propane: butane=30:70wt%)=90:10wt% is filled in tank (can).
The mensuration of test case 1 SPF (sun protection factor) SPF and isolation ultraviolet light,long wave grade PA
Based on " ultraviolet isolation features test method(s) " in food medicine Room bulletin " functional cosmetics standard and test method ", SPF (sun protection factor) is measured.Be specially: transparent plastic adhesive tape (Transpore Tape:3M, the U.S.) is attached on ready foundry goods (cast), by the cosmetic composition sample of embodiment 1-4 and comparative example 1-2 with 2mg/cm
2after being coated with, ultraviolet (UV) tester (SPF290Analyzer) is adopted to measure ultraviolet isolation effect.In addition, for isolation ultraviolet light,long wave grade PA, use is provided with artificial actinolyte Multi-port Solar simulator 601-300W (the Solar Light company of 300W xenon arc lamp (xenon arc lamp), the U.S.) as light source, utilize 3D UV instrument (Solar Light company, the U.S.) measure light intensity, thus measure the isolation ultraviolet light,long wave grade PA of the compositions of embodiment 1-5 and comparative example 1-2.SPF (sun protection factor) gets the meansigma methods of three test values, and its result is shown in following table 2 after arranging.
Table 2
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | |
| SPF | 52.8±2.3 | 52.5±3.4 | 51.5±3.6 | 50.6±3.5 | 49.6±2.5 | 45.6±2.5 | 52.4±3.7 |
| PA | +++ | +++ | +++ | +++ | +++ | ++ | +++ |
As can be seen from the value shown in upper table 2, can confirm based on embodiments of the invention and the comparative example 2 employing surfactant, although their SPF index and PA grade are all measured as very high, but when not using comparative example 1 of wax, ultraviolet isolating power fails to reach the standard of compositions provided by the present invention.In addition, when can confirm only used a kind of thickening agent embodiment 5, although PA grade is very high, SPF index does not reach 50.
Test case 2 formation of foam power measures
In order to measure the formation of foam power of compositions, with emulsion: the ratio of LPG (ratio of components propane: butane=30:70wt%)=90:10wt% is filled in tank, after mixing 20 times, be sprayed on palm with foam form, based on the persistent period of foam form, according to good, common and bad, formation of foam power is evaluated.After ejection, if foam maintain more than 3 minutes for good, maintain and within more than 30 seconds, be less than 3 minutes for common, maintain and be less than 30 seconds for bad.The results are shown in following table 3.
Table 3
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | |
| Formation of foam power | Well | Well | Common | Common | Bad | Bad | Well |
From the result shown in upper table 3, the formation of foam power of the embodiment 5 only using a kind of thickening agent and the comparative example 1 not using wax is bad; Although there is wax, respectively lack a kind of embodiment 3 of thickening agent and the formation of foam power of embodiment 4 is poor compared with embodiment 1 and embodiment 2.The formation of foam power that with the addition of the comparative example 1 of the conventional creams type of surfactant is good.
Test case 3 resistance to water effect
Resistance to water is based on resistance to water ultraviolet isolation assay method guide (COLIPA Guideline2005.12), (resistance to water: 20 minutes 2 times after the skin smearing UV-screens is repeatedly flooded in water, continue resistance to water 20 minutes 4 times), SPF (sun protection factor) is measured.Itself and the SPF (sun protection factor) of skin that not impregnated in water are compared, after calculating the resistance to water of each study subject, one-sided 90% confidence interval obtained with the mean value calculation of more than 10 is meansigma methods 50% when, be judged to be that there is resistance to water (or lasting resistance to water).The results are shown in table 4.
Table 4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | |
| Resistance to water | O | O | O | O | X | X | X |
From the result of upper table 4, thickening agent is only a kind of embodiment 5, does not use the comparative example 1 of wax and uses the comparative example 2 of surfactant not have resistance to water.
Test case 4 uses sensation satisfaction
With 25 years old to 45 years old 30 women for object, to the compositions of embodiment 1-5 and comparative example 1-2, evaluate in formation of foam power, smear, sticky sense, the aobvious total satisfactory grade such as glossy.The preparation of embodiment 1-5 and comparative example 1-2 is squeezed after on hand, is applied in face immediately, the results are shown in table 5.
Table 5
(evaluation criterion) non-constant: 1/ is poor: 2/ is common: 3/ is good: 4/ is very good: 5
Can be confirmed by the result of display in above-mentioned table 5, the embodiment 5 only using a kind of thickening agent with do not use wax comparative example 1 when, use sense satisfaction is poor; Respectively lack a kind of embodiment 3 of thickening agent and embodiment 4 compared with embodiment 1 and embodiment 2, satisfaction declines.
From the result of above-mentioned test case 1-4, the present invention is in pik woods (pickering) dosage form not using surfactant, regulate wax and thickening agent, to obtain this form of rubbing, thus there is strong ultraviolet blocked force, and obtain resistance to water certification, while directly showing the frivolous salubrious advantage of existing this type that rubs, not only may be used for isolating ultraviolet in life, when being also applicable to field or motion, isolate ultraviolet.
In addition, this type ultraviolet isolation cosmetic compositions that rubs of the present invention can carry out various deformation, and do not departing from goal of the invention situation of the present invention, the embodiment of being out of shape all should be interpreted as being included in the scope of the present invention.
Claims (24)
1. rubbing this type for isolating a ultraviolet cosmetic composition, it is characterized in that, this cosmetic composition contains wax and thickening agent; Described wax is selected from least one in aliphatic alcohols wax and fatty acid wax.
2. according to claim 1 for isolating ultraviolet cosmetic composition, wherein, described aliphatic alcohols wax is selected from least one in docosanol, octadecanol, spermol and cetearyl alcohol; Described fatty acid wax is selected from least one in stearic acid and Palmic acid.
3. according to claim 1 for isolating ultraviolet cosmetic composition, wherein, with the total weight of compositions, the content of described wax is 0.1-5 % by weight.
4. according to claim 1 for isolating ultraviolet cosmetic composition, wherein, it is two or more that described thickening agent is selected from xanthan gum, carbomer, match Bick and hydroxyethyl-cellulose.
5. according to claim 1 for isolating ultraviolet cosmetic composition, wherein, with the total weight of compositions, the content of described thickening agent is 0.1-5 % by weight.
6. according to claim 1 for isolating ultraviolet cosmetic composition, wherein, described compositions is further containing organic uv interleaving agent and inorganic UV interleaving agent two kinds.
7. according to claim 6 for isolating ultraviolet cosmetic composition, wherein, the SPF (sun protection factor) of described compositions is more than SPF50, and isolation ultraviolet light,long wave grade is PA+++.
8. according to claim 6 for isolating ultraviolet cosmetic composition; wherein, described organic uv interleaving agent is selected from least one in ethylhexyl methoxy cinnamate, iso-amyl p-methoxycinnamate, PAROSOL 1789, ethylhexyl salicylate, octocrylene, heliophan, BEMT, Uvinul T 150, Phenylbenzimidazolesulfonic acid and Uvinul A Plus.
9. according to claim 6 for isolating ultraviolet cosmetic composition, wherein, with the total weight of compositions, the content of described organic uv interleaving agent is 1-40 % by weight.
10. according to claim 6 for isolating ultraviolet cosmetic composition, wherein, described inorganic UV interleaving agent is selected from least one in titanium dioxide, zinc oxide and ferrum oxide.
11. is according to claim 6 for isolating ultraviolet cosmetic composition, and wherein, with the total weight of compositions, the content of described inorganic UV interleaving agent is 1-30 % by weight.
12. is according to claim 1 for isolating ultraviolet cosmetic composition, and wherein, described compositions is further containing oil.
13. is according to claim 12 for isolating ultraviolet cosmetic composition, wherein, and at least one of described grease separation in hydrocarbon-type oil, Esters oil, plant oil and silicone oil.
14. is according to claim 13 for isolating ultraviolet cosmetic composition, and wherein, with the total weight of compositions, the content of described oil is 1-30 % by weight.
15. is according to claim 1 for isolating ultraviolet cosmetic composition, and wherein, described compositions is further containing alcohol.
16. is according to claim 15 for isolating ultraviolet cosmetic composition, and wherein, described alcohol is selected from least one in isopropyl alcohol and ethanol.
17. is according to claim 15 for isolating ultraviolet cosmetic composition, and wherein, with the total weight of compositions, the content of described alcohol is 1-10 % by weight.
18. is according to claim 1 for isolating ultraviolet cosmetic composition, and wherein, described compositions is further containing polyhydric alcohol.
19. is according to claim 18 for isolating ultraviolet cosmetic composition, and wherein, described polyhydric alcohol is selected from least one in butanediol, glycerol, propyleneglycoles, dipropylene glycol and propylene glycol.
20. is according to claim 18 for isolating ultraviolet cosmetic composition, and wherein, with the total weight of compositions, the content of described polyhydric alcohol is 1-10 % by weight.
21. is according to claim 1 for isolating ultraviolet cosmetic composition, and wherein, described compositions is further containing powder body.
22. is according to claim 21 for isolating ultraviolet cosmetic composition, wherein, described powder body is selected from least one in polystyrene powder body, polymethyl methacrylate powder body, polyethylene powder body, nylon powder body, polymethylsilsesquioxane powder body and silicon powder.
23. is according to claim 21 for isolating ultraviolet cosmetic composition, and wherein, with the total weight of compositions, the content of described powder body is 1-10 % by weight.
24. is according to claim 1 for isolating ultraviolet cosmetic composition, wherein, described compositions be excellent water resistance for isolating ultraviolet cosmetic composition.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2012-0126576 | 2012-11-09 | ||
| KR1020120126576A KR102007800B1 (en) | 2012-11-09 | 2012-11-09 | Sunscreen cosmetic composition of mousse type |
| PCT/KR2013/010040 WO2014073867A1 (en) | 2012-11-09 | 2013-11-07 | Mousse-type uv blocking cosmetic composition |
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| CN104640536A true CN104640536A (en) | 2015-05-20 |
| CN104640536B CN104640536B (en) | 2018-05-25 |
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| CN201380048556.1A Expired - Fee Related CN104640536B (en) | 2012-11-09 | 2013-11-07 | This type that rubs is used for the cosmetic composition of isolation ultraviolet |
Country Status (4)
| Country | Link |
|---|---|
| KR (1) | KR102007800B1 (en) |
| CN (1) | CN104640536B (en) |
| SG (1) | SG11201502338UA (en) |
| WO (1) | WO2014073867A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105520850A (en) * | 2016-01-29 | 2016-04-27 | 曼秀雷敦(中国)药业有限公司 | Sunscreen composition and preparation method and application thereof |
| EP3226829B1 (en) | 2014-12-02 | 2018-02-28 | Unilever NV | A personal care cream composition |
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|---|---|---|---|---|
| KR101638013B1 (en) * | 2014-03-18 | 2016-07-11 | 이주완 | Stable o/w emulsion cosmetic composition |
| KR101921727B1 (en) * | 2016-12-28 | 2018-11-23 | 주식회사 제네웰 | Silicone resin composition, method for preparing the same and scar medicine containing the same |
| KR102017771B1 (en) * | 2017-05-24 | 2019-09-03 | 한국콜마주식회사 | Emulsifier free cosmetic composition for blocking uv |
| KR102017772B1 (en) * | 2017-05-24 | 2019-09-03 | 한국콜마주식회사 | Emulsifier free cosmetic composition for blocking uv |
| KR20190056991A (en) | 2017-11-17 | 2019-05-27 | (주)아모레퍼시픽 | Supporting agent composition for blocking ultraviolet comprising Sparassis Crispa extract, Porphyra Yezoensis extract and sunflower sprout extract |
| KR102012161B1 (en) * | 2019-04-03 | 2019-08-20 | 한국콜마주식회사 | Uv protecting cosmetic composition |
| KR20210052735A (en) | 2019-10-30 | 2021-05-11 | 코스맥스 주식회사 | Mousse type makeup cosmetic composition with adjustable discharge rate |
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- 2013-11-07 CN CN201380048556.1A patent/CN104640536B/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104640536B (en) | 2018-05-25 |
| KR20140060006A (en) | 2014-05-19 |
| WO2014073867A1 (en) | 2014-05-15 |
| SG11201502338UA (en) | 2015-05-28 |
| KR102007800B1 (en) | 2019-08-07 |
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