CN106687468B - 包含脒和取代的环戊二烯基配体的金属络合物 - Google Patents

包含脒和取代的环戊二烯基配体的金属络合物 Download PDF

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CN106687468B
CN106687468B CN201580049929.6A CN201580049929A CN106687468B CN 106687468 B CN106687468 B CN 106687468B CN 201580049929 A CN201580049929 A CN 201580049929A CN 106687468 B CN106687468 B CN 106687468B
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group
formula
ligand
metal complex
methyl
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CN106687468A (zh
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彼得·卡鲍姆
理查德·托马斯·威廉姆·斯科特
约翰·范德莫斯迪克
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Arlanxeo Netherlands BV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201580049929.6A 2014-09-18 2015-09-08 包含脒和取代的环戊二烯基配体的金属络合物 Active CN106687468B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14185359 2014-09-18
EP14185359.8 2014-09-18
PCT/EP2015/070498 WO2016041818A1 (en) 2014-09-18 2015-09-08 Metal complex comprising amidine and substituted cyclopentadienyl ligands

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Publication Number Publication Date
CN106687468A CN106687468A (zh) 2017-05-17
CN106687468B true CN106687468B (zh) 2020-04-21

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US (1) US10472431B2 (enExample)
EP (1) EP3194412B1 (enExample)
JP (1) JP6767363B2 (enExample)
KR (1) KR102506178B1 (enExample)
CN (1) CN106687468B (enExample)
WO (1) WO2016041818A1 (enExample)

Families Citing this family (4)

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Publication number Priority date Publication date Assignee Title
CN111032772B (zh) 2017-06-14 2022-07-15 埃克森美孚化学专利公司 用于交联应用的乙烯共聚物共混物
WO2019132687A1 (en) 2017-12-25 2019-07-04 Arlanxeo Netherlands B.V. Metal complex comprising amidine and thiophene fused cyclopentadienyl ligands
WO2019203676A1 (en) * 2018-04-16 2019-10-24 Arlanxeo Netherlands B.V. Metal complex comprising amidine and indole fused cyclopentadienyl ligands
WO2020058267A1 (en) * 2018-09-18 2020-03-26 Arlanxeo Netherlands B.V. Catalyst mixture

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103003319A (zh) * 2009-12-21 2013-03-27 朗盛艾拉托麦罗斯有限公司 硼烷活化的含脒及二烯烃配体的Ti催化剂体系

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4204937B2 (ja) 2002-09-30 2009-01-07 出光興産株式会社 オレフィン系グラフト共重合体組成物の製造方法
BRPI0508887B1 (pt) * 2004-03-17 2015-08-11 Lanxess Elastomers Bv Processo para preparação de um polímero, catalisador iônico compreendendo um composto organometálico, catalisador suportado e processo para produção de um composto organometálico
DE102005044549B4 (de) * 2005-09-17 2008-04-17 Eads Deutschland Gmbh Flugzeugflügel mit ausfahrbarer Nasenklappe
EP2336205A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
JP5797979B2 (ja) 2011-08-31 2015-10-21 太陽誘電株式会社 弾性波デバイス
JP2013155371A (ja) * 2012-01-06 2013-08-15 Japan Polyethylene Corp オレフィン系重合体の製造方法
WO2014022008A1 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103003319A (zh) * 2009-12-21 2013-03-27 朗盛艾拉托麦罗斯有限公司 硼烷活化的含脒及二烯烃配体的Ti催化剂体系

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Jie Zhang，等.Synthesis and structures of titanium and yttrium complexes with N,N¢-tetramethylguanidinate ligands: different reactivity of the M–N bonds toward phenyl isocyanate.《Dalton Trans.》.2009,1806-1811页. *

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Publication number Publication date
US10472431B2 (en) 2019-11-12
US20170240663A1 (en) 2017-08-24
CN106687468A (zh) 2017-05-17
WO2016041818A1 (en) 2016-03-24
EP3194412B1 (en) 2019-08-07
EP3194412A1 (en) 2017-07-26
KR102506178B1 (ko) 2023-03-07
KR20170056553A (ko) 2017-05-23
JP2017535518A (ja) 2017-11-30
JP6767363B2 (ja) 2020-10-14

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