CN106675592A - Energy-efficient indirect thermal desorption carbonization device and treatment method thereof - Google Patents

Energy-efficient indirect thermal desorption carbonization device and treatment method thereof Download PDF

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Publication number
CN106675592A
CN106675592A CN201710076920.5A CN201710076920A CN106675592A CN 106675592 A CN106675592 A CN 106675592A CN 201710076920 A CN201710076920 A CN 201710076920A CN 106675592 A CN106675592 A CN 106675592A
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tank
resolution
resolution room
cover
thermal desorption
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CN106675592B (en
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陈汝峰
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Wuxi Aipute Equipment Technology Co Ltd
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Wuxi Aipute Equipment Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2247/00Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/10Means for removing the washing fluid dispersed in the gas or vapours

Abstract

The invention belongs to the technical field of organic solid waste treatment, and particularly relates to an energy-efficient indirect thermal desorption carbonization device and a treatment method thereof. The carbonization device comprises a preheating feed system and a material heating system, wherein the preheating feed system comprises a heat-exchange-jacket-bearing spiral feeder and a chimney pipeline; the material heating system comprises a heating furnace, a first resolution chamber and a second resolution chamber; the first resolution chamber and second resolution chamber respectively comprise a feed end aggregate hood, a discharge end aggregate hood and a silicon-carbide-lined refractory steel cylinder; and a first rotatable screw conveyer and a second rotatable screw conveyer are correspondingly arranged inside the refractory steel cylinders of the first resolution chamber and second resolution chamber. The carbonization device can solve the problems of high deformation tendency, high abrasion tendency and low corrosion resistance in the chamber pipe wall and the problem of incomplete combustion of noncondensable gas. The carbonization device can remove inorganic carbon in the overproof solid-phase residues to implement further decrement, lower the heat consumption of indirect thermal desorption equipment and reduce the residue landfill disposition cost.

Description

A kind of energy-efficient indirect thermal desorption carbonizing apparatus and processing method
Technical field
The invention belongs to organic solid waste process technical field, it is more particularly to a kind of can be by the recycling energy in solid waste Source carries out extracting the energy-efficient indirect thermal desorption carbonizing apparatus and processing method for separating that simultaneously minimizing is recycled.
Background technology
It is using burning side to domestic waste, Biohazard Waste, the process of waste plastic in China most cities Formula process, i.e. high-temperature heat treatment, also many infirmaries adopt little incinerator, and this mode has in burning process fuel not The problems such as foot, cause these solid waste fully to burn, and easily produce hypertoxic dioxin, and the health of people is caused Very big harm.Innoxious waste, minimizing, resource are extremely difficult under these conditions.In addition, during dangerous waste incineration, Generally require directly to add fuel, operating cost can so increased, be also not reaching to energy-conservation.The danger produced in burning process Harmful substance also tends to produce, if not handling well, easily causes secondary pollution to environment.And thermal desorption (Pyrolysis) incinerates method The requirement for meeting and operating economic face in regulation face can be taken into account, the generation of this problem can be preferably solved.
The pyrolysis of solid waste has the advantage that compared with burning:
(1) storage that the Organic substance in solid dangerous waste can be converted into based on fuel gas, fuel oil and white carbon black Performance source;
(2) due to being anaerobic decay, capacity is few, is conducive to mitigating the secondary pollution to atmospheric environment;
(3) the harmful components major part such as sulfur, heavy metal in waste is fixed in white carbon black;
(4) yield of oxynitride is few.
So compared with burning method, indirect thermal desorption can also process the hazardous waste of those inaccurate burning disposals:Contain The heavy industries sludge such as hydrargyrum or cadmium or lead (such as chlor-alkali mercury salt sludge, paints bed mud containing zinc, PTA chromium-bearing sludges, battery plating is dirty Mud, leather-making mud), waste of the Polychlorinated biphenyls content more than 50mg or L, containing two dislike because waste etc..
A kind of electrothermal desorption stove of the disclosure of the invention of Publication No. CN2455718, its body of heater is mainly sent by a feed hopper, one The components such as material screw rod, an electrothermal tube, a discharge bucket and an airway are constituted, and petroleum chemicals garbage is sent into into stove from feed hopper In vivo, and by feeding spiro rod advance is slowly pushed, petroleum chemicals garbage is undergone the heating of electrothermal tube and is produced decomposition and split Change, lighter oil gas can be derived along top airway, so as to being collected, be sealed and being cooled down, and remaining heavier coke portion Dividing can be by the discharge bucket below rear end by its centralized recovery, so that the material after each desorption is reused.
A kind of indirect thermal desorption device material of the disclosure of the invention of Publication No. US7514049B2 is conveyed by feed system To in pyrolysis installation.Heating furnace with heat-insulation layer with natural gas or diesel oil as fuel to Resolution Room indirectly heat to 500 DEG C, together When parsing indoor auger material is pushed backward, the Organic substance such as water, organic matter or polycyclic aromatic hydrocarbon vaporization in the meantime, with solid thermal Solution is separated.Pyrolysis produce vapour mixture by parsing vapour condenser chilling, after, obtain oil water mixture and fixed gas.No Solidifying gas is back to combustor afterburning Jing after gas phase treatment, and oil water mixture enters oil water separator and produces crude oil and oil-polluted water, symbol The crude oil for closing oil field product standard can be defeated outward, and sewage enters unit for treating water.Sewage meets production requirement Jing after processing, and partly uses In chilling, partly for the solid phase residue humidification that discharges, Jing discharging spiral system outputs.
A kind of thermal desorption device for repairing mercury contaminated soil of the disclosure of the invention of Publication No. CN104096709A.Should Device includes feed system, rotary kiln heating system, dust pelletizing system, cooling condenser system, tail gas filtering system, gas discharge system System, condensate collection system, precipitation filtration system, soil cooling system and discharge system.This invention aim at mercury contaminated soil and Design, so as to repair by hydrargyrum institute contaminated soil.
What three patents of the above were that existing thermal desorption (desorption) technically carries out is partially improved, Publication No. The patent of CN2455718 is used for indirectly heat using secondary energy sources electricity as the energy, but high with cost of disposal, electrothermal tube mill Change difficult after damage, condenser is easily dirty stifled (having hidden peril of explosion), and on-condensible gas needs the shortcomings of being collected separately.Publication No. The patent of US7514049B2 adopts natural gas or diesel oil as heating energy source, because existing apparatus Resolution Room is made up of steel pipe, The upper and lower tube wall temperature difference is deformed greatly during operation so that the indoor auger of parsing is easily stuck, and auger is direct with Resolution Room inside pipe wall Contact, tube wall easily weares and teares and by material corrosion (cannot process corrosive materials), Resolution Room pipe after deformation and abrasion more Change poles its trouble;If fuel gas too high levels in fixed gas, it is back to combustor and will be unable to burn completely, causes combustion product gases Discharge is exceeded, or cannot normal regulating heating in-furnace temperature;If discharging solid phase residue heavy metal equal size is exceeded, in solid phase residue The shortcomings of due to containing a large amount of inorganic charcoals, increased later stage landfill or secondary burning expense.Publication No. CN104096709A Patent adopts rotary kiln as main thermal desorption equipment, but adopting to directly heat needs tail gas after-treatment, and equipment is complicated, body Product is huge, transports and installs inconvenient and have the shortcomings that operating cost is high, there is secondary pollution hidden danger.
The content of the invention
For defect of the prior art, the present invention provides a kind of energy-efficient indirect thermal desorption carbonizing apparatus, can be with Solve Resolution Room tube wall preferably to deform, preferably wear and tear and the problems such as not corrosion-resistant and fixed gas does not burn completely;And can remove Inorganic charcoal reaches further decrement in exceeded solid phase residue, reduces the heat consumption of indirect thermal desorption equipment and reduce residue to fill out The disposal costs buried.
The present invention provide a kind of energy-efficient indirect thermal desorption carbonizing apparatus, including preheating feed system and material add Hot systems;
The preheating feed system includes the screw feeding device with heat exchange jacket and chimney breast, the spiral charging dress The feed end put is connected with charging aperture, and the discharge end of screw feeding device is parallel with the first charging flapper and the second charging lock gas Device;The chimney breast is connected with the heat exchange jacket of screw feeding device, and water- to-water heat exchanger is provided with chimney breast, the water after heating It is flowed in the heat exchange jacket layer of screw feeding device, with the material in screw feeding device steel plate indirect heat exchange is passed through.
The material heating system include heating furnace, the first Resolution Room and the second Resolution Room, the upside of the heating furnace with Chimney breast is connected;Chimney breast is provided with air heat exchanger, the air intake and air blast of the air heat exchanger Machine is communicated, and the air outlet slit of air heat exchanger is communicated with the combustor air inlet fans entrance of heating furnace;First Resolution Room Gather materials the heat-resisting steel cylinder of cover and inner lining with silicon carbide material including gather materials cover, discharge end of feed end with the second Resolution Room;Institute Heat-resisting steel cylinder is stated through inside heating furnace and is rotatably installed in that feed end gathers materials cover and discharge end gathers materials cover, The heat-resisting steel cylinder inside of the first Resolution Room and the second Resolution Room is provided with accordingly rotatably the first auger and the second auger.
Further, to make present configuration compacter, the discharge end and first of the first charging flapper is parsed The feed end of the room cover that gathers materials is connected, and the discharge end and the feed end of the second Resolution Room of the second charging flapper gather materials cover phase Even, the feed end of the first Resolution Room gather materials cover downside and the second Resolution Room feed end gather materials on the downside of cover accordingly with the first ash discharge Flapper and the second ash discharge flapper are connected, and the discharge end of the first Resolution Room gathers materials the discharge end collection of cover downside and the second Resolution Room Material cover downside is connected accordingly with the first discharging flapper and the second discharging flapper, and the first discharging flapper and second goes out The discharge end of material flapper is connected with discharging pulverizer, and the discharging pulverizer is by gray back pump and the first Resolution Room and second The secondary feeds pipeline that Resolution Room discharge end gathers materials on the upside of cover is connected.
Further, to make present configuration compacter, the energy-efficient indirect thermal desorption carbonizing apparatus is also wrapped Include the first fixed gas processing system and the second fixed gas processing system;The first fixed gas processing system includes the first Water spray Drainer, the first breakdown of emulsion tank, the first explosion-proof compressor, the first water washing tank, the first demisting tank and the first activated carbon filtering tank, it is described First Water spray drainer, the first breakdown of emulsion tank, the first explosion-proof compressor, the first water washing tank, the first demisting tank, the first activated carbon mistake It is sequentially connected between filter tank and the first activated carbon filtering tank is connected with heating furnace;The feed end of first Resolution Room gather materials cover and The gather materials upside of cover of discharge end is connected respectively by extraction conduit with the air inlet of the first Water spray drainer;Described second does not coagulate Gas processing system includes the second Water spray drainer, the second breakdown of emulsion tank, the second explosion-proof compressor, the second water washing tank, the second demisting Tank and the second activated carbon filtering tank, the second Water spray drainer, the second breakdown of emulsion tank, the second explosion-proof compressor, the second washing It is sequentially connected between tank, the second demisting tank, the second activated carbon filtering tank and the second activated carbon filtering tank and burner for heating furnace phase Even;Sprayed with the second water by extraction conduit respectively the upside of the feed end of second Resolution Room gathers materials cover and discharge end gathers materials cover The air inlet for drenching drainer is connected.
Further, to make present configuration compacter, the energy-efficient indirect thermal desorption carbonizing apparatus is also wrapped Include condenser system, the condenser system includes oil storage tank, cooling tower and oil water separator, the oil water separator respectively with oil storage Tank is connected with cooling tower;The water return outlet of the first Water spray drainer and the second Water spray drainer with oil water separator phase Even.
Further, to make present configuration compacter, the heat-resisting steel cylinder and heating furnace of first Resolution Room Between and be equipped with and the heat-resisting steel cylinder and heating furnace of the second Resolution Room between carbon shoe, the first Resolution Room it is resistance to The heat-resisting steel cylinder of hot steel cylinder and the second Resolution Room and corresponding feed end gather materials cover and discharge end gathers materials lead between cover Cross the sealing of fish scale sheet sealing structure.
Further, to make present configuration compacter, first auger and the second auger pass through Motor drive, First auger and the second flood dragon are connected with reduction box using universal drive shaft, are mounted on increasing on the blade of the first auger and the second auger Plus material agitation lifting piece and prevent the iron chains of materials from bonding, material is defeated to the right in the case where packing auger blade is with 1.0~10rpm rotations Send, while cylinder is parsed with 1.0~2.0rpm rotating speed rotations, while heating furnace is burnt by fuel (natural gas or diesel oil), it is right Parsing cylinder outer wall carries out being heated to 500~900 DEG C, by parsing outer wall of barrel and silicon carbide lining conduction of heat to thing in cylinder Material carries out the indirectly heat under oxygen-free environment, makes material that dehydration and Organic substance thermal cracking or carbonization to occur.
Further, to make present configuration compacter, it is provided with the chimney breast for detecting oxygen in flue gas The oxygen on-line detector of concentration, automatically adjusts the burner blower fan blow rate required, it is ensured that oxygen in flue gas by oxygen concentration in flue gas Gas concentration is between 6%~10%.
Further, to make present configuration compacter, the end of the second fixed gas processing system is near flammable Gas entrance point is provided with the combustible gas on-line detector for detecting combustable gas concentration, it is ensured that fixed gas preferentially burns completely, Insufficient section can be precisely controlled parsing room temperature again by natural gas or diesel oil afterburning, reduce operating cost.
Present invention also offers a kind of energy-efficient indirect thermal desorption carbonizing apparatus processing method, comprises the following steps:
(1) broken material is delivered to into the first Resolution Room by screw feeding device;
(2) material produces parsing gas, gaseous hydrocarbon mixture and carbonizing production in the first parsing heating indoor cracking;
(3) unqualified carbonizing production enters into the second parsing interior and carries out continuous high temperature air oxidation, is further subtracted Ash after amount;
The parsing gas of (4) first Resolution Rooms Jing the first fixed gas processing system process after Jing pipelines to heating furnace For fuel supplement;The parsing gas of the second Resolution Room Jing the second fixed gas processing system process after Jing pipelines to heating furnace Fully burn on burner flame;
The discharging residue of (5) first Resolution Rooms reaches prescription, is expelled directly out then being processed recovery, while the second solution Analysis room is used to directly process supplied materials.
Beneficial effects of the present invention are:(1), solve Resolution Room steel pipe preferably deform cause auger it is stuck, it is easy abrasion and The drawbacks of corrosive materials cannot being processed;(2) heat exchange area of the first Resolution Room and the second Resolution Room, is increased so as to improve thing The rate of cleavage of material, so as to enhance production capacities;(3), by the draw-off direction of switching parsing gas, gas is parsed to entering using high temperature Material heating increases parsing gas in high-temperature region time of staying promotion further cracking;(4), increase by the second Resolution Room, by drum Enter hot-air and carry out DIC in oxidation residua to obtain further reduced training, or the second Resolution Room can also be used for processing charging, Enhance production capacities;(5), using the pre- hot feed of high-temperature flue gas, energy utilization rate is improved;(6), entered using high-temperature flue gas preheated burning device Gas and the second Resolution Room hot-air, improve energy utilization rate;(7), burner blower fan is automatically adjusted by oxygen concentration in flue gas The blow rate required, it is ensured that fuel burns completely, reduces environmental pollution;(8), by adjusting the controllable furnace temp of flue rotation speed of fan And heat exchange efficiency;(9), burner natural gas or diesel oil flow are automatically adjusted according to combustable gas concentration;Guarantee that fixed gas is preferential Burn completely, insufficient section can be precisely controlled parsing room temperature again by natural gas or diesel oil afterburning, reduce operating cost.
Description of the drawings
In order to be illustrated more clearly that the specific embodiment of the invention or technical scheme of the prior art, below will be to concrete The accompanying drawing to be used needed for embodiment or description of the prior art is briefly described.In all of the figs, similar element Or part is typically identified by similar reference.In accompanying drawing, each element or part might not draw according to actual ratio.
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the first Resolution Room and heating furnace structure schematic diagram in the present invention;
In accompanying drawing:1 represents oil storage tank;2 represent cooling tower;3 represent oil water separator;4 represent air-blaster;5 represent Air heat exchanger;6 represent the first activated carbon filtering tank;7 represent the first demisting tank;8 represent the first water washing tank;9 represent first Explosion-proof compressor;10 represent the first breakdown of emulsion tank;11 represent the second activated carbon filtering tank;12 represent the second demisting tank;13 represent the Two water washing tanks;14 represent the second explosion-proof compressor;15 represent the second breakdown of emulsion tank;16 represent the first Water spray drainer;17 represent Second Water spray drainer;18 represent chimney breast;19 represent screw feeding device;20 represent that second feeds flapper;21 tables Show the first charging flapper;22 represent the second ash discharge flapper;23 represent the first ash discharge flapper;24 represent heating furnace burning Device;25 represent the first Resolution Room;250 represent the first auger;251 represent fish scale sheet sealing structure;252 represent carbon shoe; 253 represent cylinder outer wall;26 represent the second Resolution Room;27 represent heating furnace;28 represent the first discharging flapper;29 represent discharging Pulverizer;30 represent gray back pump;31 represent the second discharging flapper.
Specific embodiment
The embodiment of technical solution of the present invention is described in detail below in conjunction with accompanying drawing.Following examples are only used for Technical scheme is clearly illustrated, therefore is only used as example, and the protection model of the present invention can not be limited with this Enclose.
As shown in Figure 1 to Figure 2, a kind of energy-efficient indirect thermal desorption carbonizing apparatus that the present invention is provided, including preheating Feed system, material heating system, the first fixed gas processing system, the second fixed gas processing system and condenser system.
The preheating feed system includes the screw feeding device 19 with heat exchange jacket and chimney breast 18, and the spiral enters The feed end of material device 19 is connected with charging aperture, and material Jing physics after graininess of the particle diameter less than 40mm is broken into by Fig. 1 institutes Screw feeding device 19 is entered at the A for showing, the discharge end of screw feeding device 19 is parallel with the first charging flapper 21 and second Charging flapper 20, at the first charging charging of flapper 21 and second flapper 20 C as shown in Figure 1 nitrogen is filled;The cigarette Chimney pipeline 18 is connected with the heat exchange jacket of screw feeding device 19, and the end of chimney breast is connected for arranging with the B shown in Fig. 1 Gas;Water- to-water heat exchanger is provided with chimney breast 18, the water after heating is flowed in the heat exchange jacket layer of screw feeding device 19, with spiral shell Material in rotation feed arrangement 19 passes through steel plate indirect heat exchange;The material heating system includes heating furnace 27, the first Resolution Room 25 and second Resolution Room 26, the upside of the heating furnace 27 is connected with chimney breast 18;Chimney breast 18 is provided with air heat and hands over Parallel operation 5, the air intake of the air heat exchanger 5 is communicated with air-blaster 4, inlet end and Fig. 1 institutes of air-blaster 4 It is connected at the G for showing;The air outlet slit of air heat exchanger 5 is communicated with the combustor air inlet fans entrance of heating furnace 27;Described One Resolution Room 25 and the second Resolution Room 26 gather materials the heat-resisting of cover and inner lining with silicon carbide material including gather materials cover, discharge end of feed end Steel cylinder;The heat-resisting steel cylinder is through the inside of heating furnace 27 and is rotatably installed in feed end and gathers materials cover and discharging End gathers materials between cover, between the heat-resisting steel cylinder and heating furnace 27 of the first Resolution Room 25 and heat-resisting with the second Resolution Room 26 Carbon shoe 252, the heat-resisting steel cylinder of the first Resolution Room 25 and the second solution are equipped between steel cylinder and heating furnace 27 The heat-resisting steel cylinder and corresponding feed end of analysis room 26 gathers materials cover and discharge end the gathers materials fish scale sheet sealing structure that pass through between cover 251 sealings.The heat-resisting steel cylinder inside of the first Resolution Room 25 and the second Resolution Room 26 is provided with rotatably first twists accordingly The auger of dragon 250 and second, the auger of first auger 250 and second passes through Motor drive, the first auger 250 and the second flood dragon It is connected using universal drive shaft with reduction box, is mounted on increasing raising for material agitation on the blade of the first auger 250 and the second auger Tablet and the iron chains for preventing materials from bonding, material is conveyed to the right in the case where packing auger blade is with 1.0~10rpm rotations, while parsing circle Cylinder is with 1.0~2.0rpm rotating speed rotations, while heating furnace 27 is burnt by fuel (natural gas or diesel oil), to parsing cylinder outer wall 253 carry out being heated to 500~900 DEG C, and nothing is carried out to material in cylinder by parsing outer wall of barrel and silicon carbide lining conduction of heat Indirectly heat under oxygen environment, makes material that dehydration and Organic substance thermal cracking or carbonization to occur.The first charging flapper 21 Discharge end and the feed end of the first Resolution Room 25 cover that gathers materials be connected, the discharge end of the second charging flapper 20 is solved with second The feed end of analysis room 26 cover that gathers materials is connected, and the feed end of the first Resolution Room 25 gathers materials the feed end of cover downside and the second Resolution Room 26 The cover downside that gathers materials is connected accordingly with the first ash discharge flapper 23 and the second ash discharge flapper 22, the first ash discharge flapper 23 and the Two ash discharge flappers 22 finally discharge inorganic salt with being connected at the D shown in Fig. 1, and the discharge end of the first Resolution Room 25 gathers materials cover downside With the discharge end of the second Resolution Room 26 gather materials cover downside accordingly with first discharging flapper 28 and second discharging the phase of flapper 31 Even, the discharge end of the first discharging flapper 28 and second discharging flapper 31 is connected with discharging pulverizer 29, it is described go out The secondary feeds that material pulverizer 29 is gathered materials on the upside of cover by the Resolution Room 25 of gray back pump 30 and first and the discharge end of the second Resolution Room 26 Pipeline is connected, and discharging pulverizer discharge end is connected with the F shown in Fig. 1.The first fixed gas processing system includes the first water Spray drainer 16, the first breakdown of emulsion tank 10, the first explosion-proof compressor 9, the first water washing tank 8, the first demisting tank 7 and the first activated carbon Filtering tank 6, the first Water spray drainer 16, the first breakdown of emulsion tank 10, the first explosion-proof compressor 9, the first water washing tank 8, first It is sequentially connected between demisting tank 7, the first activated carbon filtering tank 6 and the first activated carbon filtering tank 6 is connected with heating furnace 27;Described The upside of the feed end of one Resolution Room 25 gathers materials cover and discharge end gathers materials cover is condensed respectively by extraction conduit with the first Water spray The air inlet of tank 16 is connected;The second fixed gas processing system include the second Water spray drainer 17, the second breakdown of emulsion tank 15, the Two explosion-proof compressors 14, the second water washing tank 13, the second demisting tank 12 and the second activated carbon filtering tank 11, second Water spray is cold Solidifying tank 17, the second breakdown of emulsion tank 15, the second explosion-proof compressor 14, the second water washing tank 13, the second demisting tank 12, the second activated carbon are filtered It is sequentially connected between tank 11 and the second activated carbon filtering tank 11 is connected with burner for heating furnace 24;Second Resolution Room 26 enters The upside of material end gathers materials cover and discharge end gathers materials cover is respectively by extraction conduit and the air inlet phase of the second Water spray drainer 17 Even.The condenser system include oil storage tank 1, cooling tower 2 and oil water separator 3, the oil water separator 3 respectively with oil storage tank 1 It is connected with cooling tower 2;The water return outlet of the first Water spray drainer 16 and the second Water spray drainer 17 is and oil-water separation Device 3 is connected.
The oxygen on-line detector for detecting oxygen concentration in flue gas is provided with the chimney breast 18 of the present invention, by cigarette Oxygen concentration automatically adjusts the burner blower fan blow rate required in gas, it is ensured that oxygen concentration is between 6%~10% in flue gas.
The present invention the second fixed gas processing system end be provided with the E shown in combustible gas entrance point Fig. 1 for The combustible gas on-line detector of detection combustable gas concentration, it is ensured that fixed gas preferentially burns completely, and insufficient section is again by natural Gas or diesel oil afterburning, can be precisely controlled parsing room temperature, reduce operating cost.
The present invention operation principle be:The parsing gas of the first Resolution Room 25 will be evacuated to by the negative pressure of the first explosion-proof compressor 9 First spray drainer, the entrance of the first breakdown of emulsion tank 10 that the first spray drainer upper strata is exported with two series connection is communicated, Jing Guo One explosion-proof compressor 9 is condensed again after further compressing, and two are entered after the first water washing tank 8 and the demisting of the first demisting tank 7 It is harmful to after macromole gas in the adsorbed gas of first activated carbon filtering tank 6 of individual series connection, is then sent at burner for heating furnace 24.
The oil water mixture of the first spray drainer and the second spray drainer bottom flows under the influence of gravity into profit point From device 3, the cracked oil separated is used as the fuel of heating furnace 27 after being used to sell outward or mix with diesel oil into oil tank;Oil The sewage that water separator 3 is separated is returned to the first spray after being cooled within 60 DEG C through cooling tower 2 by water circulating pump Drench drainer and the second spray drainer;The precipitated sludge of oil water separator 3 will be parsed by irregular the beating to first of sludge pump The charging aperture of room 25, cracks again after mixing with material.
Material is pushed to the low order end of the first Resolution Room 25 after cracking, through the first discharge lock gas with nitrogen filling Pulverizer is entered after device 28, if the residue content of beary metal that discharges is exceeded, by after gray back pump 30 and high temperature preheating Hot-air together sends into the left side of the second Resolution Room 26, and temperature is also up to 500~900 DEG C in the cylinder of the second Resolution Room 26, residual DIC in slag at high temperature with air in oxygen, there is chemical reaction, the production gas such as CO2 and CO in carbon dioxide;Together When can control time of staying of residue by adjusting in the second Resolution Room 26 rotating speed of the second auger and direction, make it possible to Complete oxidation obtains further decrement;Gas in second Resolution Room 26 is after extraction pipeline into the process of the second fixed gas System, because fuel gas content is very low in the extraction gas in the second Resolution Room 26, is directly entering after activated carbon adsorption Enter heating furnace 27 to be injected on the flame of burner, be allowed to fully burn.
The exhanst gas outlet of heating furnace 27 is communicated with the high-temperature flue gas entry of air heat exchanger, through filtered air heat exchanger High temperature air out is used for combustor air inlet air and the air inlet of gray back pump 30 on heating furnace 27;Afterwards high-temperature flue gas enter charging The heat exchange jacket of conveying worm is used for pre- hot feed, is discharged in air by chimney breast 18 in the presence of blower fan again afterwards Go;System can be by adjusting flue the rotation speed of fan controllable temperature of heating furnace 27 and heat exchange efficiency and dense by oxygen in flue gas Degree automatically adjusts the burner blower fan blow rate required, it is ensured that fuel burns completely, reduces environmental pollution.
The processing method of the present invention is comprised the following steps:
Execution step S101:Broken material is delivered to into the first Resolution Room 25 by screw feeding device 19;
Execution step S102:Material adds thermal cracking in the first Resolution Room 25, produces parsing gas, gaseous hydrocarbon mixture And carbonizing production;
Execution step S103:Unqualified carbonizing production is entered in the second Resolution Room 26 and carries out continuous high temperature air oxidation, Obtain the ash after further decrement;
Execution step S104:The parsing gas of the first Resolution Room 25 Jing pipelines Jing after the process of the first fixed gas processing system are defeated Deliver in heating furnace 27 for fuel supplement;The parsing gas of the second Resolution Room 26 Jing Jing after the process of the second fixed gas processing system Pipeline is fully burnt to the flame of burner for heating furnace 24;
Execution step S105:The discharging residue of the first Resolution Room 25 reaches prescription, is expelled directly out then being processed back Receive, while the second Resolution Room 26 is used to directly process supplied materials.
Finally it should be noted that:Various embodiments above only to illustrate technical scheme, rather than a limitation;To the greatest extent Pipe has been described in detail with reference to foregoing embodiments to the present invention, it will be understood by those within the art that:Its according to So the technical scheme described in foregoing embodiments can be modified, either which part or all technical characteristic are entered Row equivalent;And these modifications or replacement, do not make the essence disengaging various embodiments of the present invention technology of appropriate technical solution The scope of scheme, it all should cover in the middle of the claim of the present invention and the scope of description.

Claims (10)

1. a kind of energy-efficient indirect thermal desorption carbonizing apparatus, it is characterised in that:Including preheating feed system and material heating System;
The preheating feed system includes the screw feeding device with heat exchange jacket and chimney breast, the screw feeding device Feed end is connected with charging aperture, and the discharge end of screw feeding device is parallel with the first charging flapper and the second charging flapper; The chimney breast is connected with the heat exchange jacket of screw feeding device, and water- to-water heat exchanger is provided with chimney breast;
The material heating system includes heating furnace, the first Resolution Room and the second Resolution Room, the upside of the heating furnace and chimney Pipeline is connected;Chimney breast is provided with air heat exchanger, air intake and the air-blaster phase of the air heat exchanger Logical, the air outlet slit of air heat exchanger is communicated with the combustor air inlet fans entrance of heating furnace;First Resolution Room and Two Resolution Rooms gather materials the heat-resisting steel cylinder of cover and inner lining with silicon carbide material including gather materials cover, discharge end of feed end;It is described resistance to Hot steel cylinder is through inside heating furnace and is rotatably installed in that feed end gathers materials cover and discharge end gathers materials cover, and first The heat-resisting steel cylinder inside of Resolution Room and the second Resolution Room is provided with accordingly rotatably the first auger and the second auger.
2. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 1, it is characterised in that:First charging The discharge end of flapper and the feed end of the first Resolution Room cover that gathers materials is connected, the discharge end and second of the second charging flapper The feed end of the Resolution Room cover that gathers materials is connected, and the gather materials feed end of cover downside and the second Resolution Room of the feed end of the first Resolution Room gathers materials Cover downside is connected accordingly with the first ash discharge flapper and the second ash discharge flapper, and the discharge end of the first Resolution Room gathers materials on the downside of cover With the discharge end of the second Resolution Room gather materials cover downside accordingly with first discharging flapper and second discharging flapper be connected, it is described The discharge end of the first discharging flapper and the second discharging flapper is connected with discharging pulverizer, and the discharging pulverizer is by returning The secondary feeds pipeline that grey pump and the first Resolution Room and the second Resolution Room discharge end gather materials on the upside of cover is connected.
3. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 2, it is characterised in that:It is described energy-efficient Indirect thermal desorption carbonizing apparatus also include the first fixed gas processing system and the second fixed gas processing system;Described first does not coagulate Gas processing system includes the first Water spray drainer, the first breakdown of emulsion tank, the first explosion-proof compressor, the first water washing tank, the first demisting Tank and the first activated carbon filtering tank, the first Water spray drainer, the first breakdown of emulsion tank, the first explosion-proof compressor, the first washing It is sequentially connected between tank, the first demisting tank, the first activated carbon filtering tank and the first activated carbon filtering tank is connected with heating furnace;It is described The upside of the feed end of the first Resolution Room gathers materials cover and discharge end gathers materials cover is condensed respectively by extraction conduit with the first Water spray The air inlet of tank is connected;
The second fixed gas processing system include the second Water spray drainer, the second breakdown of emulsion tank, the second explosion-proof compressor, second Water washing tank, the second demisting tank and the second activated carbon filtering tank, it is the second Water spray drainer, the second breakdown of emulsion tank, second explosion-proof Be sequentially connected between compressor, the second water washing tank, the second demisting tank, the second activated carbon filtering tank and the second activated carbon filtering tank with Burner for heating furnace is connected;The upside of the feed end of second Resolution Room gathers materials cover and discharge end gathers materials cover is respectively by extracting Pipeline is connected with the air inlet of the second Water spray drainer.
4. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 3, it is characterised in that:First breakdown of emulsion Tank, the second breakdown of emulsion tank, the first explosion-proof compressor, the second explosion-proof compressor, the first activated carbon filtering tank and the second activated carbon are filtered Tank is two, between two the first breakdown of emulsion tanks, between two the second breakdown of emulsion tanks, between two the first activated carbon filtering tanks and It is connected in series between two the second activated carbon filtering tanks, between two the first explosion-proof compressors and two the second explosion-proof compressions Between machine and downlink connection.
5. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 4, it is characterised in that:It is described energy-efficient Indirect thermal desorption carbonizing apparatus also include condenser system, the condenser system include oil storage tank, cooling tower and oil water separator, The oil water separator is connected respectively with oil storage tank and cooling tower;The first Water spray drainer and the second Water spray drainer Water return outlet be connected with oil water separator.
6. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 1, it is characterised in that:First parsing It is equipped between the heat-resisting steel cylinder of room and heating furnace and and the heat-resisting steel cylinder and heating furnace of the second Resolution Room between Carbon shoe, the heat-resisting steel cylinder of the first Resolution Room and the heat-resisting steel cylinder of the second Resolution Room and corresponding feed end collection Material cover and discharge end are gathered materials and sealed by fish scale sheet sealing structure between cover.
7. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 6, it is characterised in that:First auger With the second auger by Motor drive, the first auger and the second flood dragon are connected with reduction box using universal drive shaft, the first auger with The lifting piece for increasing material agitation and the iron chains for preventing materials from bonding are mounted on the blade of the second auger.
8. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 1, it is characterised in that:The chimney breast Inside it is provided with the oxygen on-line detector for detecting oxygen concentration in flue gas.
9. energy-efficient indirect thermal desorption carbonizing apparatus according to claim 1, it is characterised in that:Described second does not coagulate The end of gas processing system is provided with the combustible gas on-line detector for detecting combustable gas concentration near combustible gas entrance point.
10. a kind of energy-efficient indirect thermal desorption carbonizing treatment method, comprises the following steps:
(1) broken material is delivered to into the first Resolution Room by screw feeding device;
(2) material produces parsing gas, gaseous hydrocarbon mixture and carbonizing production in the first parsing heating indoor cracking;
(3) unqualified carbonizing production enters into the second parsing interior and carries out continuous high temperature air oxidation, after obtaining further decrement Ash;
The parsing gas of (4) first Resolution Rooms Jing pipelines Jing after the process of the first fixed gas processing system are used for heating furnace Fuel supplement;The parsing gas of the second Resolution Room Jing pipelines Jing after the process of the second fixed gas processing system are burnt to heating furnace Fully burn on device flame;
The discharging residue of (5) first Resolution Rooms reaches prescription, is expelled directly out then being processed recovery, while the second Resolution Room For directly processing supplied materials.
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CN109692869A (en) * 2019-02-22 2019-04-30 杰瑞环保科技有限公司 The rotary indirect thermal desorption device of one kind and system
CN110465542A (en) * 2019-09-23 2019-11-19 无锡伦巴第科技有限公司 Cascade the device and processing method of thermal desorption processing organic contamination solid waste

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CN104785515A (en) * 2015-04-27 2015-07-22 沈逍江 Two-section auger indirect thermal desorption device
CN206736169U (en) * 2017-02-13 2017-12-12 无锡爱普特设备科技有限公司 A kind of energy-efficient indirect thermal desorption carbonizing apparatus

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CN101100621A (en) * 2007-07-03 2008-01-09 山东省科学院能源研究所 Method and device for preparing biomass hydrogen-rich combustion gas
CN104785515A (en) * 2015-04-27 2015-07-22 沈逍江 Two-section auger indirect thermal desorption device
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CN109692869A (en) * 2019-02-22 2019-04-30 杰瑞环保科技有限公司 The rotary indirect thermal desorption device of one kind and system
CN110465542A (en) * 2019-09-23 2019-11-19 无锡伦巴第科技有限公司 Cascade the device and processing method of thermal desorption processing organic contamination solid waste
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