CN106675409A - Modified asphalt coating with saline-alkaline tolerance and root resistance and production method as well as waterproof roll and production method - Google Patents
Modified asphalt coating with saline-alkaline tolerance and root resistance and production method as well as waterproof roll and production method Download PDFInfo
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- CN106675409A CN106675409A CN201611259692.7A CN201611259692A CN106675409A CN 106675409 A CN106675409 A CN 106675409A CN 201611259692 A CN201611259692 A CN 201611259692A CN 106675409 A CN106675409 A CN 106675409A
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- salt
- alkali tolerance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
- E04B1/665—Sheets or foils impervious to water and water vapor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the field of building waterproof materials, in particular to a modified asphalt coating with saline-alkaline tolerance and root resistance and a production method as well as a waterproof roll and a production method. The modified asphalt coating with saline-alkaline tolerance and root resistance is characterized by comprising raw materials in percentage by mass as follows: 49%-60% of asphalt, 2%-12% of a softener, 6%-14% of SBS (styrene-butadiene-styrene block copolymer), 3%-8% of APAO (amorphous poly-alpha-olefins), 2%-5% of tackifying resin, 1%-2% of a root resisting agent and 17%-20% of filler. The modified asphalt coating with saline-alkaline tolerance and root resistance and the production method as well as the waterproof roll and the production method have the beneficial effects that the coating and the waterproof roll have saline-alkaline tolerance and root resistance and are applicable to waterproofing work with planting demand in saline-alkaline areas.
Description
Technical field
Material and manufacture the present invention relates to architectural waterproof material field, more particularly to Salt And Alkali Tolerance root-resistant puncturing modified pitch are coated
Method, waterproof roll and manufacture method
Background technology
The SBS elastomer modified asphalt waterproof rolls selected civil engineering construction project waterproof at present or APP plastic bodies more
Modified asphalt waterproof coiled material, not Salt And Alkali Tolerance and not root-resistant puncturing.
Modified asphalt waterproof coiled material is made up of tire base polyester blank or glass fiber blank in prior art, and tire base upper and lower surface is pasted with
Impregnated material layer, the outer surface of impregnated material layer is pasted with modified pitch coating material layer, and coating material layer outer surface is pasted with
Clad can isolated material.Its modified pitch is coated in expecting and typically contains Colophonium, softening agent, SBS synthetic rubber and filler etc..Its presence
Problem be mainly not Salt And Alkali Tolerance and not root-resistant puncturing, being not suitable for varieties in saline-alkali areas has the waterproofing work of plantation demand, it is impossible to expire
Sufficient engineer applied.
There is the waterproofing work of plantation demand to meet varieties in saline-alkali areas, now need to study a kind of modified drip of Salt And Alkali Tolerance root-resistant puncturing
Blue or green waterproof roll;Project research success, varieties in saline-alkali areas is had the waterproofing work of plantation demand waterproof play it is extremely important
Effect.
The content of the invention
Material and manufacture method, waterproof roll and system it is an object of the invention to provide Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated
Make method, described to coat material and the waterproof roll has Salt And Alkali Tolerance and a root-resistant puncturing performance, the existing skill of cost-effective solution
Problem present in art.
Concrete technical scheme of the present invention is as follows:
A kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, composition of raw materials by percentage to the quality, including following components:
Colophonium 49~60%, softening agent 2~12%, SBS 6~14%, APAO 3~8%, tackifying resin 2~5%, root resistance agent 1~
2%, filler 17~20%.
Further, composition of raw materials by percentage to the quality, including following components:Colophonium 56%, softening agent 6%, SBS
10%, APAO 5%, tackifying resin 3%, root resistance agent 1%, filler 19%.
Further, described softening agent be second line of distillation oil, subtract third fractional oil, in the line that subtracts four oil or the line oil that subtracts five any one
Or several mixture.
Further, the tackifying resin is C5 Petropols, C9 Petropols or terpene resin.
Further, described filler is ground calcium carbonate, Pulvis Talci, agstone, bentonite or slaked lime.
Further, described root resistance agent is 2- ethylhexyls -2 (R) -2- (the chloro- o- toluene of 4-) propionate.
Further, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, is comprised the following steps:
The Colophonium and the softening agent are dehydrated into 0.5~1.5h in more than 160 DEG C, are obtained being dehydrated Colophonium and dehydration is softened
Agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1~1.5h;
The APAO is added, continues to grind 0.5~1h of stirring;
The tackifying resin is added, continues to grind 0.5~1h of stirring;
Described filler is added, continues to grind 1~1.5h of stirring;
The root resistance agent is added, is continued grinding 0.5~1h of stirring and is obtained the Salt And Alkali Tolerance root-resistant puncturing modified pitch painting
Lid material.
Further, a kind of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material, changes containing the Salt And Alkali Tolerance root-resistant puncturing
Property Colophonium is coated material.
Further, a kind of manufacture method of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material, comprises the following steps:
With preimpregnation oil saturated as the long polyester non-woven fabrics of tire base, extract;
Salt And Alkali Tolerance root-resistant puncturing modified pitch described in upper and lower surface-coated in the tire base is coated material, obtains the painting
Lid material material layer;
In the material material layer outer surface coating clad can isolated material of coating;
It is placed in 8~55 DEG C of cooling water and cools down, winding, cut roll obtains the Salt And Alkali Tolerance root-resistant puncturing modified pitch and prevents
Water coiled material.
Further, the pre- immersion oil by weight percentage, including Colophonium 93%, polypropylene 5%, root resistance agent 2%;Institute
Clad can isolated material is stated for PE films, fine sand or mineral pellet.
The present invention compared with prior art, has the advantages that:
(1) the saline and alkaline root-resistant puncturing modified pitch of the present invention SBS in material that coats can contact with water, weak acid, alkali etc., tool
There are the characteristics such as excellent tensile strength, big surface friction coefficient, low temperature performance well, excellent electrical properties, good processability;APAO with
SBS blendings can improve processing characteristics, the compatibility and the viscoelasticity of material;Excellent with the SBS compatibilitys, the good adhesion-promoting of tackifying resin
Property, thermostability, stability, resistance to water, resistance to acids and bases;Under the root resistance agent collective effect, can effectively prevent plant roots from wearing
Thorn makes the material of coating, and plant root is kept out for a long time and invades coiled material, moreover it is possible to avoid producing destruction to waterproof layer, with Saline alkali tolerance
Can, it is adaptable to which there is the waterproofing work of plantation demand varieties in saline-alkali areas, can well ensure building.
(2) saline and alkaline root-resistant puncturing modified pitch of the present invention is coated and expects that making temperature is lower than prior art, has both reduced drip
Light ends volatilization, beneficial to environmental protection, delays asphalt performance aging in green grass or young crops, and energy-conservation.
Specific embodiment
The specific embodiment of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described
Embodiment be a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this area is general
The every other embodiment that logical technical staff is obtained under the premise of creative work is not made, belongs to present invention protection
Scope.
Heretofore described, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 49~60%, softening agent 2~12%, SBS 6~14%, APAO3~8%, tackifying resin 2~
5%, root resistance agent 1~2%, filler 17~20%.
Heretofore described Colophonium can select Colophonium commonly used in the art;In following embodiments, it is preferred that adopt
No. 90 heavy traffic paving asphalts.
Heretofore described softening agent is second line of distillation oil, subtract third fractional oil, in the line that subtracts four oil or the line oil that subtracts five any one
Or several mixture;In the following embodiments, it is preferred that using second line of distillation oil.
Heretofore described SBS (styrene butadiene styrene block copolymer (SBS)), in the following embodiments, preferably
, the SBS 4402 produced using Sinopec Ba Ling petrochemical industries Co., Ltd.
Heretofore described APAO (amorphous state alpha olefin copolymer), in the following embodiments, it is preferred that adopt Liaoyang
The APAO of Da Qida Chemical Manufactures.
Heretofore described tackifying resin is C5 Petropols, C9 Petropols or terpene resin;In following embodiments,
Preferably, using C5 Petropols.
Heretofore described filler particle size is 180~200 mesh;
Heretofore described filler is ground calcium carbonate, Pulvis Talci, agstone, bentonite or slaked lime;Filler can
Filling space, makes the space of compound will not be excessive, can also improve cohesiveness, thermostability and the air stability of Colophonium;It is following
In embodiment, it is preferred that using ground calcium carbonate powder.
Heretofore described root resistance agent is 2- ethylhexyls -2 (R) -2- (the chloro- o- toluene of 4-) propionate.
Heretofore described, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 0.5~1.5h in more than 160 DEG C, are obtained being dehydrated Colophonium and dehydration is softened
Agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1~1.5h;SBS can be contacted with water, weak acid, alkali etc., with excellent tensile strength, mantle friction system
Number is big, low temperature performance well, excellent electrical properties, the characteristic such as good processability;
The APAO is added, continues to grind 0.5~1h of stirring;The APAO and SBS blendings can improve material
Processing characteristics, the compatibility and viscoelasticity;
The tackifying resin is added, continues to grind 0.5~1h of stirring;The tackifying resin is excellent with the SBS compatibilitys, with good
Good adhesion-promoting, thermostability, stability, resistance to water, resistance to acids and bases;
Described filler is added, continues to grind 1~1.5h of stirring;
The root resistance agent is added, continues to grind 0.5~1h of stirring;Obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch to apply
Lid material, the root resistance agent can effectively prevent plant root puncture from making the material of coating, and plant root is kept out for a long time and invades coiled material, also
It is avoided that and destruction is produced to waterproof layer.
It is heretofore described, a kind of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material, containing resistance to of the Salt And Alkali Tolerance
Puncture modified pitch to coat material.
Heretofore described, a kind of manufacture method of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material, including it is following
Step:
With preimpregnation oil saturated as the long polyester non-woven fabrics of tire base, extract;
Salt And Alkali Tolerance root-resistant puncturing modified pitch described in upper and lower surface-coated in the tire base is coated material, obtains the painting
Lid material material layer;
There is coated side isolated material in the material material layer outer surface of coating;
It is placed in 8~55 DEG C of cooling water and cools down, winding, cut roll obtains the Salt And Alkali Tolerance root-resistant puncturing modified pitch and prevents
Water coiled material.
Heretofore described pre- immersion oil by weight percentage, including Colophonium 93%, polypropylene 5%, root resistance agent 2%;
Preferably, polypropylene weight average molecular weight be 20~300,000, in following embodiments, adopt weight average molecular weight for 300,000 polypropylene;
The heretofore described clad can isolated material is PE films, fine sand or mineral pellet, in following embodiments, with PE
It is illustrated as a example by film.
Heretofore described Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is the general thickness 4mm of this area
Or 5mm.
Embodiment 1
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 49%, softening agent 12%, SBS 6%, APAO 8%, tackifying resin 5%, root resistance agent 1% is filled out
Material 19%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1h;
The APAO is added, continues to grind stirring 0.5h;
The tackifying resin is added, continues to grind stirring 0.5h;
Described filler is added, continues to grind stirring 1.5h;
The root resistance agent, continuation grinding stirring 0.5h is added to obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat
Material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 4mm.
Embodiment 2
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute
Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 52%, softening agent 9%, SBS7%, APAO 7%, tackifying resin 4%, root resistance agent 1%, filler
20%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1.5h;
The APAO is added, continues to grind stirring 0.5h;
The tackifying resin is added, continues to grind stirring 1h;
Described filler is added, continues to grind stirring 1.5h;
Add the root resistance agent, continue to grind stirring 1h and obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 5mm.
Embodiment 3
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute
Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 54%, softening agent 8%, SBS8%, APAO 6%, tackifying resin 4%, root resistance agent 2%, filler
18%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1.5h;
The APAO is added, continues to grind stirring 1h;
The tackifying resin is added, continues to grind stirring 1h;
Described filler is added, continues to grind stirring 1h;
Add the root resistance agent, continue to grind stirring 1h and obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 4mm.
Embodiment 4
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute
Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 56%, softening agent 6%, SBS 10%, APAO 5%, tackifying resin 3%, root resistance agent 1% is filled out
Material 19%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1.5h;
The APAO is added, continues to grind stirring 1h;
The tackifying resin is added, continues to grind stirring 0.5h;
Described filler is added, continues to grind stirring 1.5h;
The root resistance agent, continuation grinding stirring 0.5h is added to obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat
Material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 5mm.
Embodiment 5
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute
Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 58%, softening agent 4%, SBS 12%, APAO 4%, tackifying resin 2%, root resistance agent 1% is filled out
Material 19%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1.5h;
The APAO is added, continues to grind stirring 1h;
The tackifying resin is added, continues to grind stirring 0.5h;
Described filler is added, continues to grind stirring 1.5h;
Add the root resistance agent, continue to grind stirring 1h and obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 4mm.
Embodiment 6
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute
Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, and composition of raw materials is with mass percent
Meter, including following components:Colophonium 60%, softening agent 2%, SBS 14%, APAO 3%, tackifying resin 2%, root resistance agent 2% is filled out
Material 17%.
Described in the present embodiment, a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated the manufacture method of material, including following step
Suddenly:
The Colophonium and the softening agent are dehydrated into 1h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
By the dehydration Colophonium, the dehydration softening agent with the elastomeric mixture of the SBS in 180 DEG C~200 DEG C
Lower colloid mill grinds 1.5h;
The APAO is added, continues to grind stirring 0.5h;
The tackifying resin is added, continues to grind stirring 1h;
Described filler is added, continues to grind stirring 1.5h;
Add the root resistance agent, continue to grind stirring 1h and obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat material.
Described in the present embodiment, Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material thickness is 5mm.
To above-mentioned preferred embodiment 4, SBS II PY PE PE 4 (SBS waterproof rolls, II types, the polyester fiber of gained
Carcass, upper surface PE polyethylene faces, lower surface PE polyethylene faces, thickness is 4mm) Salt And Alkali Tolerance root-resistant puncturing modified pitch prevents
Water coiled material, according to JC/T 1075-2008《Planted roof root resistant waterproof roll》With Q/SY YHF0034--2015《It is resistance to
Salt alkaline polymer modified asphalt waterproof roll》Standard detected, obtains testing result as shown in table 1.
The Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material examining reports of 1 SBS II PY PE PE of table 4
Finally it should be noted that:Various embodiments above only to illustrate technical scheme, rather than a limitation;To the greatest extent
Pipe has been described in detail with reference to foregoing embodiments to the present invention, it will be understood by those within the art that:Its according to
So the technical scheme described in foregoing embodiments can be modified, either which part or all technical characteristic are entered
Row equivalent;And these modifications or replacement, do not make the essence disengaging various embodiments of the present invention technology of appropriate technical solution
The scope of scheme.
Claims (10)
1. a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch is coated material, it is characterised in that composition of raw materials by percentage to the quality, including
Following components:Colophonium 49~60%, softening agent 2~12%, SBS 6~14%, APAO3~8%, tackifying resin 2~5%, resistance
Root agent 1~2%, filler 17~20%.
2. Salt And Alkali Tolerance root-resistant puncturing modified pitch as claimed in claim 1 is coated material, it is characterised in that composition of raw materials is with quality
Percentages, including following components:Colophonium 56%, softening agent 6%, SBS 10%, APAO 5%, tackifying resin 3%, root resistance agent
1%, filler 19%.
3. the Salt And Alkali Tolerance root-resistant puncturing modified pitch as any one of claim 1-2 is coated material, it is characterised in that described
Softening agent be second line of distillation oil, subtract third fractional oil, any one or a few mixture in the line that subtracts four oil or the line oil that subtracts five.
4. the Salt And Alkali Tolerance root-resistant puncturing modified pitch as any one of claim 1-2 is coated material, it is characterised in that described
Tackifying resin is C5 Petropols, C9 Petropols or terpene resin.
5. the Salt And Alkali Tolerance root-resistant puncturing modified pitch as any one of claim 1-2 is coated material, it is characterised in that described
Filler is ground calcium carbonate, Pulvis Talci, agstone, bentonite or slaked lime.
6. the Salt And Alkali Tolerance root-resistant puncturing modified pitch as any one of claim 1-2 is coated material, it is characterised in that described
Root resistance agent be 2- ethylhexyls -2 (R) -2- (the chloro- o- toluene of 4-) propionate.
7. a kind of Salt And Alkali Tolerance root-resistant puncturing modified pitch as any one of claim 1-6 is coated the manufacture method of material,
Characterized in that, comprising the following steps:
The Colophonium and the softening agent are dehydrated into 0.5~1.5h in more than 160 DEG C, obtain being dehydrated Colophonium and dehydration softening agent;
The dehydration Colophonium, the dehydration softening agent are used with the elastomeric mixture of the SBS at 180 DEG C~200 DEG C
Colloid mill grinds 1~1.5h;
The APAO is added, continues to grind 0.5~1h of stirring;
The tackifying resin is added, continues to grind 0.5~1h of stirring;
Described filler is added, continues to grind 1~1.5h of stirring;
Add the root resistance agent, continue to grind 0.5~1h of stirring and obtain the Salt And Alkali Tolerance root-resistant puncturing modified pitch and coat material.
8. a kind of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material, it is characterised in that containing such as any one of claim 1-6 institute
State Salt And Alkali Tolerance root-resistant puncturing modified pitch to coat material.
9. a kind of manufacture method of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material as claimed in claim 8, it is characterised in that
Comprise the following steps:
With preimpregnation oil saturated as the long polyester non-woven fabrics of tire base, extract;
Salt And Alkali Tolerance root-resistant puncturing modified pitch described in upper and lower surface-coated in the tire base is coated material, obtains the material of coating
Material layer;
Clad can isolated material is scribbled in the material material layer outer surface of coating;
It is placed in 8~55 DEG C of cooling water and cools down, winding, cut roll obtains the Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof volume
Material.
10. the manufacture method of Salt And Alkali Tolerance root-resistant puncturing modified asphalt waterproof coiled material as claimed in claim 9, it is characterised in that:
The pre- immersion oil by weight percentage, including Colophonium 93%, polypropylene 5%, root resistance agent 2%;The clad can isolated material is
PE films, fine sand or mineral pellet.
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CN107936913A (en) * | 2017-12-01 | 2018-04-20 | 深圳市卓宝科技股份有限公司 | A kind of self-adhesive rubber asphalt sizing material and preparation method thereof and ancient building Special waterproof coiled material therefrom |
CN109355926A (en) * | 2018-09-25 | 2019-02-19 | 四川杨氏达防水材料有限公司 | Planted roof root resistance puncture resistant waterproof roll and preparation method |
CN110080470A (en) * | 2019-04-19 | 2019-08-02 | 四川环图材料科技有限公司 | Planted roof root-resistant puncturing water proofing asphalt coiled material and preparation method |
CN110374271A (en) * | 2019-06-03 | 2019-10-25 | 宏源防水科技集团有限公司 | A kind of copper tire base root-resistant puncturing asphalt felt and preparation method thereof and process units |
CN110724455A (en) * | 2018-07-16 | 2020-01-24 | 中国石油化工股份有限公司 | Non-curing rubber asphalt waterproof coating and preparation method thereof and root puncture resistant waterproof material |
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CN109355926A (en) * | 2018-09-25 | 2019-02-19 | 四川杨氏达防水材料有限公司 | Planted roof root resistance puncture resistant waterproof roll and preparation method |
CN110080470A (en) * | 2019-04-19 | 2019-08-02 | 四川环图材料科技有限公司 | Planted roof root-resistant puncturing water proofing asphalt coiled material and preparation method |
CN110374271A (en) * | 2019-06-03 | 2019-10-25 | 宏源防水科技集团有限公司 | A kind of copper tire base root-resistant puncturing asphalt felt and preparation method thereof and process units |
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