CN106675137A - Water-based reflective thermal insulation coating - Google Patents
Water-based reflective thermal insulation coating Download PDFInfo
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- CN106675137A CN106675137A CN201611234659.9A CN201611234659A CN106675137A CN 106675137 A CN106675137 A CN 106675137A CN 201611234659 A CN201611234659 A CN 201611234659A CN 106675137 A CN106675137 A CN 106675137A
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- parts
- aqueouss
- emulsion
- reflective heat
- insulation paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based reflective thermal insulation coating, prepared from emulsion, nano-particles, perchloric acid, polyethylene glycol, acrylamide, an inorganic non-metallic compound, a reflecting material, a filler, a dispersant, a toughening agent, a binding agent, glycol and distilled water according to the following steps: firstly mixing the distilled water with the dispersant, then performing warm water bath heating, sequentially adding the nano-particles, the inorganic non-metallic compound and the reflecting material, stirring the materials uniformly, then sequentially adding the emulsion, acrylamide, perchloric acid and the polyethylene glycol, performing stirring, continuously adding the filler and glycol, adding the toughening agent and the binding agent at last, and stirring the materials uniformly. The coating disclosed by the invention has the properties of pollution resistance, high temperature resistance and reflectivity, also has good adhesive force and scrubbing resistance, is high in tensile strength and elongation at break and good in decorative effect, cannot have scars easily, is low construction cost and maintenance cost, is prepared from friendly materials, and is environment-friendly and healthy.
Description
Technical field
The present invention relates to paint field, specifically a kind of aqueouss reflective heat-insulation paint.
Background technology
With global warming, ozone layer is corrupted such that irradiation of the sunray to building is stronger, the sun
The energy of sunlight absorbs and is transmitted to interior of building, building the inside by building when light is irradiated to external surface of buildings
Temperature raise, therefore its inner space become it is uncomfortable, while the burden for increasing air conditioning system improves energy consumption, increased two
The discharge capacity of carbonoxide and greenhouse gases, not only causes a hidden trouble to the safety of installations and facilities, but also pollutes environment.In order to solve
The problems referred to above, occur in succession with functional paints such as reflective insulation, covering hair check, anti-pollutions, become human living life
Urgent needss.Reflective heat-insulation paint presence increase body of wall traditional at present bears a heavy burden, involves great expense, ornamental poor, reflective insulation effect
The shortcomings of really poor and wayward production process, it is difficult to meet the persistent requirement of energy-conserving and environment-protective.
The content of the invention
It is an object of the invention to provide a kind of aqueouss reflective heat-insulation paint, to solve above-mentioned background technology in propose ask
Topic.
For achieving the above object, the present invention provides following technical scheme:
A kind of aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:40~50 parts of emulsion, nanoparticle
3~5 parts, 2~4 parts of perchloric acid, 2~4 parts of Polyethylene Glycol, 6~8 parts of acrylamide, 5~7 parts of inorganic non-metallic compound, reflection
4~6 parts of material, 12~16 parts of filler, 8~10 parts of dispersant, 6~8 parts of toughener, 6~8 parts of binding agent, ethylene glycol 16~20
Part, 30~40 parts of distilled water.
As further scheme of the invention:The emulsion be pure-acrylic emulsion, acrylic emulsion, pure acrylate emulsion,
One kind in acrylate and vinyl acetate emulsion, methacrylic acid emulsion, water-based fluorocarbon resin emulsion.
As further scheme of the invention:The dispersant be hydrophobic modified carboxylic acid sodium salt, polyacrylic acid sodium salt or
One or more in ammonium salt.
As further scheme of the invention:The toughener is Zirconium oxide fibre, alumina fibre, carbon fiber, silicic acid
One or more in aluminum fiber.
As further scheme of the invention:The binding agent is in waterglass, aluminium dihydrogen phosphate, Ludox, Alumina gel
One or more.
As further scheme of the invention:The nanoparticle is in nano titanium oxide, nano silicon
Plant or two kinds.
As further scheme of the invention:The reflecting material is antimony-doped tin oxide, indium doping stannum oxide, aluminum doping
One or more in Zinc Oxide, Ga-doped zinc oxide or potassium titanate.
As further scheme of the invention:The inorganic non-metallic compound is boron carbide, carborundum, boron nitride, nitrogen
Change one or more in aluminum.
As further scheme of the invention:Described filler is hollow ceramic microspheres, Ultrafine Mica, zeolite powder, hollow
One or more in glass microsphere, expanded perlite.
A kind of preparation method of described aqueouss reflective heat-insulation paint, comprises the following steps:
(1) distilled water and dispersant are added in container, 5~l0min is disperseed under 600~800r/min rotating speeds;
(2) rotating speed is improved to 800~1000r/min, and water bath with thermostatic control is heated to 40~50 DEG C, sequentially adds nanoparticle
Son, inorganic non-metallic compound, reflection pigment, 20~30min of dispersed with stirring under 800~1000r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1500~2000r/min, is subsequently adding emulsion, and stirring 25~
35min, then sequentially adds acrylamide, perchloric acid, Polyethylene Glycol, stirs 10~16min;
(4) by rotational speed regulation to 1000~1200r/min, filler, ethylene glycol are continuously added, stirs 20~30min;
(5) toughener and binding agent are sequentially added, 30~40min is stirred under 600~800r/min rotating speeds, obtained final product.
Compared with prior art, the invention has the beneficial effects as follows:
Coating of the present invention is acted on by the collocation of elastic emulsion and auxiliary agent, is prepared with anti-pollution, high temperature resistant and anti-
The coating of performance such as penetrate, but also all have with good adhesive force and scrub performance, tensile strength and elongation at break
There are good effect, and good decorating effect, be less prone to scar, construction cost and maintenance cost are low, it is former using friendly
Material is prepared from, nonpoisonous and tasteless, environment protection health.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
Aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:40 parts of pure-acrylic emulsion, nano titanium oxide
3 parts, 2 parts of perchloric acid, 2 parts of Polyethylene Glycol, 6 parts of acrylamide, 5 parts of boron carbide, 4 parts of antimony-doped tin oxide, hollow ceramic microspheres
12 parts, 8 parts of hydrophobic modified carboxylic acid sodium salt, 6 parts of Zirconium oxide fibre, 6 parts of waterglass, 16 parts of ethylene glycol, 30 parts of distilled water.
The preparation process of above-mentioned aqueouss reflective heat-insulation paint is as follows:
(1) distilled water and dispersant are added in container, under 600r/min rotating speeds l0min is disperseed;
(2) rotating speed is improved to 800r/min, and water bath with thermostatic control is heated to 40 DEG C, sequentially adds nanoparticle, inorganic non-
Metallic compound, reflection pigment, dispersed with stirring 30min under 800r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1500r/min, is subsequently adding emulsion, stirs 35min, then successively
Acrylamide, perchloric acid, Polyethylene Glycol are added, 16min is stirred;
(4) by rotational speed regulation to 1000r/min, filler, ethylene glycol are continuously added, stirs 30min;
(5) toughener and binding agent are sequentially added, under 600r/min rotating speeds 40min is stirred, obtained final product.
Embodiment 2
Aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:42 parts of acrylic emulsion, nanometer titanium dioxide
3.5 parts of titanium, 2.5 parts of perchloric acid, 2.5 parts of Polyethylene Glycol, 6.5 parts of acrylamide, 5.5 parts of carborundum, indium doping stannum oxide 4.5
Part, 13 parts of Ultrafine Mica, 8.5 parts of hydrophobic modified carboxylic acid sodium salt, 6.5 parts of alumina fibre, 6.5 parts of aluminium dihydrogen phosphate, second two
17 parts of alcohol, 33 parts of distilled water.
The preparation process of above-mentioned aqueouss reflective heat-insulation paint is as follows:
(1) distilled water and dispersant are added in container, under 650r/min rotating speeds 8min is disperseed;
(2) rotating speed is improved to 850r/min, and water bath with thermostatic control is heated to 42 DEG C, sequentially adds nanoparticle, inorganic non-
Metallic compound, reflection pigment, dispersed with stirring 28min under 850r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1600r/min, is subsequently adding emulsion, stirs 32min, then successively
Acrylamide, perchloric acid, Polyethylene Glycol are added, 15min is stirred;
(4) by rotational speed regulation to 1050r/min, filler, ethylene glycol are continuously added, stirs 28min;
(5) toughener and binding agent are sequentially added, under 650r/min rotating speeds 38min is stirred, obtained final product.
Embodiment 3
Aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:45 parts of acrylate and vinyl acetate emulsion, nano silicon
4 parts, 3 parts of perchloric acid, 3 parts of Polyethylene Glycol, 7 parts of acrylamide, 6 parts of boron nitride, 5 parts of aluminium-doped zinc oxide, 14 parts of zeolite powder gathers
9 parts of acrylic acid sodium salt, 7 parts of carbon fiber, 7 parts of Ludox, 18 parts of ethylene glycol, 35 parts of distilled water.
The preparation process of above-mentioned aqueouss reflective heat-insulation paint is as follows:
(1) distilled water and dispersant are added in container, under 700r/min rotating speeds 8min is disperseed;
(2) rotating speed is improved to 800r/min, and water bath with thermostatic control is heated to 45 DEG C, sequentially adds nanoparticle, inorganic non-
Metallic compound, reflection pigment, dispersed with stirring 25min under 900r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1750r/min, is subsequently adding emulsion, stirs 30min, then successively
Acrylamide, perchloric acid, Polyethylene Glycol are added, 13min is stirred;
(4) by rotational speed regulation to 1100r/min, filler, ethylene glycol are continuously added, stirs 25min;
(5) toughener and binding agent are sequentially added, under 700r/min rotating speeds 35min is stirred, obtained final product.
Embodiment 4
Aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:48 parts of methacrylic acid emulsion, nanoparticle
4.5 parts of sub- nano silicon, 3.5 parts of perchloric acid, 3.5 parts of Polyethylene Glycol, 7.5 parts of acrylamide, inorganic non-metallic compound
6.5 parts of aluminium nitride, 5.5 parts of reflecting material Ga-doped zinc oxide, 15 parts of filler hollow glass micro-ball, dispersant polyacrylic acid sodium salt
9.5 parts, 7.5 parts of toughener alumina silicate fibre, 7.5 parts of binding agent Alumina gel, 19 parts of ethylene glycol, 37 parts of distilled water.
The preparation process of above-mentioned aqueouss reflective heat-insulation paint is as follows:
(1) distilled water and dispersant are added in container, under 750r/min rotating speeds 6min is disperseed;
(2) rotating speed is improved to 950r/min, and water bath with thermostatic control is heated to 47 DEG C, sequentially adds nanoparticle, inorganic non-
Metallic compound, reflection pigment, dispersed with stirring 23min under 950r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1900r/min, is subsequently adding emulsion, stirs 28min, then successively
Acrylamide, perchloric acid, Polyethylene Glycol are added, 12min is stirred;
(4) by rotational speed regulation to 1150r/min, filler, ethylene glycol are continuously added, stirs 22min;
(5) toughener and binding agent are sequentially added, under 750r/min rotating speeds 33min is stirred, obtained final product.
Embodiment 5
Aqueouss reflective heat-insulation paint, is prepared from by the raw material of following weight portion:50 parts of water-based fluorocarbon resin emulsion, nanometer
5 parts of particle nano titanium oxide, 4 parts of perchloric acid, 4 parts of Polyethylene Glycol, 8 parts of acrylamide, inorganic non-metallic compound aluminium nitride 7
Part, 6 parts of reflecting material potassium titanate, 16 parts of filler expanded perlite, 10 parts of dispersant ammonium salt, 8 parts of toughener alumina silicate fibre glues
8 parts of knot agent aluminium dihydrogen phosphate, 20 parts of ethylene glycol, 40 parts of distilled water.
The preparation process of above-mentioned aqueouss reflective heat-insulation paint is as follows:
(1) distilled water and dispersant are added in container, under 800r/min rotating speeds 5min is disperseed;
(2) rotating speed is improved to 1000r/min, and water bath with thermostatic control is heated to 50 DEG C, sequentially adds nanoparticle, inorganic non-
Metallic compound, reflection pigment, dispersed with stirring 20min under 1000r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 2000r/min, is subsequently adding emulsion, stirs 25min, then successively
Acrylamide, perchloric acid, Polyethylene Glycol are added, 10min is stirred;
(4) by rotational speed regulation to 1200r/min, filler, ethylene glycol are continuously added, stirs 20min;
(5) toughener and binding agent are sequentially added, under 600r/min rotating speeds 30min is stirred, obtained final product.
Measured property indices and technology in each embodiment of aqueouss reflective heat-insulation paint prepared by the present invention
Index such as following table.
Tensile strength, the elongation at tear tests data of the coating of the present invention of table 1
As apparent from Table 1, the tensile strength and elongation at break of each embodiment of coating of the present invention exceedes existing
Technical specification, even if covering trickle ability also remaining intact compared with paint film under low temperature environment.
The stain resistance test data of the coating that the institute's coating of the present invention of table 2 is formed
As apparent from Table 2, the contaminated resistance of each embodiment of coating of the present invention exceedes the technical standard of country
Require, stain resistant is both less than 15%, make film keep persistently cleaning, the reflective insulation performance for being more beneficial for film to keep for a long time.
The aqueous coating test data of the coating of the present invention of table 3
As apparent from Table 3, the heat insulating reflecting performance of each embodiment of coating of the present invention is fully achieved aqueous coating institute
The technical specification of requirement.
The construction test data of the coating of the present invention of table 4
As known from Table 4, the combination property of coating of the invention meets the technical standard of technical field, and using effect is good.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Claims (10)
1. a kind of aqueouss reflective heat-insulation paint, it is characterised in that be prepared from by the raw material of following weight portion:Emulsion 40~50
Part, 3~5 parts of nanoparticle, 2~4 parts of perchloric acid, 2~4 parts of Polyethylene Glycol, 6~8 parts of acrylamide, inorganic non-metallic compound
5~7 parts, 4~6 parts of reflecting material, 12~16 parts of filler, 8~10 parts of dispersant, 6~8 parts of toughener, 6~8 parts of binding agent, second
16~20 parts of glycol, 30~40 parts of distilled water.
2. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the emulsion is pure-acrylic emulsion, propylene
One kind in yogurt liquid, pure acrylate emulsion, acrylate and vinyl acetate emulsion, methacrylic acid emulsion, water-based fluorocarbon resin emulsion.
3. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the dispersant is hydrophobic modified carboxylic
One or more in acid sodium-salt, polyacrylic acid sodium salt or ammonium salt.
4. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the toughener be Zirconium oxide fibre,
One or more in alumina fibre, carbon fiber, alumina silicate fibre.
5. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the binding agent is waterglass, phosphoric acid
One or more in aluminum dihydrogen, Ludox, Alumina gel.
6. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the nanoparticle is nanometer titanium dioxide
One or two in titanium, nano silicon.
7. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the reflecting material is Sb doped oxidation
One or more in stannum, indium doping stannum oxide, aluminium-doped zinc oxide, Ga-doped zinc oxide or potassium titanate.
8. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that the inorganic non-metallic compound is carbon
Change one or more in boron, carborundum, boron nitride, aluminium nitride.
9. aqueouss reflective heat-insulation paint according to claim 1, it is characterised in that described filler be hollow ceramic microspheres,
One or more in Ultrafine Mica, zeolite powder, hollow glass micro-ball, expanded perlite.
10. a kind of preparation method of the aqueouss reflective heat-insulation paint as described in claim 1~9 is arbitrary, it is characterised in that include
Following steps:
(1) distilled water and dispersant are added in container, 5~l0min is disperseed under 600~800r/min rotating speeds;
(2) rotating speed is improved to 800~1000r/min, and water bath with thermostatic control is heated to 40~50 DEG C, sequentially add nanoparticle,
Inorganic non-metallic compound, reflection pigment, 20~30min of dispersed with stirring under 800~1000r/min rotating speeds;
(3) temperature is down to room temperature, and rotating speed is improved to 1500~2000r/min, is subsequently adding emulsion, stirs 25~35min, so
After sequentially add acrylamide, perchloric acid, Polyethylene Glycol, stir 10~16min;
(4) by rotational speed regulation to 1000~1200r/min, filler, ethylene glycol are continuously added, stirs 20~30min;
(5) toughener and binding agent are sequentially added, 30~40min is stirred under 600~800r/min rotating speeds, obtained final product.
Priority Applications (1)
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CN201611234659.9A CN106675137A (en) | 2016-12-28 | 2016-12-28 | Water-based reflective thermal insulation coating |
Applications Claiming Priority (1)
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CN201611234659.9A CN106675137A (en) | 2016-12-28 | 2016-12-28 | Water-based reflective thermal insulation coating |
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CN106675137A true CN106675137A (en) | 2017-05-17 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325651A (en) * | 2017-07-15 | 2017-11-07 | 合肥皖水信息科技有限公司 | A kind of fire-proof glass curtain wall |
CN107641396A (en) * | 2017-09-22 | 2018-01-30 | 南京兰庭绿色建筑技术有限公司 | A kind of sunshading and heat-insulating coating and preparation method thereof |
-
2016
- 2016-12-28 CN CN201611234659.9A patent/CN106675137A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325651A (en) * | 2017-07-15 | 2017-11-07 | 合肥皖水信息科技有限公司 | A kind of fire-proof glass curtain wall |
CN107641396A (en) * | 2017-09-22 | 2018-01-30 | 南京兰庭绿色建筑技术有限公司 | A kind of sunshading and heat-insulating coating and preparation method thereof |
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Application publication date: 20170517 |