CN106673833A - Drop irrigation fertilizer special for potatoes and production method of drop irrigation fertilizer - Google Patents
Drop irrigation fertilizer special for potatoes and production method of drop irrigation fertilizer Download PDFInfo
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- CN106673833A CN106673833A CN201611237962.4A CN201611237962A CN106673833A CN 106673833 A CN106673833 A CN 106673833A CN 201611237962 A CN201611237962 A CN 201611237962A CN 106673833 A CN106673833 A CN 106673833A
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- drip irrigation
- irrigation fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/10—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using orthophosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to the technical field of chemical engineering, and in particular to drop irrigation fertilizer special for potatoes and a production method. The drop irrigation fertilizer is prepared by taking a phosphoric acid, potassium sulfate, carbomite, trace elements, medium elements, sodium thiosulfate and an emulsifier as raw materials and through the steps of mixing, crystallizing and drying. Water-soluble fertilizer grains are small and uniform, the nutrition is comprehensive, the water solubility is high, and the fertilizer effect is remarkable.
Description
Technical field
The present invention relates to chemical technology field, the especially a kind of special drip irrigation fertilizer of potato and production method.
Background technology
Potato is Solanaceae Solanum herbaceous plant, and its stem tuber can be edible, is important grain, vegetables dual-purpose crop.Horse
Bell potato is the most important cereal crops as mankind's staple food at present in the world in addition to cereal.Its adaptability to soil
It is very strong, planted extensively in the whole world.Current nearly 5,000,000 hectares of potato of China's plantation, but per unit area yield is very low, average product per hectare
Less than 3000 kilograms, this is not only relevant with potato cultivar and soil fertility, also and during current potato planting
Fertilization Level it is relevant.
At present, the method for traditional cultivation potato is after being mixed using common fertilizer or common fertilizer
Potato special fertilizer is obtained, the method that this kind prepares potato fertilizer is difficult to meet potato to the nutrition such as N P and K calcium and magnesium unit
The demand of element;Such as Patent No. CN201510621724.2《A kind of potato release and release control fertilizer and preparation method thereof》Disclose one kind
With malicious trifoliate jewelvine 20-150 parts, bark of official magnolia 20-150 parts, aloe 15-100 parts, burmann cinnamon leaf 15-100 parts, Roots of Euphorbia soongarica 15-100 parts,
Leaf of Pterocarya Stenoptera 15-100 parts, capsicum 15-100 parts, print 15-100 parts of chinaberry, tobacco leftovers 15-100 parts, 15-100 parts of garlic bar,
Fulvic acid 10-40 parts, waste residue 10-18 parts, 8-12 parts of Pomacea canaliculata powder, biological bacteria 4-8 parts, 2-6 parts of trace element, water-loss reducer 2-
6 parts, conditioner 2-6 parts, dispersant 2-4 parts, 45-120 parts of fat, sylvite 2-3 parts, microcosmic salt 1-3 parts, nitrogen salt 1-2 parts, boron salt
0.2-0.4 parts, molysite 0.2-0.4 parts, zinc salt 0.2-0.4 parts, manganese salt 0.2-0.4 parts, the raw material such as mantoquita 0.2-0.4 parts be made,
It can be seen that, the technical scheme raw material is excessively complicated, and causes high cost, and the fertilizer impurity for obtaining is excessive.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of special drip irrigation fertilizer of potato, raw material is calculated as with weight point:Phosphorus
It is 20~45 parts of acid, 30~45 parts of potassium sulfate, 20~45 parts of phosphoamide, 1~5 part of trace element, 6~15 parts of moderate-element, thio
3~7 parts of sodium sulphate, 1~4 part of emulsifying agent.
Another object of the present invention provides the drip irrigation fertilizer production method, comprises the following steps:
(1) mix:It is (0.9-1.3) according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is
70~100 DEG C, control the mixing speed of stirred tank to stir 1~3h of hybrid reaction for 200~220r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are (0.8~1.2):(0.5
~0.7):When (1.3~1.5), stopping is crystallized and filtered, and the pore size of filter is 0.6~1.0mm, is adjusted with nitric acid
PH to 6.5~7.0, Water soluble fertilizer is turned into middle and trace element, emulsifying agent and reaction promoter adjustment fertilizer structure is added in filtrate
First finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, after drying 2~3h, adjustment moisture is 1-3%, you can the drip irrigation fertilizer for improving soil is obtained.
Wherein described trace element is the combination in molybdenum trisulfate, divalence iron chelate, boric acid, zinc sulfate, manganese sulfate.
Wherein described trace element is in parts by weight:0.2~1.1 part of molybdenum trisulfate, divalence iron chelate 0.6~1.2
Part, 0.3~0.9 part of boric acid, 0.6~1.0 part of zinc sulfate, the combination of 0.3~0.8 part of manganese sulfate.
Wherein described moderate-element is calcium sulfate, the combination of magnesium sulfate.
Wherein described moderate-element is in parts by weight 4~8 parts of calcium sulfate, the combination of 2~7 parts of magnesium sulfate.
Wherein described emulsifying agent is hydrophily sucrose ester, and its preparation method is comprised the following steps:
(1) in aliphatic acid, ethanol and the concentrated sulfuric acid being put into reaction kettle of the esterification respectively, and aliphatic acid, ethanol are in mass ratio
1:3 is that reaction temperature is 100~110 DEG C, the excessive ethanol of Distillation recovery, and washs pH to 6.5~7.0, that is, obtain intermediate
Fatty-acid ethyl ester;
(2) in propane diols, fatty-acid ethyl ester, sucrose and potassium hydroxide being put into transesterification reactor respectively, and the third two
Alcohol, fatty-acid ethyl ester, the mass ratio of sucrose are 1:3:3, reaction temperature is 80~90 DEG C, and the reaction time is 6~7h, and reaction terminates
After add citric acid, propane diols is recovered under reduced pressure, washed, add potassium perborate treatment, finally carry out being spray dried to powder,
.
Undissolved particle is dispersed in suspension within water during wherein described hydrophily sucrose ester can make solution, and can be promoted
Immiscible two kinds and above liquid form the emulsified state of stabilization, do not produce flocculation or coalesce, and sealing preserve is for a long time
Also be not in lamination, solve big droplet coalescence change, sedimentation bleed occur in current ambient temperature storage process, separate out crystal,
Even there is demulsifying phenomenon, so as to influence the performance of fertilizer efficiency.
The present invention is using phosphoric acid, potassium sulfate, phosphoamide, sodium thiosulfate, trace element, moderate-element, hydrophily sucrose
Ester is raw material, by rational proportioning, meets potato in growth course, to the demand of N P and K, so as to improve yield;Parent
The composition that aqueous sucrose ester enables each group in raw material immiscible effectively flocks together, and forms emulsified state, is dripped with tradition
Filling mode is compared, will not be because of drip irrigation during, in pipeline formed flocculation or coalesce, so as to cause the blocking of shower nozzle, meanwhile,
The addition of sodium thiosulfate causes that heavy metal in soil ion forms precipitation, coagulation heavy metal in soil with thiosulfate ion
Ion so that the growing environment of potato is effectively guaranteed.
Specific embodiment
Technical scheme is further limited with reference to specific embodiment, but claimed
Scope is not only limited to description.
Embodiment 1
Formula:Phosphoric acid 20kg, potassium sulfate 30kg, phosphoamide 20kg, trace element 1kg, moderate-element 6kg, thiosulfuric acid
Sodium 3kg, emulsifying agent 1kg;
Preparation method:
(1) mix:It is 0.9 according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is 70~100
DEG C, control the mixing speed of stirred tank to stir hybrid reaction 1h for 200r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are 1.0:0.5:When 1.3, stop
Only crystallize and filter, the pore size of filter is 0.6~1.0mm, with nitre acid for adjusting pH to 6.5, in being added in filtrate,
Trace element compound and reaction promoter adjustment fertilizer structure turn into Water soluble fertilizer just finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, after drying 2h, adjustment moisture is 3%, you can the drip irrigation fertilizer for improving soil is obtained.
Embodiment 2
Formula:Phosphatase 24 5kg, potassium sulfate 45kg, phosphoamide 45kg, trace element 5kg, moderate-element 15kg, thiosulfuric acid
Sodium 7kg, emulsifying agent 4kg;
Preparation method:
(1) mix:It is 1.2 according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is 70~100
DEG C, control the mixing speed of stirred tank to stir hybrid reaction 2h for 210r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are 0.9:0.5:When 1.2, stop
Only crystallize and filter, the pore size of filter is 0.6~1.0mm, with nitre acid for adjusting pH to 6.7, in being added in filtrate,
Trace element compound and potassium thiosulfate adjustment fertilizer structure turn into Water soluble fertilizer just finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, after drying 2h, adjustment moisture is 2%, you can the drip irrigation fertilizer for improving soil is obtained.
Embodiment 3
Formula:Phosphoric acid 30kg, potassium sulfate 40kg, phosphoamide 35kg, trace element 3kg, moderate-element 8kg, thiosulfuric acid
Sodium 5kg, emulsifying agent 3kg;
Preparation method:
(1) mix:It is 1.1 according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is 70~100
DEG C, control the mixing speed of stirred tank to stir hybrid reaction 3h for 220r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are 1.1:0.6:When 1.4, stop
Only crystallize and filter, the pore size of filter is 0.6~1.0mm, with nitre acid for adjusting pH to 6.8, in being added in filtrate,
Trace element compound and sodium thiosulfate adjustment fertilizer structure turn into Water soluble fertilizer just finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, after drying 3h, adjustment moisture is 1%, you can the drip irrigation fertilizer for improving soil is obtained.
Embodiment 4
Formula:Phosphoric acid 35kg, potassium sulfate 35kg, phosphoamide 40kg, trace element 2kg, moderate-element 9kg, thiosulfuric acid
Sodium 6kg, emulsifying agent 2kg;
Preparation method:
(1) mix:It is 1.0 according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is 70~100
DEG C, control the mixing speed of stirred tank to stir hybrid reaction 1h for 210r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are 1.1:0.7:1.5 when, stop
Only crystallize and filter, the pore size of filter is 0.6~1.0mm, with nitre acid for adjusting pH to 6.6, in being added in filtrate,
Trace element compound and magnesium thiosulfate adjustment fertilizer structure turn into Water soluble fertilizer just finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, 2h is dried, adjustment moisture is 2%, you can the drip irrigation fertilizer for improving soil is obtained.
Embodiment 5
Formula:Phosphatase 24 0kg, potassium sulfate 37kg, phosphoamide 25kg, trace element 4kg, moderate-element 12kg, thiosulfuric acid
Sodium 4kg, emulsifying agent 2.5kg;
Preparation method:
(1) mix:It is 1.3 according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, and temperature is 70~100
DEG C, control the mixing speed of stirred tank to stir hybrid reaction 3h for 220r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirring simultaneously
In kettle, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detect
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are 1.2:0.7:When 1.5, stop
Only crystallize and filter, the pore size of filter is 0.6~1.0mm, with nitre acid for adjusting pH to 6.9, in being added in filtrate,
Trace element compound and calcium thiosulfate adjustment fertilizer structure turn into Water soluble fertilizer just finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and it is 5 DEG C/min to use programming rate
45-50 DEG C is warming up to, after drying 2h, adjustment moisture is 2%, you can the drip irrigation fertilizer for improving soil is obtained.
Test example 1
Experimental group:Using the special drip irrigation fertilizer of potato of the invention;
Control group 1:The potato Controlled Release Fertilizer made using Patent No. CN201510621724.2;
Control group 2:Using 45% potato special fertilizer rich again of commercial type;
Control group 3:Using biogen potato special fertilizer;
Every group of random 30 plants of potato, after planting 40~60 days, measures its aerial part, low part potassium content, tests
Cell mean is above other 3 groups, shows to be conducive to the absorption of plant pair potassium using the fertilizer, promotes the growth hair of potato
Educate, while it is undesirable also to reflect the enrichment of potassium in inorganic fertilizer in plant, into the collecting period after decline it is serious.
Test example 2
Experimental group:Using the special drip irrigation fertilizer of potato of the invention;
Control group 1:The potato Controlled Release Fertilizer made using Patent No. CN201510621724.2;
Control group 2:Using 45% potato special fertilizer rich again of commercial type;
Control group 3:Using biogen potato special fertilizer;
Every group of random 50 plants of potato, potato planting is after 20~100 days, seedling stage control group 1, control group 2, control group 3
Potato complete stool boron element cumulative change trend is had no significant effect, using drip irrigation fertilizer of the present invention, to each growth period of potato
The accumulation of boron has significant impact, and is above other control groups, and full period is average 2.96mg/ plants.
Claims (8)
1. the special drip irrigation fertilizer of a kind of potato, it is characterised in that raw material is in parts by weight:20~45 parts of phosphoric acid, potassium sulfate 30
~45 parts, 20~45 parts of phosphoamide, trace element 1~5 part, 6~15 parts of moderate-element, 3~7 parts of sodium thiosulfate, emulsifying agent 1
~4 parts.
2. the special drip irrigation fertilizer of potato as claimed in claim 1, it is characterised in that described trace element is molybdenum trisulfate, divalence
Iron chelate, boric acid, zinc sulfate, the combination of manganese sulfate.
3. the special drip irrigation fertilizer of potato as claimed in claim 1, it is characterised in that described trace element is in parts by weight:
0.2~1.1 part of molybdenum trisulfate, 0.6~1.2 part of divalence iron chelate, 0.3~0.9 part of boric acid, 0.6~1.0 part of zinc sulfate, sulfuric acid
The combination that 0.3~0.8 part of manganese.
4. the special drip irrigation fertilizer of potato as claimed in claim 1, it is characterised in that the moderate-element is calcium sulfate, magnesium sulfate
Combination.
5. the special drip irrigation fertilizer of potato as claimed in claim 4, it is characterised in that the moderate-element is in parts by weight sulfuric acid
The combination of 4~8 parts of calcium, 2~7 parts of magnesium sulfate.
6. the special drip irrigation fertilizer of potato as claimed in claim 1, it is characterised in that the drip irrigation fertilizer production method includes following step
Suddenly:
(1) mix:It is (0.9-1.3) according to mol ratio by phosphoric acid and phosphoamide:1 in stirring-type reaction kettle, temperature be 70~
100 DEG C, control the mixing speed of stirred tank to stir 1~3h of hybrid reaction for 200~220r/min, obtain slurry;
(2) crystallize:Potassium sulfate, sodium thiosulfate, trace element, moderate-element, emulsifying agent are added to (1) stirred tank simultaneously
In, temperature is maintained at 60~80 DEG C, after stirring 1h, is placed in and is cooled to temperature≤17 DEG C in cooler crystallizer in 13s, and detection point
Nutrient content in analysis filtrate, treats that nitrogen component, phosphorus pentoxide composition, the mass ratio of potassium composition are (0.8~1.2):(0.5~
0.7):When (1.3~1.5), stopping is crystallized and filtered, and the pore size of filter is 0.6~1.0mm, uses nitre acid for adjusting pH
To 6.5~7.0, at the beginning of adding middle and trace element, emulsifying agent and reaction promoter adjustment fertilizer structure to turn into Water soluble fertilizer in filtrate
Finished product;
(3) dry:Just finished product is placed in drier the Water soluble fertilizer that step (3) is obtained, and uses programming rate to be heated up for 5 DEG C/min
To 45-50 DEG C, after drying 2~3h, adjustment moisture is 1-3%, you can be obtained for the special drip irrigation fertilizer of potato.
7. the special drip irrigation fertilizer of potato as claimed in claim 1, it is characterised in that described emulsifying agent is hydrophily sucrose ester.
8. the special drip irrigation fertilizer of potato as claimed in claim 7, it is characterised in that described hydrophily sucrose ester, its preparation side
Method is comprised the following steps:
(1) in aliphatic acid, ethanol and the concentrated sulfuric acid being put into reaction kettle of the esterification respectively, and aliphatic acid, ethanol in mass ratio 1:3 are
Reaction temperature is 100~110 DEG C, the excessive ethanol of Distillation recovery, and washs pH to 6.5~7.0, that is, obtain intermediate fatty acid
Ethyl ester;
(2) in propane diols, fatty-acid ethyl ester, sucrose and potassium hydroxide being put into transesterification reactor respectively, and propane diols, fat
Fat acetoacetic ester, the mass ratio of sucrose are 1:3:3, reaction temperature is 80~90 DEG C, and the reaction time is 6~7h, and reaction adds after terminating
Enter citric acid, propane diols be recovered under reduced pressure, washed, add potassium borate treatment, finally carry out being spray dried to powder, you can.
Priority Applications (1)
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CN201611237962.4A CN106673833A (en) | 2016-12-28 | 2016-12-28 | Drop irrigation fertilizer special for potatoes and production method of drop irrigation fertilizer |
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CN201611237962.4A CN106673833A (en) | 2016-12-28 | 2016-12-28 | Drop irrigation fertilizer special for potatoes and production method of drop irrigation fertilizer |
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CN201611237962.4A Pending CN106673833A (en) | 2016-12-28 | 2016-12-28 | Drop irrigation fertilizer special for potatoes and production method of drop irrigation fertilizer |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107602262A (en) * | 2017-11-03 | 2018-01-19 | 南昌工程学院 | A kind of southern potato drip irrigation release and release control fertilizer and preparation method thereof |
CN107793249A (en) * | 2017-12-11 | 2018-03-13 | 南昌工程学院 | Special drip irrigation fertilizer of a kind of potato containing nitrification inhibitor and preparation method thereof |
CN113416108A (en) * | 2021-08-02 | 2021-09-21 | 大理洱海生物肥业有限公司 | Preparation method of liquid organic fertilizer for potatoes |
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CN101134689A (en) * | 2006-08-29 | 2008-03-05 | 石称华 | Complete-element high-concentration water-soluble long-acting compound fertilizer and method for manufacturing same |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107602262A (en) * | 2017-11-03 | 2018-01-19 | 南昌工程学院 | A kind of southern potato drip irrigation release and release control fertilizer and preparation method thereof |
CN107602262B (en) * | 2017-11-03 | 2021-01-05 | 南昌工程学院 | Controlled-release fertilizer for southern potato drip irrigation and preparation method thereof |
CN107793249A (en) * | 2017-12-11 | 2018-03-13 | 南昌工程学院 | Special drip irrigation fertilizer of a kind of potato containing nitrification inhibitor and preparation method thereof |
CN113416108A (en) * | 2021-08-02 | 2021-09-21 | 大理洱海生物肥业有限公司 | Preparation method of liquid organic fertilizer for potatoes |
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