CN106673362A - Combined treatment process of landfill leachate - Google Patents

Combined treatment process of landfill leachate Download PDF

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Publication number
CN106673362A
CN106673362A CN201611260081.4A CN201611260081A CN106673362A CN 106673362 A CN106673362 A CN 106673362A CN 201611260081 A CN201611260081 A CN 201611260081A CN 106673362 A CN106673362 A CN 106673362A
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China
Prior art keywords
treatment
advanced oxidation
percolate
biochemical treatment
biochemical
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Pending
Application number
CN201611260081.4A
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Chinese (zh)
Inventor
胡兆吉
胡义亮
陈建新
孙洋
欧阳二明
王白杨
冯斐
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Nanchang University
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Nanchang University
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Priority to CN201611260081.4A priority Critical patent/CN106673362A/en
Publication of CN106673362A publication Critical patent/CN106673362A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1257Oxidation ditches
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/284Anaerobic digestion processes using anaerobic baffled reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2846Anaerobic digestion processes using upflow anaerobic sludge blanket [UASB] reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

Abstract

The invention provides a combined treatment process of landfill leachate. A traditional combined process of primary treatment which takes physicochemical treatment as a main part and secondary treatment which takes biochemical treatment as a main part is adopted; at a treatment phase, a traditional treatment process which is developed and widely applied and has relatively good economical efficiency can be adopted to carry out first phase of treatment on the landfill leachate, so that most of pollutants which can be removed through a traditional treatment method in the landfill leachate are removed; secondary output water is discharged and enters a high-grade oxidization treatment phase; main components, namely non-degradable macromolecular organic matters, of pollutants in the secondary output water, are effectively degraded through a strong oxidization capability of a high-grade oxidization process; at the phase, the non-degradable macromolecular organic matters are effectively degraded and the biodegradability of water quality is greatly improved; the output water, which is subjected to high-grade oxidization treatment enters a biochemical treatment phase with excellent economical efficiency and then is subjected to biochemical treatment, so that the water quality of the output water reaches emission standards of GB16889-2008 Standard for Pollution Control on the Landfill Site of National Municipal Solid Waste.

Description

A kind of combined treatment process of percolate
Technical field
The present invention relates to a kind of " twinization " of percolate+" advanced oxidation " combined treatment process, more particularly to one Plant with biochemical treatment+combined processing technique of garbage percolates of the advanced oxidation process+biochemical treatment as core, belong to sewage disposal Technology and technology field.
Background technology
With the increase of China's urban population, the expansion of city size and numerous people growth in the living standard, China Domestic waste yield is annual all in increase drastically.At present the processing method of domestic waste mainly has burning disposal, During High-Temperature Composting and sanitary landfills, wherein sanitary landfills are because its technology is simply and with excellent economic advantages so that it is obtained It is widely applied.But this processing method can produce substantial amounts of percolate.At present China is main to percolate Use the two stage treatment group technology based on the one-level and biochemistry based on materialization.But due to containing in percolate Substantial amounts of difficult degradation larger molecular organicses so that the water quality after the handling process that this tradition is used widely is processed cannot expire Sufficient GB16889-2008《National household refuse landfill sites Environmental capacity standard》In emission request.
For this case, China's city domestic refuse percolation liquid processes engineering field and occurs in that with " bi-membrane method ", i.e. film Bioreactor(MBR)+ receive worry reverse osmosiss(NF/RO)For a large amount of case histories of main process route.The technique has fine Treatment effect, but there is initial stage one-time investment high cost in it, operating cost is high.Especially receive worry reverse osmosiss(NF/ RO)Belong to typical membrane filtration, be essentially " transfer " process of pollutant, fundamentally do not get rid of pollutant, exist Concentration liquid measure is big and the outstanding problem such as is difficult to dispose.For this outstanding problem, on the basis of traditional biological treatment, By high-level oxidation technology process " twinization "+" advanced oxidation " combined treatment process for forming percolate in combination, lead to The reasonable combination of handling process is crossed, the removal to Landfill Leachate Pollutants has both been solved the problems, such as, good economy is obtained in that again And operability.
High-level oxidation technology mainly produces the hydroxyl with Strong oxdiative ability by oxidant under certain reaction condition Base free radical(•OH), react with the macromole hardly degraded organic substance in waste water, the molecular structure of Organic substance is destroyed, by it Small-molecule substance is degraded into, or even is thoroughly degraded to carbon dioxide and water, realize effective " conversion " of pollutant.Therefore, pass through Percolate secondary effluent its biodegradability after high-level oxidation technology process can be obviously improved, so that whole Individual " twinization "+advanced oxidation processes can smoothly be implemented.
The content of the invention
The purpose of the present invention be for prior art it is not enough provide it is a kind of with biochemical treatment+advanced oxidation process+biochemistry at Manage the combined processing technique of garbage percolates for core.
A kind of " twinization " of percolate+" advanced oxidation " combined treatment process its processing procedure includes:Thing Change pretreatment, a biochemical treatment, advanced oxidation process, secondary biochemical treatment, processing step is as follows:
The adjusted pond Jing water pumps of percolate once by the first sedimentation tank in materialized pretreatment stage and Ammonia blowing-out tower, it is laggard Enter biochemical treatment apparatus i.e. membrane bioreactor, percolate its biodegradability after above-mentioned process significantly drops Low, major pollutants are macromole hardly degraded organic substance in water, then are UV+ by bio-chemical effluent importing advanced oxidation processing meanss Fenton advanced oxidation processing meanss, Jing after advanced oxidation process, biodegradability of increasing water quality finally adopts again membrane bioreaction Device is answered, i.e., secondary biochemical processing causes water outlet finally to meet discharge standard.
The materialized pretreatment is based on the pretreating process of the physico-chemical processes such as coagulating sedimentation, stripping;
Biochemical treatment is with UASB(Up-flow anaerobic sludge blanket)、ABR(Anaerobic baffled reactor)Technique etc. is detested Oxygen technique and the biochemical processing process based on aerobic process such as catalytic oxidation, oxidation ditch, A/O techniques;
The Advanced Oxidation Technics in Dealing is with UV+Fenton, O3High-level oxidation technology is science and engineering at the advanced oxidation of its main body Skill;
The secondary biochemical treatment is with membrane bioreactor(MBR), BAF(BAF)Technique etc. is the follow-up of main body Biochemical processing process;
A kind of " twinization " of percolate+" advanced oxidation " combined treatment process, its materialized pretreatment and secondary Flexibly specific handling process can be arranged according to concrete water quality situation processing stage change, at two grades excellent to pass through economy Reason group technology removes the pollutant that the overwhelming majority can be removed by the technology in percolate;
A kind of " twinization " of percolate+" advanced oxidation " combined treatment process, its advanced oxidation is processed and secondary Can be processed and secondary biochemical treatment by adjusting advanced oxidation according to the concrete condition of secondary effluent water quality between biochemical treatment Between conspiracy relation so that ensure treatment effect while, with higher overall economic efficiency.
The invention has the beneficial effects as follows:By such scheme, can continue to secondary using traditional materialized pretreatment and one Changing treatment technology carries out the process of early stage to percolate, is widely used using this and technique that economic benefit is good is removed The pollutant of the overwhelming majority in percolate, then can give birth to for the percolate effluent quality after this traditional handicraft process The characteristics of property changed extreme difference, the process of next step is carried out using high-level oxidation technology, using high-level oxidation technology in secondary effluent Contained a large amount of difficult degradation larger molecular organicses carry out effective oxidative degradation, and greatly improve the biodegradability of water quality, it Biochemical processing is recycled to carry out secondary biochemical treatment to the water outlet after advanced oxidation process afterwards, so that final water outlet Water quality can reach GB16889-2008《National household refuse landfill sites Environmental capacity standard》In emission request.Said process In, concrete water quality situation can be directed to, advanced oxidation and secondary this two parts handling process of biochemistry are reasonably arranged in pairs or groups, with On the premise of final outflow water water quality meets emission request, integrated treatment cost is reduced to greatest extent.In addition such scheme is also Process that can be very easily at present existing in a large number with materialized pretreatment and biochemical processing as core sets Applying carries out corresponding technological transformation.
Description of the drawings
Fig. 1 is the process chart of processing method of the present invention;
Fig. 2 is the process chart of embodiment of the present invention 1;
Fig. 3 is the process chart of embodiment of the present invention 2;
In figure:1. just the ozone high grade oxidation of 3. Ammonia blowing-out tower of sedimentation tank, 4. membrane bioreactor 5. is processed regulating reservoir 2. The membrane bioreactor A. of device 6. is ozone to be recovered as burning B. to be recovered as discharging C. for air D..
Specific embodiment
The description below is further elaborated explanation by accompanying drawing is combined to the correlation properties of the present invention, but this is not therefore Limit the present invention in the middle of described case study on implementation scope.
Embodiment 1:" twinization " of percolate+" advanced oxidation " combined treatment process, including materialized pretreatment, Biochemical treatment, advanced oxidation process, secondary biochemical treatment.The adjusted pond of percolate(1)Jing water pumps once pass through thing Change the first sedimentation tank of pretreatment stage(2)And Ammonia blowing-out tower(3), it is afterwards membrane bioreactor into a biochemical treatment apparatus (4), percolate its biodegradability after above-mentioned process is greatly lowered, and major pollutants are the difficult drop of macromole in water Bio-chemical effluent importing advanced oxidation processing meanss are now UV+Fenton advanced oxidation processing meanss by solution Organic substance(5), Jing After advanced oxidation process, water quality biodegradability is greatly improved, membrane bioreactor is finally adopted again(6), i.e., at secondary biochemistry Reason technology causes water outlet finally to meet discharge standard, and the process chart that the program is adopted is referring to Fig. 2.
The percolate of Nanchang refuse landfill is processed using the present invention, treatment effect see the table below shown:
Knowable to the detection data obtained in table, it is processed by the invention after percolate its final outflow water water quality disclosure satisfy that GB16889-2008《National household refuse landfill sites Environmental capacity standard》In emission request.
Embodiment 2:" twinization " of percolate+" advanced oxidation " combined treatment process, including materialized pretreatment, Biochemical treatment, advanced oxidation process, secondary biochemical treatment.The adjusted pond of percolate(1)Jing water pumps once pass through thing Change the first sedimentation tank of pretreatment stage(2)And Ammonia blowing-out tower(3), it is afterwards membrane bioreactor into a biochemical treatment apparatus (4), percolate its biodegradability after above-mentioned process is greatly lowered, and major pollutants divide greatly for difficult degradation in water Sub- Organic substance, is now passed through advanced oxidation processing meanss i.e. ozone high grade oxidation processing meanss by bio-chemical effluent(5), the senior oxygen of Jing After change is processed, water quality biodegradability is greatly improved, membrane bioreactor is finally adopted again(6), i.e., secondary biochemical processing So that water outlet finally meets discharge standard, the process chart that the program is adopted is referring to Fig. 3.
The percolate of Nanchang refuse landfill is processed using the present invention, treatment effect see the table below shown:
Knowable to the detection data obtained in table, it is processed by the invention after percolate its final outflow water water quality disclosure satisfy that GB16889-2008《National household refuse landfill sites Environmental capacity standard》In emission request.

Claims (1)

1. a kind of combined treatment process of percolate, it is characterised in that:The combined treatment process process includes:Materialization is pre- Process, a biochemical treatment, advanced oxidation process, secondary biochemical treatment;Concretely comprise the following steps:
The adjusted pond Jing water pumps of percolate once by the first sedimentation tank in materialized pretreatment stage and Ammonia blowing-out tower, it is laggard Enter biochemical treatment apparatus i.e. membrane bioreactor, percolate its biodegradability after above-mentioned process significantly drops Low, major pollutants are macromole hardly degraded organic substance in water, then are UV+ by bio-chemical effluent importing advanced oxidation processing meanss Fenton advanced oxidation processing meanss, Jing after advanced oxidation process, biodegradability of increasing water quality finally adopts again membrane bioreaction Device is answered, i.e., secondary biochemical processing causes water outlet finally to meet discharge standard;
The materialized pretreatment is based on the pretreating process of coagulating sedimentation, stripping physico-chemical process;
Biochemical treatment is with UASB i.e. up-flow anaerobic sludge blanket, ABR i.e. anaerobic baffled reactor technique anaerobism Technique and based on catalytic oxidation, oxidation ditch, A/O technique aerobic process biochemical processing process;
The Advanced Oxidation Technics in Dealing is with UV+Fenton, O3High-level oxidation technology is science and engineering at the advanced oxidation of its main body Skill;
The secondary biochemical treatment is based on membrane bioreactor i.e. MBR, the BAF i.e. follow-up life of BAF techniques Change handling process.
CN201611260081.4A 2016-12-30 2016-12-30 Combined treatment process of landfill leachate Pending CN106673362A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107416962A (en) * 2017-07-12 2017-12-01 连云港亿尚景水务有限公司 A kind of advanced oxidation equipment and sewage disposal system
CN108996821A (en) * 2018-07-26 2018-12-14 广东中微环保生物科技有限公司 A kind of processing system and processing method of landfill leachate
CN109052806A (en) * 2018-07-23 2018-12-21 安吉钰禾环保科技有限公司 A kind of garbage leachate treatment device and method based on A/O- electrochemical oxidation-BAF group technology
CN111675447A (en) * 2020-07-17 2020-09-18 苏州中环建科环境科技有限公司 Treatment process of waste permeating filtrate of small and medium kitchen waste treatment station

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CN102583908B (en) * 2012-03-22 2013-09-04 南京工业大学 Landfill leachate treatment process
CN103880253A (en) * 2014-04-04 2014-06-25 深圳市百斯特环保工程有限公司 Garbage leachate advanced treatment method and Fenton reaction tower
CN204981478U (en) * 2015-05-24 2016-01-20 蓝德环保科技集团股份有限公司 Leachate treatment system

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CN102503046A (en) * 2011-11-18 2012-06-20 北京伊普国际水务有限公司 Advanced treatment system and method for high-concentration percolate in comprehensive garbage disposal plant
CN102583908B (en) * 2012-03-22 2013-09-04 南京工业大学 Landfill leachate treatment process
CN103880253A (en) * 2014-04-04 2014-06-25 深圳市百斯特环保工程有限公司 Garbage leachate advanced treatment method and Fenton reaction tower
CN204981478U (en) * 2015-05-24 2016-01-20 蓝德环保科技集团股份有限公司 Leachate treatment system

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107416962A (en) * 2017-07-12 2017-12-01 连云港亿尚景水务有限公司 A kind of advanced oxidation equipment and sewage disposal system
CN109052806A (en) * 2018-07-23 2018-12-21 安吉钰禾环保科技有限公司 A kind of garbage leachate treatment device and method based on A/O- electrochemical oxidation-BAF group technology
CN108996821A (en) * 2018-07-26 2018-12-14 广东中微环保生物科技有限公司 A kind of processing system and processing method of landfill leachate
CN108996821B (en) * 2018-07-26 2021-03-02 广东中微环保生物科技有限公司 Treatment system and treatment method for landfill leachate
CN111675447A (en) * 2020-07-17 2020-09-18 苏州中环建科环境科技有限公司 Treatment process of waste permeating filtrate of small and medium kitchen waste treatment station

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