CN204981478U - Leachate treatment system - Google Patents

Leachate treatment system Download PDF

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Publication number
CN204981478U
CN204981478U CN201520340307.6U CN201520340307U CN204981478U CN 204981478 U CN204981478 U CN 204981478U CN 201520340307 U CN201520340307 U CN 201520340307U CN 204981478 U CN204981478 U CN 204981478U
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pond
baf
oxidation
treatment system
fenton
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施军营
吴望
田玉阁
孔维芳
常霄静
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Shengao Lande Environmental Protection Technology Group Co ltd
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Bioland Environmental Technologies Group Corp Ltd
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Abstract

本实用新型涉及一种渗滤液处理系统,包括原水调节池、芬顿氧化处理系统、BAF处理系统、加药罐和清水池;其特征在于,所述的芬顿氧化处理系统包括pH调节池、芬顿氧化池和中和沉淀池;所述的BAF处理系统包括反硝化BAF池和氧化/硝化BAF池。芬顿氧化试剂产生具有极强的氧化性羟基自由基,能够将有毒难降解的有机物有效地分解,最终产生二氧化碳和水。这样可以有效提高废水的可生化性,同时很好降低了废水的色度。同时,BAF集生物膜氧化降解和滤层过滤功能于一体,是一种新型污水处理技术,具有池容小、占地面积小、出水水质好、流程简单等优点,滤池可以节省处理成本,提高出水质量。

The utility model relates to a leachate treatment system, which comprises a raw water adjustment pool, a Fenton oxidation treatment system, a BAF treatment system, a dosing tank and a clear water pool; it is characterized in that the Fenton oxidation treatment system includes a pH adjustment pool, A Fenton oxidation pond and a neutralization sedimentation pond; the BAF treatment system includes a denitrification BAF pond and an oxidation/nitrification BAF pond. Fenton's oxidation reagent produces extremely strong oxidizing hydroxyl radicals, which can effectively decompose toxic and refractory organic matter, and finally produce carbon dioxide and water. In this way, the biodegradability of the wastewater can be effectively improved, and at the same time, the chromaticity of the wastewater can be well reduced. At the same time, BAF integrates the functions of biofilm oxidation degradation and filter layer filtration. It is a new type of sewage treatment technology. It has the advantages of small pool volume, small footprint, good effluent quality, and simple process. The filter can save treatment costs. Improve effluent quality.

Description

一种渗滤液处理系统A leachate treatment system

技术领域 technical field

本实用新型属于垃圾处理技术领域,具体涉及一种渗滤液处理系统。 The utility model belongs to the technical field of garbage treatment, in particular to a leachate treatment system.

背景技术 Background technique

随着我国城市规模的扩大、城市人口的增加与居民生活水平的提高,我国城市生活垃圾的产量也在急剧上升。尤其是上海、广州等大城市,人均日产垃圾已超过1kg,接近工业发达国家的水平。根据我国垃圾处理“无害化、减量化、资源化”的原则,将新建一大批生活垃圾卫生填埋场。而垃圾渗滤液是否能被处理的达标排放是衡量一个填埋场是否为卫生填埋场的重要指标之一。 With the expansion of my country's cities, the increase of urban population and the improvement of residents' living standards, the output of my country's municipal solid waste is also rising sharply. Especially in Shanghai, Guangzhou and other big cities, the per capita daily waste production has exceeded 1kg, which is close to the level of industrially developed countries. According to the principle of "harmless, reduction, and resourceful" in my country's waste disposal, a large number of sanitary landfills for domestic waste will be built. Whether landfill leachate can be treated and discharged up to standard is one of the important indicators to measure whether a landfill is a sanitary landfill.

垃圾填埋和焚烧是目前处理垃圾的主要方法。然而,垃圾渗滤液污染却是现有固体废弃物处理和未来垃圾填埋过程中不可避免的一个问题。垃圾渗滤液会对周围地下水、地表水和土壤造成严重的环境污染。在利用填埋场、焚烧厂对城市生活垃圾进行处理以及全面管理的过程中,主要的工作内容之一就是对垃圾渗滤液采用合适的方法进行处理,避免对周围环境造成二次污染。 Landfill and incineration are the main methods of waste disposal at present. However, landfill leachate pollution is an unavoidable problem in the existing solid waste treatment and future landfill processes. Landfill leachate will cause serious environmental pollution to the surrounding groundwater, surface water and soil. In the process of using landfills and incineration plants to process and comprehensively manage municipal solid waste, one of the main tasks is to use appropriate methods to treat landfill leachate to avoid secondary pollution to the surrounding environment.

渗滤液是一种成分十分复杂的废水,含有多种难降解有机成分及氨氮,具有污染物浓度高、毒性强、水质和水量波动大等特点。垃圾渗滤液常用的深度处理方法有反渗透、化学氧化、混凝沉淀、活性炭吸附等。目前国内常用的主要为纳滤/反渗透膜过滤工艺,该工艺能够达到新标准的要求,但同时会产生约占进水总量30%的难以处理的浓水。膜过滤后的浓缩液含量更加复杂,目前常用的方法是回灌至填埋场,长期回灌会造成整个处理系统的水质变复杂,负荷升高。进一步处理的办法有蒸发处理和高级氧化处理,蒸发处理比较彻底,投资及运行费用相对较高,而高级氧化处理又存在着处理不彻底的弊端。 Leachate is a kind of wastewater with a very complex composition, containing a variety of refractory organic components and ammonia nitrogen, and has the characteristics of high pollutant concentration, strong toxicity, and large fluctuations in water quality and water volume. Commonly used advanced treatment methods for landfill leachate include reverse osmosis, chemical oxidation, coagulation sedimentation, and activated carbon adsorption. At present, nanofiltration/reverse osmosis membrane filtration process is commonly used in China. This process can meet the requirements of the new standard, but at the same time, it will produce about 30% of the total influent concentrated water that is difficult to treat. The content of the concentrated solution after membrane filtration is more complicated. The current common method is to recharge to the landfill. Long-term recharge will cause the water quality of the entire treatment system to become complicated and the load to increase. Further treatment methods include evaporation treatment and advanced oxidation treatment. Evaporation treatment is relatively thorough, and the investment and operating costs are relatively high, while advanced oxidation treatment has the disadvantage of incomplete treatment.

直接采用化学氧化深度处理垃圾渗滤液的方法及工艺,高级氧化工艺(AOPs)通常指在环境温度和压力下,通过产生具有高反应活性的羟基自由基(HO·)来氧化降解有机污染物的处理技术,包括O3氧化、Fenton氧化、光催化氧化、以及它们的组合氧化技术。高级氧化技术,产生大量高反应活性HO·,能将部分的有机物完全矿化,对废水中难以生物降解的有机污染物的也有降解能力,因而高级氧化技术在难生化降解废水处理中的应用研究越来越受到重视。 The method and process of advanced treatment of landfill leachate directly by chemical oxidation. Advanced Oxidation Process (AOPs) usually refers to the process of oxidatively degrading organic pollutants by generating highly reactive hydroxyl radicals (HO·) at ambient temperature and pressure. Treatment technologies, including O 3 oxidation, Fenton oxidation, photocatalytic oxidation, and their combined oxidation technologies. Advanced oxidation technology produces a large amount of highly reactive HO, which can completely mineralize part of the organic matter, and also has the ability to degrade organic pollutants that are difficult to biodegrade in wastewater. Therefore, the application of advanced oxidation technology in the treatment of difficult biodegradable wastewater Gaining importance.

高级氧化工艺如O3氧化,Fenton氧化,UV/O3,UV/Fe2+,H2O2,UV/TiO2等工艺用于分解垃圾渗滤液中难降解有机物(如腐殖酸等)是高效的。在工程上,若单独使用这些工艺处理垃圾渗滤液,其成本是很高的。 Advanced oxidation processes such as O 3 oxidation, Fenton oxidation, UV/O 3 , UV/Fe 2+ , H 2 O 2 , UV/TiO 2 and other processes are used to decompose refractory organic substances (such as humic acid, etc.) in landfill leachate is efficient. In terms of engineering, if these processes are used alone to treat landfill leachate, the cost is very high.

发明内容 Contents of the invention

本实用新型提供了一种渗滤液处理系统,包括原水调节池、芬顿氧化处理系统、BAF处理系统、加药罐和清水池;芬顿氧化处理系统包括pH调节池、芬顿氧化池和中和沉淀池;BAF处理系统包括反硝化BAF池和氧化/硝化BAF池;其中,原水调节池的出口通过管路与pH调节池的入口连接,pH调节池的出口与芬顿氧化池的入口管路连接,芬顿氧化池的出口通过管路与中和沉淀池的入口连接,加药罐分别与pH调节池、芬顿氧化池和中和沉淀池管路连接,中和沉淀池的出口与反硝化BAF池的入口管路连接,反硝化BAF池的出口通过管路与氧化/硝化BAF池的入口连接,氧化/硝化BAF池还设有硝化液回流口,该回流口通过管路与反硝化BAF的入口连接,氧化/硝化BAF池的出水口通过管路与清水池连接。 The utility model provides a leachate treatment system, which comprises a raw water adjustment tank, a Fenton oxidation treatment system, a BAF treatment system, a dosing tank and a clear water tank; the Fenton oxidation treatment system comprises a pH adjustment tank, a Fenton oxidation treatment system and a middle and sedimentation tank; BAF treatment system includes denitrification BAF tank and oxidation / nitrification BAF tank; wherein, the outlet of the raw water adjustment tank is connected with the inlet of the pH adjustment tank through pipelines, and the outlet of the pH adjustment tank is connected with the inlet pipe of the Fenton oxidation tank The outlet of the Fenton oxidation tank is connected to the inlet of the neutralization sedimentation tank through pipelines, the dosing tank is connected to the pH adjustment tank, the Fenton oxidation tank and the pipeline of the neutralization sedimentation tank respectively, and the outlet of the neutralization sedimentation tank is connected to the pipeline of the neutralization sedimentation tank. The inlet pipeline of the denitrification BAF pool is connected, and the outlet of the denitrification BAF pool is connected to the inlet of the oxidation/nitrification BAF pool through a pipeline. The inlet of the nitrification BAF is connected, and the outlet of the oxidation/nitrification BAF pool is connected to the clear water pool through pipelines.

所述渗滤液处理系统还包括搅拌装置。 The leachate treatment system also includes a stirring device.

所述的加药罐中含有酸、碱、H2O2和FeSO4。 The medicine adding tank contains acid, alkali, H 2 O 2 and FeSO 4 .

所述的中和沉淀池数量为2个。 The number of neutralization sedimentation tanks is 2.

本新型所述的渗滤液处理系统具有以下优点:芬顿氧化试剂产生具有极强的氧化性羟基自由基,能够将有毒难降解的有机物有效地分解,最终产生二氧化碳和水。这样可以有效提高废水的可生化性,同时很好降低了废水的色度。同时,BAF集生物膜氧化降解和滤层过滤功能于一体,是一种新型污水处理技术,具有池容小、占地面积小、出水水质好、流程简单等优点,滤池可以节省处理成本,提高出水质量。 The leachate treatment system described in the present invention has the following advantages: the Fenton oxidation reagent produces extremely strong oxidative hydroxyl radicals, which can effectively decompose toxic and refractory organic matter, and finally produce carbon dioxide and water. In this way, the biodegradability of the wastewater can be effectively improved, and at the same time, the chromaticity of the wastewater can be well reduced. At the same time, BAF integrates the functions of biofilm oxidation degradation and filter layer filtration. It is a new type of sewage treatment technology. It has the advantages of small pool volume, small footprint, good effluent quality, and simple process. The filter can save treatment costs. Improve water quality.

附图说明 Description of drawings

图1是本实用新型的结构框图。 Fig. 1 is a structural block diagram of the utility model.

具体实施方式 detailed description

以下结合说明书附图对本实用新型做进一步说明。 Below in conjunction with accompanying drawing, the utility model is further described.

废水通过原水调节池进入芬顿氧化处理系统中的pH调节池,进行pH值调节,用稀硫酸调节pH值为3~4;然后进入芬顿氧化池,加入芬顿试剂进行氧化,主要去除COD和NH3-N,出水进入中和沉淀池,加碱液进行中和至中性,然后再沉淀;中和沉淀池采用2个池子交替运行方式,以达到良好的沉淀效果。中和沉淀池出水进入反硝化BAF池进行的反硝化,将从氧化/硝化BAF池回流的硝化液反硝化脱氮,之后进入氧化/硝化BAF池进行氧化和硝化反应,部分进行回流,出水进入清水池,达标排放。 The wastewater enters the pH adjustment pool of the Fenton oxidation treatment system through the raw water adjustment pool, and adjusts the pH value, and adjusts the pH value to 3~4 with dilute sulfuric acid; then enters the Fenton oxidation pool, and adds Fenton reagent for oxidation, mainly to remove COD and NH 3 -N, the effluent enters the neutralization sedimentation tank, adds lye to neutralize to neutrality, and then precipitates; the neutralization sedimentation tank adopts the alternate operation mode of two pools to achieve a good sedimentation effect. The effluent from the neutralization sedimentation tank enters the denitrification BAF tank for denitrification. The nitrification liquid returned from the oxidation/nitrification BAF tank is denitrified and denitrified, and then enters the oxidation/nitrification BAF tank for oxidation and nitrification reactions. Part of it is refluxed, and the effluent enters the Clean water pool, up to standard discharge.

以上仅是本实用新型的优选实施方式,本实用新型的保护范围并不仅局限于上述实施例,凡属于本实用新型思路下的技术方案均属于本实用新型的保护范围。应当指出,对于本技术领域的普通技术人员来说,在不脱离本实用新型原理前提下的若干改进和润饰,应视为本实用新型的保护范围。 The above are only preferred implementations of the utility model, and the scope of protection of the utility model is not limited to the above-mentioned embodiments, and all technical solutions under the thinking of the utility model all belong to the scope of protection of the utility model. It should be pointed out that for those of ordinary skill in the art, some improvements and modifications without departing from the principle of the utility model should be regarded as the protection scope of the utility model.

Claims (4)

1. a percolation liquid treating system, comprises former water equalizing tank, Fenton oxidation treatment system, BAF treatment system, grug feeding jar and clean water basin, it is characterized in that, described Fenton oxidation treatment system comprises pH regulator pond, Fenton oxidation pond and neutralization precipitation pond, described BAF treatment system comprises denitrification BAF pond and oxidation/nitrated BAF pond, wherein, the outlet of former water equalizing tank is connected by the entrance of pipeline with pH regulator pond, the outlet in pH regulator pond is connected with the entrance pipe in Fenton oxidation pond, the outlet in Fenton oxidation pond is connected by the entrance of pipeline with neutralization precipitation pond, grug feeding jar respectively with pH regulator pond, Fenton oxidation pond is connected with neutralization precipitation pond pipeline, the outlet in neutralization precipitation pond is connected with the entrance pipe in denitrification BAF pond, the outlet in denitrification BAF pond is connected by the entrance of pipeline with oxidation/nitrated BAF pond, oxidation/nitrated BAF pond is also provided with nitrification liquid refluxing opening, this refluxing opening is connected by the entrance of pipeline with denitrification BAF, the water outlet in oxidation/nitrated BAF pond is connected with clean water basin by pipeline.
2. percolation liquid treating system according to claim 1, is characterized in that: described percolation liquid treating system also comprises whipping appts.
3. percolation liquid treating system according to claim 1, is characterized in that: containing acid, alkali, H in described grug feeding jar 2o 2and FeSO4.
4. percolation liquid treating system according to claim 1, is characterized in that: described neutralization precipitation pond quantity is 2.
CN201520340307.6U 2015-05-24 2015-05-24 Leachate treatment system Expired - Lifetime CN204981478U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673302A (en) * 2016-12-16 2017-05-17 北京桑德环境工程有限公司 Advanced wastewater treatment system for leather industry park
CN106673362A (en) * 2016-12-30 2017-05-17 南昌大学 Combined treatment process of landfill leachate
CN109179883A (en) * 2018-09-29 2019-01-11 湖南北控威保特环境科技股份有限公司 A kind of preprocess method and device for aged consumer waste infiltration liquid
CN110255763A (en) * 2019-06-20 2019-09-20 湖北中地星河环保科技有限公司 A kind of leachate integrated processing unit and method
CN112047566A (en) * 2020-08-12 2020-12-08 武汉天源环保股份有限公司 Full-quantitative treatment system and method for landfill leachate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673302A (en) * 2016-12-16 2017-05-17 北京桑德环境工程有限公司 Advanced wastewater treatment system for leather industry park
CN106673362A (en) * 2016-12-30 2017-05-17 南昌大学 Combined treatment process of landfill leachate
CN109179883A (en) * 2018-09-29 2019-01-11 湖南北控威保特环境科技股份有限公司 A kind of preprocess method and device for aged consumer waste infiltration liquid
CN109179883B (en) * 2018-09-29 2024-05-24 湖南北控威保特环境科技股份有限公司 Pretreatment method and device for aged household garbage leachate
CN110255763A (en) * 2019-06-20 2019-09-20 湖北中地星河环保科技有限公司 A kind of leachate integrated processing unit and method
CN112047566A (en) * 2020-08-12 2020-12-08 武汉天源环保股份有限公司 Full-quantitative treatment system and method for landfill leachate

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