CN106671536A - High-performance decorative material - Google Patents
High-performance decorative material Download PDFInfo
- Publication number
- CN106671536A CN106671536A CN201611268289.0A CN201611268289A CN106671536A CN 106671536 A CN106671536 A CN 106671536A CN 201611268289 A CN201611268289 A CN 201611268289A CN 106671536 A CN106671536 A CN 106671536A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- prepared
- performance
- casein
- electrostatic spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a high-performance decorative material. The material is produced by binding non-woven fabric and a PVC board through an adhesive. The non-woven fabric prepared with the method has lower specific gravity, high toughness, high tension resistance, high breaking strength, high impact resistance, excellent mildew resistance, high overall structural strength, excellent texture and hand feel, good dyeing property and dyeing fastness, and the prepared non-woven fabric has a good adsorption effect on formaldehyde gas and can play a good role in purifying air. The decorative material prepared by combining the prepared adhesive and the PVC board is pollution-free, causes no harm to environment and human bodies, has better corrosion resistance and scratch resistance, has long service life, has certain moisture absorption and humidifying performance and can effectively improve comfort of indoor environment, and the prepared adhesive can still play excellent viscosity retention performance under bad weather conditions of higher humidity, temperature and the like, has high binding strength and good binding durability.
Description
Technical field
The present invention relates to decoration material field, more particularly to a kind of high-performance ornament materials.
Background technology
Non-woven fabrics, also known as adhesive-bonded fabric, is made up of fiber orient or random, is environment-friendly materials of new generation, with anti-
Damp, ventilative, flexible, light weight, not combustion-supporting, easy decomposition, nontoxic nonirritant, rich color, cheap, recyclable etc.
Feature.PVC board is that the section being made as raw material with PVC is the sheet material of honeycomb eyed structure, the decorating film that is otherwise known as, attached glue
Film, is applied to all conglomeraties such as building materials, packaging, medicine, non-woven fabrics is combined with PVC board, the ornament materials being made, no
Only beautiful appearance is generous, and with the performance such as wear-resisting, heat-resisting, cold-resistant higher.
The content of the invention
It is an object of the invention to provide a kind of high-performance ornament materials, it is achieved through the following technical solutions：
A kind of high-performance ornament materials, is bonded together by adhesive by non-woven fabrics and PVC board and is made, described non-woven fabrics by
High-voltage electrostatic spinning method is prepared from, and the spinning solution of use is made up of following component by weight：Chitosan acid solution 10-
15th, deionized water 14-18, caprylic acid 40-42, polypropylene fibre 8-12, nanoscale bamboo powder 3-5, nano titanium oxide 2-5, receive
Meter level bentonite in powder 2-4, Pogostemon cablin leaf extract 0.2-0.5；Described adhesive is made up of following component by weight：It is beautiful
Rice starch 43, mass concentration is 0.12% liquor natrii hypochloritis 52, polyvinyl alcohol 3, acrylamide 7, AEEA 5, junket
Albumen and urea mixed solution 4, Pogostemon cablin leaf extract 0.3；The casein and urea mixed solution by casein and urea,
Water presses 1:4：20 mass ratios are mixed.
Further, the Pogostemon cablin leaf extract preparation method is：Pogostemon cablin leaf and tapioca are pressed 30:1 mass
Ratio mix, then use mass concentration be 0.1% liquor natrii hypochloritis immersion 20min, then filter, dry, pulverize to
150 mesh, then using 90% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, the refluxing extraction 3h at 46 DEG C, centrifugation
Supernatant is obtained, then is concentrated by rotary evaporation, then freeze-drying is obtained.
Further, the high-voltage electrostatic spinning method is：The spinning solution that will be prepared loads the syringe of electrostatic spinning apparatus
In, electrostatic spinning is carried out, the wherein internal diameter of syringe nozzle is 0.5mm, and the voltage of electrostatic spinning is 10kV, the extrudate flow of suspension
It is 0.26mL/h to measure, and it is 18cm to receive distance.
Further, the preparation method of the adhesive is：By liquor natrii hypochloritis, heating that mass concentration is 0.12%
To 46 DEG C, cornstarch and casein and urea mixed solution are then added, 15min, Ran Houjia are stirred with 500r/min rotating speeds
Heat stirs 15min to 80 DEG C with 800r/min rotating speeds, then adds polyvinyl alcohol, acrylamide, AEEA, the wide leaves of pulse plants
Herba Pelargonii Graveolentis extract, after stirring, is heated to 82 DEG C, and 40min is stirred with 1200r/min rotating speeds, then naturally cools to room temperature
.
Further, the non-woven fabrics and PVC board are by the technological parameter that adhesive is bonded：Adhesive consumption is
220g/m, digestion time is 12min, be 112 DEG C through excess temperature, unit pressure be 0.8MPa, time for the hot pressing of 2min at
Reason.
The beneficial effects of the invention are as follows：Non-woven fabrics proportion prepared by the inventive method is lighter, and toughness is strong, and tensile capacity is strong,
With ultimate strength high, impact resistance is strong, and mildew resistance is fabulous, and overall construction intensity is high, and texture and feel are excellent, dyeability
Good, dyeing is firm, and the non-woven fabrics PARA FORMALDEHYDE PRILLS(91,95) gas being made has good suction-operated, can play good to air
Catharsis, is combined with PVC board by the adhesive prepared using the present invention and is made ornament materials, pollution-free, to environment and people
Body is not injured, and corrosion resistance and resistance to marring are preferable, long service life, also with certain moisture absorption humidity, can be had
Effect improves the comfort level of indoor environment, and the adhesive that the present invention is prepared can be in bad gas such as humidity and temperature relatively high
The viscosity that brilliance can be still played under the conditions of time keeps performance, and adhesive strength is high, bonding persistence is good.
Specific embodiment
Embodiment 1
A kind of high-performance ornament materials, is bonded together by adhesive by non-woven fabrics and PVC board and is made, described non-woven fabrics by
High-voltage electrostatic spinning method is prepared from, and the spinning solution of use is made up of following component by weight：Chitosan acid solution 10,
It is deionized water 14, caprylic acid 40, polypropylene fibre 8, nanoscale bamboo powder 3, nano titanium oxide 2, nanoscale bentonite in powder 2, wide
Wrinkled giant hyssop leaf extract 0.2；Described adhesive is made up of following component by weight：Cornstarch 43, mass concentration is
0.12% liquor natrii hypochloritis 52, polyvinyl alcohol 3, acrylamide 7, AEEA 5, casein and urea mixed solution
4th, Pogostemon cablin leaf extract 0.3；The casein presses 1 with urea mixed solution by casein and urea, water:4：20 mass ratios
Mix.
Embodiment 2
A kind of high-performance ornament materials, is bonded together by adhesive by non-woven fabrics and PVC board and is made, described non-woven fabrics by
High-voltage electrostatic spinning method is prepared from, and the spinning solution of use is made up of following component by weight：Chitosan acid solution 15,
It is deionized water 18, caprylic acid 42, polypropylene fibre 12, nanoscale bamboo powder 5, nano titanium oxide 5, nanoscale bentonite in powder 4, wide
Wrinkled giant hyssop leaf extract 0.5；Described adhesive is made up of following component by weight：Cornstarch 43, mass concentration is
0.12% liquor natrii hypochloritis 52, polyvinyl alcohol 3, acrylamide 7, AEEA 5, casein and urea mixed solution
4th, Pogostemon cablin leaf extract 0.3；The casein presses 1 with urea mixed solution by casein and urea, water:4：20 mass ratios
Mix.
Embodiment 3
A kind of high-performance ornament materials, is bonded together by adhesive by non-woven fabrics and PVC board and is made, described non-woven fabrics by
High-voltage electrostatic spinning method is prepared from, and the spinning solution of use is made up of following component by weight：Chitosan acid solution 13,
It is deionized water 15, caprylic acid 41, polypropylene fibre 10, nanoscale bamboo powder 4, nano titanium oxide 3, nanoscale bentonite in powder 3, wide
Wrinkled giant hyssop leaf extract 0.4；Described adhesive is made up of following component by weight：Cornstarch 43, mass concentration is
0.12% liquor natrii hypochloritis 52, polyvinyl alcohol 3, acrylamide 7, AEEA 5, casein and urea mixed solution
4th, Pogostemon cablin leaf extract 0.3；The casein presses 1 with urea mixed solution by casein and urea, water:4：20 mass ratios
Mix.
In above example：
The Pogostemon cablin leaf extract preparation method is：Pogostemon cablin leaf and tapioca are pressed 30:1 mass ratio mixes, then
Use mass concentration to soak 20min for 0.1% liquor natrii hypochloritis, then filter, dry, pulverize to 150 mesh, then use
90% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, the refluxing extraction 3h at 46 DEG C, are centrifuged to obtain supernatant, then pass through
Cross rotation to be concentrated by evaporation, then freeze-drying is obtained.
The high-voltage electrostatic spinning method is：The spinning solution prepared is fitted into the syringe of electrostatic spinning apparatus, is carried out quiet
The internal diameter of Electrospun, wherein syringe nozzle is 0.5mm, and the voltage of electrostatic spinning is 10kV, and the extrusion flow of suspension is
0.26mL/h, it is 18cm to receive distance.
The preparation method of the adhesive is：By liquor natrii hypochloritis that mass concentration is 0.12%, 46 DEG C are heated to, so
Addition cornstarch and casein and urea mixed solution, 15min is stirred with 500r/min rotating speeds afterwards, is then heated to 80 DEG C,
15min is stirred with 800r/min rotating speeds, polyvinyl alcohol, acrylamide, AEEA, Pogostemon cablin leaf is then added and is extracted
Thing, after stirring, is heated to 82 DEG C, and 40min is stirred with 1200r/min rotating speeds, then naturally cools to room temperature.
The non-woven fabrics and PVC board are by the technological parameter that adhesive is bonded：Adhesive consumption is 220g/m, ageing
Time is 12min, is 112 DEG C, the hot-pressing processing that unit pressure is 0.8MPa, the time is 2min through excess temperature.
Comparative example 1：Differed only in spinning solution without Pogostemon cablin leaf extract and nanoscale bamboo powder with embodiment 1.
Comparative example 2：Differed only in adhesive without casein and urea mixed solution with embodiment 1.
Comparative example 3：Differed only in adhesive without Pogostemon cablin leaf extract with embodiment 1.
Performance detection is carried out to the non-woven fabrics in embodiment, comparative example：
Table 1
| Notch impact strength kJ/m | Elongation at break % | |
| Embodiment 1 | 6.58 | 822.5 |
| Embodiment 2 | 6.56 | 820.4 |
| Embodiment 3 | 6.58 | 820.8 |
| Comparative example 1 | 5.46 | 753.2 |
Wherein, notch impact strength is tested at room temperature by ASTM D256-2004, and elongation at break presses ASTM D638-
2003 are tested at room temperature；
As can be seen from Table 1, the non-woven fabrics performance for being prepared in the present invention is more preferable.
Adhesive adhesive strength in embodiment comparative example is detected（GB/T 9846.12-1988）：
Table 2
| Bonding strength MPa | |
| Embodiment 1 | 1.88 |
| Embodiment 2 | 1.86 |
| Embodiment 3 | 1.87 |
| Comparative example 2 | 1.36 |
| Comparative example 3 | 1.58 |
As can be seen from Table 2, the adhesive bonding strength for being prepared in the present invention is higher.
Claims (5)
1. a kind of high-performance ornament materials, it is characterised in that be bonded together by adhesive by non-woven fabrics and PVC board and be made,
Described non-woven fabrics is prepared from by high-voltage electrostatic spinning method, and the spinning solution of use is made up of following component by weight：
Chitosan acid solution 10-15, deionized water 14-18, caprylic acid 40-42, polypropylene fibre 8-12, nanoscale bamboo powder 3-5, nanometer
Titanium dioxide 2-5, nanoscale bentonite in powder 2-4, Pogostemon cablin leaf extract 0.2-0.5；Described adhesive by weight by
Following component is made：Cornstarch 43, mass concentration be 0.12% liquor natrii hypochloritis 52, polyvinyl alcohol 3, acrylamide 7,
AEEA 5, casein and urea mixed solution 4, Pogostemon cablin leaf extract 0.3；The casein mixes molten with urea
Liquid presses 1 by casein and urea, water:4：20 mass ratios are mixed.
2. a kind of high-performance ornament materials according to claim 1, it is characterised in that prepared by the Pogostemon cablin leaf extract
Method is：Pogostemon cablin leaf and tapioca are pressed 30:1 mass ratio mix, then use mass concentration for 0.1% hypochlorous acid
Sodium solution soaks 20min, then filters, and dry, pulverize to 150 mesh, then using 90% concentration of volume percent alcohol solvent,
By solid-liquid ratio 1:20, the refluxing extraction 3h at 46 DEG C, are centrifuged to obtain supernatant, then concentrated by rotary evaporation, then freeze-drying
It is obtained.
3. a kind of high-performance ornament materials according to claim 1, it is characterised in that the high-voltage electrostatic spinning method is：
The spinning solution prepared is fitted into the syringe of electrostatic spinning apparatus, electrostatic spinning is carried out, the internal diameter of wherein syringe nozzle is
0.5mm, the voltage of electrostatic spinning is 10kV, and the extrusion flow of suspension is 0.26mL/h, and it is 18cm to receive distance.
4. a kind of high-performance ornament materials according to claim 1, it is characterised in that the preparation method of the adhesive
For：By liquor natrii hypochloritis that mass concentration is 0.12%, 46 DEG C are heated to, then add cornstarch and casein and urea
Mixed solution, 15min is stirred with 500r/min rotating speeds, is then heated to 80 DEG C, stirs 15min with 800r/min rotating speeds, then
Addition polyvinyl alcohol, acrylamide, AEEA, Pogostemon cablin leaf extract, after stirring, are heated to 82 DEG C, with
1200r/min rotating speeds stir 40min, then naturally cool to room temperature.
5. a kind of high-performance ornament materials according to claim 1, it is characterised in that the non-woven fabrics and PVC board pass through
Adhesive bonding technological parameter be：Adhesive consumption is 220g/m, and digestion time is 12min, is 112 DEG C, list through excess temperature
The hot-pressing processing that position pressure is 0.8MPa, the time is 2min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268289.0A CN106671536B (en) | 2016-12-31 | 2016-12-31 | A kind of high-performance ornament materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268289.0A CN106671536B (en) | 2016-12-31 | 2016-12-31 | A kind of high-performance ornament materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106671536A true CN106671536A (en) | 2017-05-17 |
| CN106671536B CN106671536B (en) | 2018-07-27 |
Family
ID=58848913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611268289.0A Expired - Fee Related CN106671536B (en) | 2016-12-31 | 2016-12-31 | A kind of high-performance ornament materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106671536B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107338657A (en) * | 2017-07-12 | 2017-11-10 | 合肥信亚达智能科技有限公司 | A kind of preparation method of novel environment friendly ornament materials |
| CN109233686A (en) * | 2018-08-06 | 2019-01-18 | 安徽省神洲建材科技有限公司 | A kind of processing method of high performance and long service life ornament materials |
| CN113480298A (en) * | 2021-07-29 | 2021-10-08 | 景德镇陶瓷大学 | Preparation and application method of high-whiteness high-transmittance high-plasticity ceramic blank mud |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040043184A1 (en) * | 2002-08-27 | 2004-03-04 | Seiin Kobayashi | Flooring article with soft, skid-resistant backing construction and process of manufacture |
| CN101838508A (en) * | 2010-05-27 | 2010-09-22 | 湖州思伊淀粉工业有限公司 | Preparation method of starch base paper packing adhesive |
| CN203097126U (en) * | 2013-03-21 | 2013-07-31 | 邬文倩 | Composite plate |
| CN203441040U (en) * | 2013-09-05 | 2014-02-19 | 辽宁辽杰科技有限公司 | Structural board |
| CN104131668A (en) * | 2014-07-18 | 2014-11-05 | 张家港市盛港新型建材科技有限公司 | Ecological fireproof interior trimming plate and manufacturing method of ecological fireproof interior trimming plate |
-
2016
- 2016-12-31 CN CN201611268289.0A patent/CN106671536B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040043184A1 (en) * | 2002-08-27 | 2004-03-04 | Seiin Kobayashi | Flooring article with soft, skid-resistant backing construction and process of manufacture |
| CN101838508A (en) * | 2010-05-27 | 2010-09-22 | 湖州思伊淀粉工业有限公司 | Preparation method of starch base paper packing adhesive |
| CN203097126U (en) * | 2013-03-21 | 2013-07-31 | 邬文倩 | Composite plate |
| CN203441040U (en) * | 2013-09-05 | 2014-02-19 | 辽宁辽杰科技有限公司 | Structural board |
| CN104131668A (en) * | 2014-07-18 | 2014-11-05 | 张家港市盛港新型建材科技有限公司 | Ecological fireproof interior trimming plate and manufacturing method of ecological fireproof interior trimming plate |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107338657A (en) * | 2017-07-12 | 2017-11-10 | 合肥信亚达智能科技有限公司 | A kind of preparation method of novel environment friendly ornament materials |
| CN109233686A (en) * | 2018-08-06 | 2019-01-18 | 安徽省神洲建材科技有限公司 | A kind of processing method of high performance and long service life ornament materials |
| CN113480298A (en) * | 2021-07-29 | 2021-10-08 | 景德镇陶瓷大学 | Preparation and application method of high-whiteness high-transmittance high-plasticity ceramic blank mud |
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| Publication number | Publication date |
|---|---|
| CN106671536B (en) | 2018-07-27 |
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Granted publication date: 20180727 Termination date: 20201231 |