CN106661155A8 - 用单位点催化剂制备的乙烯共聚物 - Google Patents

用单位点催化剂制备的乙烯共聚物 Download PDF

Info

Publication number
CN106661155A8
CN106661155A8 CN201580044306.XA CN201580044306A CN106661155A8 CN 106661155 A8 CN106661155 A8 CN 106661155A8 CN 201580044306 A CN201580044306 A CN 201580044306A CN 106661155 A8 CN106661155 A8 CN 106661155A8
Authority
CN
China
Prior art keywords
ethylene copolymer
single site
copolymer prepared
site catalysts
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201580044306.XA
Other languages
English (en)
Other versions
CN106661155B (zh
CN106661155A (zh
Inventor
S.戈亚尔
B.吉龙
S.萨罗蒙斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Original Assignee
Nova Chemicals International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA filed Critical Nova Chemicals International SA
Publication of CN106661155A publication Critical patent/CN106661155A/zh
Publication of CN106661155A8 publication Critical patent/CN106661155A8/zh
Application granted granted Critical
Publication of CN106661155B publication Critical patent/CN106661155B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/327Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/548Creep
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • B32B2307/5825Tear resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/46Bags
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/62Boxes, cartons, cases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/04Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26Use as polymer for film forming
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

本文所述的本发明的实施方案涉及适合在封装制品、柔韧性膜和/或片材的制造中使用的聚乙烯聚合物组合物。在一个实施方案中,所述共聚物包含具有0.918g/cm3-约0.935g/cm3的密度、如由在190℃下的动态力学分析所测定的小于40Pa的在G"(500Pa)下的G'值、大于2的Mz/Mw、大于60的CDBI50的聚乙烯树脂。其他实施方案涉及适合在具有改善的抗蠕变性和高韧性及在单层和/或多层膜结构中膜刚性和可加工性的良好平衡的包括膜、片材、袋子和口袋的制品的制造中使用的具有限定的分子特征的聚合物组合物和制剂。
CN201580044306.XA 2014-08-19 2015-08-06 用单位点催化剂制备的乙烯共聚物 Active CN106661155B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462038971P 2014-08-19 2014-08-19
US62/038,971 2014-08-19
PCT/IB2015/055989 WO2016027193A1 (en) 2014-08-19 2015-08-06 Ethylene copolymers produced with single site catalyst

Publications (3)

Publication Number Publication Date
CN106661155A CN106661155A (zh) 2017-05-10
CN106661155A8 true CN106661155A8 (zh) 2017-07-11
CN106661155B CN106661155B (zh) 2021-05-28

Family

ID=53872113

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580044306.XA Active CN106661155B (zh) 2014-08-19 2015-08-06 用单位点催化剂制备的乙烯共聚物

Country Status (12)

Country Link
US (2) US10239976B2 (zh)
EP (1) EP3183276B1 (zh)
JP (1) JP6521405B2 (zh)
KR (1) KR102374856B1 (zh)
CN (1) CN106661155B (zh)
BR (1) BR112017003299B1 (zh)
CA (1) CA2957051C (zh)
DK (1) DK3183276T3 (zh)
ES (1) ES2788950T3 (zh)
MX (1) MX2017001925A (zh)
TW (1) TWI557140B (zh)
WO (1) WO2016027193A1 (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI557140B (zh) * 2014-08-19 2016-11-11 努發化工(國際)公司 使用單活性中心催化劑產生之乙烯共聚物
CA2871463A1 (en) * 2014-11-19 2016-05-19 Nova Chemicals Corporation Passivated supports: catalyst, process and product
US20190322088A1 (en) 2017-01-26 2019-10-24 Exxonmobil Chemical Patents Inc. Multilayer Films and Methods of Making the Same
CN111183160B (zh) 2017-10-06 2022-06-10 埃克森美孚化学专利公司 聚乙烯挤出物及其制备方法
CN111057172A (zh) * 2018-10-17 2020-04-24 中国石油天然气股份有限公司 辛烯改性线性低密度聚乙烯树脂、包含其的多层共挤包装膜及其制备方法
CN115380070A (zh) * 2020-03-31 2022-11-22 普瑞曼聚合物株式会社 乙烯系树脂组合物和膜
CN115521522A (zh) * 2022-09-14 2022-12-27 金发科技股份有限公司 一种聚烯烃组合物及其制备方法和应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2245375C (en) * 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
CA2411183C (en) * 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
GB0319467D0 (en) * 2003-08-19 2003-09-17 Bp Chem Int Ltd Polymer blends
US20060247373A1 (en) * 2005-04-28 2006-11-02 Nova Chemicals (International) S.A. Dual reactor polyethylene resins for electronic packaging-films, tapes, bags and pouches
JP2007002006A (ja) * 2005-06-21 2007-01-11 Hitachi Chemical Filtec Inc 表面保護フィルム及びその製造法
JPWO2009020116A1 (ja) 2007-08-09 2010-11-04 コニカミノルタオプト株式会社 光学用樹脂材料及びそれを用いた光学素子
EP2177548A1 (en) * 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
JP2011006676A (ja) * 2009-05-29 2011-01-13 Sumitomo Chemical Co Ltd フィルム用エチレン−α−オレフィン共重合体、フィルムおよび食品包装用フィルム
CA2688217C (en) * 2009-12-11 2016-07-12 Nova Chemicals Corporation Multi reactor process
CA2798855C (en) * 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US9115233B2 (en) * 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
KR102121298B1 (ko) * 2012-12-14 2020-06-11 노바 케미컬즈 (인터내셔널) 소시에테 아노님 에틸렌 공중합체 조성물, 필름 및 중합 방법
CA2809718C (en) * 2013-03-15 2020-03-24 Nova Chemicals Corporation Improved energy utilization in a solution polymerization plant
KR101568186B1 (ko) * 2014-01-06 2015-11-11 대림산업 주식회사 에틸렌과 알파-올레핀의 중합 장치 및 제조방법
TWI617588B (zh) * 2014-08-19 2018-03-11 努發化工(國際)公司 使用單活性中心催化劑生產之極低密度聚乙烯
TWI557140B (zh) * 2014-08-19 2016-11-11 努發化工(國際)公司 使用單活性中心催化劑產生之乙烯共聚物

Also Published As

Publication number Publication date
US20190161569A1 (en) 2019-05-30
EP3183276A1 (en) 2017-06-28
JP2017527662A (ja) 2017-09-21
CA2957051C (en) 2022-05-17
US20170233512A1 (en) 2017-08-17
MX2017001925A (es) 2017-04-27
TW201619214A (zh) 2016-06-01
ES2788950T3 (es) 2020-10-23
DK3183276T3 (da) 2020-06-02
EP3183276B1 (en) 2020-04-15
JP6521405B2 (ja) 2019-05-29
KR102374856B1 (ko) 2022-03-16
CN106661155B (zh) 2021-05-28
TWI557140B (zh) 2016-11-11
BR112017003299A2 (pt) 2017-11-28
WO2016027193A1 (en) 2016-02-25
US11053332B2 (en) 2021-07-06
CA2957051A1 (en) 2016-02-25
KR20170046152A (ko) 2017-04-28
CN106661155A (zh) 2017-05-10
BR112017003299B1 (pt) 2021-11-30
US10239976B2 (en) 2019-03-26

Similar Documents

Publication Publication Date Title
CN106661155A8 (zh) 用单位点催化剂制备的乙烯共聚物
MX2017004922A (es) Articulos que comprenden pelicula de alcohol polivinilico soluble en agua con mezcla de plastificante y metodos relacionados.
WO2011077280A3 (en) Biodegradable and breathable film
BR112018003571A2 (pt) folha ou película de barreira, material de embalagem laminado, e, recipiente de embalagem
MX2017001711A (es) Polietileno de muy baja densidad producido con catalizador de un solo sitio.
MX2018006965A (es) Peliculas multicapa adecuadas para usarse en aplicaciones de termoformado.
BR112016027027A8 (pt) material compósito, composição de adesivo estrutural, e, método para fabricar um laminado compósito
WO2012019083A3 (en) Biosensor membrane composition, biosensor, and methods for making same
MX2017004563A (es) Metodo para incrementar la resistencia volumetrica del papel al usar copolimeros de dialilamina-acrilamida en una prensa de encolado de una formulacion que contiene almidon.
MX2014008014A (es) Peliculas o lamina de polimero de olefina ciclica de capas multiples coextrudido que tienen barrera mejorada contra vapor de humedad.
TW200734175A (en) Composite sheet and usage thereof
MX2012014835A (es) Composiciones de polimero a base de etileno para utilizarse como un componente de combinacion en aplicaciones de pelicula de contraccion.
MY161385A (en) Photodegradable films with good tensile and dart properties
RU2017124446A (ru) Эластичный ламинат и содержащее его изделие
NZ727575A (en) Multilayer heat shrinkable films
JP2013023516A5 (zh)
WO2012007857A3 (en) Biodegradable blends and films having nano-structural features
AR102910A1 (es) Materiales adhesivos fundibles para láminas de poliolefina
MX2017011183A (es) Peliculas protectoras, mezclas, y metodos de fabricacion de las mismas.
MX2018007235A (es) Peliculas que contienen nutrientes o componentes para usarse por el suelo o plantas.
MY171762A (en) Ethylene-vinylalcohol resin composition, molded product, and multilayer structure
RU2014136807A (ru) Шина
RU2014144629A (ru) Пневматическая шина с каучуковым компонентом, содержащим композитный материал из термопластичного полимера и наполнителя
MY179653A (en) Resin composition and sheet-shaped molded body thereof
MY186918A (en) Films, and related compositions and methods of making

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CI01 Publication of corrected invention patent application
CI01 Publication of corrected invention patent application

Correction item: Priority

Correct: 62/038,971 2014.08.19 US

Number: 19

Volume: 33

CI02 Correction of invention patent application
CI02 Correction of invention patent application

Correction item: Priority

Correct: 62/038,971 2014.08.19 US

Number: 19

Page: The title page

Volume: 33

GR01 Patent grant
GR01 Patent grant