CN106659672A - Composition in form of emulsion - Google Patents

Abstract

A composition in form of an emulsion is provided, which comprising at least one fatty phase, at least one aqueous phase, and a)a combination of at least two surfactants chosen from the group consisting of: i)C 8-C 22 alkyl dimethicone copolyols; ii)dimethicone copolyols, which is different from i); iii) poly oxyalkylenated silicone elastomers, which is different from i) or ii); iv) or a mixture thereof; b)at least one third surfactant, different from the surfactant a),chosen from polydialkyl silicones containing polyglycerol or glycerol side and/or end groups; and c)at least one pigment.

Description

The composition of emulsion form

Technical field

The present invention relates to composition, is particularly useful for the cosmetics of nursing/cosmetic keratin material (especially skin and lip) Composition, the more specifically cosmetic composition of emulsion types, it shows optimized washable property effect, while keeping good Dressing effect.

Background technology

Cosmetic composition for keratin material of nursing/make up (especially skin and lip, more specifically skin) is also referred to as For foundation cream, flaw product or coloured emulsifiable paste are hidden, be commonly used to give skin (such as face) color attractive in appearance, lacked to shelter skin Fall into, such as rubescent and spot.

Several centuries, the consumer of the whole world (especially in Asia) is seeking novel cosmetic product, for improving angle egg The outward appearance of white material (and especially skin), especially appearance (uneven in visible and/or sense of touch) and/or skin complexion, The colour of skin is the outward sign of (healthy glow) radiant, health and youth.

Can be by realizing these targets to dermal administration routine foundation cream.

US2005/0008592 discloses the foundation cream of water in oil emulsion formula of liquid, and it includes fatty phase, water phase, selected from poly- C₈- C₂₂Alkyl dimethicone copolyol (C₈-C₂₂Alkyl demethicone copoyol) at least one surfactant, Selected from the volatile oil of other surfactants of at least one of dimethicone copolyol and a large amount of (more than 6%) Mixture.

US2005/0002890 also discloses that the liquid cosmetic composition of water-in-oil emulsion form, and it includes liquid aliphatic Phase, water phase, dimethicone copolyol and poly- C₈-C₂₂Alkyl dimethicone copolyol, is characterised by that it is included poly- Methyl methacrylate solid particle, and liquid aliphatic is characterised by mutually comprising the ethereal oil based on hydrocarbon, the composition is not Containing cyclotetrasiloxane.

However, such conventional products cause the worry of consumer's following aspect：First, the pigment in foundation cream may cause The blockage problem of skin pores；Secondly, remove foundation cream to expend the time and cause Keratoderma；3rd, or even after using makeup removing Still retain residue on skin.

Therefore, for the novel composition for solving the above problems has demand.

Develop conventional oil-in-water foundation/coloured emulsifiable paste to solve washable sex chromosome mosaicism.However, this based composition is only Can partly be removed by water, therefore show the washable property of difference.Additionally, such composition lacks lasting dressing effect, This is attributed to its hydrophilic nmature.

Therefore, for following aspect remains demand：It was found that stable nursing and/or cosmetic product, it shows optimization Washable property effect, while with good dressing effect, such as uniform and lasting dressing effect.

The content of the invention

Such composition can be obtained by using following material：Selected from the group of at least two following surfactants Close：C₈-C₂₂The alkyl dimethicone copolyol polydimethylsiloxanes different from above-mentioned dimethicone copolyol Alkane copolyol and/or the polyoxyalkylenated siloxanes (poly different from above-mentioned dimethicone copolyol Oxyalkylenated silicone) elastomer；At least one 3rd surfactant, its group with above-mentioned surfactant Close different, and at least one pigment.

Therefore, according in a first aspect, subject of the present invention is the composition of emulsion form, it includes at least one fat Phase, at least one water phase and：

A) selected from the combination of at least two following surfactants:

i)C₈-C₂₂Alkyl dimethicone copolyol；

Ii) dimethicone copolyol, its from it is i) different；

Iii) polyoxyalkylenated silicone elastomer, its from i) or ii) it is different；

) or its mixture iv；

B) at least one 3rd surfactant, it is different from surfactant a), selected from containing polyglycereol or glycerine side The polydialkysiloxane of base and/or end group；With

C) at least one pigment.

According to preferred embodiment, the composition of the present invention is multi-phase emulsion form, for example water-in-oil-in-water compositions or Oil in water in oil emulsion, preferred oil in water in oil emulsion.

Preferably, composition of the invention includes at least one other surfactant, its with surfactant a) and B) it is different.

In a preferred embodiment, the present invention includes at least one organic or mineral filler, its be selected from modified starch or Unmodified starch, such as preferred modified starch, acetylated oxidized starch.

According to preferred embodiment, the present invention includes at least one polymer viscosifier or mineral thickener, and its is preferred Selected from hydrophilic thickeners, lipophilicity thickener or its mixture.It is highly preferred that the thickener is selected from polysaccharide biopolymerization Thing, lipophilicity clay, hydrophobic silica or its mixture, it is highly preferred that the thickener is selected from xanthans, distearyl two First ammonium hectorite (disteardimonium hectorite), silica silylate (silica silylate) or Its mixture.

In another aspect, the invention further relates to be used to nursing/method of cosmetic skin (especially face), be characterised by it Including at least one composition of the invention of dermal administration.

As described above the present invention is stable with the time under room temperature (25 DEG C), for example, stable after storing 2 months, And it is further stable for example after storing 4 months.

The present invention provides good dressing effect for skin, such as the uniform dressing effect on skin, and on skin Lasting dressing effect.

More importantly, the present invention has optimized washable property property.

With regard to " washable property ", it is intended to represent that, when it is washed off from skin using water, this composition is washed Ability.

Detailed description of the invention

According to the present invention, the composition of emulsion form comprising at least one fat phase, at least one water phase and：

A) selected from the combination of at least two following surfactants:

i)C₈-C₂₂Alkyl dimethicone copolyol；

Ii) dimethicone copolyol, its from it is i) different；

Iii) polyoxyalkylenated silicone elastomer, its from i) or ii) it is different；

) or its mixture iv；

B) at least one 3rd surfactant, it is different from surfactant a), selected from containing polyglycereol or glycerine side The polydialkysiloxane of base and/or end group；With

C) at least one pigment.

Fatty phase

Composition of the invention includes at least one fat phase, and it contains at least one oil.

Preferably, according to a kind of embodiment, the composition of the present invention is comprising at least two fatty phases.

Term " oil " represents any fat composition in liquid form under room temperature (20-25 DEG C) and atmospheric pressure (760mmHg) Matter.

The one or more of fat for being suitable for preparing cosmetic composition of the invention mutually can be comprising based on hydrocarbon Oil, silicone oil (silicone oils), fluorine-containing oil (fluoro oil) or without fluorocarbon oil (non-fluoro oil) or its Mixture.

The oil can be volatile or nonvolatile.

According to preferred embodiment, if existing, the ratio between ethereal oil and nonvolatile oil be more than or wait In 1:3, more preferably equal to or greater than 1:1.They can derive from animal, plant, mineral or synthesis.

Term " nonvolatile oil " is represented and is retained in keratin material under room temperature (20-25 DEG C) and atmospheric pressure (760mmHg) Oil on material (especially skin and lip).More specifically, nonvolatile oil has strictly less than 0.01mg/cm²The evaporation of/min Speed.

In order to measure the evaporation rate, 15g oil or oil mixture to be tested are placed on into the crystallising dish of a diameter of 7cm In, the crystallising dish is placed on into about 0.3m³Big chamber in balance on, the chamber through temperature adjustment, in 25 DEG C At a temperature of, and through humidity regulation, under 50% relative humidity.Liquid is allowed freely to evaporate and be not stirred to it, Fan (Papst-Motoren, reference number 8550N, with 2700rpm rotations) is relied on to provide ventilation simultaneously, the fan is placed on Accommodate the upright position above the crystallising dish of described oily or described oil mixture：Blade towards crystallising dish, apart from the bottom of crystallising dish Portion 20cm.At regular intervals come measure be retained in crystallising dish it is described oil or oil mixture quality.Evaporation rate is used Per unit area (cm²) and the oily milligram number that evaporated of time per unit (minute) representing.

Term " ethereal oil " is represented under room temperature (20-25 DEG C) and atmospheric pressure (760mmHg) with keratin material (especially Skin and lip) contact when, can be less than any non-aqueous media evaporated in a hour.The ethereal oil is cosmetic Product ethereal oil, it is at room temperature liquid.More specifically, ethereal oil has 0.01mg/cm²/ min～200mg/cm²/min The evaporation rate of (including bound).

For the present invention, term " silicone oil " is represented and includes at least one silicon atom, especially at least one Si-O base The oil of group.

Term " fluorine-containing oil " represents the oil comprising at least one fluorine atom.

Term " oil based on hydrocarbon " represents the oil for mainly containing hydrogen and carbon atom.

As the oil based on hydrocarbon, can be mentioned that：

Animal origin based on the oil of hydrocarbon, the oil based on hydrocarbon of plant origin；

The straight-chain hydrocarbons or branched-chain hydrocarbons of mineral or synthesis source；

Synthesis ether containing 10～40 carbon atoms；

Synthetic ester；

Fatty alcohol, it is at room temperature liquid, and with the branched and/or undersaturated chain based on carbon, the chain contains 12～26 carbon atoms；

C₁₂-C₂₂Higher fatty acids；With

Its mixture.

Can be mentioned that based on the oil of hydrocarbon, such as liquid paraffin and its derivant；Vaseline；Poly decene；Polybutene；Hydrogenation is poly- different Butylene, such as Parleam；And saualane, such as by standing grain big (Croda) sale, can be with trade mark Pripure 3759-LQ- (GD) saualane for obtaining.

The oil can optionally include oxygen, nitrogen, sulphur and/or phosphorus atoms, for instance in hydroxyl or the form of acid groups.

According to preferred embodiment, the composition of the present invention further includes silicone oil.

As silicone oil, can be mentioned that：

- linear or ring-type ethereal oil, especially viscosity are less than or equal to 8 centistokes (cSt) (8 × 10^-6m²/ s), and especially Those containing 2～10 silicon atoms (especially 2～7 silicon atoms), these siloxanes (silicones) optionally contain 1 The alkyl or alkoxyl of～10 carbon atoms；

- linear or ring-type non-volatile dimethicones (PDMS)；Comprising side joint in siloxane chain or positioned at silicon The dimethyl silicone polymer of the alkyl, alkoxyl or phenyl (these groups contain 2～24 carbon atoms) of the end of oxygen alkane chain；

- phenyl siloxane, such as phenyl trimethicone (phenyl trimethicones), phenyl poly dimethyl Siloxanes (phenyl dimethicones), phenyl trimethicone siloxy diphenyl siloxane, diphenyl poly dimethyl silicon Oxygen alkane (diphenyl dimethicones), diphenyl methyl diphenyl trisiloxanes and 2- phenylethyl trimethyl silyls Epoxide esters of silicon acis；With

- its mixture.

In special embodiment, the siloxanes of ring six is can be mentioned that, it such as can be sold by SHIN-ETSU HANTOTAI (Shin Etsu) company The KF-996 that sells or by DOW CORNING (Dow Corning) CompanyThe trade mark of PMX-0246 etc is obtained； Or dimethyl silicone polymer, it can following trade mark acquisition：By DOW CORNING (Dow Corning) Company PMX-200silicone fluid 5cs、PMX-200silicone fluid 350cs or PMX-200silicone fluid10cs。

Preferably, composition can be comprising fatty phase, and relative to the gross weight meter of composition, it is present in group with following content In compound：1 weight %～50 weight %, preferably 2 weight %～40 weight %, more preferably 5 weight %～35 weight %.

Water phase

Composition of the invention includes at least one water phase.

Water mutually includes water.

Water mutually can also include miscible organic solvents (under 20-25 DEG C of room temperature), such as containing 2～6 carbon atoms Monohydric alcohol, such as ethanol or isopropanol；Especially (preferably comprise 2～10 carbon atoms, and preferentially containing 2～20 carbon atoms Containing 2～6 carbon atoms) polyalcohol, for example glycerine, propane diols, butanediol, pentanediol, hexylene glycol, dipropylene glycol or Diethylene glycol (DEG)；Glycol ether (especially containing 3～16 carbon atoms), such as MPG (C₁-C₄) alkyl ether, dipropylene glycol (C₁-C₄) alkyl ether or tripropylene glycol (C₁-C₄) alkyl ether, monoethylene glycol (C₁-C₄) alkyl ether, diethylene glycol (DEG) (C₁-C₄) alkyl Ether or triethylene glycol (C₁-C₄) alkyl ether and its mixture.

Water mutually can also include stabilizer, such as sodium chloride, magnesium dichloride or magnesium sulfate.

Especially, composition of the invention can bag aqueous phase, relative to the gross weight meter of composition, its content is 1 weight % ～90 weight %, especially 5 weight %～80 weight %, more specifically 10 weight %～75 weight %.

A) combination of surfactant

The composition of the present invention includes at least two combinations for being selected from following surfactant:

i)C₈-C₂₂Alkyl dimethicone copolyol；

Ii) dimethicone copolyol, its from it is i) different；

Iii) polyoxyalkylenated silicone elastomer, its from i) or ii) it is different；

) or its mixture iv.

According to the embodiment, relative to the gross weight meter of composition, the amount of the combination a) of surfactant is 0.1 Weight %～20 weight %, especially 0.5 weight %～10 weight %, more specifically 1 weight %～8 weight %.

i)C₈-C₂₂Alkyl dimethicone copolyol

The C being present in composition of the invention₈-C₂₂Alkyl dimethicone copolyol is oxypropylation And/or the poly- methyl (C of oxyethylation₈-C₂₂) alkyl-dimethyl methyl siloxane.

C₈-C₂₂Alkyl dimethicone copolyol is advantageously the compound of lower formula (I)：

Wherein：

- PE represents (- C₂H₄O)_x-(C₃H₆O)_y, selected from hydrogen atom and the alkyl of 1～4 carbon atom, x is 0～100 for-R, R, And y is 0 when being 0～80, x different with y,

- m is 1～40,

- n is 10～200,

- o is 1～100,

- p is 7～21,

- q is 0～4,

And preferably：

R=H,

M=1～10,

N=10～100,

O=1～30,

P=15,

Q=3.

As C₈-C₂₂Alkyl dimethicone copolyol, can be mentioned that Abil EM 90, example Such as cetyl dimethicone and the copolyol of the alkoxy derivative of dimethyl silicone polymer, more preferably such as spermaceti Base PEG/PPG-10/1 dimethyl silicone polymers, such as by Gao Shi meter Te (Goldschmidt) company with titleEM-90 The product of sale.

C₈-C₂₂Amount of the alkyl dimethicone copolyol in composition of the invention can be relative In the gross weight meter of emulsion, 0.1 weight %～19.9 weight %, especially with respect to the gross weight meter of composition, 0.5 weight %～ 10 weight %, even better is 1 weight %～5 weight %.

Ii) dimethicone copolyol

With above-mentioned i) C present in composition of the invention₈-C₂₂Alkyl dimethicone copolymerization The different dimethicone copolyol of alcohol is the poly dimethyl methylsiloxane of oxypropylation and/or oxyethylation.

As dimethicone copolyol, it is possible to using corresponding to lower formula (II) those：

Wherein：

R₁、R₂、R₃C is represented independently of one another₁-C₆Alkyl or group-(CH₂)_x-(OCH₂CH₂)_y-(OCH₂CH₂CH₂)_z-OR₄, At least one group R₁、R₂Or R₃It is not alkyl；R₄For hydrogen, C₁-C₃Alkyl or C₂-C₄Acyl group；

A is 0～200 integer；

B is 0～50 integer；Condition is equal to 0 when being A different with B；

X is 1～6 integer；

Y is 1～30 integer；

Z is 0～5 integer.

Preferred embodiment of the invention, in the compound of formula (II), R₁=R₃=methyl, x be 2～6 it is whole Number, and y is 4～30 integer.R₄Especially hydrogen.

As the example of formula (II) compound, formula (III) compound is can be mentioned that：

Wherein A is 20～105 integer, and B is 2～10 integer, and y is 10～20 integer.

As the example of the silicone compounds of formula (II), formula (IV) compound is can be mentioned that：

HO-(CH₂CH₂O)_y-(CH₂)₃-[(CH₃)₂SiO]_A’-[(CH₃)₂Si]-(CH₂)₃-(OCH₂CH₂)_y-OH

(IV)

Wherein A ' and y are 10～20 integers.

The dimethicone copolyol that can be used is included by DOW CORNING (Dow Corning) company with title 5329、7439-146、Those of 2-5695 and Q4-3667 sale；By SHIN-ETSU HANTOTAI (Shin-Etsu) company with title Those of KF-6013, KF-6015, KF-6016, KF-6017 and KF-6028 sale.

Compound5329、7439-146、2-5695 is formula (III) compound, wherein respectively, A Be 22, B be 2 and y be 12；A be 103, B be 10 and y be 12；A be 27, B be 3 and y be 12.

Advantageously, dimethicone copolyol is can be mentioned that, it is selected from PEG poly dimethyls siloxy ethyl poly- two Methylsiloxane, the KF6017 for example sold with trade mark KF-6017 by (Shin-Etsu) company of SHIN-ETSU HANTOTAI And/or with trade mark KF-6028 sell PEG-9 poly dimethyl siloxy ethyl dimethyl silicone polymers (and) PEG-9.

Amount of the dimethicone copolyol in emulsion of the invention can be relative to the total of composition Weight meter, 0.1 weight %～19.9 weight %, preferably with respect to the gross weight meter of composition, 0.5 weight %～10 weight %, And preferably 0.8 weight %～5 weight %.

Iii) polyoxyalkylenated silicone elastomer

Emulsify polyoxyalkylenated silicone elastomer non-limiting examples be included in U.S. Patent No. 5,236,986, Those disclosed in 5th, 412, No. 004, the 5th, 837, No. 793 and the 5th, 811, No. 487, are incorporated to these patents by quoting Herein.It is preferred that these silicone elastomers are prepared in alkymer and/or silicone oil by the form of gel.In those gels In, the form of the generally spherical particle of polyoxyalkylenated silicone elastomer.

The example of polyoxyethylated silicone elastomer includes following composition：

A) it is available from SHIN-ETSU HANTOTAI (Shin Etsu)：

- KSG-16 dimethyl silicone polymers (and) Dimethicone/Vinyl Dimethicone copolymerzation with cross-linking Thing；

- KSG-21 (active material accounts for 27%) INCI titles：Dimethyl silicone polymer/KF6017 second Thiazolinyl Dimethicone Crosspolymer)；

- KSG-20 (active material accounts for 95%) INCI titles：KF6017 cross-linked polymer)；

- KSG-30 (active material accounts for 100%) INCI titles：Lauryl PEG-15 dimethyl silicone polymer vinyl poly- two Methylsiloxane cross-linked polymer)；

- KSG-31 (active material accounts for 25%) INCI titles：Lauryl PEG-15 dimethyl silicone polymer vinyl poly- two Methylsiloxane cross-linked polymer)；

- KSG-32 or KSG-42 or KSG-320 or KSG-30 (active material accounts for 25%) INCI titles：Lauryl PEG-15 Dimethyl silicone polymer vinyl dimethicone cross polymer)；

-KSG-33：Lauryl PEG-15 (active material accounts for 20%) dimethyl silicone polymer vinylpolydimethyl silica Alkane cross-linked polymer)；

- KSG-210 (active material accounts for 25%) INCI titles：Dimethyl silicone polymer/PEG-10/15 cross-linked polymers)；

-KSG-310：The polyoxyethylated dimethyl silicone polymer that lauryl in mineral oil is modified；

- KSG-330 and KSG-340:PEG-15/ lauryl dimethicone cross-linked polymers；

- X-226146 (active material accounts for 32%) INCI titles：Dimethyl silicone polymer/KF6017 Vinyl dimethicone cross polymer)；With

B) it is available from DOW CORNING (Dow Corning)：

- DC 9010 (active material accounts for 9%) and DC9011 (active material accounts for 11%) INCI titles：The poly- diformazans of PEG-12 Radical siloxane cross-linked polymer)；

The D5s of-DC 9040 (and) Dimethicone Crosspolymer；

The dimethyl silicone polymers of-DC 9041 (and) Dimethicone Crosspolymer；Deng

With its mixture.

Form of the above product typical case in the oil-base gel containing silicone elastomer particles.

In embodiments, using KSG-210 (INCI titles：Dimethyl silicone polymer/PEG-10/15 cross-linked polymers, 25% active silicone elastomer in silicone oil).

Amount of the polyoxyalkylenated silicone elastomer in emulsion of the invention can be relative to composition Gross weight meter, 0.1 weight %～19.9 weight %, preferably 0.5 weight %～15 weight %, more preferably 1 weight %～10 weight Amount %.

B) the 3rd surfactant

The composition of the present invention includes at least one 3rd surfactant.3rd surfactant is lived with above-mentioned a) surface Property agent combination it is different.

According to the present invention, the 3rd surfactant is selected from containing polyglycereol side base and/or end group or glycerine side base and/or end The polydialkysiloxane of base.

These silicone surfactants further preferably C comprising straight or branched₁～C₂₀Pendent alkyl groups, further preferably straight chain alkane Base, such as lauryl or cetyl.Similarly, these siloxanes and glycerinated surfactant can also carry organosiloxane Side base.

Especially can be mentioned that in this classification：

- dimethyl silicone polymer, it contains polyglycereol side base, such as by SHIN-ETSU HANTOTAI (Shin Etsu) company with title KF- The disiloxane dimethyl silicone polymer of polyglyceryl -3 of 6100 sale；

- branched polydimethylsiloxanes, it contains polyglycereol side base, such as by SHIN-ETSU HANTOTAI (Shin Etsu) company with title The disiloxane poly dimethyl siloxy ethyl dimethyl silicone polymer of polyglyceryl -3 of KF-6104 sale；

- branched polydimethylsiloxanes, it contains polyglycereol side base and pendent alkyl groups, such as by SHIN-ETSU HANTOTAI (Shin Etsu) The poly dimethyl siloxy ethyl dimethyl silicone polymer of lauryl polyglyceryl -3 that company is sold with title KF-6105；

In embodiments, using KF-6100 (INCI titles：The disiloxane dimethyl silicone polymer of polyglyceryl -3).

Relative to the gross weight meter of composition, amount of the 3rd surfactant in emulsion of the invention can be with For 0.1 weight %～20 weight %, preferably 0.5 weight %～15 weight %, and preferably 1 weight %～10 weight %.

C) pigment

Composition of the invention includes at least one pigment.

" pigment " is white or coloured, organic or inorganic, hydrophily or hydrophobic non-interfering particle, and its is insoluble In aqueous medium and non-aqueous media, and it is intended to colour composition.

The inorganic pigment that can be used in the present invention includes the oxide or dioxide of titanium, zirconium or cerium；Also zinc, iron or chromium Oxide；It is Prussian blue；Manganese violet；Ultramarine blue and chromium hydroxide；And its mixture.

The organic pigment that can be used in the present invention includes D＆C pigment；Color lake based on alkermes；And based on barium, strontium, The color lake of calcium or aluminium；Or it is described in document EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/08537 In diketopyrrolopyrrolecocrystals (DPP).

According to preferred embodiment, the composition of the present invention is processed or undressed hydrophily comprising at least one Jing Or hydrophobic inorganic pigment.

Hydrophily pigment can be conventional use of in cosmetic field or available any types, example bag Include the hydrophily pigment of unprocessed state, or can be or its mixture through the pigment of hydrophilized surface process.

Advantageously, hydrophilic pigment of the invention is that Jing is processed or undressed ferriferous oxide and/or titanium titanium dioxide Thing.

During using undressed pigment, the pigment is selected, it is preferred to have so as to relatively large particle mean size There is 0.1～50 μm, more preferably 0.1～30 μm, even more preferably 0.1～20 μm of particle mean size.

In special embodiment, hydrophily pigment is undressed inorganic pigment, preferably undressed metal Oxide, such as titanium oxide and/or iron oxide.

Can be mentioned that for example from Sha Haliben (SACHTLEBEN), with the product that trade name HOMBITAN FF PHARMA sell Product；By the sun (SUN) company with trade name Sunpuro^TMIron oxide red C33-8001 (INCI title iron oxide R), Sunpuro^TM Iron oxide black C33-7001 (INCI title iron oxide B) or Sunpuro^TMIron oxide yellow C33-9001 (INCI title iron oxide Y) The product of sale.

In another kind of special embodiment, hydrophily pigment is the hydrophily pigment that Jing is processed, i.e. with any Inorganic agent carries out the pigment of hydrophilized surface process, and the inorganic agent has been conventionally used for giving pigment hydrophilic nmature.Generally, use In finish materials, so that the hydrophily organic reagent for making its being optimal of dispersion in an aqueous medium is more specifically selected from Biopolymer, carbohydrate, polysaccharide, polyacrylate and polyethyleneglycol derivative.Insoluble in solvent medium (such as water) Material Jing be processed as being dispersed in wherein.As according to the present invention for coating the biopolymer of dyestuff to be dissolved Example, can be mentioned that the polymer based on carbohydrate type monomer.More specifically, biological carbohydrate gum, shitosan be can be mentioned that and its is spread out Biology, such as butoxy shitosan, carboxymethyl chitosan, carboxylic butyl shitosan, shitosan gluconate, shitosan adipic acid Salt, shitosan glycollate, chitosan lactate etc.；Chitin and its derivative, such as carboxymethyl chitin, chitin ethanol Hydrochlorate；Cellulose and its derivates, such as cellulose acetate, microcrystalline cellulose；Di(2-ethylhexyl)phosphate starch；Sodium Hyaluronate；It is soluble Proteoglycans；Galactolipin-araban；Glucosaminoglycan；Glycogen；Sclerotium gum；Glucan；Starch and its derivative；And its Mixture.But it is also possible that using such as in silica-treated, alumina treatment, silica alumina process or oxidation By the pigment of surface treatment agent process in titanium process.

In the present invention, silica and silica (and) alumina treatment is especially preferred selection, and at this Reason itself is in the art conventional.

Such pigment is can be mentioned that, such as by JGC Catalysts and Chemicals companies with trade name Sympholight WW (INCI titles titanium dioxide and silica and aluminum oxide), Sympholight RW-S (INCI titles Iron oxide and silica), Sympholight BW-S (INCI titles iron oxide and silica), Sympholight YW-S The product of (INCI titles iron oxide and silica) sale.Advantageously, composition of the invention comprising selected from it is following at least The hydrophily pigment that a kind of Jing is processed：The titanium dioxide of silica and alumina treatment, the titanium oxide of silica-treated or Its mixture.

According to another preferred embodiment, the present invention is processed or undressed hydrophobicity face comprising at least one Jing Material.

Will be more specifically (outstanding selected from the titanium oxide and ferriferous oxide processed with least one water-repelling agent using inorganic pigment Its yellow, black and redness).

The present invention the preferred Jing water-repelling agents of pigment (more specifically Jing fluorine, aliphatic acid or amino acid or silicone compounds or Its mixture) it is surface-treated wholly or in part.

Their initial particle size D [0.5] is especially less than 20 μm, preferably 0.4～10 μm (including end points).

As an example, water repellent agent may be selected from aliphatic acid, such as stearic acid；Metallic soap, such as two aluminium myristates and The aluminium salt of h-tallow glutamic acid (hydrogenated tallow glutamate)；Phosphoric acid perfluoroalkyl ester and poly- hexafluoro oxygen Change propylene；PFPE；Amino acid；N- acylamino acids or its salt；Lecithin；Three isostearic acid isopropyl titanates (isopropyl trisostearyl titanate)；The different stearyl ester of decanedioic acid；And silicone compounds, such as poly- diformazan Radical siloxane (dimethicones or polydimethylsiloxanes)；And its mixture.

Water repellent agent is preferably selected from phosphoric acid perfluoroalkyl ester, polyhexafluoropropylene oxide, PFPE, amino acid, N- acyls Base amino acid or its salt, three isostearic acid isopropyl titanates and its mixture.

It is highly preferred that water-repelling agent is different selected from phosphoric acid perfluoroalkyl ester, N- acylamino acids or its salt, three isostearic acid metatitanic acids Propyl ester and its mixture.

Jing can be prepared according to the well-known chemistry of technical staff, electronics, chemical machinery or mechanical surface treatment technology The pigment of surface treatment.It is also possible to using commercial product.

By the generation of solvent evaporation, chemical reaction and covalent bond surface reagent can be absorbed or is adsorbed on pigment.

According to a kind of form (version), surface treatment includes the coating of pigment.

The coating can represent 0.1～10 weight % of the gross weight of the pigment of coating, more specifically 1 weight %～5 weight %.

Before pigment is incorporated in other compositions of nursing or make-up composition, for example can carry out in the following manner Coating：Optionally under heat condition, by being simply mixed pigment and liquid surface reagent with stirring, the surface reagent is adsorbed in On the surface of pigment.

For example chemical reaction can be carried out by the surface of surface reagent and pigment, and be produced between the surface reagent and pigment Give birth to covalent bond to be coated.The method is especially described in United States Patent (USP) 4,578,266.

Amino acid or fatty acid treatment agent

Water repellent agent may be selected from aliphatic acid, such as stearic acid；Metallic soap, such as two aluminium myristates and h-tallow paddy The aluminium salt of propylhomoserin；Amino acid；N- acylamino acids or its salt；Lecithin；Three isostearic acid isopropyl titanates (or be referred to as ITT)；And its mixture.

N- acylamino acids can include the acyl group with 8～22 carbon atoms, such as, such as 2- ethyl hexyls acyl group, hexanoyl Base, lauroyl, myristoyl, palmityl, stearyl or cocoyl.The salt of these compounds can be aluminium salt, Magnesium salts, calcium salt, zirconates, zinc salt, sodium salt or sylvite.Amino acid can be such as lysine, glutamic acid or alanine.

Aliphatic acid in the present invention more particularly acid with hydrocarbon chain, the hydrocarbon chain has 1～30 carbon atom, preferred tool There are 5～18 carbon atoms.The hydrocarbon chain can be saturation, monounsaturated or polyunsaturated.

The example of the pigment coated with aliphatic acid is included containing stearoyl-glutamic acid disodium/aluminium hydroxide to (pairing) Those, these especially with following trade name sale：From the NAI-TAO- of three good chemical conversion (Miyoshi Kasei) companies 77891、NAI-C33-8073-10、NAI-C33-8075、NAI-C47-051-10、NAI-C33-115、NAI-C33-134、 NAI-C33-8001-10、NAI-C33-7001-10、NAI-C33-9001-10。

The face (ITT) processed with three isostearic acid isopropyl titanates (isopropyltitanium triisostearate) The example of material includes those sold with following trade name by Kobo companies：BWBO-12 (iron oxide CI77499 and three different tristearin Sour isopropyl titanate), BWYO-12 (iron oxide CI77492 and three isostearic acid isopropyl titanates) and BWRO-12 (titanium oxide CI77491 and three isostearic acid isopropyl titanates).

Preferably, by the pigment of stearoyl-glutamic acid disodium/aluminium hydroxide coating used in the present invention.

Advantageously, composition of the invention can be comprising at least one pigment, relative to the gross weight meter of composition, its content For 0.5 weight %～30 weight %, especially 1 weight %～20 weight %, more specifically 2 weight %～15 weight %.

Filler

Composition of the invention can include at least one organic or mineralogical property filler.

Term " filler " is understood to mean that the colourless or white solid particle of any shape, its be insoluble in and be scattered in Form in the medium of composition.They make it possible to give composition softness and disappear in mineralogical property or organic nature Light, and uniform dressing effect.

Filler used in composition of the invention can be in laminar, spherical or spherical form, in fibers form Or any other intermediate form between the form that these are limited.

Filler of the invention can be the coating of Jing surfaces or can coat without surface, especially they can be by Following material surface is processed：Siloxanes (silicone), amino acid, fluorine derivative or any other promotion filler are in the composition Dispersion and compatibility material.

Talcum powder, mica, trimethyl first can be can be mentioned that among the mineral filler used in composition of the invention Silicon Trimethylsiloxysilicate, kaolin, bentonite, calcium carbonate, magnesium bicarbonate, hydroxyapatite, boron nitride, glass or ceramic micro- glue Capsule and its mixture.

Talcum powder or its mixture can be preferably suitable for the filler of the present invention.

Can among the organic filler used in composition of the invention, can be mentioned that polyamide powder (from Atochem'sOrgasol)；Poly- Beta-alanine and polyethylene powders；Polytetrafluoroethylene (PTFE) is (from Du Pont (DuPont) 's) powder；Lauroyl lysine；Modified or unmodified starch, especially aoxidizes ester modified starch, such as by reviving The acetylating oxidized starch that state peak (Suzhou Gaofeng) company is sold with trade name GF-A390；Tetrafluoroethylene polymerization Thing powder；Polymeric hollow microsphere, such as Expancel (Nobel Industrie)；Derived from containing 8～22 carbon atoms The metallic soap of the organic carboxyl acid of (preferably 12～18 carbon atoms), such as zinc stearate, magnesium stearate or lithium stearate, moon silicic acid Zinc, magnesium myristate；L 200 (Chemdal companies)；Silicone resin microballon is (such as from Toshiba (Toshiba))；Polyurethane powder, the cross-linked polyurethane powder especially comprising copolymer, the copolymer bag Caprolactone containing trihydroxy methyl, such as by Toshiki companies with title Plastic PowderOr Plastic PowderThe hexamethylene diisocyanate of sale/trihydroxy methyl caprolactone polymers；The micro- wax of babassu, such as by Micro Powders companies are with title MicroCareThe product of sale；Micro- wax of synthetic wax, such as, such as by Micro Powders companies are with title MicroEaseThe product of sale；It is made up of with the mixture of Tissuemat E Brazil wax Micro- wax, such as by Micro Powders companies with title MicroCareWithThose of sale；By cohune Micro- wax that palmitic acid wax is constituted with the mixture of synthetic wax, such as by Micro Powders companies with title MicroCarePin The product sold；The micro- wax of polyethylene, such as by Micro Powders companies with title MicropolyWithThose of sale；And its mixture.

Advantageously, it is adaptable to which the filler of the composition of the present invention is selected from modified or unmodified starch, more preferably acetyl group Change oxidized starch.

Preferably, relative to the gross weight meter of composition, at least one filler amount in the present compositions For 0 weight～20 weight %, more preferably preferably 0.01 weight %～10 weight %, 0.5 weight %～5 weight %.

Thickener

Composition of the invention can be comprising at least one thickener, and it is selected from hydrophilic thickeners, lipophilicity thickening Agent or its mixture.

Hydrophilic thickeners

Term " hydrophilic thickeners " is intended to the compound of the viscosity for representing the water phase that can increase composition.

Hydrophilic thickeners may be used alone or in combination and use.These thickeners especially may be selected from cellulosic polymer and tree Glue.

As hydrophilic thickeners, the thickening polymer of water solubility or water dispersible is especially can be mentioned that.They are especially optional From：

- PVP,

- polyvinyl alcohol,

- modified or unmodified carboxy vinyl polymer, such as by Goodrich companies with title (CTFA titles：Carbomer) sale product；

The acid of-acrylic or methacrylic or the homopolymers or copolymer of its salt and its ester, especially by association colloid (Allied Colloid) company is with title VersicolOr VersicolOr Salcare SC95 sale product, By vapour Ba-Jia Ji (Ciba-Geigy) company with title UltraholdThe product of sale；Polyacrylate and poly- methyl-prop Olefin(e) acid ester, the product for example sold with title Lubrajel and Norgel by Guardian companies or by Hispano The product that Chimica companies are sold with title Hispagel；The polyacrylic acid of Synthalen K types；

- polyacrylamide；

The copolymer of-acrylic acid and acrylamide, by Hercules companies with its sodium-salt form, with titlePin Sell；By Vanderbilt companies with title DarvanPoly- (Sodium methacrylate) of sale；By Henkel (Henkel) company With title HydagenThe sodium salt of the polyhydroxycarboxyliacid acid of sale；

- 2- acrylamide-2-methylpro panesulfonic acids polymer and copolymer, its be optionally crosslinking and/or neutralization, example Such as by Clariant (Clariant) company with title Hostacerin AMPS (CTFA titles：Polypropylene acyl group dimethyltaurine Ammonium) sale poly- (2- acrylamide-2-methylpro panesulfonic acids)；

Anionic acrylamide/the AMPS copolymer of-crosslinking, it is W/O emulsion forms, such as by match Bick (SEPPIC) Company is with (the CTFA titles of title Sepigel 305：Polyacrylamide/C13-14 isoparaffins/lauryl polyoxyethylene (7) ether (Laureth-7)) sale those and with (the CTFA titles of title Simulgel 600：Acrylamide/Sodium Acryloyldimethyl Taurate Copolymer/isohexadecane/polysorbate80) sale those；

Polyacrylic acid/the alkyl acrylate copolymer of-Pemulen types；

- polysaccharide biopolymer, such as xanthans, guar gum, Arabic gum, locust bean gum, acacin (acacia Gum), scleroglucan, chitin derivative and chitosan derivatives, carrageenan, exocellular polysaccharide, alginate or cellulose, Such as microcrystalline cellulose, carboxymethylcellulose calcium, hydroxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl cellulose.Can be mentioned that example Such as by CP Kelco companies with trade nameThe xanthans of CG-T sale；

- hydrophily the pyrogenic silica for obtaining in the following manner：Volatility silication is hydrolyzed in oxyhydrogen flame high temperature Compound, produces the silica of (finely divided) in small, broken bits.Hydrophilic silicon oxides have substantial amounts of silane on its surface Alcohol groups.Such hydrophilic silicon oxides are for example by Degussa (Degussa) company with title AerosilAerosilAerosilAerosilAnd AerosilSale；Or by Cabot (Cabot) company with title Cab-O-SilCab-O-SilCab-O-SilCab-O-SilAnd Cab-O- SilSale.It can be granularity of the nanoscale to micron order (e.g., from about 5～200nm) that they preferably have；

- hydrophilic clay；

- association polymer is for example hard with the PEG-150/ that title Aculyn 46 is sold by ROHM AND HAAS (Rohm＆Haas) Lipidol/SMDI copolymers or the stearyl polyoxy second sold with title Rheolate FX 1100 by Hai Mingsi (Elementis) Alkene (100) ether (steareth-100)/PEG-136/HDI copolymers；

- and its mixture.

Lipophilicity thickener

Term " lipophilicity thickener " is intended to the compound of the viscosity for representing the fatty phase that can increase composition.

Preferably, lipophilicity thickener is selected from mineral lipophilicity thickener.

Lipophilicity clay is especially can be mentioned that, such as optionally modified clay for example uses C₁₀～C₂₂The lithium of ammonium chloride is covered De- stone, the hectorite being for example modified with VARISOFT TA100.

Clay is the silicate containing cation, the cation may be selected from calcium, magnesium, aluminium, sodium, potassium and lithium cation and Its mixture.

As the example of class product, the clay of montmorillonite family, such as montmorillonite, hectorite, bentonite, shellfish are can be mentioned that Obtain stone or saponite, the also clay of vermiculite, magnesium-rich smectite and chlorite family.These clays can be natural origin or synthesis Source.

Clay may be selected from montmorillonite, bentonite, hectorite, attapulgite and sepiolite and its mixture.Clay is preferred For bentonite or hectorite.

Organophilic clays are with selected from following compound modified clay：Quaternary amine, tertiary amine, ammonium acetate, imidazoline, amine Soap, fatty sulfuric acid ester/salt (fatty sulfates), alkyl aryl sulfonate/salt and amine oxide and its mixture.

As organophilic clays, can be mentioned that dihydrogenated tallow alkyl dimethyl ammonium chloride with bentonitic reactant (quaternium-18bentonites), for example by Hai Mingsi (Elementis) companies with title Bentone 3, Bentone Those of 38 and Bentone 38V sale；By united catalyst (United Catalyst) company with title Tixogel VP pins Those sold；By Southern Clay (Southern Clay) company with title Claytone 34, Claytone 40 and Claytone Those of XL sale；Stearalkonium chloride and bentonitic reactant (stearalkonium Bentonites), those for example sold with title Bentone 27V by Hai Mingsi (Elementis) companies；By joint catalysis Agent (United Catalyst) company sold with title Tixogel LG those；And by Southern Clay (Southern Clay) company sold with title Claytone AF and Claytone APA those；Dihydrogenated tallow alkyl dimethyl ammonium chloride with Bentonitic reactant/alkyl dimethyl benzyl ammonium and bentonitic reactant (quaternium-18/benzalkonium Bentonites), for example by Southern Clay (Southern Clay) company with title Claytone HT and Claytone PS pins Those sold；Distearyl dimethylammonium hectorite, such as by Hai Mingsi (ELEMENTIS) companies with title Bentone 38VCG Those of sale；And its mixture.

According to one kind preferred embodiment, lipophilicity thickener is selected from the modified clay of organophilic, such as distearyl two First ammonium hectorite.

Hydrophobic silica is also can be mentioned that, for example, optionally undergoes the pyrogenic silica of hydrophobic surface treatments, its grain Degree is less than 1 μm.In fact chemical modification is carried out to the surface of silica possibly through chemical reaction, the chemistry is anti- The silanol on the surface for being present in silica for reducing quantity should be generated.Especially, it is possible to taken with hydrophobic group For silanol：Then hydrophobic silica is obtained.The hydrophobic group can be：

- trimethylsiloxy, it in the presence of HMDS particularly by processing pyrogenic silica To obtain.According to CTFA, (the 6th edition, 1995), the silica being processed as is referred to as " silica silylate ".Their examples Such as by Degussa (Degussa) company with reference name AerosilSale, and by Cabot (Cabot) company joining Examine a Cab-O-SilSale；

- dimethyl silane epoxide or polydimethylsiloxane group, it is particularly by dimethyl silicone polymer or two Process pyrogenic silica in the presence of dimethyl dichlorosilane (DMCS) to obtain.According to CTFA (the 6th edition, 1995), two for being processed as Silica is referred to as " dimetylsilyl silica ".They are for example by Degussa (Degussa) company with reference name AerosilAnd AerosilSale, and by Cabot (Cabot) company with reference name Cab-O-SilAnd Cab-O-SilSale.

It can be the granularity of nanoscale to micron order (e.g., from about 5～200nm) that Hydrophobic fumed silica preferably has.

According to preferred embodiment, if there is thickener, then it is selected from xanthans, distearyl dimethylammonium lithium and covers de- Stone, silica silylate or its mixture, it is highly preferred that thickener is distearyl dimethylammonium hectorite.

Relative to the gross weight meter of composition, amount of at least one thickener in composition of the invention can Think 0～20 weight %, preferred content is 0.01 weight %～10 weight %, and is preferably 0.5 weight %～5 weight %.

Other surfactant

The composition of the present invention further includes at least one other surfactant, and it is with above-mentioned surfactant not Together.

According to the method for Griffin, at a temperature of 25 DEG C, the HLB value of the other surfactant is more than or waits In 8.

J.Ploughshare.Cosm.Chem.1954 (volume 5), according to GRIFFIN's defined in the 249-256 page HLB value.

Preferably, the HLB value of the 3rd surfactant is 8～20 (according to the method for Griffin, in 25 DEG C of temperature Under), more preferably 10～15 (according to the method for Griffin, at a temperature of 25 DEG C).

Preferably, the 3rd surfactant is lived selected from nonionic surfactant, anion surfactant, amphoteric surface Property agent or zwitterionic surfactant or its mixture.

The nonionic surfactant for being suitable for the present composition may be selected from：

- polyoxyethylated sorbitol fatty acid ester, the product for example sold with title TWEEN 20 by ICI；

- polyoxyethylenated alcohol, the product for example sold with title REMCOPAL 21912AL by Gerland；

- polyoxyethylenated alkylphenol, such as by ROHM AND HAASSold with title TRITON X 100 Product；And

The condensation product of-ethylene oxide and propylene oxide, those for example sold with title SYNPERONIC PE by ICI, especially It refers to those of entitled L 31, L 64, F 38, F 88, L 92, P 103, F 108 and F 127；

- aliphatic acid and glycerine or the ester of polyglycereol, preferred saturation or undersaturated C₆-C₃₀(more preferably C₈-C₁₆) aliphatic acid With glycerine or the ester of polyglycereol.Can be mentioned that such as tristerin, glyceryl isostearate, two isostearic acid polyglycereol (3) Ester, stearic acid polyethylene glycol (100) ester, glycerol caprylate, capric acid polyglycereol (1-4) ester (polyglyceryl 1- 4caprate) or its mixture.Such product can be obtained commercially, such as tristerin and stearic acid polyethylene glycol (100) trade name that the mixture of ester can pass through match Bick (Seppic) Company is Simulsol^TM165 obtaining, or Person for example creates Gao Shi meter Te (Evonik Goldshmidt) company by win, with trade nameThe product of the sale of PC 41 Product capric acid polyglycereol (1-4) ester.

The ether of-polyethylene glycol and/or polypropylene glycol and glycerine, such as glycerin polyoxyethylene (26) ether (glycereth-26) With glycerine polyoxypropylene (24) polyoxyethylene (24) ether；

- derived from a) aliphatic acid and the b) ester of the reaction of polyethylene glycol and/or Polypropylene Glycol Glycerin Ether, it is such as, such as sweet Oily polyoxyethylene (7) ether (glycereth-7) or glycerin polyoxyethylene (25) ether PCA isostearates；

The ester of-sucrose and the aliphatic acid comprising 12～30 carbon atoms (especially 14～20 carbon atoms), the ester may Comprising 2～5 aliphatic chains, such as, such as sucrose distearate, sucrose tristearate and sucrose palmitate；

- alkyl polyglucoside, preferably comprises the alkyl comprising 6～30 carbon atoms (and preferably 8～16 carbon atoms), and Those containing the hydrophilic radical (glucoside) for preferably comprising 1.2～3 sugared units.For example can be mentioned that Plantacare 818 (alkane Base-C₉/C₁₁- poly glucoside (1.4)), such as by section peaceful (BASF) (Cogins (BASF)) with title 2000UP sale product, by flower Wang Huaxue (Kao Chemicals) with title MYDOLIt is the product of sale, peaceful by section (Cognis) with title2000UP sale product and by match Bick (Seppic) with titleThe product of the sale of NS 10；Caprylyl/capryl glucoside, such as by match Bick (Seppic) with titleThe product of the sale of CG 110；Lauryl glucoside, such as by section peaceful (Cognis) with title1200N andThe product of 1200 sale；And cocoyl glucoside, for example By section peaceful (Cognis) with titleThe product of 818/UP sale；Spermaceti/stearyl glucoside (cetostearylglucoside), optionally as the mixture with spermaceti/stearyl alcohol, such as by match Bick (Seppic) with name Claim MONTANOV 68 sell, by Gao Shi meter Te (Goldschmidt) with titleCARE CG90 sell and by the Chinese High (Henkel) is with title EMULGADE KE3302 sale；Peanut base glucoside, for instance in arachidic alcohol Ji behenyl alcohol and peanut The form of mixtures of base glucoside, is sold by match Bick (Seppic) with title MONTANOV 202；Cocoyl ethyl glucose Glycosides, for instance in (35/65) form of mixtures of cetanol and stearyl alcohol (by match Bick (Seppic) with title MONTANOV 82 sale)；And its mixture.

Among anion surfactant, especially can be mentioned that：

- alkyl sulfate, alkyl ether sulphate and their salt, especially their sodium salt, such as by Henkel (Henkel) with title TEXAPON ASV sell sodium laureth sulfate/laureth magnesium sulfate/ Lauryl polyoxyethylene (8) ether sodium sulfate/lauryl polyoxyethylene (8) ether sulfuric acid magnesium compound；By Henkel (Henkel) with name Claim IPON AOS 225 orLauryl ether sulfates sodium (the C of N702PASTE sale_12-1470/30) (2.2EO)；Lauryl ether sulfates ammonium (the C sold with title SIPON LEA 370 by Henkel (Henkel)_12-1470/30) (3EO)；By Rhodia Chimie with titleAlkyl (the C of AB/20 sale_12-C14) ether (9EO) sulfuric ester Ammonium；

- alkyl sulfoacetate, such as by Si Taipan (Stepan) with titleLAL sale that Kind；

- alkyl sulphosuccinates salt, such as by Witco with title SETACIN 103SPECIAL or REWOPOL SB- Oxyethylation (3EO) laruyl alcohol (C of the sale of FA 30K 4₁₂/C₁₄70/30) single sulfosuccinate ester salt；By Zschimmer The C that Schwarz is sold with title SETACIN F SPECIAL PASTE₁₂-C₁₄The disodium salt of half sulfosuccinate of alcohol；By Oxyethylation (2EO) the oleoyl amido sulfosuccinate two that Henkel (Henkel) is sold with title STANDAPOL SH 135 Sodium；Oxyethylation (5EO) the lauramide list sulfosuccinate sold with title LEBON A-5000 by Sanyo (Sanyo) Salt；By Witco with titleOxyethylation (10EO) the lauryl citrate list sulfo group of the sale of SB CS 50 The disodium salt of succinate；Or by Witco with titleThe castor oil acid monoethanol of the sale of S 1333 The disodium salt of acid amides list sulfosuccinate；

- polypeptide, it is for example by the condensation of aliphatic chain and cereal amino acid (especially wheat amino acid and oat amino acid) To obtain, such as, for example, by standing grain big (Croda) with title AMINOFOAM^TMThe lauroyl hydrolyzed wheat protein of W OR sale Sylvite；The triethanolamine salt of the cocoyl hydrolytic soya bean protein sold with title MAY-TEIN SY by Maybrook；By matching Bick (Seppic) is with title PROTEOL^TMThe sodium salt of the lauroyl oat amino acid of OAT sale；By Deutsche The hydrolysate of the collagen for being grafted to fatty acid distribution of coconut oil that Gelatine is sold with title GELIDERM 3000；Or by The soybean protein of the use hydrogenated coco acylating acid that match Bick (Seppic) is sold with title PROTEOL VS 22；

- amino acid derivativges, such as in sarcosinate, especially among acyl sarcosinates, for example by vapour bar (Ciba) with Title SARKOSYL NL 97 sale or by match Bick (Seppic) with title ORAMIX^TMThe lauroyl flesh of the sale of L 30 Propylhomoserin sodium；The myristoy sarcosine sodium sold with title NIKKOL SARCOSINATE MN by daylight (Nikkol)；Or The palmitoyl sarcosine sodium sold with title NIKKOL SARCOSINATE PN by daylight (Nikkol)；Alanine salt, for example by It is that daylight (Nikkol) is sold with title SODIUM NIKKOL ALANINATE LN 30 or (Kawaken) is ground with name by river Claim the N- lauroyls-N- methylaminopropionics sodium of ALANONE ALE sale and (Kawaken) is ground with title by river N- lauroyl-N- methylalanine the triethanolamines of ALANONE ALTA sale；N- acyl glutamates, such as by aginomoto (Ajinomoto) with single cocoyl glutamic acid triethanolamine salt of title ACYLGLUTAMATE CT-12 sale and by taste The lauroyl glutamate triethanolamine salt that element (Ajinomoto) is sold with title ACYLGLUTAMATE LT-12；Asparagus fern ammonia Hydrochlorate, the N- lauroyl aspartic acid triethanolamine salts for example sold with title ASPARACK LM-TS2 by Mitsubishi With the mixture of N- myristoyl aspartic acid triethanolamine salts；Or glycine derivative, such as N- cocoyls glycine Sodium and N- cocoyl glycine potassium, such as by aginomoto (Ajinomoto) with title AMILITE GCS-12 and AMILITE The product of GCK-12 sale；

- sulfonate, such as alpha-alkene sulfonate, such as by Si Taipan (Stepan) with title BIO-AS-40 Sale, by Witco with title WITCONATE AOSWith SULFRAMINE AOS PH 12 sale or By Si Taipan (Stepan) with title BIO-Alpha-olefin (the C of AS-40CG sale_14-16) sodium sulfonate；Or by section's Lay Grace (Clariant) is with titleThe secondary alkene sulfonic acid sodium of the sale of SAS 30；Or straight chained alkyl aryl sulfonic acid Salt, the dimethylbenzene for example sold with title MANROSOL SXS30, MANROSOL SXS40 or MANROSOL SXS93 by Manro Sodium sulfonate；

- isethionate, especially acyl-hydroxyethyl sulfonate, such as sodium cocoyl isethionate, for example by The product that Jordan is sold with title JORDAPON CI P.

Especially can be mentioned that among amphoteric surfactant or zwitterionic surfactant：

- alkylamido alkylamines derivative, such as by Rhodia Chimie with title MIRANOL C2M CONC NP As N- cocoyl-N- carboxymethoxyl ethyl-N- (carboxymethyl) ethylenediamine N- disodiums (the CTFA titles of saline solution sale： Cocounut oil acyl both sexes base diethyl acid disodium (Disodium cocoamphodiacetate))；N- cocoyl-N- ethoxy-N- (carboxymethyl) ethylenediamine N- sodium (CTFA titles：Sodium cocoamphoacetate (sodium cocoamphoacetate))；And Mixture (the CTFA titles of cocounut oil acid diethanolamide：Coconut oleoyl amine DEA)；

- glycine betaine, such as, such as coco betaine, such as by Henkel (Henkel) with title The product of AB-30 sale；Lauryl betaine, such as by Clariant (Clariant) with titleKB sells Product；Oxyethylation (10EO) lauryl betaine, such as by Shin Nihon Rica with title LAURYL ETHER (10EO) product of BETAINE sale；Or oxyethylation (10EO) stearyl betaine, such as by Shin Nihon Rica With the product that title STEARYL ETHER (10EO) BETAINE sells；

- alkylamide propyl-betaine and its derivative, such as, such as by Sanyo (Sanyo) with title LEBON 2000HG sale or by Albright＆Wilson with titleThe Cocoamidopropyl betaine of BB sale； By Witco with title REWOTERICThe lauroylamidopropyl betaine of sale；Such as cocamidopropyl propyl amide beet Alkali, the product for example sold with title TEGO BETAINE by Gao Shi meter Te (Goldschmidt)；

- imidazolidine derivatives, the product for example sold with title CHIMEXANE HD by Chimex；And

- their mixture.

Preferably, the 3rd surfactant is selected from nonionic surfactant.

It is highly preferred that the 3rd surfactant selected from the ester of aliphatic acid and glycerine or polyglycereol, alkyl polyglucoside or its Mixture.

It is highly preferred that the 3rd surfactant is selected from saturation or undersaturated C₆-C₃₀Aliphatic acid and glycerine or polyglycereol Ester, more preferably saturation or undersaturated C₆-C₁₆Aliphatic acid and glycerine or the ester of polyglycereol；Containing (excellent comprising 6～30 carbon atoms Select 8～16 carbon atoms) alkyl, and containing the alkyl of hydrophilic radical (glucoside preferably comprises 1.2～3 sugar units) Poly glucoside；Or its mixture.

According to preferred embodiment, the 3rd surfactant of the present invention is selected from tristerin, the poly- second of stearic acid Glycol (100) ester, capric acid polyglycereol (4) ester, Plantacare 818 or its mixture.

Preferably, relative to the gross weight meter of composition, composition of at least one 3rd surfactant in the present invention In amount be 0.1 weight %～20 weight %, preferably 0.5 weight %～10 weight %, more preferably 1 weight %～5 weight Amount %.

Galenical form (Galenic form)

Composition of the invention can be in various forms, the especially form especially in dispersion or emulsion, example It is such as water-in-oil emulsion or oil-in-water emulsion or multi-phase emulsion.

Dispersion can be prepared as water phase or as oil phase.

Emulsion can have oiliness continuous phase or aqueous continuous phase.Such emulsion can be for example anti-phase (inverse) (W/O) breast Liquid or positive (direct) (O/W) emulsion, or multi-phase emulsion (W/O/W or O/W/O).

In the case of emulsion, preferred multi-phase emulsion, especially oil in water in oil emulsion.

Preferred embodiment of the invention, according to following steps composition is prepared：

1) the 3rd surfactant of at least one as defined in the present invention and at least one pigment are added in water, Mixing under room temperature (25 DEG C) is until uniform, acquisition phase B；

2) at least one oil is mixed with phase B, by stirring mixing 15 minutes, to obtain emulsion 1, it was oil-in-water breast Liquid；

3) mixing is selected from least two following surfactants：

i)C₈-C₂₂Alkyl dimethicone copolyol；

Ii) dimethicone copolyol, its from it is i) different；

Iii) polyoxyalkylenated silicone elastomer, its from i) or ii) it is different；

) or its mixture iv；

And/or at least one oil, to obtain fatty phase A；

4) to step 3) in obtain fatty phase A in add step 2) in obtain emulsion 1, by stirring make mixture equal Matter, to form oil in water in oil emulsion.

Additive

In special embodiment, cosmetic composition of the invention is further comprising at least one selected from following Compound：Hydrophilic solvent, lipophilic solvent, oil in addition and its mixture.

Cosmetic composition of the invention can also include any additive commonly used in considered field, and it is selected from For example natural gum, resin, thickener in addition, structural agent (such as wax), dispersant, antioxidant, essential oil, preservative, spices, in With agent, bactericide (antiseptics), UV- screeners in addition, cosmetic active agent (such as vitamin), NMF, moisturizing Agent or collagen protective agent and its mixture.

Regulation is present in the property quality and quantity of the additive in composition of the invention, so that required cosmetic property Thus it is not affected with Properties in Stability, this is to those skilled in the art regular job problem.

Method and purposes

The composition of the present invention can be used for non-therapeutic method, such as nursing/cosmetic skin, especially facial side Method, methods described includes composition of the invention to dermal administration.

The invention further relates to composition of the invention be directly used in or in cosmetic product be used for skin (especially face And lip) with the purposes in cosmetic/nursing/cleaning/makeup removal products.

Following examples are intended to illustrate composition of the invention and method, but never in any form limiting this Bright scope.Unless otherwise mentioned, all parts and percentages in embodiment are given with weight basis, and all of measurement Obtain at about 25 DEG C.

Embodiment

Prepare

Prepare following formulation (formulas)：

Remarks：

Inventive Formulations 1 include hydrophily pigment；

Inventive Formulations 2 include hydrophobic pigment；

Relatively formulation 1 replaces the 3rd surfactant according to Inventive Formulations 2 with capric acid polyglycereol (4) ester；

Compared to Inventive Formulations 2, compare formulation 2 not comprising the 3rd surfactant.

Composition enumerated above is prepared according to following steps：

1) under room temperature (25 DEG C), the composition of mixed phase B is until uniform, acquisition phase B；

2) add fatty phase A2 in phase B, carry out homogenizing 15 minutes by stirring, to obtain emulsion 1, it is oil-in-water Emulsion；

3) under room temperature (25 DEG C), mixing phase constituent is until uniform, fatty phase A of acquisition；

4) to step 3) in obtain fatty phase A in add step 2) in obtain emulsion 1, by stirring make mixture equal Matter.

Evaluate

By means of resolution ratio for 410x410 pixels Chromasphere, according to following code, to made above this Bright formulation 1 and 2 and compare formulation 1 and 2 and carry out the evaluation of washable property effect：

In 20 DEG C under standard mode, before being applied the composition on the skin of model with exposed finger and it Afterwards, (for washable property effect assessment) is washed after applying with warm water to measure.

The code of the washable property effect of apparatus measures

Colorimetric survey is carried out by measuring the mean value of 10 Ming Nv model panels come the skin before and after to cosmetic Amount, difference (measurement) C* (colourity leaves the distance-saturation degree of neutral axis), H* (tone, the angle/direction in the range of 360 degree) With L* (brightness).For each in 10 female models, obtained for the Chromasphere of 410x410 pixels using resolution ratio Take image.Expression of results in the following manner：By the C* (colourity leaves the distance-saturation degree of neutral axis), the H* that are analyzed by camera (tone, the angle/direction in the range of 360 degree) and L* (brightness) carry out quantitative color.3 hours these variables is inclined after cosmetic Difference (Δ E₉₄) calculating the uniformity and durability.Δ E, dE or Δ E₉₄The tolerance of the difference being defined as between two kinds of colors.By The formula (TC 1-29) that CIE technical committees deliver in nineteen ninety-five is as follows：

Wherein：

K_L、K₁And K₂For weighted factor；

L₁*、C₁And H *₁* it is the coordinate of the first color to be compared in chrominance space, and L₂*、C₂And H *₂* it is the second face Coordinate of the color in chrominance space.

The measurement of washable property effect is carried out, and measurement is made in the following time：

T_10min=the measurement of 10 minutes after composition is applied

T_20min=the measurement of 20 minutes after the skin for applying composition thereon is washed with warm water

(T_10min–T₀) and (T_20min–T₀) composition washable property measurement

The panel of 10 female models is measured, before on-test, the female model stays in (22 DEG C of air-conditioning +/- 2 DEG C) 15min in waiting room.They shed its cosmetic, and the Chromasphere using resolution ratio for 410x410 pixels is obtained Take the image of one of their cheek.The image makes it possible to measurement and applies T before cosmetics₀The color at place.Then weigh The present composition 1 and 2 and comparative composition 1,2 and 3 of about 10mg, is put into surface plate (watch glass) and divides It is not applied thereto to carry out T with exposed finger₀The area of measurement is 12.56cm²Skin of face on.

After the drying time of 10min, using Chromasphere the image of the cheek region made up is obtained.The image makes Must be possible to measure color (T immediately after applied cosmetics_10min).Then with the cheek of warm water washing cosmetic.Finally, in washing The image of the cheek region of cleaning is obtained after waiting 20 minutes behind the cheek region of cosmetic using Chromasphere.The image makes Must be possible to measure color (T behind the cheek region of washing cosmetic_20min)。

By following equations expression of results：

Difference (%)=﹛ [Δ E₉₄(T_10min- T₀)-Δ E₉₄(T_20min- T₀)]/ΔE₉₄(T_10min- T₀) ﹜ × 100%

Difference (%) is bigger, and the washable property of composition is better.If difference is more than 80% (preferably greater than 85%), produce Product show excellent washable property.If difference is less than 70%, product does not have acceptable washable property effect.

Panel's assessment routine of the dressing effect of composition and washable property effect

Finally, Inventive Formulations 1 and 2 are provided respectively by the panelist of 10 female models and compares formulation The scoring of 1 and 2 dressing effect and washable property effect.

15 points after the composition that 100mg is prepared in embodiment is prepared is applied in respectively on one side of something face of female model Clock, by panelist dressing effect is evaluated.

By identical panelist, washable property effect is evaluated according to following steps：

The formulation that 100mg is prepared in embodiment is prepared is applied in into respectively one side of something face of female model；

15 minutes after formulation is applied, the face of female model is washed with warm water；

Washed with warm water 20 minutes after one side of something face for applying formulation thereon, commenting for washable property is provided by female model Point.

5：It is very good；

4：Substantially it is good；

3：It is acceptable；

2：It is slightly poor and unacceptable；

1：Difference, it is unacceptable.

The result of dressing effect and washable effect is as follows：

Observe from result enumerated above, compared to formulation 1 and 2 is compared, Inventive Formulations 1 and 2 have most The washable property effect of optimization, while with very good dressing effect.

Based on evaluation result enumerated above, the inventors discovered that, composition of the invention overcomes existing skill Technical problem present in art, and there is provided stable cosmetic composition, the composition has optimized washable property Effect, while keeping good dressing effect.

Claims (20)

1. the composition of emulsion form, its include at least one fat phase, at least one water phase and：

A) selected from the combination of at least two following surfactants：

i)C₈-C₂₂Alkyl dimethicone copolyol；

Ii) dimethicone copolyol, its from it is i) different；

Iii) polyoxyalkylenated silicone elastomer, its from i) or ii) it is different；

) or its mixture iv；

B) at least one 3rd surfactant, it is different from surfactant a), selected from containing polyglycereol or glycerine side base with/ Or the polydialkysiloxane of end group；With

C) at least one pigment.

2. the composition described in claim 1, it is multi-phase emulsion form, preferred water-in-oil-in-water compositions or Water-In-Oil bag oil breast Liquid, more preferably oil in water in oil emulsion.

3. the composition described in claim 1 or 2, wherein the surfactant i) C₈-C₂₂Alkyl dimethicone is total to Compound of the polyalcohols selected from lower formula (I)：

Wherein：

- PE represents (- C₂H₄O)_x-(C₃H₆O)_y, selected from hydrogen atom and the alkyl with 1～4 carbon atom, preferred R is H, x for-R, R For 0～100, and y is 0 when being 0～80, x different with y,

- m is 1～40, preferably 1～10,

- n is 10～200, preferably 10～100,

- o is 1～100, preferably 1～30,

- p is 7～21, preferably 15,

- q is 0～4, preferably 3.

4. the composition any one of aforementioned claims 1 to 3, wherein the surfactant i) C₈-C₂₂Alkyl poly- two Methylsiloxane copolyol is selected from Abil EM 90, the more preferably poly- diformazans of cetyl PEG/PPG-10/1 Radical siloxane.

5. the composition any one of aforementioned Claims 1 to 4, wherein the surfactant ii) polydimethylsiloxanes Compound of the alkane copolyol selected from lower formula (II)：

Wherein：

R₁、R₂、R₃C is represented independently of one another₁-C₆Alkyl or group-(CH₂)_x-(OCH₂CH₂)_y-(OCH₂CH₂CH₂)_z-OR₄, at least One group R₁、R₂Or R₃It is not alkyl；It is preferred that R₁With R₃It is identical, it is methyl, R₄For hydrogen, C₁-C₃Alkyl or C₂-C₄Acyl group, preferably R₄For hydrogen；

A is 0～200 integer；

B is 0～50 integer；Condition is equal to 0 when being A different with B；

X is 1～6, preferably 2～6 integer；

Y is 1～30, preferably 4～30 integer；

Z is 0～5 integer.

6. the composition any one of aforementioned Claims 1 to 5, wherein the surfactant ii) polydimethylsiloxanes Alkane copolyol is the compound of lower formula (III) or its mixture：

Wherein A is 20～105 integer, and B is 2～10 integer, and y is 10～20 integer, it is highly preferred that second table Face activating agent dimethicone copolyol is selected from the compound of formula (III), wherein：

It is 2 that A is 22, B, and y is 12；

It is 10 that A is 103, B, and y is 12；

It is 3 that A is 27, B, and y is 12.

7. the composition any one of aforementioned claim 1～6, wherein the dimethicone copolyol is following formula (IV) compound：

HO-(CH₂CH₂O)_y-(CH₂)₃-[(CH₃)₂SiO]_A’-[(CH₃)₂Si]-(CH₂)₃-(OCH₂CH₂)_y-OH

(IV)

Wherein A ' and y are 10～20 integers.

8. the composition any one of aforementioned claim 1～7, wherein the surfactant iii) it is selected from poly dimethyl Siloxanes (and) Dimethicone/Vinyl Dimethicone cross-linked polymer, dimethyl silicone polymer/PEG-10 Dimethyl silicone polymer vinyl dimethicone cross polymer, EG-10 Dimethicone Crosspolymers, the moon Osmanthus base PEG-15 dimethyl silicone polymer vinyl dimethicone cross polymer, lauryl PEG-15 poly dimethyl silicon Oxygen alkane vinyl dimethicone cross polymer, lauryl PEG-15 dimethyl silicone polymer vinylpolydimethyl silicon Oxygen alkane cross-linked polymer, dimethyl silicone polymer vinyl dimethicone cross polymer, dimethyl silicone polymer/ Polyoxyethylated dimethyl silicone polymer, PEG-15/ that lauryl in PEG-10/15 cross-linked polymers, mineral oil is modified Lauryl dimethicone cross-linked polymer, dimethyl silicone polymer/KF6017 vinyl poly- two Methylsiloxane cross-linked polymer, PEG-12 Dimethicone Crosspolymers, D5 (and) poly dimethyl silicon Oxygen alkane cross-linked polymer, dimethyl silicone polymer (and) Dimethicone Crosspolymer or its mixture；It is preferably selected from Dimethyl silicone polymer/PEG-10/15 cross-linked polymers.

9. the composition any one of aforementioned claim 1～8, wherein relative to the gross weight meter of the composition, institute State surfactant combination a) amount be 0.1 weight %～20 weight %, in particular 0.5 weight %～10 weight %, More particularly 1 weight %～8 weight %.

10. the composition any one of aforementioned claim 1～9, wherein the 3rd surfactant is selected from poly- Glycerinated or glycerinated side base and/or the polydialkysiloxane of end group, it includes straight or branched C₁-C₂₀Pendent alkyl groups, It is preferably selected from the dimethyl silicone polymer containing polyglycereol side base, the more preferably disiloxane of polyglyceryl -3 polydimethylsiloxanes Alkane.

Composition any one of 11. aforementioned claims 1～10, wherein relative to the gross weight meter of the composition, The amount of the 3rd surfactant is 0.1 weight %～20 weight %, preferably 0.5 weight %～15 weight %, and excellent Select 1 weight %～10 weight %.

Composition any one of 12. aforementioned claims 1～11, wherein the pigment is processed or unprocessed selected from Jing Hydrophily or hydrophobic inorganic pigment；It is preferably selected from Jing to process or undressed hydrophily or hydrophobic metal oxide； Be more preferably selected from titanium oxide, ferriferous oxide, Jing silica, silica (and) titanium oxide of alumina treatment and/or Ferriferous oxide, the titanium oxide coated by aliphatic acid and/or ferriferous oxide, preferably comprise stearoyl-glutamic acid disodium/hydroxide Those of aluminium pair, or its mixture.

Composition any one of 13. aforementioned claims 1～12, wherein relative to the gross weight meter of the composition, The amount of at least one pigment is 0.5 weight %～30 weight %, preferably 1 weight %～20 weight %, more preferably 2 weights Amount %～15 weight %.

Composition any one of 14. aforementioned claims 1～13, it includes at least one other surfactant, Itself and the surfactant i), ii) it is or iii) different, with more than or equal to 8, more preferably 8～20, more preferably 10～15 HLB value, is more preferably selected from polyoxyethylated sorbitol fatty acid ester；Polyoxyethylenated alcohol；Polyoxyethylenated alkylphenol； The condensation product of ethylene oxide and propylene oxide；Aliphatic acid and glycerine or the ester of polyglycereol；Polyethylene glycol and/or polypropylene glycol with it is sweet The ether of oil；The ester of the reaction derived from aliphatic acid and polyethylene glycol and/or Polypropylene Glycol Glycerin Ether；Sucrose with include 12～30 The ester of the aliphatic acid of carbon atom；Alkyl polyglucoside；Alkyl sodium sulfate ester, alkyl ether sulphate and their salt；Alkyl sulfobetaines second Hydrochlorate；Alkyl sulphosuccinates salt；Polypeptide；Amino acid derivativges；Sulfonate；Isethionate；Or its mixture, it is more excellent Choosing is selected from ester, alkyl polyglucoside or its mixture of aliphatic acid and glycerine or polyglycereol, is more preferably selected from glycerol stearate Ester, stearic acid polyethylene glycol (100) ester, Plantacare 818, capric acid polyglycereol (4) ester or its mixture.

Composition any one of 15. aforementioned claims 1～14, it includes at least one organic filler or mineral are filled out Material, is preferably selected from modified starch or unmodified starch, more preferably preferred modified starch, acetylated oxidized starch.

Composition any one of 16. aforementioned claims 1～15, it includes at least one thickener, and it is selected from hydrophilic Property thickener, lipophilicity thickener or its mixture, preferably the thickener selected from polysaccharide biopolymer, lipophilicity clay, Hydrophobic silica or its mixture, more preferably described thickener is selected from xanthans, distearyl dimethylammonium hectorite, first silicon Alkylation silica or its mixture.

Composition any one of 17. aforementioned claims 1～16, it includes at least one volatility or non-volatile Oil, it is selected from based on the oil of hydrocarbon, silicone oil, fluorine-containing oil or without fluorocarbon oil or its mixture, it is preferable that the grease separation is from being based on The oil of hydrocarbon, silicone oil or its mixture, it is highly preferred that the grease separation is from saualane, the siloxanes of ring six, polydimethylsiloxanes Alkane or its mixture.

Composition any one of 18. aforementioned claims 1～17, wherein relative to the gross weight meter of the composition, The amount of the one or more of fatty phases is 1 weight %～50 weight %, and preferred 2 weight %～weight 40% is more excellent Select 5 weight %～35 weight %.

Composition any one of 19. aforementioned claims 1～18, wherein relative to the gross weight meter of the composition, The amount of the one or more of water phases be 1 weight %～90 weight %, preferably 5 weight %～80 weight %, more preferably 10 weight %～75 weight %.

20. are used to nurse/cosmetic skin, especially facial method, it is characterised in that methods described is included to the dermal administration Composition according to any one of aforementioned claim 1～19.